High-pressure synthesis and special physical properties of several ordered perovskite structures

Yin Yun-Yu; Wang Xiao; Deng Hong-Shan; Zhou Long; Dai Jian-Hong; Long You-Wen

doi:10.7498/aps.66.030201

Abstract

Strongly correlated electronic systems with ABO3 perovskite and/or perovskite-like structures have received much attention. High pressure is an effective method to prepare perovskites, in particular A-site and/or B-site ordered perovskites. In these ordered perovskites, both A and B sites can accommodate transition-metal ions, giving rising to multiple magnetic and electrical interactions between A-A, B-B, and A-B sites. The presence of these new interactions can induce a wide variety of interesting physical properties. In this review paper, we will introduce an A-site ordered perovskite with chemical formula AA3'B4O12 and two A- and B-site ordered perovskites with chemical formula AA3'B2B2'O12. All of these compounds can be synthesized only under high pressure. In the A-site ordered LaMn3Cr4O12 with cubic perovskite structure, magnetoelectric multiferroicity with new multiferroic mechanism is found to occur. This is the first observation of multiferroicity appearing in cubic perovskite, thereby opening the way to exploring new multiferroic materials and mechanisms. In the A- and B-site ordered perovskite CaCu3Fe2Os2O12, a high ferrimagnetic Curie temperature is observed to be around 580 K. Moreover, this compound exhibits semiconducting conductivity with an energy band gap of about 1 eV. The CaCu3Fe2Os2O12 thus provides a rare single-phase ferrimagnetic semiconductor with high spin ordering temperature well above room temperature as well as considerable energy band gap. Moreover, theoretical calculations point out that the introducing of A'-site Cu2+ magnetic ions can generate strong Cu-Fe and Cu-Os spin interactions. As a result, this A- and B-site ordered perovskite has a much higher Curie temperature than that of the B-site only ordered perovskite Ca2FeOsO6 (~320 K). In addition, we also for the first time prepare another A- and B-site ordered perovskite LaMn3Ni2Mn2O12. In the reported ordered perovskites with Mn3+ at the A' site, the A'-B intersite spin interaction is usually negligible. In our LaMn3Ni2Mn2O12, however, there exists the considerable A'-B interaction, which is responsible for the rare formation of B-site orthogonal spin structure with net ferromagnetic moment.

Keywords:

Authors and contacts

1.
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2.
Collaborative Innovation Center of Quantum Matter, Beijing 100190, China

Corresponding author: Long You-Wen, ywlong@iphy.ac.cn

Funds: Project supported by the National Basic Research Program of China (Grant No. 2014CB921500), the National Natural Science Foundation of China (Grant No. 11574378), and the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB07030300).

