Syntheses of negative thermal expansion materials Sc2(MO4)3 (M=W, Mo) with a CO2 laser and their Raman spectra

Liang Yuan; Xing Huai-Zhong; Chao Ming-Ju; Liang Er-Jun

doi:10.7498/aps.63.248106

Abstract

Negative thermal expansion materials Sc2(MO4)3 (M={W}, Mo) are synthesized with a CO2 laser. It is shown that the synthesis of Sc2(WO4)3 or Sc2(MoO4)3 by laser sintering is a rapid process so that a sample can be synthesized within a few or tens of seconds and has the characteristic of rapid solidification. X-ray diffraction and Raman spectrum analyses demonstrate that the synthesized Sc2(MO4)3 (M={W}, Mo) are crystallized into orthorhombic structures and each have a high purity. Temperature dependent Raman spectrum analysis suggests that the synthesized samples do not have phase transitions above room temperature but possibly have weak hygroscopicities. According to the Raman analyses of MoO3, WO3, Sc2(MoO4)3, and Sc2(WO4)3, we draw a diagram describing their phonon energy levels and the photon energy of the laser, and then assess the mechanism of the synthesis by laser sintering. Transferring the laser photon energy to phonon energy is the channel of light-heat converting. The materials react in the molten pool and are solidified rapidly, forming the final products.

Keywords:

Authors and contacts

1.
College of Science, Donghua University, Shanghai 201620, China;
2.
Key Laboratory of Materials Physics of Ministry of Education, School of Physical Science and Engineering, Zhengzhou University, Zhengzhou 450052, China
Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 11104252, 11405028), the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20114101110003), the Fund for Science and Technology Innovation Team of Zhengzhou City, China (Grant No. 112PCXTD337), and the Fundamental Research Fund for the Central Universities, China.

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[32]	Li F, Liu X S, Song W B, Yuan B H, Cheng Y G, Yuan H L, Cheng F X, Chao M J, Liang E J 2014 J. Solid State Chem. 218 15
[33]	Song W B, Liang E J, Liu X S, Li Z Y, Yuan B H, Wang J Q 2013 Chin. Phys. Lett. 30 126502
[34]	Marinkovic B A, Jardim P M, Ari M, Avillez R R, Rizzo F, Ferreira F F 2008 Phys. Stat. Sol. B 245 2514
[35]	Liu X S, Cheng F X, Wang J Q, Song W B, Yuan B H, Liang E J 2013 J. Alloy. Comp. 553 1
[36]	Yan X, Li M, Li J, Cheng X 2011 Appl. Mechan. Mater. 66-68 1808
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[38]	Sumithra S, Umarji A M 2006 Solid State Sci. 8 1453
[39]	Evans J S O, Mary T A, Sleight A W 1998 J. Solid State Chem. 137 148
[40]	Evans J S O, Mary T A 2000 Inter. J. Inorg. Mater. 2 143
[41]	Liang E J, Huo H L, Wang Z, Chao M J, Wang J P 2009 Solid State Sci. 11 139
[42]	Liang E J, Wang J P, Xu E M, Du Z Y, Chao M J 2008 J. Raman Spectrosc. 39 887
[43]	Liang E J, Wu T A, Yuan B, Chao M J, Zhang W F 2007 J. Phys. D: Appl. Phys. 40 3219
[44]	Zhang J, Yuan C, Wang J Q, Liang E J, Chao M J 2013 Chin. Phys. B 22 087201
[45]	Paraguassu W, Maczka M, Souza Filho A G, Freire P T C, Melo F E A, Mendes Filho J, Hanuza J 2007 J. Vibr. Spectrosc. 44 69
[46]	Liang E J, Huo H L, Wang J P, Chao M J 2008 J. Phys. Chem. C 112 6577
[47]	Li Q J, Yuan B H, Song W B, Liang E J, Yuan B 2012 Chin. Phys. B 21 046501
[48]	Song W B, Yuan C, Li Z Y, Zhao Y, Jiang Y J, Liang E J 2011 J. Light Scatter. 23 346 (in Chinese) [宋文博, 袁超, 李志远, 赵艳, 蒋毅坚, 梁二军 2011 光散射学报 23 346]

