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以石墨烯和氮化硼为代表的二维材料为研究低维体系热传导及其相关界面热阻提供了一个绝佳的平台. 近年的研究表明, 二维材料热导率有着丰富的物理图像, 如长度效应、维度效应、同位素效应及各向异性等. 本文详细综述近十年来二维材料在热传导方面的研究进展. 首先简述二维材料热传导测量技术的原理及发展, 如热桥法、电子束自加热法、时域热反射法及拉曼法等; 其次, 介绍二维材料热传导及界面热阻的实验研究进展, 讨论其相关物理问题; 最后, 介绍二维材料在散热应用方面的研究进展, 并进行总结、指出存在的问题及进一步展望二维材料未来在散热领域的研究方向与前景.The two-dimensional (2D) materials represented by graphene and boron nitride provide an excellent platform for the study of thermal conduction and the interfacial thermal resistance in low-dimensional system. Recent studies recover exotic physics behind the novel thermal transport properties of 2D materials, such as length effect, dimensional effect, isotopic effect, anisotropic effect, etc. In this review, we introduce the recent progress of thermal properties in 2D materials in the last decade. The principle and development of thermal conduction measurement technologies used in 2D materials are introduced, followed by the experimental progress of thermal conduction and interfacial thermal resistance. Special attention is paid to the abnormal thermal transport and relevant physical problems. Finally, we present thermal management and heat dissipation in 2D electronic devices, summarize and point out the problems and bottlenecks, and forecast the future research directions and foregrounds.
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Keywords:
- thermal conductivity /
- two-dimensional materials /
- interfacial thermal resistance /
- micro/nano-scale thermal conduction
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图 1 (a)热桥器件示意图; (b)器件热流图; (c)接触热阻对测量的影响; (d)和(e)悬空热桥法改良——比较器法示意图及改良前(黑色实线)和改良后(红色及蓝色)系统温漂随时间变化关系[39]
Fig. 1. (a), (b) Sketch and heat flow of thermal bridge device; (c) influence of thermal contact resistance; (d), (e) diagram of modified comparator method and temperature drift of experimental system[39].
图 3 (a) 拉曼法测量原理图; (b) (c) 单层悬空石墨烯拉曼G峰频率与温度以及激光能量的关系[31,61]; (d) 双拉曼法示意图[67]; (e) ET-Raman法示意图[70]
Fig. 3. (a) Sketch of the Raman method; (b), (c) experimental data for the Raman G peak shift with respect to temperature and laser power[31,61]; (d), (e) sketch of the Two-Raman method[67] and ET-Raman method[70].
图 4 (a)时域热反射法测量系统; (b)经正弦调制的飞秒脉冲激光、材料表面温度响应、锁相放大器所输出的同相信号和反相信号与延迟时间之间的关系; (c)采用时域热反射法测量GaN热导率及Al/GaN界面热导[33]
Fig. 4. (a) Experimental setup of the TDTR method; (b) femtosecond pulse laser with sinusoidal modulation, temperature response of sample surface, the in-phase signal and out-of-phase signal of Lock-in Amplifier versus delay-time; (c) using TDTR method to measure thermal conductivity of GaN and interface thermal conductance of Al/GaN[33].
图 8 (a) 室温下单层悬空石墨烯中声子平均自由程[104]; (b), (c)理论及实验上单层悬空石墨烯室温热导率随长度变化[17,102,175,176]; (d)实验上不同宽度的单层石墨烯悬空热导率随温度变化[17,98,177-180]
Fig. 8. Single-layer suspended graphene (a) the mean free path at room temperature[104]; (b), (c) length-dependent thermal conductivity in theory and experiment respectively[17,102,175,176]; (d) width-dependent thermal conductivity in experiment[17,98,177-180].
图 10 (a) 石墨烯(悬空/衬底)面内热导率的厚度效应[64,103,110,196,197]; (b) 四层氮化硼悬空热导率与温度之间的关系[44]; (c) 氮化硼(悬空)面内热导率的厚度效应[41,44,56,120,198]; (d) 硫化钼(悬空)面内热导率的厚度效应[18]
Fig. 10. (a) Thickness-dependent in-plane thermal conductivity of graphene (suspended and supported) [64,103,110,196,197]; (b) thermal conductivity of four-layers h-BN (suspended) versus temperature[44]; (c) thickness-dependent in-plane thermal conductivity of h-BN (suspended) [41,44,56,120,198]; (d) thickness-dependent in-plane thermal conductivity of MoS2 (suspended)[18].
