Preparation and red long-afterglow luminescence of Y2O3:Eu, Dy

Xie Wei; Wang Yin-Hai; Hu Yi-Hua; Luo Li; Wu Hao-Yi; Deng Liu-Yong

doi:10.7498/aps.59.3344

Abstract

The rare-earth doped phosphors Y2O3：Eu3+0.01and Y2O3：Eu3+0.01, Dy3+0.01 were synthesized by a high temperature solid-state reaction method. The phase structures of the phosphors were characterized by X-ray diffraction. The Eu3+and Dy3+doping does not change the crystal sructure of Y2O3, the Eu3+and Dy3+ ions enter into the host crystal lattice . The emission spectra due to 5D0→7FJof Eu3+show that Eu3+is the only luminescence center. There is no glow peak from Dy3+. The decay characteristics of phosphors Y2O3：Eu3+0.01, Dy3+0.01 follows the Double exponential distribution. The measurement of thermoluminescence reveals that the trap is generated by Eu3+. The Dy3+doping doesn’t change the trap depth, and helps the electrons escape from the trap, which induces long-afterglow luminescence.

Keywords:

Authors and contacts

1.
广东工业大学物理与光电工程学院,广州 510006

References

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[11]	］Chander H, Haranath D, Virendra S, Pooja S 2004 Journal of Crystal Growth 271 307
[12]	］Aizawa H, Katsumata T, Takahashi J, Matsunaga K, Komuro S, Morikawa T 2003 Review of Scientific Instruments 74 1344
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[20]	］Liu C, Wang Y H, Hu Y H, Chen R, Liao F 2007 Journal of Alloys and Compounds 470 473
[21]	］Xie W, Wang Y H, Hu Y H, Wu H Y, Deng L Y 2010 Acta Phys.Sin.59 1148 (in Chinese) ［谢伟、王银海、胡义华、吴浩怡、邓柳咏 2010 59 1148］
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[25]	］ Katsumata T, Toyomane S, Tonegawa A, Kanai Y, Kaneyama U 2002 Journal of Crystal Growth. 361 237
[26]	］Zhang C X, Tang Q, Luo D L 2002 Acta Phys.Sin.51 2881 (in Chinese) ［张纯祥、唐强、罗达玲 2002 51 2881］
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Cited By

[1]	［1］Yang Z P, Liu Y F 2006 Acta Phys.Sin.55 4946 (in Chinese) ［杨志平、刘玉峰 2006 55 4946］
[2]	［2］Liao Q R, Zhuang WD, Xia T, Liu R H, Hu Y S, Tng X M, Liu Y H 2009 Acta Phys.Sin.58 2776 (in Chinese) ［廖秋荣、庄卫东、夏天、刘荣辉、胡运生、滕晓明、刘元红 2009 58 2776］
[3]	［3］ Setlur A A， Srivastava A M， Pham H L， Hannah M E，Happek 2008 Journal of Applied Physics 103 053513
[4]	［4］Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys.Sin.57 4575 (in Chinese) ［王志军、李盼来、王刚、杨志平、郭庆林 2008 57 4575］
[5]	［5］Wang Z J 2010 Chin. Phys. B 19 (in Press)
[6]	［6］Grace D M, Eric D R, Shen H E, Nathaniel T W, Volkmar D, Michael W 2009 Journal of Applied Physics 105 053101
[7]	［7］Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys.Sin.56 546 (in Chinese) ［杨志平、刘玉峰、王利伟、余泉茂、熊志军、徐小岭 2007 56 546］
[8]	［8］Sun J Y, Du H Y 2003 Solid Luminescent Materials (Beijing：Chemical Industry Press) (in Chinese)［孙家跃、杜海燕 2003 固体发光材料 (北京：化学工业出版社)］
[9]	［9］Qiu J , Miura K, Inouye H 1998 Applied Physics Letters 73 1763
[10]	］Kowatari M, Koyama D, Satoh Y, Iinuma K, Uchida S 2002 Nuclear Instruments and Methods in Physics Research A 480 431
[11]	］Chander H, Haranath D, Virendra S, Pooja S 2004 Journal of Crystal Growth 271 307
[12]	］Aizawa H, Katsumata T, Takahashi J, Matsunaga K, Komuro S, Morikawa T 2003 Review of Scientific Instruments 74 1344
[13]	］Katsumata T, Toyomane S, Tonegawa A, Kanai Y, Kaneyama U, Shakuno K, Sakai R, Komuro S, Morikawa T 2002 Journal of Crystal Growth 237-239 361
[14]	］Si W, Jiang D, Gao H, Wang X H, Zhai Y C 2008 Chinese Rare Earths 29 24 (in Chinese) ［司伟、姜妲、高宏、王修慧、翟玉春 2008 稀土 29 24］
[15]	］Ferrari J L, Pires A M, Davolos M R 2009 Materials Chemistry and Physics 113 587
[16]	］Huang Y, Ye H Q, Zhuang W D, Hu Y S, Zhao C L, Li C, Guo S X 2007 Transactions of Nonferrous Metals Society of China 17 644
[17]	］Meng Q Y, Chen B J, Xu W, Wang X J,Xie Y H, Lai H S, Di W H, Ren G Z, Zhao X X, Yang Y M 2006 Spectroscopy and Spectral Analysis 26 1377 (in Chinese) ［孟庆裕、陈宝玖、许武、王晓君、王晓君、谢宜华、赖华生、狄伟华、任国仲、赵晓霞、杨艳民 2006 光谱学与光谱分析 26 1377］
[18]	］Pei Y H, Liu X R 1996 Journal of Luminescence 17 52 (in Chinese) ［裴轶慧、刘行仁 1996 发光学报 17 52］
[19]	］Abanti Nag, Kutty T R N 2003 Journal of Alloys and Compounds 354 221
[20]	］Liu C, Wang Y H, Hu Y H, Chen R, Liao F 2007 Journal of Alloys and Compounds 470 473
[21]	］Xie W, Wang Y H, Hu Y H, Wu H Y, Deng L Y 2010 Acta Phys.Sin.59 1148 (in Chinese) ［谢伟、王银海、胡义华、吴浩怡、邓柳咏 2010 59 1148］
[22]	］Matsuzawa T, Aoki Y, Takeuchi N 1996 Journal of The Electrochemical Society 143 1670
[23]	］Jia W Y, Yuan H B, Lu L Z, Lu L Z, Liu H M, Yen W M 1998 Journal of Luminescence 76-77 424
[24]	］Zhang T Z, Su Q, Wang S B 1999 Journal of Luminescence 20 170 (in Chinese) ［张天之、苏铿、王淑彬 1999 发光学报 20 170］
[25]	］ Katsumata T, Toyomane S, Tonegawa A, Kanai Y, Kaneyama U 2002 Journal of Crystal Growth. 361 237
[26]	］Zhang C X, Tang Q, Luo D L 2002 Acta Phys.Sin.51 2881 (in Chinese) ［张纯祥、唐强、罗达玲 2002 51 2881］
[27]	］ McKeever S W S 1985 Thermoluminescence of Solids. (Cambridge University Press. Cambridge) p99
[28]	］Shalgaonkar C S, Narlikar A V 1972 Journal of Materials Science 7 1465

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Vol. 59, Issue 5 - 2010-03-05

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