Cited By

[1]	Mary T A, Evans J S O, Vogt T, Sleight A W 1996 Science 272 90
[2]	Liang Y, Zhou H Y, Liang E J, Yuan B, Chao M J 2008 Chin. J. Inorg. Chem. 24 1551 (in Chinese) [梁源, 周鸿颖, 梁二军, 袁斌, 晁明举 2008 无机化学学报 24 1551]
[3]	Miller W, Smith C W, Mackenzie D S, Evans K E 2009 J. Mater. Sci. 44 5441
[4]	Liang E J 2010 Rec. Pat. Mater. Sci. 3 106
[5]	Lind C, Coleman M R, Kozy L C, Sharma G R 2011 Phys. Status Solidi B 248 123
[6]	Liang E J, Liang Y, Zhao Y, Liu J, Jiang Y J 2008 J. Phys. Chem. A 112 12582
[7]	Liang E J, Wang S H, Wu T A 2007 J. Raman Spectrosc. 38 1186
[8]	Guo X Y, Cheng C X, Zhang J, Liang E J 2011 J. Light Scatter. 23 228 (in Chinese) [郭向阳, 程春晓, 张洁, 梁二军 2011 光散射学报 23 228]
[9]	Sahoo P P, Sumithra S, Madras G, Guru Row T N 2011 Inorg. Chem. 50 8774
[10]	Yuan H L, Yuan B H, Li F, Liang E J 2012 Acta Phys. Sin. 61 226502 (in Chinese) [袁焕丽, 袁保合, 李芳, 梁二军 2012 61 226502]
[11]	Guzman-Afonso C, Gonzalez-Silgo C, Gonzalez-Platas J, Torres M E, Lozano-Gorrin A D, Sabalisck N, Sanchez-Fajardo V, Campo J, Rodriguez-Carvajal J 2011 J. Phys. Condens. Matter 23 325402
[12]	Marinkovic B A, Jardim P M, De Avillez R R, Rizzo F 2005 Solid State Sci. 7 1377
[13]	Wang Z P, Song W B, Zhao Y, Jiang Y J, Liang E J 2011 J. Light Scatter. 23 250
[14]	Li Z Y, Song W B, Liang E J 2011 J. Phys. Chem. C 115 17806
[15]	Xiao X L, Cheng Y Z, Peng J 2008 Solid State Sci. 10 321
[16]	Isobe T, Umezome T, Kameshima Y, Nakajima A, Okada K 2009 Mater. Res. Bull. 44 2045
[17]	Shang R, Hu Q L, Liu X S, Liang E J, Yuan B, Chao M J 2012 Int. J. Appl. Ceram. Technol. 9 1
[18]	Rashmi C, Shrivastava O P 2011 Solid State Sci. 13 444
[19]	Xie D Y, Wang Z H, Liu X S, Song W B, Yuan B H, Liang E J 2012 Ceram. Int. 38 3807
[20]	Wang X W, Huang Q Z, Deng J X, Yu R B, Chen J, Xing X R 2011 Inorg. Chem. 50 2685
[21]	Amos T G, Sleight A W J 2001 Solid State Chem. 160 230
[22]	Sanson A, Rocca F, Dalba G, Fornasini P, Grisenti R, Dapiaggi M, Artioli G 2006 Phys. Rev. B 73 214305
[23]	Goodwin A L, Calleja M, Conterio M J, Dove M T, Evans J S O, Keen D A, Peters L, Tucker M G 2008 Science 319 794
[24]	Ding P, Liang E J, Jia Y 2008 J. Phys. Condens. Matter 20 275224
[25]	Li C W, Tang X, Munoz J A, Keith J B, Tracy S J, Abernathy D L, Fultz B 2011 Phys. Rev. Lett. 107 195504
[26]	Wang L, Yuan P F, Wang F, Sun Q, Liang E J, Jia Y 2012 Mater. Res. Bull. 47 1113
[27]	Chen J, Fan L L, Ren Y, Pan Z, Deng J X, Yu R B, Xing X R 2013 Phys. Rev. Lett. 110 115901
[28]	Tong P, Wang B S, Sun Y P 2013 Chin. Phys. B 22 067501
[29]	Higgins B, Graeve O A, Edwards D D 2013 J. Am. Ceram. Soc. 96 2402
[30]	Liu F S, Chen X P, Xie H X, Ao W Q, Li J Q 2010 Acta Phys. Sin. 59 3350 (in Chinese) [刘福生, 陈贤鹏, 谢华兴, 敖伟琴, 李均钦 2010 59 3350]
[31]	Suzuki T, Omote A 2004 J. Am. Ceram. Soc. 87 1365
[32]	Li F, Liu X S, Song W B, Yuan B H, Cheng Y G, Yuan H L, Cheng F X, Chao M J, Liang E J 2014 J. Solid State Chem. 218 15
[33]	Song W B, Liang E J, Liu X S, Li Z Y, Yuan B H, Wang J Q 2013 Chin. Phys. Lett. 30 126502
[34]	Marinkovic B A, Jardim P M, Ari M, Avillez R R, Rizzo F, Ferreira F F 2008 Phys. Stat. Sol. B 245 2514
[35]	Liu X S, Cheng F X, Wang J Q, Song W B, Yuan B H, Liang E J 2013 J. Alloy. Comp. 553 1
[36]	Yan X, Li M, Li J, Cheng X 2011 Appl. Mechan. Mater. 66-68 1808
[37]	Tyagi A K, Achary S N, Mathews M D 2002 J. Alloys Comp. 339 207
[38]	Sumithra S, Umarji A M 2006 Solid State Sci. 8 1453
[39]	Evans J S O, Mary T A, Sleight A W 1998 J. Solid State Chem. 137 148
[40]	Evans J S O, Mary T A 2000 Inter. J. Inorg. Mater. 2 143
[41]	Liang E J, Huo H L, Wang Z, Chao M J, Wang J P 2009 Solid State Sci. 11 139
[42]	Liang E J, Wang J P, Xu E M, Du Z Y, Chao M J 2008 J. Raman Spectrosc. 39 887
[43]	Liang E J, Wu T A, Yuan B, Chao M J, Zhang W F 2007 J. Phys. D: Appl. Phys. 40 3219
[44]	Zhang J, Yuan C, Wang J Q, Liang E J, Chao M J 2013 Chin. Phys. B 22 087201
[45]	Paraguassu W, Maczka M, Souza Filho A G, Freire P T C, Melo F E A, Mendes Filho J, Hanuza J 2007 J. Vibr. Spectrosc. 44 69
[46]	Liang E J, Huo H L, Wang J P, Chao M J 2008 J. Phys. Chem. C 112 6577
[47]	Li Q J, Yuan B H, Song W B, Liang E J, Yuan B 2012 Chin. Phys. B 21 046501
[48]	Song W B, Yuan C, Li Z Y, Zhao Y, Jiang Y J, Liang E J 2011 J. Light Scatter. 23 346 (in Chinese) [宋文博, 袁超, 李志远, 赵艳, 蒋毅坚, 梁二军 2011 光散射学报 23 346]

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Vol. 63, Issue 24 - 2014-12-20

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