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The resonance Raman spectra of nonpolar molecule all-trans--carotene and polar molecule canthaxanthin in nonpolar CS2 and polar 1,2-dicholoroethane in a temperature range from 243K to 293K are measured. The results show that polarities of the solute and solvent have a great effect on Raman spectrum. Raman scattering cross-section of nonpolar all-trans--carotene in nonpolar solvent CS2 is biggest and its bandwidth is narrowest. Raman scattering cross-section of polar canthaxanthin in polar solvent 1,2-dicholoroethane is smallest and its bandwidth is widest. The experimental phenomena are explained by solvent effects, coherent weakly damped electron-lattice vibration and effective conjugated length.
[1] Qian P, Saiki K, Mizoguchi T, Hara K, Sashima T, Fujii R, Koyama Y 2001 Photochemistry and Photobiology 74 444
[2] Luer L, Manzoni C, Cerullo G 2007 Chem. Phys. Lett. 444 61
[3] Zhao X H, Ma F, Wu Y S, Ai X C, Zhang J P 2008 Acta Phys. Sin. 57 289 (in Chinese) [赵晓辉, 马菲, 吴义室, 艾希成, 张建平 2008 57 289]
[4] Johansson E M J, Edvinsson T, Odelius M, Hagberg D P, Sun L, Hagfeldt A, Siegbahn H, Rensmo H 2007 J. Phys. Chem. C 111 8580
[5] Widjaja E, Garland M 2010 Talanta 80 1665
[6] Oliveira V E, Castro H V, Edwards H G M, Oliveira L F C 2010 J. Raman Spectrosc. 41 642
[7] Niedzwiedzki D M, Enriquez M M, La Fountain A M, Frank H A 2010 Chem. Phys. 373 80
[8] Frank H A, Young A J, Britton G, Cogdell R J 1999 Advances in Photosynthesis (Dordrecht: Kluwer Academic Publishers)
[9] Liu T Y, Sun C L, Li Z W, Zhou M 2012 Acta Phys. Sin. 61 107801 (in Chinese) [刘天元, 孙成林, 里佐威, 周密 2012 61 107801]
[10] Fang C, Liu M L 2012 Acta Phys. Sin. 61 097802 (in Chinese) [房超, 刘马林 2012 61 097802]
[11] Valentin M D, Ceola S, Agostini G, Giacometti G M, Angerhofer A, Crescenzi O, Barone V, Carbonera D 2008 Biochimica et Biophysica Acta 1777 295
[12] Shimada R, Hamaguchi H O 2011 J. Chem. Phys. 134 034516
[13] Li Z L, Ou Yang S L, Cao B, Zhou M, Li Z W, Gao S Q 2009 Acta Phys. Sin. 58 6908 (in Chinese) [李占龙, 欧阳顺利, 曹彪, 周密, 里佐威, 高淑琴 2009 58 6908]
[14] Qu G N, Li D F, Li Z L, Ouyang S L, Li Z W 2010 Acta Phys. Sin. 59 3168 (in Chinese) [曲冠男, 李东飞, 李占龙, 欧阳顺利, 里佐威 2010 59 3168]
[15] He Z F, Gosztola D, Deng Y, Gao G Q, Wasielewski M R, Kispert L D 2000 J. Phys. Chem. B 104 6668
[16] Applequist J 1991 J. Phys. Chem. 95 3539
[17] Lee J Y, Mhin J B, Kim K S 1997 J. Phys. Chem. 107 4881
[18] Liu W L, Wang D M, Zheng Z R, Li A H, Su W H 2010 J. Chin. Phys. B 19 013102
[19] Kakimoto M, Fujiyama T 1975 Bulletin of the Chemical Society of Japan 48 2258
[20] Krawczyk S 1998 Chemical Physics 230 297
[21] Rimai L, Kilponen R G, Gill D 1970 J. Am. Chem. Soc. 92 3824
[22] Inagaki F, Tasumi M, Miyazawa T 1974 J. Mol. 50 286
[23] Sufrá S, Dellepiane G, Masetti G, Zerbi G 1977 J. Raman Spectrosc 6 267
[24] Warshel A, Dauber P 1977 J. Chem. Phys. 66 5477
[25] Dudik J M, Johnson C R, Asher S A 1985 J. Chem. Phys. 82 173
[26] Biswas N, Umapathy S 1998 Appl. Spectrosc. 52 496
