高温高压下金刚石大单晶研究进展

尤悦; 李尚升; 宿太超; 胡美华; 胡强; 王君卓; 高广进; 郭明明; 聂媛

doi:10.7498/aps.69.20200692

摘要

金刚石具有一系列优于其他材料的极限特性, 应用领域十分广泛. 金刚石大单晶更能充分发挥其功能特性, 从而成为国内外研究的热点. 为此, 本文在介绍金刚石大单晶高温高压合成原理及工艺技术的基础上, 重点综述了四种类型的金刚石大单晶以及掺杂金刚石大单晶的研究现状和研究重点. Ia型金刚石大单晶可由Ib型金刚石通过高温高压退火处理得到, 其中氮的转变机制及效率研究十分重要; 对Ib型金刚石大单晶的表面分析表征、晶体缺陷控制、再结晶石墨析出、多晶种法批量化生产方面进行了综述; 对IIa型金刚石大单晶中除氮剂和触媒的选择、微晶石墨析出与抑制方面的研究进行了介绍; 研究了IIb型金刚石中硼元素的扇区存在及其对合成金刚石生长特性的影响; 掺杂金刚石大单晶主要从B, N, S, P等不同掺杂元素的不同掺杂源或与硼等协同掺杂的研究状况进行了介绍. 并提出金刚石大单晶需要在Ib及IIa型的批量化、IIb型的超导特性、掺杂n型半导体方面加强研究.

关键词:

Abstract

Diamond has a series of extreme characteristics superior to other materials, and also very wide application scope. The large diamond single crystal can play a role in its functional characteristics, which has become a research hotspot. In this paper, we introduce the principle and process of synthesizing large diamond single crystal by temperature gradient method (TGM) under high pressure and high temperature (HPHT), and summarizes the research status and research directions of different types of and additives-doped large diamond single crystals respectively. The principle of the temperature gradient method is that the carbon source, driven by the temperature gradient, diffuses from the high concentration region at the high temperature end to the low concentration region at the low temperature end, and diamonds are grown on the seed crystal. The growth rate of diamond crystal is controlled by adjusting the axial temperature gradient at synthesis cell, and the shape growth of Ib-type large diamond is controlled by the distribution in the V-shaped growth area. We introduce different kinds of diamond large single crystals from five aspects. Firstly, the Ia-type diamond large single crystal can be obtained by the annealing treatment of Ib-type diamond under HPHT. The conversion rate of C centre to A centre for nitrogen in diamond is improved by optimizing the conditions of HPHT. Secondly, the Ib-type larger diamond is studied very much in the following areas: the analysis of its surface characteristic, the control of inclusions and cracks, the precipitation mechanism and the elimination measures of regrown graphite and the mass production technology of multiseed method. Thirdly, IIa-type large diamond single crystal is introduced in which the nitrogen getter is selected due to the ability Al and Ti (Cu) to getter nitrogen, the catalyst is selected because of its effect on the nitrogen content in the diamond synthesized with Fe or Ni based catalyst, and the elimination method of microcrystalline graphite precipitation is presented by analyzing its mechanism. Fourthly, the boron elements exist in IIb-type diamond and have influence on the growth characteristics of synthetic diamond. Fifthly, introduced is the research status of diamond synthesized with B, N, S, P doping elements, in which its individual substance or their compound is used as a doping source or boron and other elements with small radius are used as co-doping agent. Then S or P with B co-doping is more conducive to the improvement of the performance of n-type diamond large single crystal semiconductor. Therefore, it is proposed that the large diamond single crystal need strengthening in mass production of IIa-type large diamond single crystal, superconducting characteristics of IIb-type large diamond single crystal, and doping of n-type semiconductors.

Keywords:

作者及机构信息

1.
河南理工大学材料科学与工程学院, 河南省深地材料科学与技术重点实验室, 焦作　454003

2.
河南理工大学物理与电子信息学院, 焦作　454003

通信作者: 李尚升, lishsh@hpu.edu.cn

基金项目: 河南省自然科学基金(批准号: 182300410279)、河南省科技攻关项目(批准号: 182102210311)、河南省高校重点科研项目(批准号: 18A430017)、河南省高等学校青年骨干教师培养计划(批准号: 2018GGJS057)和河南省高校科技创新团队(批准号: 19IRTSTHN027)资助的课题

Authors and contacts

1.
Henan Key Laboratory of Materials on Deep-Earth Engineering, School of Materials Science and Engineering, Henan Polytechnic University, Jiaozuo 454003, China

2.
School of Physics & Electronic Information Engineering, Henan Polytechnic University, Jiaozuo 454003, China

Corresponding author: Li Shang-Sheng, lishsh@hpu.edu.cn

Funds: Project supported by the Natural Science Foundation of Henan Province, China (Grant No. 182300410279), the Key Science and Technology Program of Henan Province, China (Grant No. 182102210311), the Key Scientific Research Project in Colleges and Universities of Henan Province, China (Grant No. 18A430017), the Young Core Instructor Training Program of Higher Education of Henan Province, China (Grant No. 2018GGJS057), and the Science and Technology Innovation Team in Colleges and Universities of Henan Province, China (Grant No. 19IRTSTHN027)

