Phase structure and thermoelectric properties of Cu1.8–x Sbx S thermoelectric material

Zhao Ying-Hao; Zhang Rui; Zhang Bo-Ping; Yin Yang; Wang Ming-Jun; Liang Dou-Dou

doi:10.7498/aps.70.20201852

Abstract

Cu_1.8S-based materials have become potential thermoelectric materials due to their rich raw material reserves, low toxicity, and excellent electrical and thermal properties. In this study, a series of Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04) bulk materials is synthesized by using mechanical alloying combined with spark plasma sintering process. This preparation method can shorten the preparation cycle of materials, and effectively improve the research and development efficiency of thermoelectric (TE) materials due to its simple process. The effects of different Sb doping amounts on the structure, micromorphology, and thermoelectric transport properties of Cu_1.8–x Sb_x S phase are investigated. The results show that when 0 ≤ x < 0.02, the bulk samples are single-phase Cu_1.8S. With the further increase of Sb doping to 0.02 ≤ x ≤ 0.04, the second phase CuSbS₂ is formed when Sb content exceeds the solid solubility limit of x = 0.02 in Cu_1.8S, all Cu_1.8–x Sb_x S bulk samples exhibit p-type conductivity characteristics. Benefitting from the synergistic phonon scattering effect by multiscale defects, such as point defects (${\rm{Sb}}_{{\rm{Cu}}}^{ \bullet\bullet }$, $ {\rm{V}}_{\rm{S}}^{ \bullet \bullet } $), nanopores, secondary phases (CuSbS₂), and dislocations, the thermal conductivity κ declines significantly from 1.76 W·m^–1·K^–1 (x = 0) to 0.99 W·m^–1·K^–1 at 723 K for the Cu_1.76Sb_0.04S sample. Finally, the peak dimensionless TE figure of merit (ZT ) value of 0.37 is achieved at 723 K for Cu_1.77Sb_0.03S resulting from a low thermal conductivity of 1.11 W·m^–1·K^–1 combining an appropriate power factor of 563 μW·m^–1·K^–2, which is 12% higher than that (0.33) of pristine Cu_1.8S. Although the Sb doped Cu_1.8S-based samples have lower thermal conductivity κ, the reduced power factor cannot be offset by reducing the thermal conductivity κ, so the TE figure of merit (ZT ) value is not significantly improved. Therefore, there is still much room for improving the performance of Sb doped Cu_1.8S-based thermoelectric material, and its thermoelectric performance can be further optimized through nano-second phase recombination, energy band engineering, and introducing multi-scale defects, etc. Our results suggest that the introduction of Sb into thermoelectric materials is an effective and convenient strategy to improve ZT value by reducing thermal conductivity κ.

Keywords:

Authors and contacts

School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: Zhang Bo-Ping, bpzhang@ustb.edu.cn

Funds: Project supported by the National Key Research and Development Program of China (Grant No. 2018YFB0703600) and the National Natural Science Foundation of China (Grant No. 11474176)

