Progress on hydrogen-rich superconductors under high pressure

Sun Ying; Liu Han-Yu; Ma Yan-Ming

doi:10.7498/aps.70.20202189

Abstract

In recent years, hydrogen-rich compounds under extremely high pressure have become the hot target materials for high-temperature superconductors. At present, two landmark progresses have been made in this field. Covalent H₃S hydrogen-rich superconductors (T_c = 200 K) and ionic hydrogen-rich superconductors with hydrogen-cage structure, such as LaH₁₀ (T_c = 260 K, –13 ℃), YH₆ and YH₉, have been successively synthesized, setting a new record of superconducting temperature. These studies have given rise to the hope of discovering room-temperature superconductors in hydrogen-rich compounds under high pressure. This paper focuses on the progress of hydrogen-rich superconductors with high critical temperature under high pressure, discusses the physical mechanism of high-temperature superconductivity in hydrogen-rich compounds, provide an outlook on the possibility of discovering room-temperature superconductors in hydrogen-rich compounds in the future, and offer the candidate system for high superconductivity in multiple hydrogen-rich compounds.

Keywords:

Authors and contacts

1.
State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012, China
2.
International Center for Computational Method and Software, College of Physics, Jilin University, Changchun 130012, China
3.
International Center of Future Science, Jilin University, Changchun 130012, China

Corresponding author: Liu Han-Yu, lhy@calypso.cn ; Ma Yan-Ming, mym@jlu.edu.cn

Funds: Project supported by the Major Program of the National Natural Science Foundation of China (Grant No. 52090024), the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDB33000000), the National Natural Science Foundation of China (Grant No. 12074138), and the China Postdoctoral Science Foundation (Grant No. 2020M681032)

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References

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图 1 超导体年表. 方形、圆形和菱形色块分别表示BCS超导体、铜氧化物超导体和铁基超导体. 黑色和蓝色标签分别标注常压超导材料和高压超导材料及合成压强

Figure 1. Timeline of superconductors. The square, circle, and rhombus color blocks respectively represent BCS superconductors, cuprate superconductors, and iron-based superconductors. Black and blue labels represent superconducting materials at atmospheric pressure and high pressure as well as the pressure value required to synthesize these superconductors.