文章全文 : translate this paragraph

参考文献

[1]	Kiflawi I, Bruley J 2000 Diamond Relat. Mater. 9 87 Google Scholar
[2]	龚春生, 李尚升, 张贺 2016 材料导报 30 36 Google Scholar Gong C S, Li S S, Zhang H 2016 Mater. Rev. 30 36 Google Scholar
[3]	唐敬友, 董庆东, 谷岩 2000 金刚石与磨料磨具工程 03 24 Google Scholar Tang J Y, Dong Q D, Gu Y 2000 Diamond Abras. Eng. 03 24 Google Scholar
[4]	胡美华, 马红安, 颜丙敏, 张壮飞, 李勇, 周振翔, 秦杰明, 贾晓鹏 2012 61 078102 Google Scholar Hu M H, Ma H A, Yan B M, Zhang Z F, Li Y, Zhou Z X, Qin J M, Jia X P 2012 Acta Phys. Sin. 61 078102 Google Scholar
[5]	满卫东, 吕继磊, 吴宇琼, 陈朋, 朱金凤, 董维 2010 宝石和宝石学杂志 12 6 Google Scholar Man W D, Lv J L, Wu Y Q, Chen P, Zhu J F, Dong W 2010 J. Gems Gemmol. 12 6 Google Scholar
[6]	Mankelevich Y A, May P W 2008 Diamond Relat. Mater. 17 1021 Google Scholar
[7]	Chrenko R M, Strong H M, Tuft R E 1971 Philos. Mag. A 23 313 Google Scholar
[8]	Kanda H, Akaishi M, Yamaoka S 1999 Diamond Relat. Mater. 8 1441 Google Scholar
[9]	Sumiya H, Harano K, Tamasaku K 2015 Diamond Relat. Mater. 58 221 Google Scholar
[10]	Demlow S N, Rechenberg R, Grotjohn T 2014 Diamond Relat. Mater. 49 19 Google Scholar
[11]	Stefanova A, Ayata S, Erema A, Ernst S, Baltruschat H 2013 Electrochim. Acta 110 560 Google Scholar
[12]	Blank V D, Kuznetsov M S, Nosukhin S A, Terentiev S A, Denisov V N 2007 Diamond Relat. Mater. 16 800 Google Scholar
[13]	Grotjohn T A, Tran D T, Yaran M K, Demlow S N, Schuelke T 2014 Diamond Relat. Mater. 44 129 Google Scholar
[14]	李尚升, 马红安, 臧传义, 田宇, 张亚飞, 肖宏宇, 尹斌华, 贾晓鹏 2006 金刚石与磨料磨具工程 152 16 Google Scholar Li S S, Ma H A, Zang C Y, Tian Y, Zhang Y F, Xiao H Y, Yin B H, Jia X P 2006 Diamond Abras. Eng. 152 16 Google Scholar
[15]	Li S S, Zhang H, Su T C, Hu Q, Hu M H, Gong C S, Ma H A, Jia X P, Li Y, Xiao H Y 2017 Chin. Phys. B 26 068102 Google Scholar
[16]	Zhang H, Li S S, Su T C, Hu M H, Ma H A, Jia X P, Li Y 2017 Chin. Phys. B 26 058102 Google Scholar
[17]	罗宁, 李尚升, 贾晓鹏 2012 金刚石与磨料磨具工程 32 15 Google Scholar Luo N, Li S S, Jia X P 2012 Diamond Abras. Eng. 32 15 Google Scholar
[18]	熊礼威, 汪建华, 满卫东, 刘长林, 翁俊 2010 材料导报 24 117 Google Scholar Xiong L W, Wang J H, Man W D, Li C L, Weng J 2010 Mater. Rev. 24 117 Google Scholar
[19]	Chevallier J, Ballutaud D, Bertrand T, Jomard F, Deneuville A, Etienne G, Pruvost F 1999 Phys. Status Solidi A 174 73 Google Scholar
[20]	Wentorf R H 1971 J. Phys. Chem. 75 1833 Google Scholar
[21]	肖宏宇, 苏剑峰, 张永胜, 鲍志刚 2012 61 248101 Google Scholar Xiao H Y, Su J F, Zhang Y S, Bao Z G 2012 Acta Phys. Sin. 61 248101 Google Scholar
[22]	张聪, 韩奇钢, 马红安, 肖宏宇, 李瑞, 李战厂, 田宇, 贾晓鹏 2010 59 1923 Google Scholar Zhang C, Han Q G, Ma H A, Xiao H Y, Li R, Li Z C, Jia X P 2010 Acta Phys. Sin. 59 1923 Google Scholar
[23]	Li Z C, Jia X P, Huang G F, Hu M H, Li Y, Yan B M, Ma H A 2013 Chin. Phys. B 22 014701 Google Scholar
[24]	Hu M H, Li S S, Ma H A, Su T C, Li X L, Hu Q, Ji X P 2012 Chin. Phys. B 21 098101 Google Scholar
[25]	Li Y D, Jia X P, Yan B M, Chen N, Fang C, Li Y, Sun S S, Ma H A 2016 RSC Adv. 6 40330 Google Scholar
[26]	肖宏宇, 秦玉琨, 刘利娜, 鲍志刚, 唐春娟, 孙瑞瑞, 张永胜, 李尚升, 贾晓鹏 2018 67 140702 Google Scholar Xiao H Y, Qin Y K, Li L N, Bao Z G, Tang C J, Sun R R, Zhang Y S, Li S S, Jia X P 2018 Acta Phys. Sin. 67 140702 Google Scholar
[27]	Sumiya H, Toda N, Satoh S 2002 J. Cryst. Growth 237 1281 Google Scholar
[28]	Kiflawi I, Kanda H, Lawson S C 2002 Diamond Relat. Mater. 11 204 Google Scholar
[29]	Reutsky V N, Borzdov Y M, Palyanov Y N 2012 Diamond Relat. Mater. 21 7 Google Scholar
[30]	Tian Y, Ma H A, Li S S, Xiao H Y, Zhang Y F, Huang G F, Ma L Q, Jia X P 2007 Chin. Phys. Lett. 24 2115 Google Scholar
[31]	肖宏宇, 秦玉琨, 隋永明, 梁中翥, 刘利娜, 张永胜 2016 65 070705 Google Scholar Xiao H Y, Qin Y K, Sui Y M, Liang Z Z, Liu L N, Zhang Y S 2016 Acta Phys. Sin. 65 070705 Google Scholar
[32]	秦玉琨, 肖宏宇, 刘利娜, 孙瑞瑞, 胡秋波, 鲍志刚, 张永胜, 李尚升, 贾晓鹏 2019 68 020701 Google Scholar Qin Y K, Xiao H Y, Liu L N, Sun R R, Hu Q B, Bao Z G, Zhang Y S, Li S S, Jia X P 2019 Acta Phys. Sin. 68 020701 Google Scholar
[33]	张恒涛, 肖长江, 尚秋元, 栗正新, 朱玲艳 2013 材料导报 27 65 Google Scholar Zhang H T, Xiao C J, Shang Q Y, Li Z X, Zhu L Y 2013 Mater. Rev. 27 65 Google Scholar
[34]	Sumiya H, Toda N, Satoh S 2005 Sei. Tech. Rev. 60 10
[35]	Abbaschian R, Zhu H, Clarke C 2005 Diamond Relat. Mater. 14 1916 Google Scholar
[36]	Xiao H Y, Jia X P, Zang C Y, Li S S, Tian Y, Zhang Y F, Huang G F, Ma L Q, Ma H A 2008 Chin. Phys. Lett. 25 1469 Google Scholar
[37]	王君卓, 李尚升, 宿太超, 胡美华, 胡强, 吴玉敏, 王健康, 韩飞, 于昆鹏, 高广进, 郭明明, 贾晓鹏, 马红安, 肖宏宇 2018 67 168101 Google Scholar Wang J Z, Li S S, Su T C, Hu M H, Hu Q, Wu Y M, Wang J K, Han F, Yu K P, Gao G J, Guo M M, Jia X P, Ma H A, Xiao H Y 2018 Acta Phys. Sin. 67 168101 Google Scholar
[38]	Chrenko R M, Tuft R E, Strong H M 1977 Nature 270 141 Google Scholar
[39]	Chepurov A A, Dereppe J M, Fedorov I I, Chepurov A I 2000 Diamond Relat. Mater. 9 1374 Google Scholar
[40]	Evans T, Qi Z 1982 Proc. R. Soc. A 381 159 Google Scholar
[41]	Mainwood A 1994 Phys. Rev. B 49 7934 Google Scholar
[42]	Kanda H, Akaishi M, Setaka N, Yamaoka S, Fukunaga O 1980 J. Mater. Sci. 15 2743 Google Scholar
[43]	Zang C Y, Huang G F, Ma H A, Jia X P 2007 Chin. Phys. Lett. 24 2991 Google Scholar
[44]	张贺, 李尚升, 宿太超, 胡美华, 周佑默, 樊浩天, 龚春生, 贾晓鹏, 马红安, 肖宏宇 2015 64 198103 Google Scholar Zhang H, Li S S, Su T C, Hu M H, Zhou Y M, Fan H T, Gong C S, Jia X P, Ma H A, Xiao H Y 2015 Acta Phys. Sin. 64 198103 Google Scholar
[45]	Beha K, Batalov A, Manson N B, Bratschitsch R, Leitenstorfer A 2012 Phys. Rev. Lett. 109 097404 Google Scholar
