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Recent progress in polarization-sensitive photodetectors based on low-dimensional semiconductors

Wei Zhong-Ming ,  Xia Jian-Bai

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Recent progress in polarization-sensitive photodetectors based on low-dimensional semiconductors

Wei Zhong-Ming, Xia Jian-Bai
Acta Phys. Sin., 2019, 68(16): 163201.
doi: 10.7498/aps.68.20191002
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  • Abstract

    Polarized photodetection technology has good application value in the fields of remote sensing imaging, environmental monitoring, medical detection and military equipment. Polarized photodetectors based on low-dimensional materials can use the natural anisotropy of materials to detect polarized information. Some two-dimensional materials have strong in-plane anisotropy due to their low-symmetrical crystal structure, such as black-phosphorus, black-arsenic, ReS2, GaTe, GeSe, GeAs, and TiS3. These anisotropic two-dimensional materials are appropriate for the working medium of polarized photodetectors. Numerous researchs focused on polarized photodetectors with different materials and device structures and our works are introduced. Polarized photodetectors based on such low-dimensional materials have realized a broadband photodetection, including ultraviolet, visible, and infrared lights.

    Authors and contacts

    • State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, China

      • Corresponding author: Wei Zhong-Ming, zmwei@semi.ac.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant No. 61622406).

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  • 图 1  黑磷的特性[50]　(a)原子结构; (b)典型的偏振拉曼光谱; (c)三层黑磷的能带结构和理论计算的各向异性吸收

    Figure 1.  Characteristics of black-phosphorus[50](Reproduced with permission, Copyright 2016, American Chemical Society): (a) Atomic structure; (b) typical polarized Raman spectra; (c) band structure of trilayer black-phosphorus and theoretical polarized absorption

    DownLoad: Full-Size Img PowerPoint

    图 2  (a)圆形电极的偏振光探测器的显微镜照片[52]; (b) 沿扶手和锯齿方向400−1700 nm波长范围内黑磷的偏振光电流响应[52]; (c) 黑磷/MoS2异质结偏振光探测器[54]; (d)等离激元修饰的黑磷偏振光探测器[29]

    Figure 2.  (a) Optical image of the polarized-light detector with the circular electrode, (b) polarized photoresponse along armchair and zigzag orientations under 400−1700 nm illumination of black-phosphorus (reproduced with permission[52], Copyright 2015, Springer Nature); (c) polarized-light detector based on the black-phosphorus/MoS2 heterojunction(reproduced with permission[54], Copyright 2018, Springer Nature); (d) polarized-light detectorenhanced by the plasmonic structure(reproduced with permission[29], Copyright 2018, American Chemical Society).

    DownLoad: Full-Size Img PowerPoint

    图 3  原子结构　(a) ReS2[32]; (b) WTe2[71]

    Figure 3.  Crystal structures: (a) ReS2(reproduced with permission[32], Copyright 2015, American Chemical Society); (b) WTe2(reproduced with permission[71], Copyright 2016, RSC Publishing).

    DownLoad: Full-Size Img PowerPoint

    图 4  (a)偏振光电测试示意图[34]; (b) 极坐标下ReS2的偏振光吸收和光电流[33]; (c) ReS2/ReSe2异质结偏振光响应[79]; (d) WTe2偏振光探测性能[35]

    Figure 4.  (a) Schematic of polarized photoelectric test(reproduced with permission[34], Copyright 2016, American Chemical Society); (b) photocurrent and absorption of ReS2 in the polar coordinates(Reproduced with permission[33], Copyright 2016, John Wiley and Sons); (c) polarized photoresponse of ReS2/ReSe2 heterojunction(reproduced with permission[79], Copyright 2018, John Wiley and Sons); (d) polarized photoresponse of WTe2(reproduced with permission[35], Copyright 2018, John Wiley and Sons).

    DownLoad: Full-Size Img PowerPoint

    图 5  (a) GaTe的晶体结构[80]; (b) TlSe的STEM图像[37]; (c) 基于TlSe的偏振光探测器的角分辨光电流[37]

    Figure 5.  (a) Crystal structure of GaTe(reproduced with permission[80], Copyright 2016, American Chemical Society); (b) STEM image of TlSe and (c) photocurrent of the polarized photodetector based on TlSe (reproduced with permission[37], Copyright 2018, American Chemical Society).

    DownLoad: Full-Size Img PowerPoint

    图 6  (a) MX晶体的原子结构[83]; (b) GeS2晶体的原子结构[41]; (c) SnS沿不同方向的光电流响应速度[38]; (d) GeSe2对450 nm偏振光响应[42]

    Figure 6.  (a) Crystal structure of MX (reproduced with permission[83], Copyright 2015, AIP Publishing); (b) crystal structure of GeS2(reproduced with permission[41], Copyright 2019, John Wiley and Sons); (c) response times of SnS along different directions(reproduced with permission[38], Copyright 2017, Royal Society of Chemistry); (d) polarized photocurrent of GeSe2 under the 450 nm illumination(reproduced with permission[42], Copyright 2018, American Chemical Society).