FullText HTML : translate this paragraph

References

[1]	葛振华, 张波萍, 于昭新, 刘勇, 李敬锋 2012 61 048401 Google Scholar Ge Z H, Zhang B P, Yu Z X, Liu Y, Li J F 2012 Acta Phys. Sin. 61 048401 Google Scholar
[2]	赵立东, 张波萍, 李敬锋, 刘玮书, 周敏 2007 稀有金属材料与工程 36 408 Google Scholar Zhao L D, Zhang B P, Li J F, Liu W S, Zhou M 2007 Rare Metal Mat. Eng. 36 408 Google Scholar
[3]	张贺, 骆军, 朱航天, 刘泉林, 梁敬魁, 饶光辉 2012 61 086101 Google Scholar Zhang H, Luo J, Zhu H T, Liu Q Lin, Liang J K, Rao G H 2012 Acta Phys. Sin. 61 086101 Google Scholar
[4]	王作成, 李涵, 苏贤礼, 唐新峰 2011 60 027202 Google Scholar Wang Z C, Li H, Su X L, Tang X F 2011 Acta Phys. Sin. 60 027202 Google Scholar
[5]	Snyder G J, E S Toberer 2008 Nat. Mater. 7 105 Google Scholar
[6]	Francis J D 1999 Science 285 703 Google Scholar
[7]	He J, Tritt T M 2017 Science 357 k9997 Google Scholar
[8]	Tan G, Zhao L, Kanatzidis M G 2016 Chem. Rev. 116 12123 Google Scholar
[9]	Zhu T, Liu Y, Fu C, Heremans J P, Snyder J G, Zhao X 2017 Adv. Mater. 29 1605884 Google Scholar
[10]	Liu Z, Mao J, Liu T, Chen G, Ren Z 2018 MRS. Bull. 43 181 Google Scholar
[11]	Liu Z, Sun J, Mao J, Zhu H, Ren W, Zhou J, Wang Z, Singh D J, Sui J, Chu C, Ren Z 2018 Proc. Natl. Acad. Sci. U. S. A. 115 5332 Google Scholar
[12]	Wang L, Li J, Zhang C, Ding T, Xie Y, Li Y, Liu F, Ao W, Zhang C 2020 J. Mater. Chem. A 8 1660 Google Scholar
[13]	Qiu P F, Zhu Y Q, Qin Y T, Shi X, Chen L D 2016 APL Mater. 4 104805 Google Scholar
[14]	Zhao L, Wang X, Fei F Y, Wang J, Cheng Z, Dou S, Wang J, Snyder G J 2015 J. Mater. Chem. A 3 9432 Google Scholar
[15]	Ge Z, Zhang B, Chen Y, Yu Z, Liu Y, Li J 2011 Chem. Commun. 47 12697 Google Scholar
[16]	Dennler G, Chmielowski R, Jacob S, Capet F, Roussel P, Zastrow S, Nielsch K, Opahle I, Madsen G K H 2014 Adv. Energy Mater. 4 1301581 Google Scholar
[17]	Qin P, Qian X, Ge Z H, Zheng L, Feng J, Zhao L D 2017 Inog. Chem. Front. 4 1192 Google Scholar
[18]	Ge Z, Liu X, Feng D, Lin J, He J 2016 Adv. Energy Mater. 6 1600607 Google Scholar
[19]	Ge Z H, Chong X, Feng D, Zhang Y X, Qiu Y, Xie L, Guan P W, Feng J, He J 2019 Mater. Today Phys. 8 71 Google Scholar
[20]	Zou L, Zhang B, Ge Z, Gao C, Zhang D, Liu Y 2013 Phys. Status Solidi A. 210 2550 Google Scholar
[21]	Qin P, Ge Z, Feng J 2017 J. Alloys Compd. 696 782 Google Scholar
[22]	Yao Y, Zhang B, Pei J, Han Y, Zhou M 2016 Ceram. Int. 42 17518 Google Scholar
[23]	Liang D, Ge Z, Li H, Zhang B, Li F 2017 J. Alloys Compd. 708 169 Google Scholar
[24]	Ge Z, Zhang Y, Song D, Chong X, Qin P, Zheng F, Feng J, Zhao L 2018 J. Mater. Chem. A 6 14440 Google Scholar
[25]	Tang H, Zhuang H, Cai B, Asfandiyar A, Dong J, Sun F, Li J 2019 J. Mater. Chem. C 7 4026 Google Scholar
[26]	Bayikadi K S, Wu C T, Chen L, Chen K, Chou F, Sankar R 2020 J. Mater. Chem A 8 5332 Google Scholar
[27]	Chen T, Zhang K, Wang H, Su W, Mehmood F, Wang T, Zhai J, Wang X, Huo T, Wang C 2020 J. Mater. Chem. C 8 1679 Google Scholar
[28]	Zhao K, Qiu P, Song Q, Blichfeld A B, Eikeland E, Ren D, Ge B, Iversen B B, Shi X, Chen L 2017 Mater. Today Phys. 1 14 Google Scholar
[29]	Poudel B, Hao Q, Ma Y, Lan Y, Minnich A, Yu B, Yan X, Wang D, Muto A, Vashaee D, Chen X, Liu J, Dresselhaus M S, Chen G, Ren Z 2008 Science 320 634 Google Scholar
[30]	Li J, Zhang X, Chen Z, Lin S, Li W, Shen J, Witting I T, Faghaninia A, Chen Y, Jain A, Chen L, Snyder G J, Pei Y 2018 Joule 2 976 Google Scholar
[31]	Zhao L D, Wu H J, Hao S Q, Wu C I, Zhou X Y, Biswas K, He J Q, Hogan T P, Uher C, Wolverton C, Dravid V P, Kanatzidis M G 2013 Energy Environ. Sci. 6 3346 Google Scholar
[32]	Xu Q, Huang B, Zhao Y F, Yan Y F, Noufi R, Wei S H 2012 Appl. Phys. Lett. 100 061906 Google Scholar
[33]	Chakrabarti D J, Laughlin D E 1983 Bull. Alloy Phase Diagrams 4 254 Google Scholar
[34]	Tang C, Liang D, Li H, Luo K, Zhang B 2019 J. Adv. Ceram. 8 209 Google Scholar
[35]	Zhou Y, Ge Z, Gan G, Song P, Feng J 2019 Solid State Sci. 95 105953 Google Scholar
[36]	Zhang Y, Ma Z, Ge Z, Qin P, Zheng F, Feng J 2018 J. Alloys Compd. 764 738 Google Scholar
[37]	Qin P, Ge Z, Feng J 2017 J. Mater. Res. 32 3029 Google Scholar