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[1]	赵忠贤, 陈立泉, 崔长庚, 黄玉珍, 刘锦湘, 陈赓华, 李山林, 郭树权, 何业冶 1987 科学通报 32 177 Google Scholar Zhao Z X, Chen L Q, Cui C G, Huang Y Z, Liu J X, Chen G H, Li S L, Guo S Q, He Y Z 1987 Chin. Sci. Bull. 32 177 Google Scholar
[2]	赵忠贤, 陈立泉, 杨乾声, 黄玉珍, 陈赓华, 唐汝明, 刘贵荣, 崔长庚, 陈烈, 王连忠 1987 科学通报 32 412 Google Scholar Zhao Z X, Chen L Q, Yang Q S, Huang Y Z, Chen G H, Tang R M, Liu G R, Cui C G, Chen L, Wang L Z 1987 Chin. Sci. Bull. 32 412 Google Scholar
[3]	Chu C W, Gao L, Chen F, Huang Z J, Meng R L, Xue Y Y 1993 Nature 365 323 Google Scholar
[4]	Gao L, Xue Y Y, Chen F, Xiong Q, Meng R L, Ramirez D, Chu C W, Eggert J H, Mao H K 1994 Phys. Rev. B 50 4260 Google Scholar
[5]	Ren Z A, Che G C, Dong X L, Yang J, Lu W, Yi W, Shen X L, Li Z C, Sun LL, Zhou F, Zhao Z X 2008 Europhys. Lett. 83 17002 Google Scholar
[6]	Wang Q Y, Li Z, Zhang W H, Zhang Z C, Zhang J S, Li W, Ding H, Ou Y B, Deng P, Chang K, Wen J, Song C L, He K, Jia J F, Ji S H, Wang Y Y, Wang L L, Chen X, Ma X C, Xue Q K 2012 Chin. Phys. Lett. 29 037402 Google Scholar
[7]	Zhang L, Wang Y, Lv J, Ma Y M 2017 Nat. Rev. Mater. 2 17005 Google Scholar
[8]	Mao H K, Chen X J, Ding Y, Li B, Wang L 2018 Rev. Mod. Phys. 90 015007 Google Scholar
[9]	Lv J, Sun Y, Liu H, Ma Y 2020 Matter Radiat. Extrem. 5 068101 Google Scholar
[10]	Hamlin J J 2015 Physica C 514 59 Google Scholar
[11]	Prakash O, Kumar A, Thamizhavel A, Ramakrishnan S 2017 Science 355 52 Google Scholar
[12]	Schilling A, Cantoni M, Guo J D, Ott H R 1993 Nature 363 56 Google Scholar
[13]	Ren Z A, Lu W, Yang J, Yi W, Shen X L, Li Z C, Che G C, Dong X L, Sun L L, Zhou F, Zhao Z X 2008 Chin. Phys. Lett. 25 2215 Google Scholar
[14]	罗会仟 2018 物理 47 676 Google Scholar Luo H Q 2018 Physics 47 676 Google Scholar
[15]	靳常青 2017 科学通报 62 3947 Google Scholar Jin C Q 2017 Chin. Sci. Bull. 62 3947 Google Scholar
[16]	孙建平, Shahi P, 周花雪, 倪顺利, 王少华, 雷和畅, 王铂森, 董晓莉, 赵忠贤, 程金光 2018 67 207404 Google Scholar Sun J P, Shahi P, Zhou H X, Ni S L, Wang S H, Lei H C, Wang B S, Dong X L, Zhao Z X, Cheng J G 2018 Acta Phys. Sin. 67 207404 Google Scholar
[17]	Drozdov A P, Eremets M I, Troyan I A, Ksenofontov V, Shylin S I 2015 Nature 525 73 Google Scholar
[18]	Drozdov A P, Kong P P, Minkov V S, Besedin S P, Kuzovnikov M A, Mozaffari S, Balicas L, Balakirev F F, Graf D E, Prakapenka V B, Greenberg E, Knyazev D A, Tkacz M, Eremets M I 2019 Nature 569 528 Google Scholar
[19]	Somayazulu M, Ahart M, Mishra A K, Geballe Z M, Baldini M, Meng Y, Struzhkin V V, Hemley R J 2019 Phys. Rev. Lett. 122 027001 Google Scholar
[20]	Troyan I A, Semenok D V, Kvashnin A G, Ivanova A G, Prakapenka V B, Greenberg E, Gavriliuk A G, Lyubutin I S, Struzhkin V V, Oganov A R 2019 arXiv: 1908.01534