[46]	董杨, 杜博, 张少春, 陈向东, 孙方稳 2018 67 160301 Google Scholar Dong Y, Du B, Zhang S C, Chen S C, Sun F W 2018 Acta Phys. Sin. 67 160301 Google Scholar
[47]	Chen L C, Miao X Y, Ma H A, Guo L S, Chen L X, Wang Z K, Yang Z Q, Jia X P 2018 CrystEngComm 20 7164 Google Scholar
[48]	Chen N, Ma H A, Yan B M, Chen L C, Chen L X, Guo L S, Miao X Y, Fang C, Jia X P 2018 Cryst. Growth Des. 18 3870 Google Scholar
[49]	Han F, Li S S, Jia X F, Chen W Q, Su T C, Hu M H, Yu K P, Wang J K, WuY M, Ma H A, Jia X P 2019 Chin. Phys. B 28 028103 Google Scholar
[50]	Tatsumi N, Tamasaku K, Ito T, Sumiya H 2017 J. Cryst. Growth 458 27
[51]	Masuya S, Hanada K, Oshima T, Sumiya H, Kasu M 2017 Diamond Relat. Mater. 75 155 Google Scholar
[52]	臧传义, 马红安, 黄国峰, 贾晓鹏 2007 人工晶体学报 36 536 Google Scholar Zang C Y, Ma H A, Huang G F, Jia X P 2007 J. Synthetic Cryst. 36 536 Google Scholar
[53]	臧传义, 马红安, 黄国锋, 贾晓鹏 2007 吉林大学学报: 工学版 37 1097 Zang C Y, Ma H A, Huang G F, Jia X P 2007 J. Jilin Univ: Technol. Ed. 37 1097
[54]	Zang C Y, Chen X Z, Hu Q, Ma H A, Jia X P 2009 Chin. Sci. Bull. 54 2535 Google Scholar
[55]	黄国锋, 臧传义, 马红安, 李尚升, 田宇, 肖宏宇, 张亚飞, 马利秋, 李勇, 陈孝洲, 贾晓鹏 2008 超硬材料工程 20 9 Google Scholar Huang G F, Zang C Y, Ma H A, Li S S, Tian Y, Xiao H Y, Zhang Y F, Ma L Q, Li Y, Chen X Z, Jiao X P 2008 Superhard Mater. Eng. 20 9 Google Scholar
[56]	胡美华, 毕宁, 李尚升, 宿太超, 李小雷, 胡强, 贾晓鹏, 马红安 2013 62 188103 Hu M H, Bi N, Li S S, Su T C, Li X L, Hu Q, Jia X P, Ma H A 2013 Acta Phys. Sin. 62 188103
[57]	Han Q G, Ban Q C, Zhu P W 2015 J. Cryst. Growth 422 29 Google Scholar
[58]	Li S S, Li X L, Ma H A, Su TC, Xiao H Y, Huang G F, Li Y, Zhang Y S, Jia X P 2011 Chin. Phys. Lett. 28 68101 Google Scholar
[59]	Wang X C, Ma H A, Zang C Y, Tian Y, Li S S, Jia X P 2005 Chin. Phys. Lett. 22 1800 Google Scholar
[60]	Li S S, Jia X P, Zang C Y, Tian Y, Zang Y F, Xiao H Y, Huang G F, Ma L Q, Li Y, Li X L, Ma H A 2008 Chin. Phys. Lett. 25 3801 Google Scholar
[61]	Lysakovskii V V, Ivakhnenko S A 2009 J. Superhard Mater. 31 7 Google Scholar
[62]	Guo M M, Li S S, Hu M H, Su T C, Wang J Z, Gao G J, You Y, Nie Y 2020 Chin. Phys. B 29 018101 Google Scholar
[63]	李尚升, 张曙光, 李小雷, 宿太超, 肖宏宇, 黄国锋, 李勇, 马红安, 贾晓鹏 2011 功能材料 42 58 Li S S, Zhang S G, Li X L, Su T C, Xiao H Y, Huang G F, Li Y, Ma H A, Jia X P 2011 J. Funct. Mater. 42 58
[64]	Li S S, Gong C S, Su T C, Hu M H, Zhang H, Ma H A, Jia X P 2017 Int. J. Refract. Met. Hard Mater. 62 37 Google Scholar
[65]	Bormashov V S, Tarelkin S A, Buga S G, Kuznetsov M S, Terentiev S A, Semenov A N, Blank V N 2013 Diamond Relat. Mater. 35 19 Google Scholar
[66]	Ma L Q, Ma H A, Xiao H Y, Li S S, Li Y, Jia X P 2010 Chin. Sci. Bull. 55 677 Google Scholar
[67]	肖宏宇, 李尚升, 秦玉琨, 梁中翥, 张永胜, 张东梅, 张义顺 2014 63 198101 Google Scholar Xiao H Y, Li S S, Qin Y K, Liang Z Z, Zhang Y S, Zhang D M, Zhang Y S 2014 Acta Phys. Sin. 63 198101 Google Scholar
[68]	Howell D, Collins A T, Loudin L C, Diggle P L, D'Haenens-Johanssonf U F S, Smit K V, Katrusha A N, Butler J E, Nestola F 2019 Diamond Relat. Mater. 96 207 Google Scholar
[69]	肖宏宇, 刘利娜, 秦玉琨, 张东梅, 张永胜, 隋永明, 梁中翥 2016 65 050701 Xiao H Y, Liu L N, Qin Y K, Zhang D M, Zhang Y S, Sui Y M, Liang Z Z 2016 Acta Phys. Sin. 65 050701
[70]	Dai Y, Long R, Huang B B, Zhang Z K 2007 Diamond Relat. Mater. 16 353 Google Scholar
[71]	Palyanov Y N, BorzdovY M, Khokhryakov A F, Kupriyanov I N, Sokol A G 2010 Cryst. Growth Des. 10 3169 Google Scholar
[72]	Huang G F, Jia X P, Li S S, Zhang Y F, Li Y, Zhao M, Ma H A 2010 Chin. Phys. B 19 118101 Google Scholar
[73]	Wang J Z, Li S S, Hu M H, Su T C, Gao G J, Guo M M, You Y, Nie Y 2020 Int. J. Refract. Met. Hard Mater. 87 105150 Google Scholar
[74]	Kalish R 2001 Diamond Relat. Mater. 10 1749 Google Scholar
[75]	Zhimulev E I, Sonin V M, Mironov A M, Chepurov A I 2016 Geochem. Int. 54 415 Google Scholar
[76]	Fang S, Ma H A, Cai Z H, Chun X, Wang C X, Fang C, Zhao Z D, Lu Z Y, Wang Y K, Chen L C, Jia X P 2020 CrystEngComm 22 602 Google Scholar
[77]	Chen N, Ma H A, Chen L X, Yan B M, Fang C, Liu X B, Li Y D, Guo L S, Chen L C, Jia X P 2018 Int. J. Refract. Met. Hard Mater. 71 141 Google Scholar
[78]	Zhang H, Li S S, Su T C, Hu M H, Li G H, Ma H A, JiaX P 2016 Chin. Phys. B 25 118104 Google Scholar
[79]	Wan J K, Li S S, Gui J L, Feng L, Yu H, Su T C, Hu M H, Yu K P, Han F, Ma H A, Jia X P 2019 Int. J. Refract. Met. Hard Mater. 81 100 Google Scholar
[80]	Wan J K, Li S S, Wang N, Liu H J, Su T C, Hu M H, Yu K P, Han F, Ma H A 2019 Chin. Phys. Lett. 36 046101 Google Scholar
[81]	Tang L, Yue R F, Wang Y 2018 Carbon 130 458 Google Scholar
[82]	Zhang H, Li S S, Li G H, Su T C, Hu M H, Ma H A, Jia X P, Li Y 2017 Int. J. Refract. Met. Hard Mater. 66 26 Google Scholar
[83]	Gong C S, Li S S, Zhang H R, Su T C, Hu M H, Ma H A, Jia X P, Li Y 2017 Int. J. Refract. Met. Hard Mater. 66 116 Google Scholar
[84]	Yu K P, Li S S, Yang q, Leng K Q, Hu M H, Su T C, Guo M M, Gao G J, Wang J Z, You Y 2019 Cryst. Eng. Comm. 21 6810 Google Scholar
[85]	Yan B M, Jia X P, Fang C, Chen N, Li Y D, Sun S S, Ma H A 2016 Int. J. Refract. Met. Hard Mater. 54 309 Google Scholar
[86]	Yan B M, Jia X P, Sun S S, Zhou X Z, Fang C, Chen N, Li Y D, Li Y, Ma H A 2015 Int. J. Refract. Met. Hard Mater. 48 56 Google Scholar
[87]	Sun S S, Cui W, Jia X P, Ma H A, Lv J 2016 Int. J. Refract. Met. Hard Mater. 59 56 Google Scholar
[88]	Hu M H, Bi N, Li S S, Su T C, Hu Q, Ma H A, Jia X P 2017 CrystEngComm 19 4571 Google Scholar
[89]	Liu X B, Chen X, Singh D J, Stern R A, Wu J, Petitgirard S, Bina C R, Jacobsen S D 2019 Proc. Natl. Acad. Sci. 116 7703 Google Scholar

