氧空位对Eu2+, Dy3+掺杂的Ca5MgSi3O12发光及余辉性能的影响

龚宇; 陈柏桦; 熊亮萍; 古梅; 熊洁; 高小铃; 罗阳明; 胡胜; 王育华

doi:10.7498/aps.62.153201

摘要

利用高温固相法合成了稀土离子Eu2+, Dy3+掺杂的Ca5MgSi3O12长余辉发光材料. 利用光谱学证明了在材料内部存在与氧空位有关的缺陷发光. 通过对比不同条件下合成样品的发光及余辉性能, 发现氧空位对材料的发光及余辉均起到促进作用. 同时发现氧空位发光可以向发光中心传递能量. 利用热释光曲线系统的分析了氧空位对余辉性能的影响. Ca5MgSi3O12:Eu2+,Dy3+是一种潜在的长余辉发光材料.

关键词:

长余辉 /
氧空位 /
能量传递 /
热释光

Abstract

Ca5MgSi3O12:Eu2+, Dy3+ was synthesized by solid-state reaction. The luminescence center related to the oxygen vacancies existed in the host matrix. Comparing the fluorescence and phosphorescence properties of samples synthesized under different air condiction, we find that the oxygen vacancies played an important role in the fluorescence and phosphorescence properties. Oxygen vacancies can transfer its energy to the luminescence center. Thermoluminescence spectra were used to characterize the effect of oxygen vacancies on the phosphorescence properties. Ca5MgSi3O12:Eu2+,Dy3+ has a great potential to become a promising candidate to be used as long-lasting phosphors.

Keywords:

作者及机构信息

1.
中国工程物理研究院核物理与化学研究所, 绵阳 621900;

2.
兰州大学物理科学与技术学院, 兰州 730000

基金项目: 中国工程物理研究院科技发展基金(批准号: 2013B0301037)资助的课题.

Authors and contacts

1.
Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China;

2.
Department of Materials Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China

Funds: Project supported by the Science and Technology Funds of China Academy of Engineering Physics (Grant No. 2013B0301037).

参考文献

[1]	Yang Z P, Liu Y F 2006 Acta Phys. Sin. 55 4946 (in Chinese) [杨志平, 刘玉峰 2006 55 4946]
[2]	Liao Q R, Zhuang W D, Xia T, Liu R H, Hu Y S, Teng X M, Liu Y H 2009 Acta Phys. Sin. 58 2776 (in Chinese) [廖秋荣, 庄卫东, 夏天, 刘荣辉, 胡运生, 滕晓明, 刘元红 2009 58 2776]
[3]	Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys. Sin. 56 546 (in Chinese) [杨志平, 刘玉峰, 王利伟, 余泉茂, 熊志军, 徐小岭 2007 56 546]
[4]	Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys. Sin. 57 4575 (in Chinese) [王志军, 李盼来, 王刚, 杨志平, 郭庆林 2008 57 4575]
[5]	Jia D, Meltzer R S, Yen W M, Jia W, Wang X J 2002 Appl. Phys. Lett. 80 1535
[6]	Tavangarian F, Emadi R 2011 Materials Letter 65 2354
[7]	Anthony J W, Bideaux R A, Bladh K W, Nichols M C 1990 Handbook of mineralogy (Mineral Data Publishing Tucson, Arizona)
[8]	Mardare C, Mardare A, Fernandes J, Joanni E, Pina S, Fernandes M, Correia R 2003 Journal of the European Ceramic Society 23 1027
[9]	Vitale-Brovarone C, Nunzio S D, Bretcanu O, Vern E 2004 Journal of Materials Science: Materials in Medicine 15 209
[10]	Kobayashi T, Okada K, Kuroda T, Sato K 1997 Journal of Biomedical Materials Research 37 100
[11]	Ryu H S, Hong K S, Lee J K, Kim D J, Lee J H, Chang B S, Lee D, Lee C K, Chung S S 2004 Biomaterials 25 393
[12]	Hannan M T, Felson D T, Dawsonughes B, Tucker K L, Cupples L A, Wilson P W F, Kiel D P 2000 Journal of Bone and Mineral Research 15 710
[13]	Sojka J, Weaver C 1995 Nutr Rev. 53 71
[14]	Stendig-Lindberg G, Tepper R, Leichter I 1993 Magnesium research: official organ of the International Society for the Development of Research on Magnesium 6 155
[15]	Sripanyakorn S, Jugdaohsingh R, Elliott H, Walker C, Mehta P, Shoukru S, Thompson R P H, Powell J J 2004 British Journal of Nutrition 91 403
[16]	Zhang E, Yang L, Xu J, Chen H 2003 Acta Biomaterialia 6 1756
[17]	Jiang L, Chang C, Mao D, Feng C 2004 Optical Materials 27 51
[18]	Wang B, Sun L, Ju H, Zhao S, Deng D, Wang H, Xu S 2009 Materials Letter 63 1329
[19]	Allen P B, Perebeinos V 1999 Phys. Rev. Lett. 83 4828
[20]	Liu Y, Kuang J, Lei B, Shi C 2005 J. Mater. Chem. 15 4025
[21]	Wang W, Jiang C, Shen M, Fang L, Zheng F, Wu X 2009 J. Appl. Phys. Lett. 94 081904
[22]	Dexter D, Schulman J H 1954 The Journal of Chemical Physics 22 1063
[23]	Lin Y, Tang Z, Zhang Z, Nan C W 2002 Appl. Phys. Lett. 81 996
[24]	Kinoshita T, Yamazaki M, Kawazoe H, Hosono H 1999 Journal of Applied Physics 86 3729
[25]	Aitasalo T, Deren P, Hls J, Jungner H, Krupa J C, Lastusaari M, Legendziewicz J, Niittykoski J, Strek W 2003 Journal of Solid State Chemistry 171 114