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Cited By

[1]	Fu H X, Cohen R E 2000 Nature 403 281
[2]	Eitel R E, Randall C A, Shrout T R, Rehrig P W, Hackenberger W, Park S E 2001 Jpn. J. Appl. Phys. 40 5999
[3]	Cox D E, Noheda B, Shirane G, Uesu Y, Fujishiro K, Yamada Y 2001 Appl. Phys. Lett. 79 400
[4]	Panda P K 2009 J. Mater. Sci. 44 5049
[5]	Cohen R E 1992 Nature 358 136
[6]	Bersuker I B 1966 Phys. Lett. 20 589
[7]	Goto T, Kimura T, Lawes G, Ramirez A P, Tokura Y 2004 Phys. Rev. Lett. 92 257201
[8]	Bednorz J G, Mller K A 1988 Rev. Mod. Phys. 60 585
[9]	Xiao G, Cieplak M Z, Gavrin A, Streitz F H, Bakhshai A, Chien C L 1988 Phys. Rev. Lett. 60 1446
[10]	Cava R J, Batlogg B, Krajewski J J, Farrow R, Rupp Jr L W, White A E, Short K, Peck W F, Kometani T 1988 Nature 332 814
[11]	Maeno Y, Hashimoto H, Yoshida K, Nishizaki S, Fujita T, Bednorz J G, Lichtenberg F 1994 Nature 372 532
[12]	Helmolt R V, Wecker J, Holzapfel B, Schultz L, Samwer K 1993 Phys. Rev. Lett. 71 2331
[13]	Moritomo Y, Asamitsu A, Kuwahara H, Tokura Y 1996 Nature 380 141
[14]	Tokura Y, Tomioka Y, Kuwahara H, Asamitsu A, Moritomo Y, Kasai M 1996 J. Appl. Phys. 79 5288
[15]	Tokura Y 2006 Rep. Prog. Phys. 69 797
[16]	Fiebig M 2005 J. Phys. D:Appl. Phys. 38 R123
[17]	Eerenstein W, Mathur N D, Scott J F 2006 Nature 442 759
[18]	Ramesh R, Spaldin N A 2007 Nat. Mater. 6 21
[19]	Spaldin N A, Cheong S K, Ramesh R 2010 Phys. Today 63 38
[20]	Mackenzie A P, Julian S R, Diver A J, McMullan G J, Ray M P, Lonzarich G G, Maeno Y, Nishizaki S, Fujita T 1996 Phys. Rev. Lett. 76 3786
[21]	Hwang H Y, Iwasa Y, Kawasaki M, Keimer B, Nagaosa N, Tokura Y 2012 Nat. Mater. 11 103
[22]	Calder S, Garlea V O, McMorrow D F, Lumsden M D, Stone M B, Lang J C, Kim J W, Schlueter J A, Shi Y G, Yamaura K, Sun Y S, Tsujimoto Y, Christianson A D 2012 Phys. Rev. Lett. 108 257209
[23]	Carter J M, Shankar V V, Zeb M A, Kee H Y 2012 Phys. Rev. B 85 115105
[24]	Yan B H, Jansen M, Felser C 2013 Nat. Phys. 9 709
[25]	Chen Y G, Lu Y M, Kee H Y 2015 Nat. Commun. 6 6593
[26]	Kobayashi K I, Kimura T, Sawada H, Terakura K, Tokura Y 1998 Nature 395 677
[27]	Krockenberger Y, Mogare K, Reehuis M, Tovar M, Jansen M, Vaitheeswaran G, Kanchana V, Bultmark F, Delin A, Wilhelm F, Rogalev A, Winkler A, Alff L 2007 Phys. Rev. B 75 020404
[28]	Shimakawa Y, Shiraki H, Saito T 2008 J. Phys. Soc. Jpn. 77 113702
[29]	Ramirez A P, Subramanian M A, Gardel M, Blumberg G, Li D, Vogt T, Shapiro S M 2000 Solid State Commun. 115 217
[30]	Long Y W, Hayashi N, Saito T, Azuma M, Muranaka S, Shimakawa Y 2009 Nature 458 60
[31]	Long Y W, Kawakami T, Chen W T, Saito T, Watanuki T, Nakakura Y, Liu Q Q, Jin C Q, Shimakawa Y 2012 Chem. Mater. 24 2235
[32]	Long Y W, Saito T, Tohyama T, Oka K, Azuma M, Shimakawa Y 2009 Inorg. Chem. 48 8489
