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Germanium based metal oxide semiconductor (MOS) device has been a research hotspot and considered as a potential candidate for future complementary MOS (CMOS) technology due to its high and symmetric carrier mobility. However, the poor quality of gate dielectric/channel interface significantly restricts the performances of germanium based MOS devices. Besides, the solid-solubility and activation concentration of dopants in Ge are both quite low, and the dopants diffuse fast in Ge, which makes it difficult to achieve ultra-shallow junction with high dopant concentration, especially for Ge NMOS devices.To solve these problems, different techniques are proposed and overviewed. The proposed nitrogen-plasma-passivation method can effectively suppress the regrowth of germanium sub-oxide and reduce the interface state density. Thus the performance of the fabricated Ge NMOS device is significantly improved. To enhance the n-type dopant activation in Ge, the multiple implantation technique and the multiple annealing technique are proposed. High electrical activation over 1 1020 cm-3 is achieved, and the corresponding contact resistivity is reduced to 3.8 10-7 cm2. Besides, the implantation after germanide (IAG) technique is first proposed to modulate the Schottky barrier height (SBH). The record-low electron SBH of 0.10 eV is obtained by IAG technique, and the optimized process window is given. In addition, the poor thermal stability of NiGe restricts the further improvement in performance of Ge MOS device. P and Sb co-implantation technique and novel ammonium fluoride pretreatment method are proposed to improve the thermal stability of NiGe. The electrical characteristic of NiGe/Ge diode is also improved simultaneously. The results provide the guidelines for further enhancing the performances of germanium-based MOS devices.
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Keywords:
- high mobility channel /
- gate engineering /
- source/drain engineering /
- metal oxide semiconductor
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[2] Oishi A, Fujii O, Yokoyama T, et al. 2005 International Electron Devices Meeting Washington, DC, America, December 5-7, 2005 p229
[3] Kim S D, Jain S, Rhee H, et al. 2010 International Conference on Simulation of Semiconductor Processes and Devices Bologna, Italy, Sept. 6-8, 2010 p79
[4] Yang B, Nummy K, Waite A, et al. 2007 Symposium on VLSI Technology Kyoto, Japan, June 12-14, 2007 p126
[5] Claeys C, Simoen E 2007 Germanium-Based Technologies: From Materials to Devices (Amsterdam: Elsevier)
[6] Mitard J, De Jaeger B, Leys F E, et al. 2008 International Electron Devices Meeting San Francisco, America, December 15-17, 2008 p873
[7] Heyns M, Alian A, Brammertz G, et al. 2011 International Electron Devices Meeting Washington, DC, America, December 5-7, 2011 p299
[8] Duriez B, Vellianitis G, van Dal M J H, et al. 2013 International Electron Devices Meeting Washington, DC, America, December 9-11, 2013 p522
[9] Mitard J, Witters L, Loo R, et al. 2014 Symposium on VLSI Technology Honolulu, Hawaii, America, June 9-12, 2014 p138
[10] Witters L, Mitard J, Loo R, et al. 2015 Symposium on VLSI Technology Kyoto, Japan, June 16-18, 2015 p56
[11] Wu H, Luo W, Zhou H, Si M W, Zhang J Y, Ye P D 2015 Symposium on VLSI Technology Kyoto, Japan, June 16-18, 2015 p58
[12] Bernstein R B, Cubicciotti D 1951 J. Amer. Chem. Soc. 73 4112
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[14] Kita K, Wang S K, Yoshida M, Lee C, Nagashio K, Nishimura T, Toriumi A 2009 International Electron Devices Meeting Baltimore, America, December 7-9, 2009 p693
[15] Wang S K, Kita K, Nishimura T, Nagashio K, Toriumi A 2011 Jpn. J. Appl. Phys. 50 04DA01
[16] Wang S K, Kita K, Lee C, Tabata T, Nishimura T, Nagashio K, Toriumi A 2010 J. Appl. Phys. 108 054104
[17] Lee D, Lee H, Kanashima T, Okuyama M 2010 Appl. Surf. Sci 257 917
