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The smooth, uniform, and transparent solid nitrogen-molecular film was grown by applying the slow thermal cycles near the triple-point temperature to the growth process in our home-made liquid/solid preparation apparatus. The infrared absorption spectra of solid nitrogen at near-triple point temperature are measured by the infrared spectroscopy system. A broad absorption band can be observed from 2222 to 2439 cm-1 with the strongest peak at 2288 cm-1. This has been well explained theoretically on the basis of the ground-state vibration and the coupling between the ground-state vibration and rotation at low temperatures within the framework of anharmonic approximation.
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Keywords:
- low temperature /
- nitrogen /
- infrared absorpion /
- vibration
[1] McCluskey M D, Zhuravlev K K 2002 J. Chem. Phys. 116 1607
[2] Sheng D T, Ewing G E 1971 J. Chem. Phys. 55 5425
[3] Manzanares C I, Muñoz A, Hidalgo D 1984 Chem. Phys. 87 363
[4] Herzberg G 1938 Astrophys. J. 87 428
[5] Gebbie H A, Stone N W B, Williams D 1963 Mol. Phys. 6 215
[6] Reddy S P, Cho C W 1965 Can. J. Phys. 43 2331
[7] Dressler K 1962 J. Quant. Spectrosc. Radiat. Transfer. 4 683
[8] Brooker H R, Haigh P J, Scott T A 1961 Phys. Rev. 123 2143
[9] Fuller G H 1976 J. Phys. Chem. Ref. Data 5 835
[10] Scott T A 1976 Phys. Rep. 27 89
[11] Venables J A, English C A 1974 Acta Crystallogr. B 30 929
[12] Bolz L H, Boyd M E, Mauer F A, Peiser H S 1959 Acta Crystallogr. 12 247
[13] Jordan T H, Smith H W, Streib W E, Lipscomb W N 1964 J. Chem. Phys. 41 756
[14] Crawford M F, Welsh H L, Locke J L 1949 Phys. Rev. 75 1607
[15] Courtois D, Jouve P 1979 J. Mol. Spectrosc. 55 18
[16] Tryka K A 1995 Icarus. 166 409
[17] Bi P, LiuY Q, Tang Y J, Yang X D, Lei H L 2010 Acta Phys. Sin. 59 7531 (in Chinese) [毕鹏, 刘元琼, 唐永建, 杨向东, 雷海乐 2010 59 7531]
[18] Liu J P, Bi P, Lei H L, Li J, Wei J J 2013 Acta Phys. Sin. 62 163301 (in Chinese) [刘江平, 毕鹏, 雷海乐, 黎军, 韦建军 2013 62 163301]
[19] Bi P, Xie D, Lin W, Wang K, Liu J P, Tang Y J, Yang X D, Lei H L 2013 Chin. Phys. B 22 034401
[20] Giauque W F, Clayton J O 1933 J. Amer. Chem. Soc. 55 4875
[21] Lei H L, Li J, Tang Y J, Shi H L, Liu Y Q 2009 High Power Laser and Particle Beams 21 53 (in Chinese) [雷海乐, 黎军, 唐永建, 师洪丽, 刘元琼 2009 强激光与粒子束 21 53]
[22] Nowak P, Kleinrahm R, Wagner W 1997 J. Chem. Thermodyn. 29 1157
[23] Lei H L, Li J, Tang Y J, Liu Y Q 2009 Rev. Sci. Instrum. 80 033103
[24] Wang K, Lin W, Liu Y Q, Xie D, Li J, Ma K Q, Tang Y J, Lei H L 2012 Acta Phys. Sin. 61 195204 (in Chinese) [王凯, 林伟, 刘元琼, 谢端, 黎军, 马坤全, 唐永建, 雷海乐 2012 61 195204]
[25] Xu G X, Wang X Y 2010 Structure of Substance (2st ED.) (Beijing: Science Press) p441 (in Chinese) [徐光宪, 王祥云 2010 物质结构(第二版)(北京: 科学出版社)第441页]
[26] Huber K P, Herzberg G 1979 Molecular Spectra and Molecular Structure (Vol. IV) (New York: Van Reinhold Press) p420
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[1] McCluskey M D, Zhuravlev K K 2002 J. Chem. Phys. 116 1607
[2] Sheng D T, Ewing G E 1971 J. Chem. Phys. 55 5425
[3] Manzanares C I, Muñoz A, Hidalgo D 1984 Chem. Phys. 87 363
[4] Herzberg G 1938 Astrophys. J. 87 428
[5] Gebbie H A, Stone N W B, Williams D 1963 Mol. Phys. 6 215
[6] Reddy S P, Cho C W 1965 Can. J. Phys. 43 2331
[7] Dressler K 1962 J. Quant. Spectrosc. Radiat. Transfer. 4 683
[8] Brooker H R, Haigh P J, Scott T A 1961 Phys. Rev. 123 2143
[9] Fuller G H 1976 J. Phys. Chem. Ref. Data 5 835
[10] Scott T A 1976 Phys. Rep. 27 89
[11] Venables J A, English C A 1974 Acta Crystallogr. B 30 929
[12] Bolz L H, Boyd M E, Mauer F A, Peiser H S 1959 Acta Crystallogr. 12 247
[13] Jordan T H, Smith H W, Streib W E, Lipscomb W N 1964 J. Chem. Phys. 41 756
[14] Crawford M F, Welsh H L, Locke J L 1949 Phys. Rev. 75 1607
[15] Courtois D, Jouve P 1979 J. Mol. Spectrosc. 55 18
[16] Tryka K A 1995 Icarus. 166 409
[17] Bi P, LiuY Q, Tang Y J, Yang X D, Lei H L 2010 Acta Phys. Sin. 59 7531 (in Chinese) [毕鹏, 刘元琼, 唐永建, 杨向东, 雷海乐 2010 59 7531]
[18] Liu J P, Bi P, Lei H L, Li J, Wei J J 2013 Acta Phys. Sin. 62 163301 (in Chinese) [刘江平, 毕鹏, 雷海乐, 黎军, 韦建军 2013 62 163301]
[19] Bi P, Xie D, Lin W, Wang K, Liu J P, Tang Y J, Yang X D, Lei H L 2013 Chin. Phys. B 22 034401
[20] Giauque W F, Clayton J O 1933 J. Amer. Chem. Soc. 55 4875
[21] Lei H L, Li J, Tang Y J, Shi H L, Liu Y Q 2009 High Power Laser and Particle Beams 21 53 (in Chinese) [雷海乐, 黎军, 唐永建, 师洪丽, 刘元琼 2009 强激光与粒子束 21 53]
[22] Nowak P, Kleinrahm R, Wagner W 1997 J. Chem. Thermodyn. 29 1157
[23] Lei H L, Li J, Tang Y J, Liu Y Q 2009 Rev. Sci. Instrum. 80 033103
[24] Wang K, Lin W, Liu Y Q, Xie D, Li J, Ma K Q, Tang Y J, Lei H L 2012 Acta Phys. Sin. 61 195204 (in Chinese) [王凯, 林伟, 刘元琼, 谢端, 黎军, 马坤全, 唐永建, 雷海乐 2012 61 195204]
[25] Xu G X, Wang X Y 2010 Structure of Substance (2st ED.) (Beijing: Science Press) p441 (in Chinese) [徐光宪, 王祥云 2010 物质结构(第二版)(北京: 科学出版社)第441页]
[26] Huber K P, Herzberg G 1979 Molecular Spectra and Molecular Structure (Vol. IV) (New York: Van Reinhold Press) p420
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