图 13 悬空石墨烯面内热导率 (a) 同位素效应[202]; (b) 晶粒尺寸的影响[205]; (c) 晶界夹角的影响[207]; (d) 空位率的影响[208]
Fig. 13. In-plane thermal conductivity of suspended graphene: (a) Isotope effect[202]; (b) influence of grain size[205]; (c) influence of misorientation angle between grains[207]; (d) influence of vacancy ratio[208].
图 15 微纳尺度热二极管设计原理 (a) 热导率随温度变化趋势不同; (b) 声子透射率不对称[219]; 非对称结构悬空石墨烯[224] (c)SEM图; (d) 热二极管实验结果
Fig. 15. Design principle of thermal diode in micro/nano-scale: (a) Different tendency between thermal conductivity and temperature; (b) asymmetric phonon transmission ratio[219]; asymmetric structure of suspended graphene[224] (c) SEM image; (b) the experiment result of thermal diode.
图 16 (a) 氮化硼厚度对金属/氮化硼/氧化硅界面热阻的影响[234]; (b)利用3ω法测量不同方法制备的氮化硼对硒化钨器件的界面热阻的影响[250]; (c)在界面处引入化学键对金属/单层石墨烯/氧化硅界面热导的影响[256]; (d) 在界面处加电压对氧化硅/多层石墨烯/氧化硅界面热阻的影响[257]
Fig. 16. (a) Thickness-depend interfacial thermal resistance of metal/h-BN/SiO2[234]; (b) interfacial thermal resistance of WSe2 device with h-BN prepared by different method[250]; (c) improving interfacial thermal resistance of Al/single-layer graphene/SiO2 by introducing chemical bond[256]; (d) the influence of voltage at interface to interfacial thermal resistance of SiO2/graphene/ SiO2[257].
图 19 氮化硼对硒化钨以及硫化钼器件中温度分布的影响[250]: (a)−(d) SThM温度扫描图; (e)器件边界处温度变化图; (f)器件中温度分布柱状统计图
Fig. 19. Effect of h-BN on temperature distribution in WSe2 and MoSe2 devices [250]: (a)−(d) Temperature scanned by SThM; (e) temperature variation at device boundary; (f) histogram of temperature distribution in devices.
表 1 不同文献中测量悬空石墨烯热导率实验细节
Table 1. Experimental detail of thermal conductivity in suspended single/few-layer graphene from different literature.
制备方式 石墨烯层数 热导率 κ /W·(m·K)–1 备注 拉曼法 机械剥离[31] 1层 ~4840—5300 (室温) 数值高估, 见本节文字部分 机械剥离[97] 1层 ~3080—5150 (室温) 化学气相沉积[66] 1层 ~2500 +1100/–1050 (T = 350 K) / 化学气相沉积[66] 1层 ~1400 +500/–480 (T = 500 K) / 化学气相沉积[98] 1层 ~2600 — 3100 (T = 350 K) / 机械剥离[63] 1层 ~630 (T = 660 K) / 机械剥离[99] 1层 ~1800 (T = 325 K) / 机械剥离[99] 1层 ~710 (T = 500 K) / 化学气相沉积[69] 1层 ~850—1100 (T = 303—644 K) / 机械剥离[69] 1层 ~1500 (T = 330—445 K) / 机械剥离[69] 2层 ~970 (T = 303—630 K) / 悬空热桥法 化学气相沉积[100] 1层 ~190(T = 280 K, L = 0.5 μm) / 化学气相沉积[43] 2层 ~560—620(室温, L = 5 μm) / 化学气相沉积[17] 1层 ~1689—1831(T = 300 K, L = 9 μm) / SThM 化学气相沉积[85] 1层 ~2100—2430(T = 335 K) / 表 2 不同实验中悬空单层/多层h-BN热导率实验测量细节表
Table 2. Experimental detail of thermal conductivity of suspended single/few-layer h-BN in different literature.
表 3 不同文献中硫化钼单层/多层热导率实验测量细节表
Table 3. Experimental detail of thermal conductivity of single/few-layer MoS2 in different literature.