[18] Xie R, Yu M, Lai M, Chan L, Zhu C 2008 Appl. Phys. Lett. 92 163505
[19] Kamata Y, Ino T, Koyama M, Nishiyama A 2008 Appl. Phys. Lett. 92 063512
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[28] Lee C H, Tabata T, Nishimura T, Nagashio K, Kita K, Toriumi A 2009 Appl. Phys. Expr. 2 071404,
[29] Lee C H, Nishimura T, Nagashio K, Kita K, Toriumi A 2011 IEEE Trans. Electron Devices 58 1295
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[33] Lin M, An X, Li M, Yun Q X, Li M, Li Z Q, Liu P Q, Zhang X, Huang R 2014 Chin. Phys. B 23 067701
[34] Lau W S, Qian P W, Sandler N P, McKinley K A, Chu P K 1997 Jpn. J. Appl. Phys. 36 661
[35] Chui C O, Kim H, McIntyre P C, Saraswat K C 2004 IEEE Electron Device Lett. 25 274
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[52] Bhatt P, Swarnkar P, Misra A, Biswas J, Hatem C, Nainani A, Lodha S 2015 IEEE Trans. Electron Devices 62 69
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[58] Lin J Y, Roy A M, Saraswat K C 2012 IEEE Electron Device Lett. 33 1541
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[60] Liu P Q, Li M, An X, Lin M, Zhao Y, Zhang B X, Xia X X, Huang R 2015 Silicon Nanoelectronics Workshop Kyoto, Japan, June 14-15, 2015
[61] Claeys C, Firrincieli A, Martens K, Kittl J A, Simoen E 2012 8th International Caribbean Conference on Devices, Circuits and Systems Playa del Carmen, Mexico, March 14-17, 2012 p1
[62] Nishimura T, Kita K, Toriumi A 2007 Appl. Phys. Lett. 91 123123
[63] Brillson L J 2007 J. Vac. Sci. Techn. A 25 943
[64] Heine V 1965 Phys. Rev. A 138 1689
[65] Nishimura T, Kita K, Toriumi A 2008 Appl. Phys. Express 1 051406
[66] Zhou Y, Ogawa M, Han X, Wang K L 2008 Appl. Phys. Lett. 93 202105
[67] Lin J Y J, Roy A M, Nainani A, Sun Y, Saraswat K C 2011 Appl. Phys. Lett. 98 092113
[68] Lieten R, Degroote S, Kuijk M, Borghs G 2008 Appl. Phys. Lett. 92 022106
[69] Kobayashi M, Kinoshita A, Saraswat K, Wong H S P, Nishi Y 2009 J. Appl. Phys. 105 023702
[70] Li Z Q, An X, Yun Q X, Lin M, Zhang X, Huang R 2012 ECS Solid State Lett. 1 Q33
[71] Thathachary A V, Bhat K N, Bhat N, Hegde M S 2010 Appl. Phys. Lett. 96 152108
[72] Tong Y, Liu B, Lim P S Y, Yeo Y C 2012 IEEE Electron Device Lett. 33 773
[73] Ikeda K, Yamashita Y, Sugiyama N, Taoka N, Takagi S 2006 Appl. Phys. Lett. 88 152115
[74] Thornton R 1981 Electron. Lett. 17 485
[75] Yamauchi T, Nishi Y, Tsuchiya Y, Kinoshita A, Koga J, Kato K 2007 International Electron Devices Meeting Washington, DC, America, December 10-12, 2007 p963
[76] Zhen Z, Qiu Z, Ran L, Ostling M, Zhang S L 2007 IEEE Electron Device Lett. 28 565
[77] Mueller M, Zhao Q T, Urban C, Sandow C, Buca D, Lenk S, Estevez S, Mantl S 2008 Mater. Sci. Eng. B 154 168
[78] Li Z Q, An X, Li M, Yun Q X, Lin M, Li M, Zhang X, Huang R 2012 IEEE Electron Device Lett. 33 1687
[79] Guo Y, An X, Huang R, Fan C H, Zhang X 2010 Appl. Phys. Lett. 96 143502
[80] Li Z Q, An X, Li M, Yun Q X, Lin M, Li M, Zhang X, Huang R 2013 IEEE Electron Device Lett. 34 596
[81] Lee K, Liew S, Chua S, Chi D, Sun H, Pan X 2004 Materials Research Society Spring Meeting San Francisco, CA, America, April 12-16, 2004 pC2.4
[82] Ashburn S P, Öztrk M C, Harris G, Maher D M 1993 J. Appl. Phys. 74 4455
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[84] Nakatsuka O, Suzuki A, Sakai A, Ogawa M, Zaima S 2007 International Workshop on Junction Technology Kyoto, Japan, June 8-9, 2007 p87
[85] Zhu S, Yu M, Lo G, Kwong D 2007 Appl. Phys. Lett. 91 051905
[86] Zhang Y Y, Oh J, Li S G, Jung S Y, Park K Y, Shin H S, Lee G W, Wang J S, Majhi P, Tseng H H, Jammy R, Bae T S, Lee H D 2009 Electrochem. Solid-State Lett. 12 H18
[87] Zhang Y Y, Oh J, Han I S, Zhong Z, Li S G, Jung S Y, Park K Y, Shin H S, Choi W H, Kwon H M, Loh W Y, Majhi P, Jammy R, Lee H D 2009 IEEE Trans. Electron Devices 56 348
[88] Guo Y, An X, Wang R S, Zhang X, Huang R 2011 IEEE Electron Device Lett. 32 554
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