施引文献

[1]	Yang Z P, Liu Y F 2006 Acta Phys. Sin. 55 4946 (in Chinese) [杨志平, 刘玉峰 2006 55 4946]
[2]	Liao Q R, Zhuang W D, Xia T, Liu R H, Hu Y S, Teng X M, Liu Y H 2009 Acta Phys. Sin. 58 2776 (in Chinese) [廖秋荣, 庄卫东, 夏天, 刘荣辉, 胡运生, 滕晓明, 刘元红 2009 58 2776]
[3]	Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys. Sin. 56 546 (in Chinese) [杨志平, 刘玉峰, 王利伟, 余泉茂, 熊志军, 徐小岭 2007 56 546]
[4]	Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys. Sin. 57 4575 (in Chinese) [王志军, 李盼来, 王刚, 杨志平, 郭庆林 2008 57 4575]
[5]	Jia D, Meltzer R S, Yen W M, Jia W, Wang X J 2002 Appl. Phys. Lett. 80 1535
[6]	Tavangarian F, Emadi R 2011 Materials Letter 65 2354
[7]	Anthony J W, Bideaux R A, Bladh K W, Nichols M C 1990 Handbook of mineralogy (Mineral Data Publishing Tucson, Arizona)
[8]	Mardare C, Mardare A, Fernandes J, Joanni E, Pina S, Fernandes M, Correia R 2003 Journal of the European Ceramic Society 23 1027
[9]	Vitale-Brovarone C, Nunzio S D, Bretcanu O, Vern E 2004 Journal of Materials Science: Materials in Medicine 15 209
[10]	Kobayashi T, Okada K, Kuroda T, Sato K 1997 Journal of Biomedical Materials Research 37 100
[11]	Ryu H S, Hong K S, Lee J K, Kim D J, Lee J H, Chang B S, Lee D, Lee C K, Chung S S 2004 Biomaterials 25 393
[12]	Hannan M T, Felson D T, Dawsonughes B, Tucker K L, Cupples L A, Wilson P W F, Kiel D P 2000 Journal of Bone and Mineral Research 15 710
[13]	Sojka J, Weaver C 1995 Nutr Rev. 53 71
[14]	Stendig-Lindberg G, Tepper R, Leichter I 1993 Magnesium research: official organ of the International Society for the Development of Research on Magnesium 6 155
[15]	Sripanyakorn S, Jugdaohsingh R, Elliott H, Walker C, Mehta P, Shoukru S, Thompson R P H, Powell J J 2004 British Journal of Nutrition 91 403
[16]	Zhang E, Yang L, Xu J, Chen H 2003 Acta Biomaterialia 6 1756
[17]	Jiang L, Chang C, Mao D, Feng C 2004 Optical Materials 27 51
[18]	Wang B, Sun L, Ju H, Zhao S, Deng D, Wang H, Xu S 2009 Materials Letter 63 1329
[19]	Allen P B, Perebeinos V 1999 Phys. Rev. Lett. 83 4828
[20]	Liu Y, Kuang J, Lei B, Shi C 2005 J. Mater. Chem. 15 4025
[21]	Wang W, Jiang C, Shen M, Fang L, Zheng F, Wu X 2009 J. Appl. Phys. Lett. 94 081904
[22]	Dexter D, Schulman J H 1954 The Journal of Chemical Physics 22 1063
[23]	Lin Y, Tang Z, Zhang Z, Nan C W 2002 Appl. Phys. Lett. 81 996
[24]	Kinoshita T, Yamazaki M, Kawazoe H, Hosono H 1999 Journal of Applied Physics 86 3729
[25]	Aitasalo T, Deren P, Hls J, Jungner H, Krupa J C, Lastusaari M, Legendziewicz J, Niittykoski J, Strek W 2003 Journal of Solid State Chemistry 171 114

