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In this paper, by choosing catalyst of FeNiMnCo alloy, boron-doped diamond single crystals are synthesized under 5.1–5.6 GPa and 1230–1600℃; the temperature field is studied by finite element method (FEM). First, the P-T phase diagram for diamond single crystal growth, in the synthesis system of FeNiMnCo-C-B, is obtained, and the lowest synthesis conditions of 5.1 GPa and 1230℃ is found in the studies. By simulation with FEM, it is found that the content of boron element should be less and less in the growth of diamond single crystal in the {111} sector, and the reason is that the growth speed is reduced in the sectors. By growing diamond crystals with {111} faces, it is also found that the content of boron element in {111} secondary sector is greater than that in {111} primary sector, which is duo to the rapid growth of {111} secondary sector. Compared with the synthesis of diamond single crystal by film growth method, the diamond crystals thus obtained has no pits, the doping content of boron can be greater, and the diamond can be synthesized by temperature gradient method.
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Keywords:
- high temperature and high pressure /
- temperature gradient /
- diamond /
- catalyst
[1] Sumiya H, Toda N, Nishibayashi Y, Satoh S 1997 Journal of Crystal Growth 178 485
[2] Schein J, Campbell K M, Prasad R R, Prasad R R, Binder R, Krishnan M 2002 Review of Scientific Instruments 73 18
[3] Yamamoto M, Kumasaka T, Ishikawa T 2000 Review of High Pressure Science and Technology 10 56
[4] Sumiya H, Toda N, Satoh S 2002 Journal of Crystal Growth 237-239 1281
[5] Kanda H 2001 Radiation Effects and Defects in Solids 156 163
[6] El-Hajj H, Denisenko A, Kaiser A, Balmer R S, Kohn E 2008 Diamond and Related Materials 17 1259
[7] Guy O J, Doneddu D, Lodzinski M, Igic P, Albery R, Wilks S, Twitchen D 2007 IDR. Industrial Diamond Review 3 65
[8] Bundy F P, Bassett W A, Weathers M S, Hemley R J, Mao H U, Goncharov A F 1996 Carbon 34 14
[9] Bormashov V S, Tarelkin S A, Buga S G, Kuznetsov M S, Terentiev S A, Semenov A N, Blank V D 2013 Diamond & Related Materials 35 19
[10] Sun S S, Jia X P, Zhang Z F, Li Y, Yan B M, Liu X B, Ma H A 2013 Journal of Crystal Growth 377 22
[11] Li S S, Ma H A, Li X L, Su T C, Huang G F, Li Y, Jia X P 2011 Chin. Phys. B 20 028103
[12] Zhang N, Li M S, Zhang Y P, Tian B 2010 Journal of Synthetic Crystals 39 295(in Chinese) [张娜, 李木森, 张元培, 田斌 2010 人工晶体学报 39 295]
[13] Bundy F P 1980 Journal of Geophysical Research: Solid Earth. 85 6930
[14] Naka S, Horii K, Takeda Y, Hanawa T 1976 Nature 259 38
[15] Sumiya H, Toda N, Satoh S 2005 Sei Technical Review-English Edition 60 10
[16] Chen K, Zhang L, Zang C Y, Zheng X G, Zhu Y G 2013 Journal of Synthetic Crystals 39 324(in Chinese) [陈奎, 张莉, 臧传义, 郑喜贵, 朱永刚 2013 人工晶体学报 39 324]
[17] Xu R W, Guo L X, Fan T Q 2013 Acta Phys. Sin. 62 170301(in Chinese) [徐润汶, 郭立新, 范天奇 2013 62 170301]
[18] Yu G, Han Q G, Li M Z, Jia X P, Ma H A, Li Y F 2012 Acta Phys. Sin. 61 040702(in Chinese) [于歌, 韩奇钢, 李明哲, 贾晓鹏, 马红安, 李月芬 2012 61 040702]
[19] Li Z C, Jia X P, Huang G F, Hu M H, Li Y, Yan B M, Ma H A 2013 Chin. Phys. B 22 014701
[20] Ding Z D, Peng L M, Shi C H 2011 Rock and Soil Mechanics 32 3387(in Chinese) [丁祖德, 彭立敏, 施成华 2011 岩土力学 32 3387]