Cited By

图 1 Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04)粉体样品的室温 XRD图谱(2θ = 20º−60º) (a)和(0 1 20)晶面放大峰(b)

Figure 1. XRD patterns of the Cu_1.8–x Sb_x S powder samples (x = 0, 0.005, 0.02, 0.03, 0.04) at 2θ range of 20°−60° (a) and the enlarged (0 1 20) peaks (b).

DownLoad: Full-Size Img PowerPoint

图 2 Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04)块体样品的XRD图谱　(a) 2θ = 20º−60º; (b) 2θ = 31º−33º

Figure 2. XRD patterns of the Cu_1.8–x Sb_x S bulk samples (x = 0.00, 0.005, 0.02, 0.03, 0.04) at 2θ range of 20º−60º (a) and 31º−33º (b).

DownLoad: Full-Size Img PowerPoint

图 3 Cu_1.8–x Sb_x S块体样品的晶粒尺寸分布及断口FESEM照, 其中x取值分别为(a) x = 0, (b) x = 0.005, (c) x = 0.02, (d) x = 0.03, (e) x = 0.04; (f) 密度和相对密度随x变化图

Figure 3. Grain size distributions of Cu_1.8–x Sb_x S bulks with FESEM images of the fractured surfaces in the inset at (a) x = 0.00, (b) x = 0.005, (c) x = 0.02, (d) x = 0.03, (e) x = 0.04; (f) density and relative density.

DownLoad: Full-Size Img PowerPoint

图 4 Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04)块体样品的电输运性能　(a) 电导率; (b) Seebeck系数; (c) 功率因子

Figure 4. Temperature dependence of electrical transport properties for Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04) bulks: (a) Electrical conductivity σ; (b) Seebeck coefficient α; (c) power factor PF.

DownLoad: Full-Size Img PowerPoint

图 5 Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04)块体样品的热输运性能　(a) 总热导率κ; (b) 洛伦兹常数L; (c) 电子热导率与总热导率的比值κ_e /κ

Figure 5. Temperature dependence of thermal transport properties for Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04) bulks: (a) Total thermal conductivity κ; (b) Lorenz number L; (c) the ratios of electronic thermal conductivity to total thermal conductivity (κ_e /κ).

DownLoad: Full-Size Img PowerPoint

图 6 (a) Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04)块体的ZT值; (b) 723 K时不同Cu_1.8S基材料的热电性能对比^{[18,21,34-37]}

Figure 6. (a) Temperature dependence of ZT for Cu_1.8–x Sb_x S (x = 0, 0.005, 0.02, 0.03, 0.04) bulks; (b) comparisons of thermoelectric properties of different Cu_1.8S-based materials at 723 K^{[18,21,34-37]}.

