硼烯和碱土金属硼化物二维纳米材料的制备、结构、物性及应用研究

郭泽堃; 田颜; 甘海波; 黎子娟; 张彤; 许宁生; 陈军; 陈焕君; 邓少芝; 刘飞

doi:10.7498/aps.66.217702

摘要

随着石墨烯研究的兴起，二维纳米材料得以迅速发展.在众多的二维纳米材料中，硼烯和碱土金属硼化物二维材料由于具有高费米速度、高杨氏模量、高透光性、高延展性、高度的各向异性、大的泊松比和高的化学稳定性等独特的性质，成为研究人员关注的焦点.本文侧重介绍目前硼烯和碱土金属硼化物二维纳米材料的制备工艺、结构、物性和应用情况.首先总结了目前硼烯的主要结构构型和制备及掺杂工艺；其次介绍了碱土金属硼化物二维纳米材料的理论结构构型和可能的制备路线；最后对硼烯和二维碱土金属硼化物纳米材料的物理特性进行归纳总结，同时预测它们未来最可能实现应用的领域.

关键词:

Abstract

With the rise of graphene, two-dimensional nanomaterials have been significantly developed in recent years. As novel two-dimensional nanostructures, borophene and alkaline-earth metal boride two-dimensional materials have received much attention because of their unique physical and chemical properties, such as high Fermi velocities, high electron mobilities, large Young's moduli, high transparencies, negative Poisson's ratios and high chemical stabilities. This paper focuses on the researches of the fabrication techniques, structure configurations, properties and applications of borophene and two-dimensional alkaline-earth metal boride nanomaterials. Firstly, the current preparation methods and structure configurations of borophene are summarized. Secondly, the possible structures and fabrication techniques of two-dimensional alkaline-earth metal boride nanomaterials are introduced in detail. Thirdly, the physical properties of borophene and two-dimensional alkaline-earth metal boride nanomaterials are investigated. Finally, the most promising application areas of borophene and two-dimensional alkaline-earth metal boride nanomaterials in the future are predicted.

Keywords:

borophene /
two-dimensional alkaline-earth metal boride nanostructures /
fabrication technique /
structure configuration

作者及机构信息

1.
中山大学电子与信息工程学院, 广东省显示材料与技术重点实验室, 光电材料与技术国家重点实验室, 广州 510275

通信作者: 刘飞, liufei@mail.sysu.edu.cn

基金项目: 国家重点基础研究发展计划（批准号：2013CB933601）、国家重大科学仪器设备开发专项（批准号：2013YQ12034506）、广东省自然科学基金（批准号：2016A030313313）、教育部留学回国人员科研启动基金（批准号：教外司留[2014]1685号）、中央高校基本科研业务费专项资金（批准号：111gzd05）和光电材料与技术国家重点实验室自主课题（批准号：OEMT-2015-RC-05）资助的课题.

Authors and contacts

1.
Guangdong Key Laboratory of Display Materials and Technologies, State Key Laboratory of Optoelectronic Materials and Technology, School of Electronics and Information Technology, Sun Yat-sen University, Guangzhou 510275, China

Corresponding author: Liu Fei, liufei@mail.sysu.edu.cn

Funds: Project supported by the National Basic Research Program of China (Grant No. 2013CB933601), the Special Foundation of State Major Scientific Instrument and Equipment Development of China (Grant No. 2013YQ12034506), the Natural Science Foundation of Guangdong Province, China (Grant No. 2016A030313313), the Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China (Grant No.[2014]1685), the Fundamental Research Funds for the Central Universities, China (Grant No. 111gzd05), and the State Key Laboratory of Optoelectronic Materials and Technology Independent Subject (Grant No. OEMT-2015-RC-05).

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施引文献

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