[21] Xiao H Y, Su J F, Zhang Y S, Bao Z G 2012 Acta Phys. Sin. 61 248101(in Chinese) [肖宏宇, 苏剑峰, 张永胜, 鲍志刚 2012 61 248101]
[22] Nazare M H, Neves A J 2001 Properties, Growth, and Applications of Diamond (EMIS Datareview series No. 26) (INSPEC: Institution of Electrical Engineers)
[23] Nishi T, Shibata H, Ohta H, Waseda Y 2003 Met. Mat. Trans. A34A 2801
[24] Taylor R E, Davis F E, Powell R W 1969 High Temperatures-High Pressures 1 663
[25] Zang J Q 2008 Ph. D. Dissertation (Changchun: Jilin University) (in Chinese) [张健琼2008博士学位论文(长春: 吉林大学)]
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[1] Sumiya H, Toda N, Nishibayashi Y, Satoh S 1997 Journal of Crystal Growth 178 485
[2] Schein J, Campbell K M, Prasad R R, Prasad R R, Binder R, Krishnan M 2002 Review of Scientific Instruments 73 18
[3] Yamamoto M, Kumasaka T, Ishikawa T 2000 Review of High Pressure Science and Technology 10 56
[4] Sumiya H, Toda N, Satoh S 2002 Journal of Crystal Growth 237-239 1281
[5] Kanda H 2001 Radiation Effects and Defects in Solids 156 163
[6] El-Hajj H, Denisenko A, Kaiser A, Balmer R S, Kohn E 2008 Diamond and Related Materials 17 1259
[7] Guy O J, Doneddu D, Lodzinski M, Igic P, Albery R, Wilks S, Twitchen D 2007 IDR. Industrial Diamond Review 3 65
[8] Bundy F P, Bassett W A, Weathers M S, Hemley R J, Mao H U, Goncharov A F 1996 Carbon 34 14
[9] Bormashov V S, Tarelkin S A, Buga S G, Kuznetsov M S, Terentiev S A, Semenov A N, Blank V D 2013 Diamond & Related Materials 35 19
[10] Sun S S, Jia X P, Zhang Z F, Li Y, Yan B M, Liu X B, Ma H A 2013 Journal of Crystal Growth 377 22
[11] Li S S, Ma H A, Li X L, Su T C, Huang G F, Li Y, Jia X P 2011 Chin. Phys. B 20 028103
[12] Zhang N, Li M S, Zhang Y P, Tian B 2010 Journal of Synthetic Crystals 39 295(in Chinese) [张娜, 李木森, 张元培, 田斌 2010 人工晶体学报 39 295]
[13] Bundy F P 1980 Journal of Geophysical Research: Solid Earth. 85 6930
[14] Naka S, Horii K, Takeda Y, Hanawa T 1976 Nature 259 38
[15] Sumiya H, Toda N, Satoh S 2005 Sei Technical Review-English Edition 60 10
[16] Chen K, Zhang L, Zang C Y, Zheng X G, Zhu Y G 2013 Journal of Synthetic Crystals 39 324(in Chinese) [陈奎, 张莉, 臧传义, 郑喜贵, 朱永刚 2013 人工晶体学报 39 324]
[17] Xu R W, Guo L X, Fan T Q 2013 Acta Phys. Sin. 62 170301(in Chinese) [徐润汶, 郭立新, 范天奇 2013 62 170301]
[18] Yu G, Han Q G, Li M Z, Jia X P, Ma H A, Li Y F 2012 Acta Phys. Sin. 61 040702(in Chinese) [于歌, 韩奇钢, 李明哲, 贾晓鹏, 马红安, 李月芬 2012 61 040702]
[19] Li Z C, Jia X P, Huang G F, Hu M H, Li Y, Yan B M, Ma H A 2013 Chin. Phys. B 22 014701
[20] Ding Z D, Peng L M, Shi C H 2011 Rock and Soil Mechanics 32 3387(in Chinese) [丁祖德, 彭立敏, 施成华 2011 岩土力学 32 3387]
[21] Xiao H Y, Su J F, Zhang Y S, Bao Z G 2012 Acta Phys. Sin. 61 248101(in Chinese) [肖宏宇, 苏剑峰, 张永胜, 鲍志刚 2012 61 248101]
[22] Nazare M H, Neves A J 2001 Properties, Growth, and Applications of Diamond (EMIS Datareview series No. 26) (INSPEC: Institution of Electrical Engineers)
[23] Nishi T, Shibata H, Ohta H, Waseda Y 2003 Met. Mat. Trans. A34A 2801
[24] Taylor R E, Davis F E, Powell R W 1969 High Temperatures-High Pressures 1 663
[25] Zang J Q 2008 Ph. D. Dissertation (Changchun: Jilin University) (in Chinese) [张健琼2008博士学位论文(长春: 吉林大学)]
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