DownLoad: Full-Size Img PowerPoint

map

[1]	葛振华, 张波萍, 于昭新, 刘勇, 李敬锋 2012 61 048401 Google Scholar Ge Z H, Zhang B P, Yu Z X, Liu Y, Li J F 2012 Acta Phys. Sin. 61 048401 Google Scholar
[2]	赵立东, 张波萍, 李敬锋, 刘玮书, 周敏 2007 稀有金属材料与工程 36 408 Google Scholar Zhao L D, Zhang B P, Li J F, Liu W S, Zhou M 2007 Rare Metal Mat. Eng. 36 408 Google Scholar
[3]	张贺, 骆军, 朱航天, 刘泉林, 梁敬魁, 饶光辉 2012 61 086101 Google Scholar Zhang H, Luo J, Zhu H T, Liu Q Lin, Liang J K, Rao G H 2012 Acta Phys. Sin. 61 086101 Google Scholar
[4]	王作成, 李涵, 苏贤礼, 唐新峰 2011 60 027202 Google Scholar Wang Z C, Li H, Su X L, Tang X F 2011 Acta Phys. Sin. 60 027202 Google Scholar
[5]	Snyder G J, E S Toberer 2008 Nat. Mater. 7 105 Google Scholar
[6]	Francis J D 1999 Science 285 703 Google Scholar
[7]	He J, Tritt T M 2017 Science 357 k9997 Google Scholar
[8]	Tan G, Zhao L, Kanatzidis M G 2016 Chem. Rev. 116 12123 Google Scholar
[9]	Zhu T, Liu Y, Fu C, Heremans J P, Snyder J G, Zhao X 2017 Adv. Mater. 29 1605884 Google Scholar
[10]	Liu Z, Mao J, Liu T, Chen G, Ren Z 2018 MRS. Bull. 43 181 Google Scholar
[11]	Liu Z, Sun J, Mao J, Zhu H, Ren W, Zhou J, Wang Z, Singh D J, Sui J, Chu C, Ren Z 2018 Proc. Natl. Acad. Sci. U. S. A. 115 5332 Google Scholar
[12]	Wang L, Li J, Zhang C, Ding T, Xie Y, Li Y, Liu F, Ao W, Zhang C 2020 J. Mater. Chem. A 8 1660 Google Scholar
[13]	Qiu P F, Zhu Y Q, Qin Y T, Shi X, Chen L D 2016 APL Mater. 4 104805 Google Scholar
[14]	Zhao L, Wang X, Fei F Y, Wang J, Cheng Z, Dou S, Wang J, Snyder G J 2015 J. Mater. Chem. A 3 9432 Google Scholar
[15]	Ge Z, Zhang B, Chen Y, Yu Z, Liu Y, Li J 2011 Chem. Commun. 47 12697 Google Scholar
[16]	Dennler G, Chmielowski R, Jacob S, Capet F, Roussel P, Zastrow S, Nielsch K, Opahle I, Madsen G K H 2014 Adv. Energy Mater. 4 1301581 Google Scholar
[17]	Qin P, Qian X, Ge Z H, Zheng L, Feng J, Zhao L D 2017 Inog. Chem. Front. 4 1192 Google Scholar
[18]	Ge Z, Liu X, Feng D, Lin J, He J 2016 Adv. Energy Mater. 6 1600607 Google Scholar
[19]	Ge Z H, Chong X, Feng D, Zhang Y X, Qiu Y, Xie L, Guan P W, Feng J, He J 2019 Mater. Today Phys. 8 71 Google Scholar
[20]	Zou L, Zhang B, Ge Z, Gao C, Zhang D, Liu Y 2013 Phys. Status Solidi A. 210 2550 Google Scholar
[21]	Qin P, Ge Z, Feng J 2017 J. Alloys Compd. 696 782 Google Scholar
[22]	Yao Y, Zhang B, Pei J, Han Y, Zhou M 2016 Ceram. Int. 42 17518 Google Scholar
[23]	Liang D, Ge Z, Li H, Zhang B, Li F 2017 J. Alloys Compd. 708 169 Google Scholar
[24]	Ge Z, Zhang Y, Song D, Chong X, Qin P, Zheng F, Feng J, Zhao L 2018 J. Mater. Chem. A 6 14440 Google Scholar
[25]	Tang H, Zhuang H, Cai B, Asfandiyar A, Dong J, Sun F, Li J 2019 J. Mater. Chem. C 7 4026 Google Scholar
[26]	Bayikadi K S, Wu C T, Chen L, Chen K, Chou F, Sankar R 2020 J. Mater. Chem A 8 5332 Google Scholar
[27]	Chen T, Zhang K, Wang H, Su W, Mehmood F, Wang T, Zhai J, Wang X, Huo T, Wang C 2020 J. Mater. Chem. C 8 1679 Google Scholar
[28]	Zhao K, Qiu P, Song Q, Blichfeld A B, Eikeland E, Ren D, Ge B, Iversen B B, Shi X, Chen L 2017 Mater. Today Phys. 1 14 Google Scholar
[29]	Poudel B, Hao Q, Ma Y, Lan Y, Minnich A, Yu B, Yan X, Wang D, Muto A, Vashaee D, Chen X, Liu J, Dresselhaus M S, Chen G, Ren Z 2008 Science 320 634 Google Scholar
[30]	Li J, Zhang X, Chen Z, Lin S, Li W, Shen J, Witting I T, Faghaninia A, Chen Y, Jain A, Chen L, Snyder G J, Pei Y 2018 Joule 2 976 Google Scholar
[31]	Zhao L D, Wu H J, Hao S Q, Wu C I, Zhou X Y, Biswas K, He J Q, Hogan T P, Uher C, Wolverton C, Dravid V P, Kanatzidis M G 2013 Energy Environ. Sci. 6 3346 Google Scholar
[32]	Xu Q, Huang B, Zhao Y F, Yan Y F, Noufi R, Wei S H 2012 Appl. Phys. Lett. 100 061906 Google Scholar
[33]	Chakrabarti D J, Laughlin D E 1983 Bull. Alloy Phase Diagrams 4 254 Google Scholar
[34]	Tang C, Liang D, Li H, Luo K, Zhang B 2019 J. Adv. Ceram. 8 209 Google Scholar
[35]	Zhou Y, Ge Z, Gan G, Song P, Feng J 2019 Solid State Sci. 95 105953 Google Scholar
[36]	Zhang Y, Ma Z, Ge Z, Qin P, Zheng F, Feng J 2018 J. Alloys Compd. 764 738 Google Scholar
[37]	Qin P, Ge Z, Feng J 2017 J. Mater. Res. 32 3029 Google Scholar