施引文献

图 1 TGM原理示意图

Fig. 1. Schematic diagram of temperature gradient method

下载: 全尺寸图片幻灯片

图 2 金刚石晶体生长不同阶段的温度场分布　(a) 0.5 h; (b) 6.5 h; (c) 10.0 h; (d) 13.0 h; (e) 17.5 h; (f) 23.0 h^[23]

Fig. 2. Distribution of temperature field in different stages of diamond crystal growth: (a) 0.5 h; (b) 6.5 h; (c) 10.0 h; (d) 13.0 h; (e) 17.5 h; (f) 23.0 h^[23].

下载: 全尺寸图片幻灯片

图 3 三种不同高度触媒的对流场分布　(a) 2.0 mm; (b) 2.4 mm; (c) 2.8 mm^[25]

Fig. 3. Distributions of convection field of the catalyst with three different heights: (a) 2.0 mm; (b) 2.4 mm; (c) 2.8 mm^[25].

下载: 全尺寸图片幻灯片

图 4 不同尺寸籽晶生长优质金刚石单晶的极限生长速度与合成时间关系曲线　(a) 0.8 mm; (b) 1.5 mm; (c) 2.2 mm^[32]

Fig. 4. Curves between the limit growth rate and the synthesis time of the high quality diamonds with different diameters of the seed-crystals: (a) 0.8 mm; (b) 1.5 mm; (c) 2.2 mm^[32].

下载: 全尺寸图片幻灯片

图 5 不同生长面生长的金刚石大单晶的V形生长区示意图^[37]

Fig. 5. Schematic diagram of the V-shaped growth region of large diamond single crystals grown on different growth surfaces^[37].

下载: 全尺寸图片幻灯片

图 6 A中心(左)、B中心(中)和C中心(右)示意图, 氮原子以黑色、碳以白色、空位以虚线圆圈表示^[41]

Fig. 6. Schematics of A-centre(left), B-centre(middle), C-centre (right)^[41].

下载: 全尺寸图片幻灯片

图 7 不同温度下合成Ib型金刚石大单晶表面中心及棱角处显微照片^[44]　(a), (a') 1250 ℃; (b), (b') 1280 ℃, (c), (c') 1310 ℃

Fig. 7. The microscopic photographs of surface centers and angularities of type Ib single crystal diamond synthesized at different temperatures^[44]: (a), (a') 1250 ℃; (b),(b') 1280 ℃, (c), (c') 1310 ℃

下载: 全尺寸图片幻灯片

图 8 金刚石NV色心介绍　(a) 金刚石中的NV色心原子结构; (b) NV色心的能级示意图^[46]

Fig. 8. Introduction of the NV center in diamond: (a) Schematic of the NV center structure in diamond; (b) energy level diagram of NV^[46]

下载: 全尺寸图片幻灯片

图 9 再结晶石墨析出原理示意图^[53]

Fig. 9. Formation mechanism schematic diagram of regrown graphite ^[53].

下载: 全尺寸图片幻灯片

图 10 样品腔体组装图(左半部分)和腔体温度分布图及放大图(右半部分)^[57]　(a) 传统CHPA样品腔体组装图; (b) 新型CHPA样品腔体组装图

Fig. 10. Plots of the sample cell assembly (in the left half) and the distributions of cell temperature as well as the enlarged figure (in the right half) ^[57]: (a) The sample cell assembly used for the conventional CHPA; (b) the sample cell assembly used for the novel CHPA.

下载: 全尺寸图片幻灯片

图 11 生长IIa型金刚石黑色石墨粉末SEM图^[63]

Fig. 11. The SEM photo of black powder at growing type IIa diamond^[63].

