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Femtosecond filament-induced breakdown spectroscopy (FIBS) is employed to qualitatively analyze the heavy metal elements (Ca, Fe and Cr) in poplar leaves, at the same age, from four representative locations in Changchun City, i.e. Changchun First Automobile Factory, Railway Station, Jingyue National Forest Park, and Changchun University of Science and Technology (CUST) in the same season. The stem and mesophyll from the same leaf are investigated as samples by the FIBS technique. Experimental results demonstrate that the concentration of Ca and Fe elements in the leaf stem are higher than those in the leaf mesophyll through comparing the spectral intensities of Ca Ⅱ 393.37 nm and Fe Ⅰ 422.87 nm. Based on the analysis of the FIBS spectral intensity of heavy metals mentioned above in the poplar leaves from the four different locations, the heavy metal elements Ca, Fe and Cr in the poplar leaves gathered from the Automobile factory area have the highest concentration among the four locations, and those from Jingyue National Forest Park are the lowest. The FIBS technique can obtain stable plasma spectrum for the poplar leaves with irregular surfaces because of the optical intensity clamping effect inside the femtosecond filament. This experiment demonstrates that FIBS can be utilized to find new applications in the environmental pollution on-site detection.
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Keywords:
- femtosecond filament /
- laser induced breakdown spectroscopy /
- poplar leaves /
- qualitative analysis
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[2] Guo K M, Hao Z Q, Lin J Q, Sun C K, Gao X, Zhao Z M 2013 Chin. Phys. B 22 035203
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[4] Gao X, Du C, Li C, Liu L, Song C, Hao Z Q, Lin J Q 2014 Acta Phys. Sin 63 095203 (in Chinese) [高勋, 杜闯, 李丞, 刘潞, 宋超, 郝作强, 林景全 2014 63 095203]
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[7] Tzortzakis S, Anglos D, Gray D 2006 Opt. Letter 31 1139
[8] Xu H L, Mejean G, Liu W, Kamali Y, Daigle J F, Azarm A, Simard P T, Mathieu P, Roy G, Simard J R, Chin S L 2007 Appl. Phys. B 87 151
[9] Daigle J F, Kamali Y, Roy G, Chin S L 2008 Appl. Phys. B 93 759
[10] Xu H L, Simard P T, Kamali Y, Daigle J F, Marceau C, Bernhardt J, Dubois J, Chateauneuf M, Theberge F, Roy G, Chin S L 2012 Laser Phys. 22 1767
[11] Myriam B, Hao Z Q, Mattheu B, Yu J, Zhang Z, Zhang J 2007 Chin. Phys. Lett. 24 3466
[12] Lu C P, Liu W Q, Zhao N J, Liu L T, Chen D, Zhang Y J, Liu J G 2011 Acta Phys. Sin. 60 045206 (in Chinese) [鲁翠萍, 刘文清, 赵南京, 刘立拓, 陈东, 张玉钧, 刘建国 2011 60 045206]
[13] Braun, Korn G., Liu X., Du D, Squier J, Mourou G A 1995 Optics Letters 20 73
[14] Wu Y Y, Wang X, Liang R L, Wu T Z, Chen H M, Zheng C R, Xie Y Y, Tian X F, Lan Z D, Li H Y, Chen S Y 1997 Chin. Journal of Appl. Ecology 8 545 (in Chinese) [吴燕玉, 王新, 梁仁禄, 陈怀满, 郑春蓉, 谢玉英, 田秀芬, 蓝中东, 李惠英, 陈素英 1997 应用生态学报 8 545]
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[1] Margetic V, Pakulev A, Stockhaus A, Bolshov M, Niemax K, Hergenroder R 2000 Spectrochim. Acta Part B 55 1771
[2] Guo K M, Hao Z Q, Lin J Q, Sun C K, Gao X, Zhao Z M 2013 Chin. Phys. B 22 035203
[3] He X N, Hu W, Li C M, Guo L B, Lu Y F 2011 Opt. Express 19 10997
[4] Gao X, Du C, Li C, Liu L, Song C, Hao Z Q, Lin J Q 2014 Acta Phys. Sin 63 095203 (in Chinese) [高勋, 杜闯, 李丞, 刘潞, 宋超, 郝作强, 林景全 2014 63 095203]
[5] Ji Z G, Liu J S, Wang Z X, Ju J, Lu X M, Jiang Y H, Leng Y X, Liang X Y, Liu W, Chin S L, Li R X, Xu Z Z 2010 Laser Phys. 20 886
[6] Liu W, Xu H L, Mejean G, Kamali Y, Daigle J K, Azarm A, Simard P T, Mathieu P, Roy G, Chin S L 2007 Spectrochim Acta Part B 62 76
[7] Tzortzakis S, Anglos D, Gray D 2006 Opt. Letter 31 1139
[8] Xu H L, Mejean G, Liu W, Kamali Y, Daigle J F, Azarm A, Simard P T, Mathieu P, Roy G, Simard J R, Chin S L 2007 Appl. Phys. B 87 151
[9] Daigle J F, Kamali Y, Roy G, Chin S L 2008 Appl. Phys. B 93 759
[10] Xu H L, Simard P T, Kamali Y, Daigle J F, Marceau C, Bernhardt J, Dubois J, Chateauneuf M, Theberge F, Roy G, Chin S L 2012 Laser Phys. 22 1767
[11] Myriam B, Hao Z Q, Mattheu B, Yu J, Zhang Z, Zhang J 2007 Chin. Phys. Lett. 24 3466
[12] Lu C P, Liu W Q, Zhao N J, Liu L T, Chen D, Zhang Y J, Liu J G 2011 Acta Phys. Sin. 60 045206 (in Chinese) [鲁翠萍, 刘文清, 赵南京, 刘立拓, 陈东, 张玉钧, 刘建国 2011 60 045206]
[13] Braun, Korn G., Liu X., Du D, Squier J, Mourou G A 1995 Optics Letters 20 73
[14] Wu Y Y, Wang X, Liang R L, Wu T Z, Chen H M, Zheng C R, Xie Y Y, Tian X F, Lan Z D, Li H Y, Chen S Y 1997 Chin. Journal of Appl. Ecology 8 545 (in Chinese) [吴燕玉, 王新, 梁仁禄, 陈怀满, 郑春蓉, 谢玉英, 田秀芬, 蓝中东, 李惠英, 陈素英 1997 应用生态学报 8 545]
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