[1]	He Jun-Song, Luo Feng, Wang Jian, Yang Shi-Guan, Zhai Li-Jun, Cheng Lin, Liu Hong-Xia, Zhang Yan, Li Yan-Li, Sun Zhi-Gang, Hu Ji-Fan. Thermoelectric properties of Co doped TiNiCo_xSn alloys fabricated by melt spinning. Acta Physica Sinica, 2024, 73(10): 107201. doi: 10.7498/aps.73.20240112
[2]	Huang Lu-Lu, Zhang Jian, Kong Yuan, Li Di, Xin Hong-Xing, Qin Xiao-Ying. Optimization of thermoelectric transport performance of nickel-doped CuGaTe₂. Acta Physica Sinica, 2021, 70(20): 207101. doi: 10.7498/aps.70.20211165
[3]	Huang Qing-Song, Duan Bo, Chen Gang, Ye Ze-Chang, Li Jiang, Li Guo-Dong, Zhai Peng-Cheng. Mn-In-Cu co-doping to optimize thermoelectric properties of SnTe-based materials. Acta Physica Sinica, 2021, 70(15): 157401. doi: 10.7498/aps.70.20202020
[4]	Guo Jing-Yun, Chen Shao-Ping, Fan Wen-Hao, Wang Ya-Ning, Wu Yu-Cheng. Improving interface properties of Te based thermoelectric materials and composite electrodes. Acta Physica Sinica, 2020, 69(14): 146801. doi: 10.7498/aps.69.20200436
[5]	Wang Tuo, Chen Hong-Yi, Qiu Peng-Fei, Shi Xun, Chen Li-Dong. Thermoelectric properties of Ag₂S superionic conductor with intrinsically low lattice thermal conductivity. Acta Physica Sinica, 2019, 68(9): 090201. doi: 10.7498/aps.68.20190073
[6]	Tao Ying, Qi Ning, Wang Bo, Chen Zhi-Quan, Tang Xin-Feng. Microstructure and thermoelectric properties of In2O3/poly(3, 4-ethylenedioxythiophene) composites. Acta Physica Sinica, 2018, 67(19): 197201. doi: 10.7498/aps.67.20180382
[7]	Wu Zi-Hua, Xie Hua-Qing, Zeng Qing-Feng. Preparation and thermoelectric properties of Ag-ZnO nanocomposites synthesized by means of sol-gel. Acta Physica Sinica, 2013, 62(9): 097301. doi: 10.7498/aps.62.097301
[8]	Li Xiao-Na, Zhang Xin, Zhang Jiu-Xing, Bao Li-Hong, Zhang Ning, Zhang Fan-Xing. Synthesis and properties of multiple boride Pr1-xCexB6 cathodes by reactive spark plasma sintering. Acta Physica Sinica, 2012, 61(22): 228104. doi: 10.7498/aps.61.228104
[9]	Huo Feng-Ping, Wu Rong-Gui, Xu Gui-Ying, Niu Si-Tong. Thermoelectric properties of (AgSbTe2)100-x (GeTe)x fabricated by hot pressing method. Acta Physica Sinica, 2012, 61(8): 087202. doi: 10.7498/aps.61.087202
[10]	Ge Zhen-Hua, Zhang Bo-Ping, Yu Zhao-Xin, Liu Yong, Li Jing-Feng. Effects of mechanical alloying process on thermoelectric properties of Bi2S3 Bulk. Acta Physica Sinica, 2012, 61(4): 048401. doi: 10.7498/aps.61.048401
[11]	Fan Ping, Zheng Zhuang-Hao, Liang Guang-Xing, Zhang Dong-Ping, Cai Xing-Min. Preparation and characterization of Sb2Te3 thermoelectric thin films by ion beam sputtering. Acta Physica Sinica, 2010, 59(2): 1243-1247. doi: 10.7498/aps.59.1243
