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Research progress of quartz-enhanced photoacoustic spectroscopy based gas sensing

Ma Yu-Fei

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Research progress of quartz-enhanced photoacoustic spectroscopy based gas sensing

Ma Yu-Fei
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  • Laser spectroscopy based techniques have the advantages of high sensitivities, high selectivities, non-invasiveness and in situ, real-time observations. They are widely used in numerous fields, such as environmental monitoring, life science, medical diagnostics, manned space flight, and planetary exploration. Owing to the merits of low cost, compact volume and strong environment adaptability, quartz-enhanced photoacoustic spectroscopy (QEPAS) based sensing is an important laser spectroscopy-based method of detecting the trace gas, which was invented in 2002. Detection sensitivity is a key parameter for gas sensors because it determines their real applications. In this paper, focusing on the detection sensitivity, the common methods for QEPAS are summarized. High power laser including amplified diode laser by erbium doped fiber amplifier (EDFA), and quantum cascade laser are used to improve the excitation intensity of acoustic wave. The absorption line of gas molecules located at the fundamental bands of mid-infrared region is adopted to increase the laser absorption strength. Micro-resonator is employed to enhance the generated acoustic pressure by forming a standing wave cavity. Quartz tuning forks (QTFs) with low resonant frequency are used to increase the accumulation time of acoustic energy in itself. Multi-pass strategy is utilized to amplify the action length between laser beam and target gas in the prongs of QTF. The advantages and disadvantages of the above methods are discussed respectively. For the issues in real applications, the all-fiber strucure in near-infared region and mid-infrared region and miniaturization using three-dimensional(3D) printing technique for QEPAS sensor are summarized. A QEPAS technique based multi-gas sensor is used to quantify the concentration of carbon monoxide (CO), carbon dioxide (CO2), hydrogen cyanide (HCN), and hydrogen chloride (HCl) for post-fire cleanup aboard spacecraft, which is taken for example for the real application.Finally, the methods of further improving the sensitivity of QEPAS sensor are proposed.
      Corresponding author: Ma Yu-Fei, mayufei@hit.edu.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 62022032, 61875047, 61505041), the Outstanding Youth Scientsit Fund of the Natural Science Foundation of Heilongjiang Province of China (Grant No. YQ2019F006), the Scientific Rearch Starting Funds for the Postdoctoral of Heilongjiang Province, China (Grant No. LBH-Q18052), the Fundamental Research Funds for the Central Universities
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  • 图 1  QEPAS传感示意图 (a) QEPAS技术原理; (b) 声波产生及探测

    Figure 1.  Schematic diagram of QEPAS sensing: (a) Principle of QEPAS; (b) generation and detection of acoustics wave.

    图 2  石英音叉弯曲振动模式 (a) 音叉模型; (b) 面外基频模态; (c) 面内基频模态; (d) 面内第一泛频模态

    Figure 2.  Flexural mode of quartz tuning fork: (a) Mode of quartz tuning fork; (b) out-of-plane fundamental mode; (c) in-plane fundamental mode; (d) in-plane 1st overtone mode

    图 3  EDFA光放大 (a) 种子光发射谱; (b) 放大后的发射谱[38]

    Figure 3.  Laser amplification by EDFA: (a) Emission spectrum for seed diode laser; (b) emission spectrum for amplified diode laser. Reproduced from Ref. [38], with the permission of AIP Publishing.

    图 4  内腔增强型QEPAS传感系统[59]

    Figure 4.  Intracavity enhanced QEPAS sensor system. Reproduced from Ref. [59], with the permission of AIP Publishing.

    图 5  基于THz激光源的QEPAS传感系统[45]

    Figure 5.  QEPAS sensing system based on THz laser. Reproduced from Ref. [45], with the permission of AIP Publishing.

    图 6  微共振腔对石英音叉QTF的增强效果示意图

    Figure 6.  The configuration of micro-resonator and the enhanced effect of acoustic pressure.

    图 7  微共振腔结构 (a) “共轴”式; (b) “离轴”式; (c) 单管“共轴”式; (d) 嵌入“离轴”式

    Figure 7.  The configuration of micro-resonator: (a) On-beam; (b) off-beam; (c) single-tube on-beam; (d) embedded off-beam.

    图 8  (a) 不同模式下石英音叉的最佳激发位置; (b) 基频振动模态; (c) 第一泛频振动模态; (d) 基频与第一泛频的复合振动模态[62]

    Figure 8.  (a) Optimal excitation position for different modes of quartz tuning fork; (b) fundamental mode; (c) 1st overtone mode; (d) combined mode. Reproduced from Ref. [62], with the permission of AIP Publishing.

    图 9  双波腹激发下的QEPAS传感器[56]

    Figure 9.  Double antinode excited QEPAS sensor. Reproduced from Ref. [56], with the permission of AIP Publishing.

    图 10  基于多光程吸收的QEPAS传感器[57]

    Figure 10.  Multi-pass based QEPAS sensor. Reprinted with permission from Ref. [57] © The Optical Society.

    图 11  面内激光入射的QEPAS传感器[58]

    Figure 11.  In-plane QEPAS sensor. Reproduced from Ref. [58], with the permission of AIP Publishing.

    图 12  基于倏逝场激发的准分布式全光纤QEPAS传感器[66]

    Figure 12.  Quasi-distributed gas sensing based on fiber evanescent wave QEPAS sensor. Reproduced from Ref. [66], with the permission of AIP Publishing.