下载: 全尺寸图片幻灯片

图 12 金刚石掺杂元素分类

Fig. 12. Diamond doped element classification.

下载: 全尺寸图片幻灯片

图 13 氮源重量比为0.1%的合成孪晶金刚石的光学图像 (a) 1513 K; (b) 1553 K^[73]

Fig. 13. Optical image of diamond synthesized with N source weight percent of 0.1%: (a) 1513 K; (b) 1553 K^[73].

下载: 全尺寸图片幻灯片

图 14 金刚石中B-O杂质态理论　(a) B₃O和(b)B₄O化合物的优化结构(左上)和电子定位功能等值面(左下). 为了清楚起见, 仅示出结构图中的B和O原子相邻的C原子. 蓝色、红色和黑色球体分别对应于B, O和C原子. B₃O和B₄O金刚石的计算带结构和PDOS分别在右侧图中显示^[89]

Fig. 14. Theoretical results of B-O impurity states in diamond. Optimized structures (upper left) and electron localization function isosurfaces (lower left) for (a) B₃O and (b) B₄O complexes. Only the C atoms adjacent to the B and O atoms in the structure pictures are illustrated for clarity. The blue, red, and black spheres correspond to B, O, and C atoms, respectively. The calculated band structures and PDOS for B₃O and B₄O diamond are shown in right, respectively^[89].

下载: 全尺寸图片幻灯片

表 1 不同触媒和除氮剂组合的使用效果

Table 1. Effect of different catalysts and nitrogen getter.

合金触媒	除氮剂	除氮效果	晶体质量
FeNiCo	Ti^[59]	氮含量明显减少, 除氮效果好, 很难得到优质IIa型金刚石	金刚石晶体中存在夹杂物和表面蚀坑
FeNiCo	Ti/Cu^[15]	氮含量小于1 ppm, 除氮效果好	优质IIa型金刚石
NiMnCo	Al^[58]	Al和N存在可逆反应, 除氮效果不好, 很难得到IIa型金刚石	金刚石晶体中存在夹杂物和表面蚀坑
NiMnCo	Ti/Cu^[15]	氮含量小于1 ppm, 除氮效果好	优质IIa型金刚石
FeCo	Ti^[61]	氮含量明显减少, 除氮效果好, 很难得到优质IIa型金刚石	表面出现夹杂物
FeCo	Zr^[61]	氮含量明显减少除氮效果好	需要严格控制其生长速度

下载: 导出CSV

表 2 金刚石不同掺杂元素电学性能

Table 2. Electrical properties of different doped elements in diamond.

掺杂元素	P^[83]	Mn₃P₂^[84]	S^[78]	FeS^[79]	NiS^[80]	B-FeS^[82]	B-S^[79]
掺杂方式	替位式	替位式	替位式	替位式	替位式	替位式	替位式
半径大小	r_C < r_P	r_C < r_P	r_C < r_S	r_C < r_S	r_C < r_S	r_C > r_B r_C < r_S	r_C > r_B r_C < r_S
最小电阻率/10⁶ Ω·cm	3.560	0.516	0.963	0.813	1.163	0.096	0.933
特性	n型	n型	n型	n型	n型	n型	n(p)型