[21]	Kong P P, Minkov V S, Kuzovnikov M A, Besedin S P, Drozdov A P, Mozaffari S, Balicas L, Balakirev F F, Prakapenka V B, Greenberg E, Knyazev D A, Eremets M I 2019 arXiv: 1909.10482
[22]	Semenok D V, Kvashnin A G, Ivanova A G, Svitlyk V, Fominski V Y, Sadakov A V, Sobolevskiy O A, Pudalov V M, Troyan I A, Oganov A R 2020 Mater. Today 33 36 Google Scholar
[23]	Li Y, Hao J, Liu H, Li Y, Ma Y M 2014 J. Chem. Phys. 140 174712 Google Scholar
[24]	Liu H, Naumov, I I, Hoffmann R, Ashcroft N W, Hemley R J 2017 Proc. Natl. Acad. Sci. U.S.A. 114 6990 Google Scholar
[25]	Peng F, Sun Y, Pickard C J, Needs R J, Wu Q, Ma Y M 2017 Phys. Rev. Lett. 119 107001 Google Scholar
[26]	Wigner E, Huntington H B 1935 J. Chem. Phys. 3 764 Google Scholar
[27]	Ashcroft N W 1968 Phys. Rev. Lett. 21 1748 Google Scholar
[28]	Bardeen J, Cooper L N, Schrieffer J R 1957 Phys. Rev. 108 1175 Google Scholar
[29]	Pickard C J, Needs R J 2007 Nat. Phys. 3 473 Google Scholar
[30]	Zhang L J, Niu Y L, Li Q, Cui T, Wang Y, Ma Y M, He Z, Zou G T 2007 Solid State Commun. 141 610 Google Scholar
[31]	Cudazzo P, Profeta G, Sanna A, Floris A, Continenza A, Massidda S, Gross E K 2008 Phys. Rev. Lett. 100 257001 Google Scholar
[32]	Liu H, Zhu L, Cui W, Ma Y M 2012 J. Chem. Phys. 137 074501 Google Scholar
[33]	Liu H Y, Wang H, Ma Y M 2012 J. Phys. Chem. C 116 9221 Google Scholar
[34]	McMahon J M, Ceperley D M 2011 Phys. Rev. B 84 144515 Google Scholar
[35]	Dias R P, Silvera I F 2017 Science 355 715 Google Scholar
[36]	Eremets M I, Drozdov A P, Kong P P, Wang H 2019 Nat. Phys. 15 1246 Google Scholar
[37]	Loubeyre P, Occelli F, Dumas P 2020 Nature 577 631 Google Scholar
[38]	Monacelli L, Errea I, Calandra M, Mauri F 2020 Nat. Phys.
[39]	Ginzburg V L 1999 Physics Uspekhi 42 353 Google Scholar
[40]	Wang H, Li X, Gao G Y, Li Y W, Ma Y M 2018 Wires. Comput. Mol. Sci. 8 e1330
[41]	Flores-Livas J A, Boeri L, Sanna A, Profeta G, Arita R, Eremets M 2020 Phys. Rep. 856 1 Google Scholar
[42]	Gilman J J 1971 Phys. Rev. Lett. 26 546 Google Scholar
[43]	Satterthwaite C B, Toepke I L 1970 Phys. Rev. Lett. 25 741 Google Scholar
[44]	Skoskiewicz T 1972 Phys. Status Solidi A 11 K123 Google Scholar
[45]	Stritzker B, Buckel W 1972 Z. Phys. 257 8
[46]	Stritzker B 1974 Z. Phys. 268 261 Google Scholar
[47]	Welter J M, Johnen F J 1977 Z. Phys. B 27 227 Google Scholar
[48]	Ashcroft N W 2004 Phys. Rev. Lett. 92 187002 Google Scholar
[49]	Eremets M I, Trojan I A, Medvedev S A, Tse J S, Yao Y 2008 Science 319 1506 Google Scholar
[50]	Kim D Y, Scheicher R H, Lebegue S, Prasongkit J, Arnaud B, Alouani M, Ahuja R 2008 Proc. Natl. Acad. Sci. U.S.A. 105 16454 Google Scholar
[51]	Martinez-Canales M, Oganov A R, Ma Y, Yan Y, Lyakhov A O, Bergara A 2009 Phys. Rev. Lett. 102 087005 Google Scholar
[52]	Degtyareva O, Proctor J E, Guillaume C L, Gregoryanz E, Hanfland M 2009 Solid State Commun. 149 1583 Google Scholar