    图 13  基于机械加工方式所得到的光学及声波探测部分[69]

    Figure 13.  Optical and acoustic detection parts for QEPAS sensor based on mechanical processing[69].

    图 14  基于3D打印方式所得到的光学及声波探测部分[70]

    Figure 14.  Optical and acoustic detection parts for QEPAS sensor based on 3D printing. Reprinted with permission from Ref. [70] © The Optical Society.

    图 15  多通道QEPAS传感器[71]

    Figure 15.  Multi-channel QEPAS sensor[71].

    Baidu
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    Khalil M A K, Rasmussen R A 1984 Science 224 54Google Scholar

    [2]

    Logan J A, Prather M J, Wofsy S C, McElroy M B 1981 J. Geophys. Res. 86 7210Google Scholar

    [3]

    Wojtas J, Tittel F K, Stacewicz T, Bielecki Z, Lewicki R, Mikolajczyk J, Nowakowski M, Szabra D, Stefanski P, Tarka J 2014 Int. J. Thermophys. 35 2215Google Scholar

    [4]

    Milde T, Hoppe M, Tatenguem H, Mordmüller M, Ogorman J, Willer U, Schade W, Sacher J 2018 Appl. Opt. 57 C120Google Scholar

    [5]

    Ma Y F, Qiao S D, He Y, Li Y, Zhang Z H, Yu X, Tittel F K 2019 Opt. Express 27 14163Google Scholar

    [6]

    Spagnolo V, Dong L, Kosterev A A, Tittel F K 2012 Opt. Express 20 3401Google Scholar

    [7]

    Krzempek K, Dudzik G, Abramski K 2018 Opt. Express 26 28861Google Scholar

    [8]

    Qiao S D, Qu Y C, Ma Y F, He Y, Wang Y, Hu Y Q, Yu X, Zhang Z H, Tittel F K 2019 Sensors 19 4187Google Scholar

    [9]

    Bradshaw J L, Bruno J D, Lascola K M, Leavitt R P, Pham J T, Towner F J, Sonnenfroh D M, Parameswaran K R 2011 Proc. SPIE 8032 80320D

    [10]

    Ma Y F, He Y, Tong Y, Yu X, Tittel F K 2018 Opt. Express 26 32103Google Scholar

    [11]

    Bell A G 1880 Am. J. Sci. 20 305

    [12]

    Kosterev A A, Bakhirkin Y A, Curl R F, Tittel F K 2002 Opt. Lett. 27 1902Google Scholar

    [13]

    Liu K, Li J, Wang L, Tan T, Zhang W, Gao X. M, Chen W D, Tittel F K 2009 Appl. Phys. B 94 527Google Scholar

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    Ma Y F 2020 Front. Phys. 8 268Google Scholar

    [15]

    Giglio M, Patimisco P, Sampaolo A, Zifarelli A, Blanchard R, Pfluegl C, Witinski M F, Vakhshoori D, Tittel F K, Spagnolo V 2018 Appl. Phys. Lett. 113 171101Google Scholar

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    Ma Y F, Yu X, Yu G, Li X D, Zhang J B, Chen D Y, Sun R, Tittel F K 2015 Appl. Phys. Lett. 107 021106Google Scholar

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    Lassen M, Lamard L, Feng Y, Peremans A, Petersen J C 2016 Opt. Lett. 41 4118Google Scholar

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    [22]

    Petra, N, Zweck J, Kosterev A A, Minkoff S E, Thomazy D 2009 Appl. Phys. B 94 673Google Scholar

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    Patimisco P, Sampaolo A, Dong L, Tittel F K, Spagnolo V 2018 Appl. Phys. Rev. 5 011106Google Scholar

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    Patimisco P, Sampaolo A, Dong L, Giglio M, Scamarcio G, Tittel F K, Spagnolo V 2016 Sens. Actuators, B 227 539Google Scholar

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    [35]

    Li Y, Wang R Z, Tittel F K, Ma Y F 2020 Opt. Lasers Eng. 132 106155Google Scholar

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    Ma Y F, Lewicki R, Razeghi M, Tittel F K 2013 Opt. Express 21 1008Google Scholar

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    Wu H P, Sampaolo A, Dong L, Patimisco P, Liu X L, Zheng H D, Yin X K, Ma W G, Zhang L, Yin W B, Spagnolo V, Jia S T, Tittel F K 2015 Appl. Phys. Lett. 107 111104Google Scholar

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    He Y, Ma Y F, Tong Y, Yu X, Tittel F K 2018 Opt. Express 26 9666Google Scholar

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    Yi H M, Maamary R, Gao X M, Sigrist M W, Fertein E, Chen W D 2015 Appl. Phys. Lett. 106 101109Google Scholar

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    Borri S, Patimisco P, Sampaolo A, Beere H E, Ritchie D A, Vitiello M S, Scamarcio G, Spagnolo V 2013 Appl. Phys. Lett. 103 021105Google Scholar

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Metrics
  • Abstract views:  10866
  • PDF Downloads:  484
  • Cited By: 0
Publishing process
  • Received Date:  12 April 2021
  • Accepted Date:  05 May 2021
  • Available Online:  07 June 2021
  • Published Online:  20 August 2021

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