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超小晶粒锡掺杂CsPbBr3蓝光量子点的合成及其光学性能研究

曾凡菊 谭永前 Wei Hu 唐孝生 张小梅 尹海峰

超小晶粒锡掺杂CsPbBr3蓝光量子点的合成及其光学性能研究

曾凡菊, 谭永前, Wei Hu, 唐孝生, 张小梅, 尹海峰

Synthesis and optical properties of ultra-small Tin doped CsPbBr3 blue luminescence quantum dots

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  • 近年来,铅卤钙钛矿CsPbX3(X=Cl,Br或I)因其发光波段可调、荧光量子产率高(Photoluminescence quantum yield,PLQY)以及荧光半峰宽窄等优点而被广泛应用于光电器件领域。然而,与PLQY接近于100%的绿光和红光相比,蓝光的PLQY仍比较低。在此,采用过饱和结晶的方法在室温下合成了粒径低于4 nm的超小晶粒锡(Sn2%2B)离子掺杂CsPbBr3量子点,并对其晶体结构、光学性能、发光机理及其发光稳定性进行了研究。结果表明:随着SnBr2添加量的增加,量子点晶粒粒径略微减小,荧光发射峰发生明显蓝移,粒径由添加SnBr2为0.03 mmol 时的3.33 nm减小2.23 nm(SnBr2为0.06 mmol时),对应的荧光发射峰由490 nm蓝移至472 nm。当添加SnBr2为0.05 mmol时合成的超小晶粒量子点具有最优的光学性能,其粒径约为2.91 nm,对应的XRD各晶面衍射峰强度最强,荧光发射峰位于472 nm处,PLQY最高,达到了53.4%,在空气中存放15天后,其荧光发射峰位置不发生明显改变,荧光PLQY仍保留最初的80%,为42.7%。证明适量添加SnBr2对CsPbBr3进行Sn2%2B离子掺杂可有效提高超小晶粒量子点的结晶性能、光学性能和发光稳定性。该方法合成的超小晶粒蓝光量子点在蓝光二极管及激光领域具有潜在的应用前景。
    All-inorganic perovskite CsPbX3 (X=Cl, Br and I) quantum dots (QDs) have been wildly utilized in optoelectronic devices due to its tunable photoluminescence, high photoluminescence quantum yield (PLQY), and narrow-line width photoluminescence. However, the blue luminescence PLQY of CsPbX3 perovskite quantum dots is still lag behind their red and green luminescence (PLQYs nearly 100%) counterparts. Herein, we present a facile strategy to synthetic ultra-small blue luminescence Sn2%2B ions doped CsPbBr3 perovskite QDs by supersaturated recrystallization synthetic approach at room temperature, and the particle size of as-prepared QDs is lower than 4 nm. The crystal structure, morphology, optical property, and stable luminescence property of Sn2%2B doped CsPbBr3 QDs are characterized by XRD, TEM, ultraviolet-visible spectrophotometer, and fluorescence spectrophotometer. The results show that the particle size of as-prepared QDs is slightly shrink from 3.33 nm (SnBr2 0.03 mmol) to 2.23 nm (SnBr2 0.06 mmol) as the SnBr2 adding amount increase, but there is no obvious change in the lattice spacing of doped QDs. The partial Pb2%2B for Sn2%2B replacement leads to a blue-shift from 490 nm (SnBr2 0.03 mmol) to 472 nm (SnBr2 0.06 mmol) of the optical spectra. The highest PLQY and the strongest XRD diffraction of ultra-small Sn2%2B doped CsPbBr3 blue luminescence QDs is obtained by adding SnBr2 0.05 mmol, and the blue luminescence located at 472 nm with the PLQY of 53.4%. There is no any change in PL peak of Sn2%2B doped CsPbBr3 QDs (SnBr2 0.05 mmol) by storing it under the ambient atmosphere for 15 days, and the PLQY of Sn2%2B doped QDs is still remain 80% of the initial after 15 days. It is concluded that the crystallization and optical property could be effectively improved in Sn2%2B doped CsPbBr3 QDs by partially replacing appropriate amount of Pb2%2B ion by Sn2%2B ion. This ultra-small Tin doped CsPbBr3 blue luminescence QDs shows promising application in lighting-emitting diode and laser.
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出版历程
  • 收稿日期:  2021-10-12
  • 上网日期:  2021-10-29

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