Bi2O3-B2O3-BaO玻璃的制备及其近红外发光性能的研究

刘军芳; 苏良碧; 徐军

doi:10.7498/aps.62.037804

摘要

采用高温熔融法制备了xBi2O3-50B2O3-(50-x)BaO玻璃, 测定了样品玻璃的近红外光区的发射谱、荧光寿命以及Raman光谱. 在808 nm波长光的激发下, 50Bi2O3-50B2O3二元玻璃中未观察到近红外发光; 随体系中BaO的加入, 当x为40, 45以及49时, 玻璃样品中观察到了近红外宽带发光现象; BaO含量进一步增加, 当x=1030时, 近红外发光现象消失; 而当玻璃中Bi浓度很低时, 在0.5Bi2O3-50B2O3-50BaO及1Bi2O3-50B2O3-50BaO玻璃中发现了近红外发光现象, 且存在多个发光峰. 对铋离子近红外发光机理进行了初步的探讨.

关键词:

近红外发光 /
Bi离子 /
非桥氧

Abstract

xBi2O3-50B2O3-(50-x)BaO glasses are prepared by melting method. Their infrared luminescence spectra, fluorescence decay curves and Raman scattering spectra are measured. No obvious near-infrared (NIR) luminescence is observed in 50Bi2O3-50B2O3 glass under 808 nm laser diode (LD) pumping. Adding BaO, broadband NIR luminescences are observed in 40Bi2O3-50B2O3-10BaO glass, 45Bi2O3-50B2O3-5BaO glass and 49Bi2O3-50B2O3-1BaO glass. With the increase of BaO concentration, no obvious NIR luminescences are observed in 30Bi2O3-50B2O3-20BaO glass, 20Bi2O3-50B2O3-30BaO glass and 10Bi2O3-50B2O3-40BaO glass. The NIR emissions with several emission peaks appear in 0.5Bi2O3-50B2O3-50BaO glass and 1Bi2O3-50B2O3-50BaO glass. The mechanism for the emission is investigated preliminarily.

Keywords:

作者及机构信息

1.
同济大学材料科学与工程学院, 上海 200092;

2.
同济大学, 先进土木工程材料教育部重点实验室, 上海 200092;

3.
中国科学院上海硅酸盐研究所, 透明与光功能无机材料重点实验室, 上海 201800

基金项目: 国家自然科学基金青年科学基金(批准号: 61008045)和中央高校基本科研业务费专项资金资助的课题.

Authors and contacts

1.
College of Materials Science and Engineering, Tongji University, Shanghai 200092, China;

2.
Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, Shanghai 200092, China;

3.
Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China

Funds: Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 61008045) and the Fundamental Research Funds for the Central Universities, China.

参考文献

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施引文献

[1]	Yamada M, Ono H, Ohishi Y 1998 Electron. Lett 34 1490
[2]	Fujimoto Y, Nakatsuka M 2001 Jpn. J. Appl. Phys 40 L279
[3]	Peng M Y, Qiu J R, Cheng D P 2004 Opt. Lett. 29 1998
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[5]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1628
[6]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1635
[7]	Dvoyrin V V, Mashinsky V M Bulatov L I 2006 Opt. Lett. 31 2966
[8]	Arai Y, Suzuki T, Ohishi Y 2007 Appl. Phys. Lett. 90 261110
[9]	Sun H T, Miwa Y, Shimaoka F 2009 Opt. Lett. 34 1219
[10]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett 33 1488
[11]	Ren J, Wu B, Jiang X 2007 Appl. Phys. B 88 363
[12]	Ren J, Qiu J R, Cheng D P 2008 J. Alloys and Compounds 463 L5
[13]	Zhou S F, Dong H F, Zeng H P 2007 Appl. Phys. Lett. 91 061919
[14]	S F, Jiang N, Zhu B 2008 Advanced Functional Materials 18 1407
[15]	Peng M Y, Zhao Q Z, Qiu J R 2009 J. Am. Ceram. Soc. 92 542
[16]	Zhou S F, Jiang N, Zhu B 2009 Advanced Functional Materials 19 2081
[17]	Xia H P, Wang X J 2006 Appl. Phys. Lett. 89 051917
[18]	Xia H P, Wang X J 2008 Spectrochimica Acta A 70 122
[19]	Xia H P, Wang X J 2006 Optics Communications 268 75
[20]	Wang X J, Xia H P 2006 Acta Phys. Sin. 55 5263 (in Chinese) [王雪俊, 夏海平 2006 55 5263
[21]	Su L B, Xu J, Zhou P 2009 Opt. Lett. 34 2504
[22]	Xu J, Zhao H Y, Su L B 2010 Opt. Express 18 3385
[23]	Fujimoto Y, Nakatsuka M 2003 Appl. Phys. Lett. 82 3325
[24]	Ruan J, Su L B, Qiu J R 2009 Opt. Express 17 5136
[25]	Dvoyrin V V, Mashinsky V M, Dianov A A 2005 31st European Conference on Optics Communication Glasgow, Scotland 4 949
[26]	Yang Z W, Liu Z L, Song Z G 2011 Materials Research Innovations 15 264
[27]	Zhou D C, Liu Z L. Song Z G 2012 Acta Phys. Sin. 61 127802 (in Chinese) [周大成, 刘志亮, 宋志国 2012 61 127802]
[28]	Zhang N, Qiu J R, Dong G P 2012 Journal of Materials Chemistry 22 3153
[29]	Alexey N R, Zukhra T F, Alexander A V 2012 Opt. Expres 20 7212
[30]	Alexey N R, Zukhra T F, Denis M Z 2011 Optical Materials 33 631
[31]	Guo X, Li H J, Su LB 2012 Optical Materials 34 675
[32]	Yu P S, Su LB, Zhao H Y 2011 Optical Materials 33 831
[33]	Baia L, Stefan Rn, Kiefer W 2002 Journal of Non-Crystalline Solids 303 379
[34]	Liu J F, Su LB Xu J 2012 Acta Phys. Sin. 61 127806 (in Chinese) [刘军芳, 苏良碧, 徐军 2012 61 127806]
[35]	Su L B, Zhou P, Xu J 2009 Opt. Express 17 13554

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