[53]	Bi T, Zarifi N, Terpstra T, Zurek E 2019 Reference Module in Chemistry, Molecular Sciences and Chemical Engineering (Amsterdam: Elsevier)
[54]	Chen X J, Struzhkin V V, Song Y, Goncharov A F, Ahart M, Liu Z, Mao H K, Hemley R J 2008 Proc. Natl. Acad. Sci. U.S.A. 105 20 Google Scholar
[55]	Gao G, Oganov A R, Bergara A, Martinez-Canales M, Cui T, Iitaka T, Ma Y, Zou G 2008 Phys. Rev. Lett. 101 107002 Google Scholar
[56]	Tse J S, Yao Y, Tanaka K 2007 Phys. Rev. Lett. 98 117004 Google Scholar
[57]	Li Y, Gao G, Xie Y, Ma Y, Cui T, Zou G 2010 Proc. Natl. Acad. Sci. U.S.A. 107 15708 Google Scholar
[58]	Drozdov A P, Eremets M I, Troyan I A 2015 arXiv: 1812.01561
[59]	Pepin C, Loubeyre P, Occelli F, Dumas P 2015 Proc. Natl. Acad. Sci. U.S.A. 112 7673 Google Scholar
[60]	Struzhkin V V, Kim D Y, Stavrou E, Muramatsu T, Mao H K, Pickard C J, Needs R J, Prakapenka V B, Goncharov A F 2016 Nat. Commun. 7 12267 Google Scholar
[61]	Chen W, Semenok D V, Kvashnin A G, Kruglov I A, Galasso M, Song H, Huang X, Duan D, Goncharov A F, Prakapenka V B 2020 arXiv: 2004.12294
[62]	Wang H, Tse J S, Tanaka K, Iitaka T, Ma Y 2012 Proc. Natl. Acad. Sci. U.S.A. 109 6463 Google Scholar
[63]	Duan D, Liu Y, Tian F, Li D, Huang X, Zhao Z, Yu H, Liu B, Tian W, Cui T 2014 Sci. Rep. 4 6968
[64]	Einaga M, Sakata M, Ishikawa T, Shimizu K, Eremets M I, Drozdov A P, Troyan I A, Hirao N, Ohishi Y 2016 Nat. Phys. 12 835 Google Scholar
[65]	Li Y W, Wang L, Liu H Y, Zhang Y W, Hao J, Pickard C J, Nelson J R, Needs R J, Li W T, Huang Y W, Errea I, Calandra M, Mauri F, Ma Y M 2016 Phys. Rev. B 93 020103(R)
[66]	Bernstein N, Hellberg C S, Johannes M D, Mazin I I, Mehl M J 2015 Phys. Rev. B 91 060511(R)Google Scholar
[67]	Strobel T A, Ganesh P, Somayazulu M, Kent P R, Hemley R J 2011 Phys. Rev. Lett. 107 255503 Google Scholar
[68]	Yuan Y, Li Y, Fang G, Liu G, Pei C, Li X, Zheng H, Yang K, Wang L 2019 Natl. Sci. Rev. 6 524 Google Scholar
[69]	Degtyarenko N N, Mazur E A 2016 J. Exp. Theor. Phys. 123 277 Google Scholar
[70]	Flores-Livas J A, Amsler M, Heil C, Sanna A, Boeri L, Profeta G, Wolverton C, Goedecker S, Gross E K U 2016 Phys. Rev. B 93 020508 Google Scholar
[71]	Fu Y H, Du X P, Zhang L J, Peng F, Zhang M, Pickard C J, Needs R J, Singh D J, Zheng W T, Ma Y M 2016 Chem. Mater. 28 1746 Google Scholar
[72]	Liu H Y, Li Y W, Gao G Y, Tse J S, Naumov I I 2016 J. Phys. Chem. C 120 3458 Google Scholar
[73]	Shamp A, Terpstra T, Bi T, Falls Z, Avery P, Zurek E 2016 J. Am. Chem. Soc. 138 1884 Google Scholar
[74]	Liu H Y, Naumov I I, Geballe Z M, Somayazulu M, Tse J S, Hemley R J 2018 Phys. Rev. B 98 100102 Google Scholar
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Vol. 70, Issue 1 - 2021-01-05

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