掺铋离子BaO-B2O3玻璃的制备及其近红外发光性能的研究

刘军芳; 苏良碧; 唐慧丽; 徐军

doi:10.7498/aps.61.127806

摘要

采用高温熔融法制备了掺Bi离子的BaO-B2O3玻璃, 测定了样品玻璃的近红外以及可见光区的激发、发射谱、荧光衰减曲线以及Raman光谱. 在808 nm波长光的激发下, 在掺Bi离子的BaO-B2O3玻璃中发现了近红外发光现象, 且存在多个发光峰, 讨论了玻璃网络结构对Bi离子发光的影响, 对其发光机理进行了初步的探讨.

关键词:

Bi-doped BaO-B2O3 glasses are prepared by the melting method. Visible and infrared luminescence spectra, fluorescence decay curve and Raman scattering spectra are measured. NIR emissions, not only one broadband emission peak but also several emission peaks, appear in Bi-doped BaO-B2O3 glass under 808 nm LD pumping. The effect of the network structure of BaO-B2O3 glass on the NIR emission is discussed, and the mechanism for the emission is investigated preliminarily.

Keywords:

作者及机构信息

1.
同济大学材料科学与工程学院, 上海 200092;

2.
同济大学先进土木工程材料教育部重点实验室, 上海 200092;

3.
中国科学院上海硅酸盐研究所透明与光功能无机材料重点实验室, 上海 201800

基金项目: 国家自然科学基金青年科学基金(批准号: 61008045)资助的课题.

Authors and contacts

1.
College of Materials Science and Engineering, Tongji University, Shanghai 200092, China;

2.
Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, Shanghai 200092, China;

3.
Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute if Ceramics, Chinese Academy of Sciences, Shanghai 201800, China

Funds: Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 61008045) and the Fundamental Research Funds for the Central Universities.

参考文献

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施引文献

[1]	Yamada M, Ono H, Ohishi Y 1998 Electron. Lett. 34 1490
[2]	Fujimoto Y, Nakatsuka M 2001 Jpn. J. Appl. Phys. 40 L279
[3]	Dvoyrin V V, Mashinsky V M, Bulatov L I 2006 Opt. Lett. 31 2966
[4]	Arai Y, Suzuki T, Ohishi Y 2007 Appl. Phys. Lett. 90 261110
[5]	Sun H T, Miwa Y, Shimaoka F 2009 Opt. Lett. 34 1219
[6]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett. 33 1488
[7]	Peng M Y, Qiu J R, Cheng D P 2004 Opt. Lett. 29 1998
[8]	Peng M Y, Qiu J R, Cheng D P 2005 Opt. Lett. 30 2433
[9]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1628
[10]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1635
[11]	Ren J, Wu B, Jiang X 2007 Appl. Phys. B 88 363
[12]	Ren J, Qiu J R, Cheng D P 2008 J. of Alloys and Compounds 463 L5
[13]	Zhou S F, Dong H F, Zeng H P 2007 Appl. Phys. Lett. 91 061919
[14]	Peng M Y, Wu B T, Da N 2008 Journal of Non-Crystalline Solids 354 1221
[15]	Qiu J R, PengMY, Ren J J 2008 Journal of Non-Crystalline Solids 354 1235
[16]	Zhou S F, Jiang N, Zhu B 2008 Advanced Functional Materials 18 1407
[17]	Peng M Y, Zhao Q Z, Qiu J R 2009 J. Am. Ceram. Soc. 92 542
[18]	Zhou S F, Jiang N, Zhu B 2009 Advanced Functional Materials 192081
[19]	Xia H P Wang X J 2006 Appl. Phys. Lett. 89 051917
[20]	Xia H P, Wang X J 2008 Spectrochimica Acta A 70 122
[21]	Xia H P, Wang X J 2006 Optics Communications 268 75
[22]	Wang X J, Xia H P 2006 Acta Phys. Sin. 55 5263 (in Chinese)[王雪俊, 夏海平 2006 55 5263]
[23]	Su L B, Xu J, Zhou P 2009 Opt. Lett. 34 2504
[24]	Ruan J, Su L B, Qiu J R 2009 Optical Express 17 5163
[25]	Su L B, Zhou P, Xu J 2009 Optical Express 17 13554
[26]	Xu J, Zhao H Y, Su L B 2010 Optical Express 18 3385
[27]	Fujimoto Y, Nakatsuka M 2003 Appl. Phys. Lett. 82 3325
[28]	Khonthon S, Morinoto S, Arai Y 2007 J. Ceramic Society Jap. 115 259
[29]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett. 33 1488
[30]	Sharonov M Y, Bykov A B, Petricevic V 2008 Opt. Lett. 33 2131
[31]	Blasse G, Bril A 1968 J. Chem. Phys. 48 217
[32]	Srivastava A 1998 J. Lumin. 78 239
[33]	Andrey N, Akira Y, Martin M 2006 J. Cryst. Growth. 92 236
[34]	Zhang H J, Su Q 1998 Chinese J. Lumin. 9 231 (in Chinese)[张洪杰, 苏锵 1988 发光学报 9 231]
[35]	Blasse G, Meijerink A, Nomes M, Zuidema J 1994 J. Phys. Chem. Solids. 55 171
[36]	Mariska A. Hamastra, Hilda F. Folkerts, Geroge Blasse 1994 J. Mater. Chem. 4 1349
[37]	Chi G W, Zhou D C, Song Z G 2009 Optical Materials 31 945
[38]	Guo F Q 1997 Materials Science Engineering 15 39 (in Chinese) [郭凤岐 1997 材料科学与工程 15 39]
[39]	Guo F Q, Le X J, Cui W Q 1987 J. Wuhan University of Technology 1 61 (in Chinese)[郭凤岐, 乐雄军, 崔万秋 1987 武汉工业大学学报 1 61]
[40]	Huang P N, Jin Y F, Huang X H 1984 Acta Phys. Sin. 33 523 (in Chinese)[黄彭年, 金宜芬, 黄熙怀 1984 33 523]
[41]	Jin Y F, Ji Y S, Chen X S, Huo G Q, Huang X H 1985 Acta Phys. Sin. 34 1174 (in Chinese)[金宜芬, 季允送, 陈祥生, 霍根泉, 黄熙怀 1985 34 1174]
[42]	Santos C N, Menses D D S, Echegut P, Neuville D R, Hernandes A C, Ibanez A 2009 Appl. Phys. Lett. 94 151901
[43]	Zhou L F, Lin H X, Chen W Luo L 2008 Journal of Physics and Chemistry of Solids 69 2499

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