几种范德瓦耳斯铁电材料中新奇物性的研究进展

金鑫; 陶蕾; 张余洋; 潘金波; 杜世萱

doi:10.7498/aps.71.20220349

摘要

铁电材料因具有电场可调的自发极化, 在各类功能器件中有着广泛的应用. 受器件小型化发展趋势的影响, 二维范德瓦耳斯铁电材料及其层状母体块材成为了铁电领域的重点研究对象之一. 近年来, 研究人员已经制备出了数种二维范德瓦耳斯铁电材料, 并通过理论计算与实验结合的方法发现这些材料及其母体块材具有许多优良的、新奇的物理性质. 本文主要介绍近年来几种范德瓦耳斯铁电材料的一些研究进展, 包括体相范德瓦耳斯材料CuInP₂S₆的新奇物性的理论预测与实验证实, 以及两类二维范德瓦耳斯铁电材料M₂X₂Y₆ (M = 金属, X = Si, Ge, Sn, Y = S, Se, Te), QL-M₂O₃ (M = Al, Y)及相关功能器件的理论设计, 最后对范德瓦耳斯铁电材料蕴含的丰富物理内涵及其发展前景进行了简要探讨, 希望能够为该领域的相关研究提供一些思路和参考.

关键词:

Abstract

Ferroelectric (FE) materials possess electrically switchable spontaneous polarizations, showing broad applications in various functional devices. For the miniaturization of electronic devices, two-dimensional (2D) van der Waals (vdW) ferroelectric materials and the corresponding bulk counterparts have aroused more interest of researchers. Recently, several kinds of 2D vdW ferroelectrics have been fabricated in experiment. These 2D vdW FEs, as well as their bulk counterparts, exhibit novel properties as demonstrated in experiment or predicted in theory. This paper is to review the recent progress of novel properties of several vdW ferroelectrics. In Section II, we introduce the unusual ferroelectric property—a uniaxial quadruple potential well for Cu displacements—enabled by the van der Waals gap in copper indium thiophosphate (CuInP₂S₆). The electric field drives the Cu atoms to unidirectionally cross the vdW gaps, which is distinctively different from dipole reorientation, resulting in an unusual phenomenon that the polarization of CuInP₂S₆ aligns against the direction of the applied electric field. The potential energy landscape for Cu displacements is strongly influenced by strain, accounting for the origin of the negative piezoelectric coefficient and making CuInP₂S₆ a rare example of a uniaxial multi-well ferroelectric. In Section III, we introduce the distinct geometric evolution mechanism of the newly reported M₂Ge₂Y₆ (M = metal, X = Si, Ge, Sn, Y = S, Sn, Te) monolayers and a high throughput screening of 2D ferroelectric candidates based on this mechanism. The ferroelectricity of M₂Ge₂Y₆ originates from the vertical displacement of Ge-dimer in the same direction driven by a soft phonon mode of the centrosymmetric configuration. Another centrosymmetric configuration is also dynamically stable but higher in energy than the ferroelectric phase. The metastable centrosymmetric phase of M₂Ge₂Y₆ monolayers allows a new two-step ferroelectric switching path and may induce novel domain behaviors. In Section IV, a new concept about constructing 2D ferroelectric QL-M₂O₃/graphene heterostructure to realize monolayer-based FE tunnel junctions or potentially graphene p-n junctions is reviewed. These findings provide new perspectives of the integration of graphene with monolayer FEs, as well as related functional devices. Finally, the challenge and prospect of vdW ferroelectrics are discussed, providing some perspective for the field of ferroelectrics.

Keywords:

作者及机构信息

1.
中国科学院物理研究所, 北京凝聚态物理国家研究中心, 北京　100190

2.
中国科学院大学, 北京　100049

3.
松山湖材料实验室, 东莞　523808

4.
中国科学院大学, 中国科学院拓扑量子计算卓越创新中心, 北京　100190

通信作者: 潘金波, jbpan@iphy.ac.cn ; 杜世萱, sxdu@iphy.ac.cn

基金项目: 国家自然科学基金(批准号: 61888102)、国家重点研发计划(批准号: 2016YFA0202300, 2018YFA0305800)和中国科学院战略性先导科技专项(批准号: XDB30000000)资助的课题.