下载: 导出CSV

map

[1]	Kiflawi I, Bruley J 2000 Diamond Relat. Mater. 9 87 Google Scholar
[2]	龚春生, 李尚升, 张贺 2016 材料导报 30 36 Google Scholar Gong C S, Li S S, Zhang H 2016 Mater. Rev. 30 36 Google Scholar
[3]	唐敬友, 董庆东, 谷岩 2000 金刚石与磨料磨具工程 03 24 Google Scholar Tang J Y, Dong Q D, Gu Y 2000 Diamond Abras. Eng. 03 24 Google Scholar
[4]	胡美华, 马红安, 颜丙敏, 张壮飞, 李勇, 周振翔, 秦杰明, 贾晓鹏 2012 61 078102 Google Scholar Hu M H, Ma H A, Yan B M, Zhang Z F, Li Y, Zhou Z X, Qin J M, Jia X P 2012 Acta Phys. Sin. 61 078102 Google Scholar
[5]	满卫东, 吕继磊, 吴宇琼, 陈朋, 朱金凤, 董维 2010 宝石和宝石学杂志 12 6 Google Scholar Man W D, Lv J L, Wu Y Q, Chen P, Zhu J F, Dong W 2010 J. Gems Gemmol. 12 6 Google Scholar
[6]	Mankelevich Y A, May P W 2008 Diamond Relat. Mater. 17 1021 Google Scholar
[7]	Chrenko R M, Strong H M, Tuft R E 1971 Philos. Mag. A 23 313 Google Scholar
[8]	Kanda H, Akaishi M, Yamaoka S 1999 Diamond Relat. Mater. 8 1441 Google Scholar
[9]	Sumiya H, Harano K, Tamasaku K 2015 Diamond Relat. Mater. 58 221 Google Scholar
[10]	Demlow S N, Rechenberg R, Grotjohn T 2014 Diamond Relat. Mater. 49 19 Google Scholar
[11]	Stefanova A, Ayata S, Erema A, Ernst S, Baltruschat H 2013 Electrochim. Acta 110 560 Google Scholar
[12]	Blank V D, Kuznetsov M S, Nosukhin S A, Terentiev S A, Denisov V N 2007 Diamond Relat. Mater. 16 800 Google Scholar
[13]	Grotjohn T A, Tran D T, Yaran M K, Demlow S N, Schuelke T 2014 Diamond Relat. Mater. 44 129 Google Scholar
[14]	李尚升, 马红安, 臧传义, 田宇, 张亚飞, 肖宏宇, 尹斌华, 贾晓鹏 2006 金刚石与磨料磨具工程 152 16 Google Scholar Li S S, Ma H A, Zang C Y, Tian Y, Zhang Y F, Xiao H Y, Yin B H, Jia X P 2006 Diamond Abras. Eng. 152 16 Google Scholar
[15]	Li S S, Zhang H, Su T C, Hu Q, Hu M H, Gong C S, Ma H A, Jia X P, Li Y, Xiao H Y 2017 Chin. Phys. B 26 068102 Google Scholar
[16]	Zhang H, Li S S, Su T C, Hu M H, Ma H A, Jia X P, Li Y 2017 Chin. Phys. B 26 058102 Google Scholar
[17]	罗宁, 李尚升, 贾晓鹏 2012 金刚石与磨料磨具工程 32 15 Google Scholar Luo N, Li S S, Jia X P 2012 Diamond Abras. Eng. 32 15 Google Scholar
[18]	熊礼威, 汪建华, 满卫东, 刘长林, 翁俊 2010 材料导报 24 117 Google Scholar Xiong L W, Wang J H, Man W D, Li C L, Weng J 2010 Mater. Rev. 24 117 Google Scholar
[19]	Chevallier J, Ballutaud D, Bertrand T, Jomard F, Deneuville A, Etienne G, Pruvost F 1999 Phys. Status Solidi A 174 73 Google Scholar
[20]	Wentorf R H 1971 J. Phys. Chem. 75 1833 Google Scholar
[21]	肖宏宇, 苏剑峰, 张永胜, 鲍志刚 2012 61 248101 Google Scholar Xiao H Y, Su J F, Zhang Y S, Bao Z G 2012 Acta Phys. Sin. 61 248101 Google Scholar
[22]	张聪, 韩奇钢, 马红安, 肖宏宇, 李瑞, 李战厂, 田宇, 贾晓鹏 2010 59 1923 Google Scholar Zhang C, Han Q G, Ma H A, Xiao H Y, Li R, Li Z C, Jia X P 2010 Acta Phys. Sin. 59 1923 Google Scholar
[23]	Li Z C, Jia X P, Huang G F, Hu M H, Li Y, Yan B M, Ma H A 2013 Chin. Phys. B 22 014701 Google Scholar
[24]	Hu M H, Li S S, Ma H A, Su T C, Li X L, Hu Q, Ji X P 2012 Chin. Phys. B 21 098101 Google Scholar
[25]	Li Y D, Jia X P, Yan B M, Chen N, Fang C, Li Y, Sun S S, Ma H A 2016 RSC Adv. 6 40330 Google Scholar
[26]	肖宏宇, 秦玉琨, 刘利娜, 鲍志刚, 唐春娟, 孙瑞瑞, 张永胜, 李尚升, 贾晓鹏 2018 67 140702 Google Scholar Xiao H Y, Qin Y K, Li L N, Bao Z G, Tang C J, Sun R R, Zhang Y S, Li S S, Jia X P 2018 Acta Phys. Sin. 67 140702 Google Scholar
[27]	Sumiya H, Toda N, Satoh S 2002 J. Cryst. Growth 237 1281 Google Scholar
[28]	Kiflawi I, Kanda H, Lawson S C 2002 Diamond Relat. Mater. 11 204 Google Scholar
[29]	Reutsky V N, Borzdov Y M, Palyanov Y N 2012 Diamond Relat. Mater. 21 7 Google Scholar
[30]	Tian Y, Ma H A, Li S S, Xiao H Y, Zhang Y F, Huang G F, Ma L Q, Jia X P 2007 Chin. Phys. Lett. 24 2115 Google Scholar
[31]	肖宏宇, 秦玉琨, 隋永明, 梁中翥, 刘利娜, 张永胜 2016 65 070705 Google Scholar Xiao H Y, Qin Y K, Sui Y M, Liang Z Z, Liu L N, Zhang Y S 2016 Acta Phys. Sin. 65 070705 Google Scholar
[32]	秦玉琨, 肖宏宇, 刘利娜, 孙瑞瑞, 胡秋波, 鲍志刚, 张永胜, 李尚升, 贾晓鹏 2019 68 020701 Google Scholar Qin Y K, Xiao H Y, Liu L N, Sun R R, Hu Q B, Bao Z G, Zhang Y S, Li S S, Jia X P 2019 Acta Phys. Sin. 68 020701 Google Scholar
[33]	张恒涛, 肖长江, 尚秋元, 栗正新, 朱玲艳 2013 材料导报 27 65 Google Scholar Zhang H T, Xiao C J, Shang Q Y, Li Z X, Zhu L Y 2013 Mater. Rev. 27 65 Google Scholar
[34]	Sumiya H, Toda N, Satoh S 2005 Sei. Tech. Rev. 60 10
[35]	Abbaschian R, Zhu H, Clarke C 2005 Diamond Relat. Mater. 14 1916 Google Scholar
[36]	Xiao H Y, Jia X P, Zang C Y, Li S S, Tian Y, Zhang Y F, Huang G F, Ma L Q, Ma H A 2008 Chin. Phys. Lett. 25 1469 Google Scholar
[37]	王君卓, 李尚升, 宿太超, 胡美华, 胡强, 吴玉敏, 王健康, 韩飞, 于昆鹏, 高广进, 郭明明, 贾晓鹏, 马红安, 肖宏宇 2018 67 168101 Google Scholar Wang J Z, Li S S, Su T C, Hu M H, Hu Q, Wu Y M, Wang J K, Han F, Yu K P, Gao G J, Guo M M, Jia X P, Ma H A, Xiao H Y 2018 Acta Phys. Sin. 67 168101 Google Scholar
[38]	Chrenko R M, Tuft R E, Strong H M 1977 Nature 270 141 Google Scholar
[39]	Chepurov A A, Dereppe J M, Fedorov I I, Chepurov A I 2000 Diamond Relat. Mater. 9 1374 Google Scholar
[40]	Evans T, Qi Z 1982 Proc. R. Soc. A 381 159 Google Scholar
[41]	Mainwood A 1994 Phys. Rev. B 49 7934 Google Scholar
[42]	Kanda H, Akaishi M, Setaka N, Yamaoka S, Fukunaga O 1980 J. Mater. Sci. 15 2743 Google Scholar
[43]	Zang C Y, Huang G F, Ma H A, Jia X P 2007 Chin. Phys. Lett. 24 2991 Google Scholar
[44]	张贺, 李尚升, 宿太超, 胡美华, 周佑默, 樊浩天, 龚春生, 贾晓鹏, 马红安, 肖宏宇 2015 64 198103 Google Scholar Zhang H, Li S S, Su T C, Hu M H, Zhou Y M, Fan H T, Gong C S, Jia X P, Ma H A, Xiao H Y 2015 Acta Phys. Sin. 64 198103 Google Scholar
[45]	Beha K, Batalov A, Manson N B, Bratschitsch R, Leitenstorfer A 2012 Phys. Rev. Lett. 109 097404 Google Scholar
