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Progress of application research on Cu2ZnSnS4 thin film and its device

Liu Hao Xue Yu-Ming Qiao Zai-Xiang Li Wei Zhang Chao Yin Fu-Hong Feng Shao-Jun

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Progress of application research on Cu2ZnSnS4 thin film and its device

Liu Hao, Xue Yu-Ming, Qiao Zai-Xiang, Li Wei, Zhang Chao, Yin Fu-Hong, Feng Shao-Jun
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  • Recently, Cu2ZnSnS4 (CZTS) has emerged as one of the most promising thin film materials due to its being environment friendly, abundant in storage and low cost. To date, solar cell with up to 12.6% efficiency have been reached with using Cu2ZnSn(S, Se)4 (CZTSSe) absorber by hydrazine solution method. In this paper, the structural, optical, electrical, interface layer properties of CZTS thin films are introduced and the effect of sodium diffusion on the CZTS thin film is also discussed. Furthermore, different methods to fabricate CZTS thin films and the corresponding device performances are discussed. Finally, the existing problems and future researches are summarized.
    • Funds: Project supported by the National High Technology Research and Development Program of China (Grant No. 2012AA050701).
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    Liu F F, Sun Y, He Q 2014 Acta Phys. Sin. 63 047201 (in Chinese) [刘芳芳, 孙云, 何青 2014 63 047201]

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    Mao Q N, Zhang X Y, Li X G, He J X, Yu P R, Wang D 2014 Acta Phys. Sin. 63 118802 (in Chinese) [毛启楠, 张晓勇, 李学耕, 贺劲鑫, 于平荣, 王东 2014 63 118802]

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    Todorov T K, Tang J, Bag S, Gunawan O, Gokmen T, Zhu Y, Mitzi D B 2013 Adv. Energy Mater. 3 34

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    Shin B, Gunawan O, Zhu Y, Bojarczuk N A, Chey S J, Guha S 2013 Prog. Photovolt: Res. Appl. 21 72

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    Ennaoui A, Steiner M L, Weber A, Ras D A, Kotschau I, Schock H W, Schurr R, Holzing A, Jost S, Hock R, Voß T, Schulze J, Kirbs A 2009 Thin Solid Films 517 2511

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    Miskin C K, Carter N J, Yang W C, Hages C J, Stach E, Agrawal R 2013 Proceedings of the 39th IEEE Photovoltaic Specialists Conference Tampa, Florida, June 16-21, 2013 p0034

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    Katagiri H, Jimbo K, Tahara M, Araki H, Oishi K 2009 Mater. Res. Soc. Symp. Proc. 1165 1165-M04-01

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    Tanaka K, Oonuki M, Moritake N, Uchiki H 2009 Sol. Energy Mater. Sol. Cells 93 583

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    Ki W, Hillhouse H W 2011 Adv. Energy Mater. 1 732

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    Delbos S 2012 EP. J. Photovolt. 3 35004

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Publishing process
  • Received Date:  16 September 2014
  • Accepted Date:  21 October 2014
  • Published Online:  05 March 2015

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