[27] Vardeny Z, Ehrenfreund E, Brafman O 1983 Phys. Rev. Lett. 25 (51) 2326
[28] Koyama Y, Kuki M, Anderson P O, Gillbro T 1996 Photochem. Photobiolo. 63 243
[29] Hoskins L C 1980 J. Chem. Phys. 72 4488
[30] Borges C A M, Marletta A, Faria R M, Guimarãe F E G 2004 Brazilian J. Phys. 34 590
[31] Paraschuk D Y, Kobryanskii Y M 2001 Phys. Rev. Lett. 87 207
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[1] Qian P, Saiki K, Mizoguchi T, Hara K, Sashima T, Fujii R, Koyama Y 2001 Photochemistry and Photobiology 74 444
[2] Luer L, Manzoni C, Cerullo G 2007 Chem. Phys. Lett. 444 61
[3] Zhao X H, Ma F, Wu Y S, Ai X C, Zhang J P 2008 Acta Phys. Sin. 57 289 (in Chinese) [赵晓辉, 马菲, 吴义室, 艾希成, 张建平 2008 57 289]
[4] Johansson E M J, Edvinsson T, Odelius M, Hagberg D P, Sun L, Hagfeldt A, Siegbahn H, Rensmo H 2007 J. Phys. Chem. C 111 8580
[5] Widjaja E, Garland M 2010 Talanta 80 1665
[6] Oliveira V E, Castro H V, Edwards H G M, Oliveira L F C 2010 J. Raman Spectrosc. 41 642
[7] Niedzwiedzki D M, Enriquez M M, La Fountain A M, Frank H A 2010 Chem. Phys. 373 80
[8] Frank H A, Young A J, Britton G, Cogdell R J 1999 Advances in Photosynthesis (Dordrecht: Kluwer Academic Publishers)
[9] Liu T Y, Sun C L, Li Z W, Zhou M 2012 Acta Phys. Sin. 61 107801 (in Chinese) [刘天元, 孙成林, 里佐威, 周密 2012 61 107801]
[10] Fang C, Liu M L 2012 Acta Phys. Sin. 61 097802 (in Chinese) [房超, 刘马林 2012 61 097802]
[11] Valentin M D, Ceola S, Agostini G, Giacometti G M, Angerhofer A, Crescenzi O, Barone V, Carbonera D 2008 Biochimica et Biophysica Acta 1777 295
[12] Shimada R, Hamaguchi H O 2011 J. Chem. Phys. 134 034516
[13] Li Z L, Ou Yang S L, Cao B, Zhou M, Li Z W, Gao S Q 2009 Acta Phys. Sin. 58 6908 (in Chinese) [李占龙, 欧阳顺利, 曹彪, 周密, 里佐威, 高淑琴 2009 58 6908]
[14] Qu G N, Li D F, Li Z L, Ouyang S L, Li Z W 2010 Acta Phys. Sin. 59 3168 (in Chinese) [曲冠男, 李东飞, 李占龙, 欧阳顺利, 里佐威 2010 59 3168]
[15] He Z F, Gosztola D, Deng Y, Gao G Q, Wasielewski M R, Kispert L D 2000 J. Phys. Chem. B 104 6668
[16] Applequist J 1991 J. Phys. Chem. 95 3539
[17] Lee J Y, Mhin J B, Kim K S 1997 J. Phys. Chem. 107 4881
[18] Liu W L, Wang D M, Zheng Z R, Li A H, Su W H 2010 J. Chin. Phys. B 19 013102
[19] Kakimoto M, Fujiyama T 1975 Bulletin of the Chemical Society of Japan 48 2258
[20] Krawczyk S 1998 Chemical Physics 230 297
[21] Rimai L, Kilponen R G, Gill D 1970 J. Am. Chem. Soc. 92 3824
[22] Inagaki F, Tasumi M, Miyazawa T 1974 J. Mol. 50 286
[23] Sufrá S, Dellepiane G, Masetti G, Zerbi G 1977 J. Raman Spectrosc 6 267
[24] Warshel A, Dauber P 1977 J. Chem. Phys. 66 5477
[25] Dudik J M, Johnson C R, Asher S A 1985 J. Chem. Phys. 82 173
[26] Biswas N, Umapathy S 1998 Appl. Spectrosc. 52 496
[27] Vardeny Z, Ehrenfreund E, Brafman O 1983 Phys. Rev. Lett. 25 (51) 2326
[28] Koyama Y, Kuki M, Anderson P O, Gillbro T 1996 Photochem. Photobiolo. 63 243
[29] Hoskins L C 1980 J. Chem. Phys. 72 4488
[30] Borges C A M, Marletta A, Faria R M, Guimarãe F E G 2004 Brazilian J. Phys. 34 590
[31] Paraschuk D Y, Kobryanskii Y M 2001 Phys. Rev. Lett. 87 207
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