Authors and contacts

1.
Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

2.
University of Chinese Academy of Sciences, Beijing 100049, China

3.
Songshan Lake Materials Laboratory, Dongguan 523808, China

4.
CAS Center for Excellence in Topological Quantum Computation, University of Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Pan Jin-Bo, jbpan@iphy.ac.cn ; Du Shi-Xuan, sxdu@iphy.ac.cn

Funds: Project supported by National Nature Science Foundation of China (Grant No. 61888102), the National Key R&D Program of China (Grant Nos. 2016YFA0202300, 2018YFA0305800), and the Strategic Priority Research Program of the Chinese Academy of Sciences, China (Grant No. XDB30000000).

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施引文献

图 1 (a), (b) 弛豫后的体相CuInP₂S₆的晶体结构, CuInP₂S₆分别处于$ + $LP和$ + $HP态, 对应其能量-极化曲线右侧第1个和第2个局域能量极小值; (c), (d) 体相CuInP₂S₆的能量随极化变化的曲线, (c) CuInP₂S₆晶格常数c取其平衡晶格常数13.09 Å, (d) CuInP₂S₆晶格常数c分别取13.62, 13.35, 12.83和12.57 Å^[16]

Fig. 1. (a), (b) Relaxed atomic configurations of bulk CuInP₂S₆ in $ + $LP and $ + $HP states, respectively, corresponding to the first and second local energy minimum in energy-polarization curve; (c), (d) energy of bulk CuInP₂S₆ as a function of its polarization, in which the lattice parameter c is equilibrium lattice constant 13.09 Å (c) and 13.62, 13.35, 12.83 and 12.57 Å (d), respectively^[16].

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图 2 (a), (b) CuInP₂S₆ $ + $HP态、$ + $LP态极化随应力的变化曲线; (c) CuInP₂S₆的定量压电系数图; (d) 图(c)中CuInP₂S₆压电系数的直方图统计, 其中4个极大值通过高斯函数进行拟合, 图中虚线为理论计算所得的压电系数^[16].

Fig. 2. (a), (b) Polarization as a function of stress for $ + $HP and $ + $LP state of CuInP₂S₆, respectively. (c) Quantified piezoelectric constant map of CuInP₂S₆. (d) histogram of piezoelectric constant extracted from (c), where the four distinct maxima are fitted by Gaussian function. The dashed lines denote the calculated piezoelectric constant of CuInP₂S₆^[16].

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图 3 (a) 实验上观察到的CuInP₂S₆的一条铁电翻转路径中, 极化随脉冲持续时间的变化曲线; (b) 图(a)中所示的翻转路径中, Cu原子相对位移随脉冲持续时间的变化曲线; (c) 图(a)所对应的翻转路径示意图; (d) 含有过量Cu原子的CuInP₂S₆在外电场下, 其中两层的Cu原子的演化轨迹^[17]

Fig. 3. (a) Polarization as a function of pulse duration time for one of the experimentally observed switching paths of CuInP₂S₆; (b) Cu relative displacement of as a function of pulse duration time for the switching paths in (a); (c) schematics of the switching path in (a); (d) evolution trajectory of Cu atoms in two individual layers for CuInP₂S₆ with excess Cu under external electric field^[17]

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图 4 目前已知的几类典型的二维铁电材料^{[18,19,22,34,36-38]}. “exp”代表该类材料已在实验上制备, “th”代表该类材料为理论预测结果. 箭头表示铁电极化方向

Fig. 4. Several typical known two-dimensional ferroelectric materials^{[18,19,22,34,36-38]}. “exp” and “th” denote that the corresponding materials are experimentally fabricated and theoretically predicted, respectively. Arrows represent the directions of ferroelectric polarizations.