[33]	Long Y W, Shimakawa Y 2010 New J. Phys. 12 063029
[34]	Yamada I, Etani H, Tsuchida K, Marukawa S, Hayashi N, Kawakami T, Mizumaki M, Ohgushi K, KusanoY, Kim J, Tsuji N, Takahashi R, Nishiyama N, Inoue T, Irifune T and Takano M 2013 Inorg. Chem. 52 13751
[35]	Wang J, Neaton J B, Zheng H, Nagarajan V, Ogale S B, Liu B, Viehland D, Vaithyanathan V, Schlom D G, Waghmare U V, Spaldin N A, Rabe K M, Wuttig M, Ramesh R 2003 Science 299 1719
[36]	Kimura T, Goto T, Shintani H, Ishizaka K, Arima T, Tokura Y 2003 Nature 426 55
[37]	Katsura H, Nagaosa N, Balatsky V 2005 Phys. Rev. Lett. 95 057205
[38]	Sergienko I A, Dagotto E 2006 Phys. Rev. B 73 094434
[39]	Sergienko I A, Sen C, Dagotto E 2006 Phys. Rev. Lett. 97 227204
[40]	Mostovoy M 2006 Phys. Rev. Lett. 96 067601
[41]	Wang X, Chai Y S, Zhou L, Cao H B, Cruz C D, Yang J Y, Dai J H, Yin Y Y, Yuan Z, Zhang S J, Yu R Z, Azuma M, Shimakawa Y, Zhang H M, Dong S, Sun Y, Jin C Q, Long Y W 2015 Phys. Rev. Lett. 115 087601
[42]	Long Y W, Saito T, Mizumaki M, Agui A, Shimakawa Y 2009 J. Am. Chem. Soc. 131 16244
[43]	Tokura Y, Seki S, Naoto N 2014 Rep. Prog. Phys. 77 076501
[44]	ArimaT 2007 J. Phys. Soc. Jpn. 76 073702
[45]	Iyama A, Kimura T 2013 Phys. Rev. B 87 180408
[46]	Wolf S A, Awschalom D D, Buhrman R A, Daughton J M, von Molnár S, Roukes M L, Chtchelkanova A Y, Treger D M 2001 Science 294 1488
[47]	Awschalom D D, Flatte M E, Samarth N 2002 Sci. Am. 286 66
[48]	Dietl T 2010 Nat. Mater. 9 965
[49]	Žutić I, Fabian J, Das Sarma S 2004 Rev. Mod. Phys. 76 323
[50]	Zeng Z, Greenblatt M, Subramanian M A, Croft M 1999 Phys. Rev. Lett. 82 3164
[51]	Alonso J A, Sánchez-Benítez J, de Andrés A, Martínez-Lope M J, Casais M T, Martínez J L 2003 Appl. Phys. Lett. 83 2623
[52]	Takata K, Yamada I, Azuma M, Takano M, Shimakawa Y 2007 Phys. Rev. B 76 024429
[53]	Deng H S, Liu M, Dai J H, Hu Z W, Kuo C Y, Yin Y Y, Yang J Y, Wang X, Zhao Q, Xu Y J, Fu Z M, Cai J W, Guo H Z, Jin K J, Pi T W, Soo Y L, Zhou G H, Cheng J G, Chen K, Ohresser P, Yang Y F, Jin C Q, Tjeng L H, Long Y W 2016 Phys. Rev. B 94 024414
[54]	Blaha P, Schwarz K, Madsen G K H, Kvasnicka D, Luitz J 2002 WIEN2K, An Augmented Plane Wave Plus Local Orbitals Program for Calculating Crystal Properties (Vienna:Technische Universitat Wien)
[55]	Byeon S H, Lufaso M W, Parise J B 2003 Chem. Mater. 15 3798
[56]	Brown I D, Altermatt D 1985 Acta Cryst. B 41 244
[57]	Brese N E, O'Keeffe M 1991 Acta Cryst. B 47 192
[58]	Hollmann N, Hu Z, Maignan A, Gunther A, Jang L Y, Tanaka A, Lin H J, Chen C T, Thalmeier P, Tjeng L H 2013 Phys. Rev. B 87 155122
[59]	Huang M J, Deng G, Chin Y Y, Hu Z, Cheng J G, Chou F C, Conder K, Zhou J S, Pi T W, Goodenough J B, Lin H J, Chen C T 2013 Phys. Rev. B 88 014520