制备方式 硫化钼薄膜层数 测量方法 热导率 (300 K/室温) κ /(W·(m·K)–1) 悬空 化学气相沉积[59] 11层 拉曼法 ~52 机械剥离[60] 1层 拉曼法 34.5 ± 4 机械剥离[126] 4层 热桥法 ~44—45 机械剥离[126] 7层 热桥法 ~48—52 机械剥离[127] 1层 拉曼法 84 ± 17 机械剥离[127] 2层 拉曼法 77 ± 25 机械剥离[54] 4层 电子束自加热 34 ± 6 机械剥离[54] 5层 电子束自加热 30 ± 3 化学气相沉积[128] 1层 拉曼法 13.3 ± 1.4 化学气相沉积[128] 2层 拉曼法 15.6 ± 1.5 化学气相沉积[47] 1层 热桥法 ~21—24 化学气相沉积[18] 1层 拉曼法 60.3 ± 5.2 化学气相沉积[18] 2层 拉曼法 38.4 ± 3.1 化学气相沉积[18] 3层 拉曼法 44.8 ± 5.9 化学气相沉积[18] 4层 拉曼法 36.9 ± 4.9 衬底 机械剥离[129] 1层 拉曼法 ~62.2 机械剥离[65] 4层 拉曼法 60.3 ± 5 表 4 除硫化钼外, 其他单层/多层过渡金属硫化物的悬空热导率实验测量细节表
Table 4. Experimental detail of thermal conductivity of single/few-layer transition metal sulfide (expect MoS2) in different literature.
制备方式 薄膜层数 测量方法 热导率 (300 K/室温) κ/(W·(m·K)–1) 硒化钼 机械剥离[127] 1层 拉曼法 59 ± 18 机械剥离[127] 2层 拉曼法 42 ± 13 机械剥离[70] 45 nm 拉曼法 11.1 ± 0.4 机械剥离[70] 140 nm 拉曼法 20.3 ± 0.9 机械剥离[132] 5 nm 拉曼法 6.2 ± 0.9 机械剥离[132] 36 nm 拉曼法 10.8 ± 1.7 硒化钽 机械剥离[133] 45 nm 拉曼法 ~9 机械剥离[133] 55 nm 拉曼法 ~11 硫化钨 化学气相沉积[134] 1层 拉曼法 ~32 化学气相沉积[134] 2层 拉曼法 ~53 化学气相沉积[18] 1层 拉曼法 74.8 ± 17.2 硒化钨 化学气相沉积[18] 1层 拉曼法 66 ± 20.9 碲化钨 机械剥离[135] 220 nm TDTR ~2 机械剥离[136] 11.2 nm 拉曼 ~0.639—0.743 硫化铼 机械剥离[137] 150 nm TDTR ~50—70 表 5 常见二维材料的界面热导实验测量值
Table 5. Experimental results of interfacial thermal conductance of two-dimensional materials.
界面结构 室温界面热导 界面结构 室温界面热导 Gint/MW·(m2·K)–1 Gint/MW·(m2·K)–1 石墨烯 (G) G/h-BN[235] ~17 MoS2/h-BN[236] ~52.2 SiO2/G/SiO2[237] ~83—179 硫化钼 (MoS2)、硒化钼 (MoSe2) G/SiO2[238] ~50 G/Al2O3[239] ~17 MoS2/SiO2 or AlN[240] ~15 Au/Ti/G/SiO2[241] ~25 MoS2/Au[127] ~0.44—0.74 Au/Ti/G/SiO2[196] ~20 MoS2/SiO2[129] ~1.94 Al/G/Si[242] ~62—65 MoS2/SiO2[243] ~14 Al/G/SiO2[242] ~21—24 MoS2/SiO2[244] ~21 Au/Ti/G/sapphire[245] ~33.5 MoSe2/SiO2[127] ~0.09—0.13 Au/Ti/G/diamond[245] ~6.2 MoSe2/SiO2[243] ~2 G/Au[76] ~23 黑磷 (BP) G/Al[76] ~27 G/Ti[76] ~31 BP/SiOX[246] ~21.7—114 G/Au[66] ~18.8—44 BP/SiOX[247] ~202—60 氮化硼 (h-BN) 硒化钨 (WSe2) h-BN/SiO2/Si[248] ~8.3 WSe2/Si/SiO2[249] ~10—32 Metal/h-BN/SiO2[234] ~29—63 WSe2/SiO2[250] ~22 -
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