[46]	董杨, 杜博, 张少春, 陈向东, 孙方稳 2018 67 160301 Google Scholar Dong Y, Du B, Zhang S C, Chen S C, Sun F W 2018 Acta Phys. Sin. 67 160301 Google Scholar
[47]	Chen L C, Miao X Y, Ma H A, Guo L S, Chen L X, Wang Z K, Yang Z Q, Jia X P 2018 CrystEngComm 20 7164 Google Scholar
[48]	Chen N, Ma H A, Yan B M, Chen L C, Chen L X, Guo L S, Miao X Y, Fang C, Jia X P 2018 Cryst. Growth Des. 18 3870 Google Scholar
[49]	Han F, Li S S, Jia X F, Chen W Q, Su T C, Hu M H, Yu K P, Wang J K, WuY M, Ma H A, Jia X P 2019 Chin. Phys. B 28 028103 Google Scholar
[50]	Tatsumi N, Tamasaku K, Ito T, Sumiya H 2017 J. Cryst. Growth 458 27
[51]	Masuya S, Hanada K, Oshima T, Sumiya H, Kasu M 2017 Diamond Relat. Mater. 75 155 Google Scholar
[52]	臧传义, 马红安, 黄国峰, 贾晓鹏 2007 人工晶体学报 36 536 Google Scholar Zang C Y, Ma H A, Huang G F, Jia X P 2007 J. Synthetic Cryst. 36 536 Google Scholar
[53]	臧传义, 马红安, 黄国锋, 贾晓鹏 2007 吉林大学学报: 工学版 37 1097 Zang C Y, Ma H A, Huang G F, Jia X P 2007 J. Jilin Univ: Technol. Ed. 37 1097
[54]	Zang C Y, Chen X Z, Hu Q, Ma H A, Jia X P 2009 Chin. Sci. Bull. 54 2535 Google Scholar
[55]	黄国锋, 臧传义, 马红安, 李尚升, 田宇, 肖宏宇, 张亚飞, 马利秋, 李勇, 陈孝洲, 贾晓鹏 2008 超硬材料工程 20 9 Google Scholar Huang G F, Zang C Y, Ma H A, Li S S, Tian Y, Xiao H Y, Zhang Y F, Ma L Q, Li Y, Chen X Z, Jiao X P 2008 Superhard Mater. Eng. 20 9 Google Scholar
[56]	胡美华, 毕宁, 李尚升, 宿太超, 李小雷, 胡强, 贾晓鹏, 马红安 2013 62 188103 Hu M H, Bi N, Li S S, Su T C, Li X L, Hu Q, Jia X P, Ma H A 2013 Acta Phys. Sin. 62 188103
[57]	Han Q G, Ban Q C, Zhu P W 2015 J. Cryst. Growth 422 29 Google Scholar
[58]	Li S S, Li X L, Ma H A, Su TC, Xiao H Y, Huang G F, Li Y, Zhang Y S, Jia X P 2011 Chin. Phys. Lett. 28 68101 Google Scholar
[59]	Wang X C, Ma H A, Zang C Y, Tian Y, Li S S, Jia X P 2005 Chin. Phys. Lett. 22 1800 Google Scholar
[60]	Li S S, Jia X P, Zang C Y, Tian Y, Zang Y F, Xiao H Y, Huang G F, Ma L Q, Li Y, Li X L, Ma H A 2008 Chin. Phys. Lett. 25 3801 Google Scholar
[61]	Lysakovskii V V, Ivakhnenko S A 2009 J. Superhard Mater. 31 7 Google Scholar
[62]	Guo M M, Li S S, Hu M H, Su T C, Wang J Z, Gao G J, You Y, Nie Y 2020 Chin. Phys. B 29 018101 Google Scholar
[63]	李尚升, 张曙光, 李小雷, 宿太超, 肖宏宇, 黄国锋, 李勇, 马红安, 贾晓鹏 2011 功能材料 42 58 Li S S, Zhang S G, Li X L, Su T C, Xiao H Y, Huang G F, Li Y, Ma H A, Jia X P 2011 J. Funct. Mater. 42 58
[64]	Li S S, Gong C S, Su T C, Hu M H, Zhang H, Ma H A, Jia X P 2017 Int. J. Refract. Met. Hard Mater. 62 37 Google Scholar
[65]	Bormashov V S, Tarelkin S A, Buga S G, Kuznetsov M S, Terentiev S A, Semenov A N, Blank V N 2013 Diamond Relat. Mater. 35 19 Google Scholar
[66]	Ma L Q, Ma H A, Xiao H Y, Li S S, Li Y, Jia X P 2010 Chin. Sci. Bull. 55 677 Google Scholar
[67]	肖宏宇, 李尚升, 秦玉琨, 梁中翥, 张永胜, 张东梅, 张义顺 2014 63 198101 Google Scholar Xiao H Y, Li S S, Qin Y K, Liang Z Z, Zhang Y S, Zhang D M, Zhang Y S 2014 Acta Phys. Sin. 63 198101 Google Scholar
[68]	Howell D, Collins A T, Loudin L C, Diggle P L, D'Haenens-Johanssonf U F S, Smit K V, Katrusha A N, Butler J E, Nestola F 2019 Diamond Relat. Mater. 96 207 Google Scholar
[69]	肖宏宇, 刘利娜, 秦玉琨, 张东梅, 张永胜, 隋永明, 梁中翥 2016 65 050701 Xiao H Y, Liu L N, Qin Y K, Zhang D M, Zhang Y S, Sui Y M, Liang Z Z 2016 Acta Phys. Sin. 65 050701
[70]	Dai Y, Long R, Huang B B, Zhang Z K 2007 Diamond Relat. Mater. 16 353 Google Scholar
[71]	Palyanov Y N, BorzdovY M, Khokhryakov A F, Kupriyanov I N, Sokol A G 2010 Cryst. Growth Des. 10 3169 Google Scholar
[72]	Huang G F, Jia X P, Li S S, Zhang Y F, Li Y, Zhao M, Ma H A 2010 Chin. Phys. B 19 118101 Google Scholar
[73]	Wang J Z, Li S S, Hu M H, Su T C, Gao G J, Guo M M, You Y, Nie Y 2020 Int. J. Refract. Met. Hard Mater. 87 105150 Google Scholar
[74]	Kalish R 2001 Diamond Relat. Mater. 10 1749 Google Scholar
[75]	Zhimulev E I, Sonin V M, Mironov A M, Chepurov A I 2016 Geochem. Int. 54 415 Google Scholar
[76]	Fang S, Ma H A, Cai Z H, Chun X, Wang C X, Fang C, Zhao Z D, Lu Z Y, Wang Y K, Chen L C, Jia X P 2020 CrystEngComm 22 602 Google Scholar
[77]	Chen N, Ma H A, Chen L X, Yan B M, Fang C, Liu X B, Li Y D, Guo L S, Chen L C, Jia X P 2018 Int. J. Refract. Met. Hard Mater. 71 141 Google Scholar
[78]	Zhang H, Li S S, Su T C, Hu M H, Li G H, Ma H A, JiaX P 2016 Chin. Phys. B 25 118104 Google Scholar
[79]	Wan J K, Li S S, Gui J L, Feng L, Yu H, Su T C, Hu M H, Yu K P, Han F, Ma H A, Jia X P 2019 Int. J. Refract. Met. Hard Mater. 81 100 Google Scholar
[80]	Wan J K, Li S S, Wang N, Liu H J, Su T C, Hu M H, Yu K P, Han F, Ma H A 2019 Chin. Phys. Lett. 36 046101 Google Scholar
[81]	Tang L, Yue R F, Wang Y 2018 Carbon 130 458 Google Scholar
[82]	Zhang H, Li S S, Li G H, Su T C, Hu M H, Ma H A, Jia X P, Li Y 2017 Int. J. Refract. Met. Hard Mater. 66 26 Google Scholar
[83]	Gong C S, Li S S, Zhang H R, Su T C, Hu M H, Ma H A, Jia X P, Li Y 2017 Int. J. Refract. Met. Hard Mater. 66 116 Google Scholar
[84]	Yu K P, Li S S, Yang q, Leng K Q, Hu M H, Su T C, Guo M M, Gao G J, Wang J Z, You Y 2019 Cryst. Eng. Comm. 21 6810 Google Scholar
[85]	Yan B M, Jia X P, Fang C, Chen N, Li Y D, Sun S S, Ma H A 2016 Int. J. Refract. Met. Hard Mater. 54 309 Google Scholar
[86]	Yan B M, Jia X P, Sun S S, Zhou X Z, Fang C, Chen N, Li Y D, Li Y, Ma H A 2015 Int. J. Refract. Met. Hard Mater. 48 56 Google Scholar
[87]	Sun S S, Cui W, Jia X P, Ma H A, Lv J 2016 Int. J. Refract. Met. Hard Mater. 59 56 Google Scholar
[88]	Hu M H, Bi N, Li S S, Su T C, Hu Q, Ma H A, Jia X P 2017 CrystEngComm 19 4571 Google Scholar
[89]	Liu X B, Chen X, Singh D J, Stern R A, Wu J, Petitgirard S, Bina C R, Jacobsen S D 2019 Proc. Natl. Acad. Sci. 116 7703 Google Scholar

