Preparation of boron nanowires using AuPd nanoparticles as catalyst and their field emission behavios

Yang Xiu-Qing; Hu Yi; Zhang Jing-Lu; Wang Yan-Qiu; Pei Chun-Mei; Liu Fei

doi:10.7498/aps.63.048102

Abstract

Large-area boron nanowires are successfully prepared by chemical vapor deposition using different compositions of AuPd bimetal nanoparticles as catalysts. The lengths of the boron nanowires are in a range of 5–10 μm and their average diameter is 50 nm. Structural and morphology analysis indicate that these nanowires are single crystalline with a β-rhombohedral structure. The diameters of nanowires gradually decrease with the increase of the concentration of Pd in bimetal nanoparticles. Field emission results show that the field emission properties of boron nanowires can be tuned through using different diameters and densities of boron nanowires.

Keywords:

Authors and contacts

1.
Beijing Polytechnic, Beijing 100029, China;
2.
Key Laboratory of Display Material and Technology of Guangdong Province, State Key Laboratory of Photo-Electronics Materials and Technology, School of Physics and Engineering, Sun Yat-sen University, Guangzhou 510275, China
Funds: Project supported by the National Natural Science Foundation of China (Grant No. 50872147).

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[42]	Stratton R 1955 Proc. Phys. Soc. B 68 746
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Cited By

[1]	Iijima S 1991 Nature 354 56
[2]	de Heer W A, Chatelain A, Ugarte D 1995 Science 270 1179
[3]	Hu J T, Wang T R, Lieber C M 1999 Acc. Chem. Res. 32 435
[4]	Wang Z L 2003 Adv. Mater. 15 432
[5]	Lu J G, Chang P C, Fan Z Y 2006 Mater. Sci. Eng. R 52 49
[6]	Quandt A, Boustani I 2005 Chem. Phys. Chem. 6 2001
[7]	Wu J Z, Yun S H, Dibos A, Kim D K, Tidrow M 2003 Microelectronics J. 34 463
[8]	Wu Y Y, Messer B, Yang P D 2001 Adv. Mater. 13 1487
[9]	Otten C J, Lourie O R, Yu M F, Cowley J M, Dyer M J, Ruoff R S, Buhro W E 2002 J. Am. Chem. Soc. 124 4564
[10]	Franz R, Werheit H 1989 Europhys. Lett. 9 145
[11]	Boustani I, Quandt A, Herna'ndez E, Rubio A 1999 J. Chem. Phys. 110 3176
[12]	Tang H, Ismail-Beigi S 2007 Phys. Rev. Lett. 99 115501
[13]	Liu F, Shen C M, Su Z J, Ding X L, Deng S Z, Chen J, Xu N S, Gao H J 2010 J. Mater. Chem. 20 2197
[14]	Tian J F, Xu Z C, Shen C M, Liu F, Xu N S, Gao H J 2010 Nanoscale 2 1375
[15]	Wang D W, Lu J G, Otten C J, Buhro W E 2003 Appl. Phys. Lett. 83 5280
[16]	Cao L M, Zhang Z, Sun L L, He M, Wang Y Q, Li Y C, Zhang X Y, Li G, Zhang J, Wang W K 2001 Adv. Mater. 13 1701
[17]	Kirihara K, Wang Z, Kawaguchi K, Shimizu Y, Sasaki T, Koshizaki N, Sogac K, Kimura K 2005 Appl. Phys. Lett. 86 212101
[18]	Liu F, Tian J F, Bao L H, Yang T Z, Shen C M, Xu N S, Gao H J 2008 Adv. Mater. 20 2609
[19]	Tian J F, Cai J M, Hui C, Zhang C D, Bao L H, Gao M, Shen C M, Gao H J 2008 Appl. Phys. Lett. 93 122105
[20]	Bao L H, Li C, Tian Y, Tian J F, Hui C, Wang X J, Shen C M, Gao H J 2008 Chin. Phys. B 17 4585
[21]	Wang X J, Tian J F, Yang T Z, Bao L H, Hui C, Shen C M, Gao H J 2007 Adv. Mater. 19 4480
[22]	Bao L H, Li C, Tian Y, Tian J F, Hui C, Wang X J, Shen C M, Gao H J 2008 Chin. Phys. B 17 4247
[23]	Wang X J, Tian J F, Bao L H, Yang T Z, Hui C, Liu F, Shen C M, Xu N S, Gao H J 2008 Chin. Phys. B 17 3827
[24]	Li C, Tian Y, Wang D K, Shi X Z, Hui C, Shen C M, Gao H J 2011 Chin. Phys. B 20 037903
[25]	Qian W, Liu T, Wang Z, Yu H, Li Z, Wei F, Luo G 2003 Carbon 41 2487
[26]	Tsoufis T, Xidas P, Jankovic L, Gournis D, Saranti A, Bakas T, Karakassides M A 2007 Diamond Rela ted Mater. 16 155
[27]	Reyhani A, Mortazavi S Z, Akhavan O, Moshfegh A Z, Lahooti S 2007 Appl. Surf. Sci. 253 8458
[28]	Mortazavi S Z, Reyhani A, Irajizad A 2008 Appl. Sur. Sci. 254 6416
[29]	Khan Z H, Islam S S, Kung S C, Perng T P, Khan S, Tripathi K N, Agarwal M, Zulfequar M, Husain M 2006 Physica B 373 317
[30]	Chen C M, Dai Y M, Huang J G, Jehng J M 2006 Carbon 44 1808
[31]	Huang Z P, Wang D Z, Wen J G, Sennett M, Gibson H, Ren Z F 2002 Appl. Phys. A 74 387
[32]	Tian Y, Shen C M, Li C, Shi X Z, Huang Y, Gao H J 2011 Nano Res. 4 780
[33]	Scott R W J, Wilson O M, Oh S K, Kenik E A, Crooks R M 2004 J. Am. Chem. Soc. 126 15583
[34]	Hou W B, Dehm N A, Scott R W J 2008 J. Catal. 253 22
[35]	Jiang J H, Kucernak A 2009 Electrochim. Acta 54 4545
[36]	Shen C M, Hui C, Yang T Z, Xiao C W, Tian J F, Bao L H, Chen S T, Ding H, Gao H J 2008 Chem. Mater. 20 6939
[37]	Chen B, Wu P 2005 Carbon 43 3172
[38]	Hart A J, Slocum A H, Royer L 2006 Carbon 44 348
[39]	Liu Z Q, Pan Z W, Sun L F, Tang D S, Zhou W Y, Wang G, Qian L X, Xie S S 2000 J. Phys. Chem. Solids 61 1171
[40]	Moshfegh A Z 2009 J. Phys. D: Appl. Phys. 42 233001
[41]	JCPDS-International Center for Diffraction Data, PCPDFWIN, v.2.1, 2000
[42]	Stratton R 1955 Proc. Phys. Soc. B 68 746
[43]	Fowler R H, Nordheim L 1928 Roc. Roy. Soc. London A 119 173
[44]	Li S Q, Liang Y X, Wang T H 2006 Appl. Phys. Lett. 88 053107

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Vol. 63, Issue 4 - 2014-02-20

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