[1]	续卓, 郭竞渊, 熊正烨, 唐强, 高沐. 掺Tm³⁺和Tb³⁺的LiMgPO₄磷光体的发光光谱与能量转移. , 2021, 70(16): 167801. doi: 10.7498/aps.70.20210357
[2]	王泽普, 付念, 于涵, 徐晶威, 何祺, 郑树凯, 丁帮福, 闫小兵. 铟掺杂钨位增强钨酸铋氧空位光催化效率. , 2019, 68(21): 217102. doi: 10.7498/aps.68.20191010
[3]	刘盛意, 张金苏, 孙佳石, 陈宝玖, 李香萍, 徐赛, 程丽红. 实验优化设计Sr₂MgSi₂O₇:Eu²⁺, Dy³⁺的合成及长余辉特性. , 2019, 68(5): 053301. doi: 10.7498/aps.68.20182015
[4]	栗苹, 许玉堂. 氧空位迁移造成的氧化物介质层时变击穿的蒙特卡罗模拟. , 2017, 66(21): 217701. doi: 10.7498/aps.66.217701
[5]	吴丽, 王倩, 李国栋, 窦巧娅, 吉旭. 不同退火温度的Al2O3:C薄膜热释光和光释光性能. , 2016, 65(3): 037802. doi: 10.7498/aps.65.037802
[6]	蒋然, 杜翔浩, 韩祖银, 孙维登. Ti/HfO2/Pt阻变存储单元中的氧空位聚簇分布. , 2015, 64(20): 207302. doi: 10.7498/aps.64.207302
[7]	罗达玲, 唐强, 郭竞渊, 张纯祥. MSO4:Eu2+(M =Mg, Ca, Sr, Ba)的等电子陷阱与热释光特性. , 2015, 64(8): 087805. doi: 10.7498/aps.64.087805
[8]	程帅, 徐旭辉, 王鹏久, 邱建备. 新型电子俘获型材料β-Sr2SiO4:Eu2+, La3+长余辉和光激励发光性能的研究. , 2015, 64(1): 017802. doi: 10.7498/aps.64.017802
[9]	王鹏久, 徐旭辉, 邱建备, 周大成, 刘雪娥, 程帅. 高亮度蓝绿色长余辉材料Ba4 (Si3O8)2：Eu2+, Pr3+的发光性能及其余辉机理研究. , 2014, 63(7): 077804. doi: 10.7498/aps.63.077804
[10]	谢伟, 王银海, 全军, 邹长伟, 梁枫, 邵乐喜. H3BO3对Y1.98O3：Eu0.01, Dy0.01红色长余辉发光材料结构和余辉性能的影响. , 2014, 63(1): 016101. doi: 10.7498/aps.63.016101
[11]	沈庆鹤, 高志伟, 丁怀义, 张光辉, 潘楠, 王晓平. Ga掺杂对ZnO纳米结构可见光发射的抑制效应. , 2012, 61(16): 167105. doi: 10.7498/aps.61.167105
[12]	胡克艳, 李红军, 徐军, 杨秋红, 苏良碧, 唐强. 不同粒径-Al2O3:C晶态粉体热释光和光释光特性. , 2012, 61(15): 157802. doi: 10.7498/aps.61.157802
[13]	李海玲, 王银海, 张万鑫, 王显盛, 赵慧. Eu3+掺杂CaO的合成与红色长余辉发光性能研究. , 2012, 61(22): 227802. doi: 10.7498/aps.61.227802
[14]	谢伟, 王银海, 胡义华, 张军, 邹长伟, 李达, 邵乐喜. Sr0.6Ba0.2Ca0.2Al2O4 ∶Eu,Dy的制备与长余辉发光性能研究. , 2011, 60(6): 067801. doi: 10.7498/aps.60.067801
[15]	牟中飞, 王银海, 胡义华, 吴浩怡, 邓柳咏, 谢伟, 符楚君, 廖臣兴. Y3Al5O12∶Ce3+的余辉和热释光特性. , 2011, 60(1): 013201. doi: 10.7498/aps.60.013201
[16]	张斌, 张浩佳, 杨秋红, 陆神洲. α-Al2O3透明陶瓷的发光及热释光特性. , 2010, 59(2): 1333-1337. doi: 10.7498/aps.59.1333
[17]	谢伟, 王银海, 胡义华, 罗莉, 吴浩怡, 邓柳咏. Y2O3: Eu,Dy的制备与红色长余辉发光性能研究. , 2010, 59(5): 3344-3349. doi: 10.7498/aps.59.3344
[18]	杨新波, 李红军, 徐军, 程艳, 苏良碧, 唐强. α-Al2O3:C晶体的热释光和光释光特性. , 2008, 57(12): 7900-7905. doi: 10.7498/aps.57.7900
[19]	张纯祥, 唐强, 罗达玲. CaSO4∶Eu磷光体的热释光特性研究. , 2002, 51(12): 2881-2886. doi: 10.7498/aps.51.2881
[20]	刘波, 施朝淑, 周东方, 戚泽明, 胡关钦, 汤洪高. 掺Gd3+,Y3+对PbWO_4低温热释光的影响. , 2001, 50(8): 1627-1631. doi: 10.7498/aps.50.1627

计量

文章访问数: 6978
PDF下载量: 851
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板