[1]	田毅, 杜明浩, 张佳威, 贺端威. 立方大腔体静高压装置中叶腊石的传压及密封性能研究. , 2024, 73(1): 019101. doi: 10.7498/aps.73.20231087
[2]	肖宏宇, 李勇, 鲍志刚, 佘彦超, 王应, 李尚升. 触媒组分对高温高压金刚石大单晶生长及裂纹缺陷的影响. , 2023, 72(2): 020701. doi: 10.7498/aps.72.20221841
[3]	杨功章, 谢雷, 陈喜平, 何瑞琦, 韩铁鑫, 牛国梁, 房雷鸣, 贺端威. 巴黎-爱丁堡压机中子衍射高压下温度加载实验. , 2022, 71(15): 156101. doi: 10.7498/aps.71.20220419
[4]	秦玉琨, 肖宏宇, 刘利娜, 孙瑞瑞, 胡秋波, 鲍志刚, 张永胜, 李尚升, 贾晓鹏. 籽晶尺寸对宝石级金刚石单晶生长的影响. , 2019, 68(2): 020701. doi: 10.7498/aps.68.20181855
[5]	李勇, 王应, 李尚升, 李宗宝, 罗开武, 冉茂武, 宋谋胜. 硼硫协同掺杂金刚石的高压合成与电学性能研究. , 2019, 68(9): 098101. doi: 10.7498/aps.68.20190133
[6]	张步强, 许振宇, 刘建国, 姚路, 阮俊, 胡佳屹, 夏晖晖, 聂伟, 袁峰, 阚瑞峰. 基于波长调制技术的高温高压流场温度测量方法. , 2019, 68(23): 233301. doi: 10.7498/aps.68.20190515
[7]	肖宏宇, 秦玉琨, 刘利娜, 鲍志刚, 唐春娟, 孙瑞瑞, 张永胜, 李尚升, 贾晓鹏. 降温工艺对宝石级金刚石单晶品质的影响. , 2018, 67(14): 140702. doi: 10.7498/aps.67.20180207
[8]	王君卓, 李尚升, 宿太超, 胡美华, 胡强, 吴玉敏, 王健康, 韩飞, 于昆鹏, 高广进, 郭明明, 贾晓鹏, 马红安, 肖宏宇. Ib型金刚石大单晶的限形生长. , 2018, 67(16): 168101. doi: 10.7498/aps.67.20180356
[9]	肖宏宇, 刘利娜, 秦玉琨, 张东梅, 张永胜, 隋永明, 梁中翥. B2O3添加宝石级金刚石单晶的生长特性. , 2016, 65(5): 050701. doi: 10.7498/aps.65.050701
[10]	李勇, 李宗宝, 宋谋胜, 王应, 贾晓鹏, 马红安. 硼氢协同掺杂Ib型金刚石大单晶的高温高压合成与电学性能研究. , 2016, 65(11): 118103. doi: 10.7498/aps.65.118103
[11]	肖宏宇, 秦玉琨, 隋永明, 梁中翥, 刘利娜, 张永胜. 合成腔体尺寸对Ib型六面体金刚石单晶生长的影响. , 2016, 65(7): 070705. doi: 10.7498/aps.65.070705
[12]	房超, 贾晓鹏, 陈宁, 周振翔, 李亚东, 李勇, 马红安. 添加Fe(C5H5)2合成氢掺杂金刚石大单晶及其表征. , 2015, 64(12): 128101. doi: 10.7498/aps.64.128101
[13]	房超, 贾晓鹏, 颜丙敏, 陈宁, 李亚东, 陈良超, 郭龙锁, 马红安. 高温高压下氮氢协同掺杂对{100}晶面生长宝石级金刚石的影响. , 2015, 64(22): 228101. doi: 10.7498/aps.64.228101
[14]	张贺, 李尚升, 宿太超, 胡美华, 周佑默, 樊浩天, 龚春生, 贾晓鹏, 马红安, 肖宏宇. 温度对Ib型和IIa型金刚石大单晶(100)表面特征的影响. , 2015, 64(19): 198103. doi: 10.7498/aps.64.198103
[15]	肖宏宇, 李尚升, 秦玉琨, 梁中翥, 张永胜, 张东梅, 张义顺. 高温高压下掺硼宝石级金刚石单晶生长特性的研究. , 2014, 63(19): 198101. doi: 10.7498/aps.63.198101
[16]	胡美华, 毕宁, 李尚升, 宿太超, 李小雷, 胡强, 贾晓鹏, 马红安. 国产六面顶压机多晶种法合成宝石级金刚石单晶. , 2013, 62(18): 188103. doi: 10.7498/aps.62.188103
[17]	肖宏宇, 苏剑峰, 张永胜, 鲍志刚. 温度梯度法宝石级金刚石的合成及表征. , 2012, 61(24): 248101. doi: 10.7498/aps.61.248101
[18]	秦杰明, 张莹, 曹建明, 田立飞. 纯铁触媒合成磨料级金刚石及表征. , 2011, 60(5): 058102. doi: 10.7498/aps.60.058102
[19]	姜本学, 徐军, 李红军, 王静雅, 赵广军, 赵志伟. 温度梯度法生长Nd:YAG激光晶体的核心分布. , 2007, 56(2): 1014-1019. doi: 10.7498/aps.56.1014
[20]	曾雄辉, 赵广军, 徐军. 温度梯度法生长的Ce: YAlOZr3高温闪烁晶体的光谱分析. , 2004, 53(6): 1935-1939. doi: 10.7498/aps.53.1935

计量

文章访问数: 13671
PDF下载量: 455
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板