[60]	Haupricht T, Sutarto R, Haverkort M W, Ott H, Tanaka A, Hsieh H H, Lin H J, Chen C T, Hu Z, Tjeng L H 2010 Phys. Rev. B 82 035120
[61]	Paul A K, Jansen M, Yan B, Felser C, Reehuis M, Abdala P M 2013 Inorg. Chem. 52 6713
[62]	Senn M S, Chen W T, Saito T, García-Martín S, Attfield J P, Shimakawa Y 2014 Chem. Mater. 26 4832
[63]	Prodi A, Gilioli E, Cabassi R, Bolzoni F, Licci F, Huang Q Z, Lynn J W, Affronte M, Gauzzi A, Marezio M 2009 Phys. Rev. B 79 085105
[64]	Yin Y Y, Liu M, Dai J H, Wang X, Zhou L, Cao H B, Cruz C D, Chen C T, Xu Y J, Shen X, Yu R C, Alonso J A, Muñoz A, Yang Y F, Jin C Q, Hu Z W, Long Y W 2016 Chem. Mater. 28 8988
[65]	Byeon S H, Lee S S, Parise J B, Woodward P M, Hur N H 2005 Chem. Mater. 17 3552
[66]	Byeon S H, Lee S S, Parise J B, Woodward P M 2006 Chem. Mater. 18 3873
[67]	Chen W T, Mizumaki M, Saito T, Shimakawa Y 2013 Dalton Trans. 42 10116
[68]	Chen W T, Mizumaki M, Seki H, Senn M S, Saito T, Kan D, Attfield J P, Shimakawa Y 2014 Nat. Commun. 5 4909
[69]	Prodi A, Gilioli E, Gauzzi A, Lolzoni F, Marezio M, Bolzon F, Huang Q, Ssntoro A, Lynn J W 2004 Nat. Mater. 3 48
[70]	Inaguma Y, Tanaka K, Tsuchiya T, Mori D, Katsumata T, Ohba T, Hiraki K, Takahashi T, Saitoh H 2011 J. Am. Chem. Soc. 133 16920
[71]	Hu Z, Mazumdar C, Kaindl G, de Groot F M F, Warda S A, Reinen D 1998 Chem. Phys. Lett. 297 321
[72]	Hu Z, Golden M S, Fink J, Kaindl G, Warda S A, Reinen D, Mahadevan P, Sarma D D 2000 Phys. Rev. B 61 3739
[73]	Tohyama T, Saito T, Mizumaki M, Agui A, Shimakawa Y 2010 Inorg. Chem. 49 2492
[74]	Kim D H, Lee E, Kim H W, Kolesnik S, Dabrowski B, Kang C J, Kim M, Min B I, Lee H K, Kim J Y, Kang J S 2015 Phys. Rev. B 91 075113
[75]	Azuma M, Takata K, Saito T, Ishiwata S, Shimakawa Y, Takano M 2005 J. Am. Chem. Soc. 127 8889
[76]	Rogado N S, Li J, Sleight A W, Subramanian M A 2005 Adv. Mater. 17 2225
[77]	Toyoda M, Saito T, Yamauchi K, Shimakawa Y, Oguchi T 2015 Phys. Rev. B 92 014420
[78]	Yi W, Princep A J, Guo Y F, Johnson R D, Khalyavin D, Manuel P, Senyshyn A, Presniakov I A, Sobolev A V, Matsushita Y, Tanaka M, Belik A A, Boothroyd A T 2015 Inorg. Chem. 54 8012
[79]	Wei Y, Liang Q F, Matsushita Y, Tanaka M, Belik A A 2013 Inorg. Chem. 52 14108
[80]	Asai K, Fujiyoshi K, Nishimori N, Satoh Y, Kobayashi Y, Mizoguchi M 1998 J. Phys. Soc. Jpn. 67 4218
[81]	Booth R J, Fillman R, Whitaker H, Nag A, Tiwari R M, Ramanujachary K V, Gopalakrishnan J, Lofland S E 2009 Mater. Res. Bull. 44 1559
[82]	Manna K, Bera A K, Jain M, Elizabeth S, Yusuf S M, Anil Kumar P 2015 Phys. Rev. B 91 224420
[83]	Retuerto M, Muñoz á, Martínez-Lope M J, Alonso J A, Mompeán F J, Fernández-Díaz M T, Sánchez-Benítez J 2015 Inorg. Chem. 54 10890
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Vol. 66, Issue 3 - 2017-02-05

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