[12]	Ren Rong, Wu Yu-Cheng, Tang Wen-Ming, Wang Feng-Tao, Zheng Zhi-Xiang. Structural evolution and grain growth kinetics of the mechanically alloyed Fe42.5Al42.5Ti5B10 induced by annealing. Acta Physica Sinica, 2008, 57(9): 5774-5781. doi: 10.7498/aps.57.5774
[13]	Zhang Xin, Li Jia, Lu Qing-Mei, Zhang Jiu-Xing, Liu Yan-Qin. Mechanical alloying synthesis of (Bi1-xAgx)2(Te1-ySey)3 powder and thermoelectric properties of its bulk materials prepared by spark plasma sintering. Acta Physica Sinica, 2008, 57(7): 4466-4470. doi: 10.7498/aps.57.4466
[14]	Yan Yong-Gao, Tang Xin-Feng, Liu Hai-Jun, Yin Ling-Ling, Zhang Qing-Jie. Thermoelectric properties of nonstoichiometric Ag1－xPb18SbTe20 materials. Acta Physica Sinica, 2007, 56(6): 3473-3478. doi: 10.7498/aps.56.3473
[15]	Jiang Jun, Li Ya-Li, Xu Gao-Jie, Cui Ping, Wu Ting, Chen Li-Dong, Wang Gang. Effect of preparation methods on thermoelectric properties of p-type Bi2Te3-based materials. Acta Physica Sinica, 2007, 56(5): 2858-2862. doi: 10.7498/aps.56.2858
[16]	Liu Wei-Shu, Zhang Bo-Ping, Li Jing-Feng, Liu Jing. Thermodynamic explanation of solid-state reactions in synthesis process of CoSb3 via mechanical alloying. Acta Physica Sinica, 2006, 55(1): 465-471. doi: 10.7498/aps.55.465
[17]	Hu Jian-Min, Xin Jiang-Bo, Lü Qiang, Wang Yue-Yuan, Rong Jian-Ying. Powders (Sb2Te3)0.75(1－x)(Bi2Te3)0.25(1－x)(Sb2Se3)x prepared by mechanical alloying and thermoelectric properties of cold-pressed and s. Acta Physica Sinica, 2006, 55(9): 4843-4848. doi: 10.7498/aps.55.4843
[18]	Yan Wen-Sheng, Yin Shi-Long, Fan Jiang-Wei, Li Yu-Zhi, Liu Wen-Han, Hao Lu-Yuan, Pan Zhi-Yun, Wei Shi-Qiang. Structural transition of Fe80Cu20 alloy induced by annealing. Acta Physica Sinica, 2005, 54(12): 5707-5712. doi: 10.7498/aps.54.5707
[19]	Fan Jiang-Wei, Bian Qing, Yin Shi-Long, Yan Wen-Sheng, Liu Wen-Han, Wei Shi-Qiang. X-ray absorption fine structure and x-ray diffraction studies on structures of Fe70Cu30 alloys affected by mechanical alloying. Acta Physica Sinica, 2004, 53(2): 514-520. doi: 10.7498/aps.53.514
[20]	YAN WEN-SHENG, FAN JIANG-WEI, LI YU-ZHI, CUI HONG-BIN, LIU WEN-HAN, ZHANG XIN-YI, WEI SHI-QIANG. LOCAL STRUCTURES OF MECHANICALLY ALLOYED Fe100-xCux SOLID SOLUTIONS STUDIED BY X-RAY ABSORPTION FINE STRUCTURE. Acta Physica Sinica, 2001, 50(4): 758-764. doi: 10.7498/aps.50.758

Catalog

Vol. 70, Issue 12 - 2021-06-20

Metrics

Abstract views: 4826
PDF Downloads: 108
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板