    DownLoad: Full-Size Img PowerPoint

    图 7  (a) GeAs, SiAs, GeP和SiP的晶体结构; (b) GeAs2的晶体结构[45]

    Figure 7.  (a) Crystal structures of GeAs, SiAs, GeP, and Si; (b) crystal structures of GeAs2 (reproduced with permission[45], Copyright 2018, John Wiley and Sons).

    DownLoad: Full-Size Img PowerPoint

    图 8  (a) ZrS3的光学图像[46]; (b) ZrS3的晶体结构[46]; (c) KP15原子结构示意图[99]

    Figure 8.  (a) Optical image of ZrS3 and (b) crystal structure of ZrS3(reproduced with permission[46], Copyright 2019, John Wiley and Sons); (c) crystal structure of KP15(reproduced with permission[99], Copyright 2018, American Chemical Society).

    DownLoad: Full-Size Img PowerPoint

    图 9  (a) GeSe的偏振光吸收谱[40]; (b) 不同方向的偏振光下准一维ZrS3纳米带的吸收光谱[46]; (c)准一维ZrS3纳米带在450 nm和532 nm的激光下的偏振光电流[46]

    Figure 9.  (a) Polarization-resolved absorption spectra of GeSe(reproduced with permission[40], Copyright 2017, American Chemical Society); (b) absorption spectra of ZrS3 nanoribbon under polarized light in different directions and (c) polarized photocurrent of ZrS3 nanoribbon under 450 nm and 532 nm laser illumination(reproduced with permission[46], Copyright 2019, John Wiley and Sons).

    DownLoad: Full-Size Img PowerPoint

    图 10  (a) GeSe对808 nm光照的偏振光电流[40]; (b) GeAs偏振光吸收光谱图[43]; (c) GeAs在520 nm和830 nm偏振光照射下的光响应极坐标图[43]; (d) GeAs 30 mV栅压下角度依赖的空间分辨光响应分布图[43]

    Figure 10.  (a) Polarized photocurrent of GeSe under the 808 nm laser illumination(reproduced with permission[40], Copyright 2017, American Chemical Society); (b) polarization-resolved absorption spectra of GeAs, (c) polarization-sensitive photocurrents plotted with the linear-polarization laser of 520 and 830 nm of GeAs in the polar coordinates, and (d) polarization-dependent photocurrent mapping of GeAs device under 30 mV gate voltage and the linear-polarization laser (reproduced with permission[43], Copyright 2018, American Chemical Society).

    DownLoad: Full-Size Img PowerPoint

    表 1  低维半导体材料的各向异性光电性能

    Table 1.  Anisotropic optoelectronic properties of low-dimensional semiconductors.

    禁带宽度/eV载流子迁移率/cm2·V–1·s–1光响应强度二向色性比值参考文献
    黑磷0.3 (体材料)
    1.5 (单层)    		1000 (空穴, x)600 (空穴, y)14.2 mA/W8.7 (1550 nm)[29]
    黑砷0.3 (体材料)1—
    1.5 (单层)    		376.7 (电子, zigzag)1.5 (电子, armchair)
    60.7 (空穴, zigzag)10606 (空穴, armchair)    		[14,30]
    锑烯1.3—1.7100 (3.2 eV)[31]
    ReS21.4 (体材料)23.1 (电子, DS-chains方向)14.8 (电子, 垂直DS-chains方向)103 A·W–1 (532 nm)~ 4[32,33]
    ReSe21.17—1.2101.5 mA·W–1 (633 nm)2 (633 nm)[34]
    MoTe2外尔半金属110 mA·W–1 (1064 nm)[10]
    WTe2外尔半金属4.9 (514.5 nm)[35]
    GaTe1.70.2 (空穴)104 A·W–1 (532 nm)[36]
    TlSe0.731.48 A·W–1 (633 nm)2.56 (633 nm)[37]
    SnS1.320 (zisgzag)μzigzag/μarmchair ≈ 1.7365 A·W–1 (808 nm)1.49 (808 nm)[38,39]
    GeSe1.34 (体材料)
    1.7 (单层)    		4.25 A·W–12.16 (808 nm)[40]
    GeS2> 32.1 (325 nm)[41]
    GeSe22.743.4 (450 nm)[42]
    GeAs0.83 (体材料)
    2.07 (单层)    		4.4 (808 nm)[43]
    GeP0.51 (体材料)
    1.68 (单层)    		电导率比值: 1.523.11—0.43 A·W–11.83 (532 nm)[44]
    GeAs20.98 (体材料)
    1.62 (单层)    		2.5 (空穴, a)1.3 (空穴, b)2[45]
    ZrS31.79 (体材料)230 m A·W–1 (520 nm)2.55 (520 nm)[46]
    TiS31.132500 A·W–1 (808 nm)4[47]
    α-MoO32.70.06–0.09 (电子, b)0.03—0.04 (电子, c)67.9 A·W–15 (254 nm)[12]
    DownLoad: CSV
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  • Received Date:  29 June 2019
  • Accepted Date:  12 August 2019
  • Available Online:  19 August 2019
  • Published Online:  20 August 2019

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