Preparation, structure configuration, physical properties and applications of borophene and two-dimensional alkaline-earth metal boride nanomaterials

Guo Ze-Kun; Tian Yan; Gan Hai-Bo; Li Zi-Juan; Zhang Tong; Xu Ning-Sheng; Chen Jun; Chen Huan-Jun; Deng Shao-Zhi; Liu Fei

doi:10.7498/aps.66.217702

Abstract

With the rise of graphene, two-dimensional nanomaterials have been significantly developed in recent years. As novel two-dimensional nanostructures, borophene and alkaline-earth metal boride two-dimensional materials have received much attention because of their unique physical and chemical properties, such as high Fermi velocities, high electron mobilities, large Young's moduli, high transparencies, negative Poisson's ratios and high chemical stabilities. This paper focuses on the researches of the fabrication techniques, structure configurations, properties and applications of borophene and two-dimensional alkaline-earth metal boride nanomaterials. Firstly, the current preparation methods and structure configurations of borophene are summarized. Secondly, the possible structures and fabrication techniques of two-dimensional alkaline-earth metal boride nanomaterials are introduced in detail. Thirdly, the physical properties of borophene and two-dimensional alkaline-earth metal boride nanomaterials are investigated. Finally, the most promising application areas of borophene and two-dimensional alkaline-earth metal boride nanomaterials in the future are predicted.

Keywords:

borophene /
two-dimensional alkaline-earth metal boride nanostructures /
fabrication technique /
structure configuration

Authors and contacts

1.
Guangdong Key Laboratory of Display Materials and Technologies, State Key Laboratory of Optoelectronic Materials and Technology, School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou 510275, China

Corresponding author: Liu Fei, liufei@mail.sysu.edu.cn

Funds: Project supported by the National Basic Research Program of China (Grant No. 2013CB933601), the Special Foundation of State Major Scientific Instrument and Equipment Development of China (Grant No. 2013YQ12034506), the Natural Science Foundation of Guangdong Province, China (Grant No. 2016A030313313), the Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China (Grant No.[2014]1685), the Fundamental Research Funds for the Central Universities, China (Grant No. 111gzd05), and the State Key Laboratory of Optoelectronic Materials and Technology Independent Subject (Grant No. OEMT-2015-RC-05).

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Cited By

[1]	Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A 2004 Science 306 666
[2]	Mayorov A S, Gorbachev R V, Morozov S V, Britnell L, Jalil R, Ponomarenko L A, Blake P, Novoselov K S, Watanabe K, Taniguchi T, Geim A K 2011 Nano Lett. 11 2396
[3]	Nair R R, Blake P, Grigorenko A N, Novoselov K S, Booth T J, Stauber T, Peres N M, Geim A K 2008 Science 320 1308
[4]	Lee C, Wei X, Kysar J W, Hone J 2008 Science 321 385
[5]	Balandin A A 2011 Nat. Mater. 10 569
[6]	Palmer D J 2006 Mater. Today 9 13
[7]	Cai L, Wang H P, Yu G 2016 Prog. Phys. 36 21 (in Chinese) [蔡乐, 王华平, 于贵 2016 物理学进展 36 21]
[8]	Huo N J, Yang Y J, Li J B 2017 J. Semicond. 38 031002
[9]	Bhimanapati G R, Lin Z, Meunier V, Jung Y, Cha J, Das S, Xiao D, Son Y, Strano M S, Cooper V R, Liang L, Louie S G, Ringe E, Zhou W, Kim S S, Naik R R, Sumpter B G, Terrones H, Xia F, Wang Y, Zhu J, Akinwande D, Alem N, Schuller J A, Schaak R E, Terrones M, Robinson J A 2015 ACS Nano 9 11509
[10]	Grazianetti C, Cinquanta E, Molle A 2016 2D Mater. 3 012001
[11]	Bianco E, Butler S, Jiang S, Restrepo O D, Windl W, Goldberger J E 2013 ACS Nano 7 4414
[12]	Balendhran S, Walia S, Nili H, Sriram S, Bhaskaran M 2015 Small 11 640
[13]	Camilli L, Sutter E, Sutter P 2014 2D Mater. 1 025003
[14]	Kamal C, Ezawa M 2015 Phys. Rev. B 91 085423
[15]	Zhang S, Yan Z, Li Y, Chen Z, Zeng H 2015 Angew. Chem. Int. Ed. Engl. 54 3112
[16]	Mannix A J, Zhou X F, Kiraly B, Wood J D, Alducin D, Myers B D, Liu X, Fisher B L, Santiago U, Guest J R, Yacaman M J, Ponce A, Oganov A R, Hersam M C, Guisinger N P 2015 Science 350 1513
[17]	Li L, Yu Y, Ye G J, Ge Q, Ou X, Wu H, Feng D, Chen X H, Zhang Y 2014 Nat. Nanotechnol. 9 372
[18]	Xu L C, Du A, Kou L 2016 Phys. Chem. Chem. Phys. 18 27284
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[20]	Lherbier A, Botello-Mendez A R, Charlier J C 2016 2D Mater. 3 045006
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[22]	Quhe R, Fei R, Liu Q, Zheng J, Li H, Xu C, Ni Z, Wang Y, Yu D, Gao Z, Lu J 2012 Sci. Rep. 2 853
[23]	Ye M, Quhe R, Zheng J X, Ni Z Y, Wang Y Y, Yuan Y K, Tse G, Shi J J, Gao Z X, Lu J 2014 Phys. E: Low-Dimensional Syst. Nanostruct. 59 60
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[28]	Gan L Y, Wang R, Jin Y J, Ling D B, Zhao J Z, Xu W P, Liu J F, Xu H 2017 Phys. Chem. Chem. Phys. 19 8210
[29]	Tai G, Hu T, Zhou Y, Wang X, Kong J, Zeng T, You Y, Wang Q 2015 Angew. Chem. Int. Ed. Engl. 54 15473
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[51]	Tsai H S, Hsiao C H, Lin Y P, Chen C W, Ouyang H, Liang J H 2016 Small 12 5251
[52]	Mannix A J, Kiraly B, Hersam M C, Guisinger N P 2017 Nat. Rev. Chem. 1 0014
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[54]	Jun Y W, Choi J S, Cheon J 2006 Angew. Chem. Int. Ed. Engl. 45 3414
[55]	Fan L, Zou J, Li Z, Li X, Wang K, Wei J, Zhong M, Wu D, Xu Z, Zhu H 2012 Nanotechnology 23 115605
[56]	Manzeli S, Ovchinnikov D, Pasquier D, Yazyev O V, Kis A 2017 Nat. Rev. Mater. 2 17033
[57]	Zhang G, Wang J, Wu Z, Shi R, Ouyang W, Amini A, Chandrashekar B N, Wang N, Cheng C 2017 ACS Appl. Mater. Interfaces 9 763
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Vol. 66, Issue 21 - 2017-11-05

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