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图 5 (a) 单层M₂X₂Y₆中通过X-dimer位移打破中心对称性的示意图; (b)—(d) 单层M₂X₂Y₆的高通量初筛结果. 对于被标识的金属原子M, 红色圆点表示初筛后所有的M₂X₂Y₆均保持铁电结构, 红色圆圈表示初筛后部分M₂X₂Y₆(一种或两种)保持铁电结构, 蓝色圆圈表示初筛后M₂X₂Y₆结构为扭曲极化结构^[40]

Fig. 5. (a) Schematic for the centrosymmetry breaking in M₂X₂Y₆ monolayer through X-dimer displacement; (b)–(d) primary high-throughput screening results for M₂X₂Y₆ monolayers. For the marked metal atom M, red dot represents that the M₂X₂Y₆ monolayers show ferroelectric structure after primary screening, red circle represents that one or two of the M₂X₂Y₆ monolayers show ferroelectric structure after primary screening, blue circle represents that the M₂X₂Y₆ monolayers show distorted polar structure after primary screening^[40].

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图 6 (a)—(c) 中心对称-I相、铁电相、中心对称-II相的单层Hf₂Ge₂Te₆的原子结构侧视图; (d)—(f) 中心对称-I相、铁电相、中心对称-II相的单层Hf₂Ge₂Te₆的声子谱; (g)—(i) 图(d)和(e)中标记点处的声子振动模式, 以及铁电相和中心对称-II相结构形成示意图, 图中红色箭头所示为Ge原子的振动方向^[40]

Fig. 6. (a)–(c) Side views of the atomic configurations of Hf₂Ge₂Te₆ monolayer in centrosymmetric-I, ferroelectric and centrosymmetric-II phases, respectively; (d)–(f) phonon dispersions of Hf₂Ge₂Te₆ monolayer in centrosymmetric-I, ferroelectric and centrosymmetric-II phases, respectively; (g)–(i) schematic of vibration modes at the marked points in panel (d) and (e), and the formation of the ferroelectric and centrosymmetric-II Hf₂Ge₂Te₆ monolayers, where the red arrows represent the vibration direction of Ge atoms^[40]

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图 7 (a), (c) 单层铁电Hf₂Ge₂Y₆ (Y = S, Se, Te)两种可能的铁电翻转路径的势垒; (b), (d) 两种可能的铁电翻转路径的示意图; (e)单层铁电Hf₂Ge₂Y₆从均匀极化向上态↑↑↑↑翻转为均匀极化向下态↓↓↓↓过程的翻转势垒, 图中每个势垒对应一个原胞内的极化翻转, 红色和黑色箭头代表每个原胞内的极化方向; (f)基于单层铁电Hf₂Ge₂Y₆的高密度存储器件示意图^[40]

Fig. 7. (a), (c) Ferroelectric switching barriers of the two possible switching paths of ferroelectric monolayers Hf₂Ge₂Y₆ (Y = S, Se, Te). (b), (d) Schematics of the two possible switching paths. (e) Ferroelectric switching barriers of Hf₂Ge₂Y₆ monolayers from a uniformed polarization up state ↑↑↑↑ to a polarization down state ↓↓↓↓, in which each barrier corresponds to polarization switching in one unit cell. The red and black arrows represent the polarization direction in each unit cell. (f) Schematic of the high-density storage device based on ferroelectric monolayer Hf₂Ge₂Y₆^[40].

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图 8 (a)—(c) 弛豫后的石墨烯/QL-In₂Se₃/Ru、石墨烯/QL-Al₂O₃/Ru异质结的原子构型, (b), (c)中QL-Al₂O₃的极化方向分别指向和远离石墨烯; (d)—(f) 图(a)—(c)所示构型的面平均静电势^[23]

Fig. 8. (a)–(c) Relaxed atomic configurations of graphene/QL-In₂Se₃/Ru and graphene/QL-M₂O₃/Ru heterostructure. The polarization of QL-Al₂O₃ in (b) and (c) points to and away from graphene, respectively. (d)–(f) Plane-averaged electrostatic potential (ESP) of (a)–(c), respectively^[23].

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图 9 (a), (b) 石墨烯/QL-Al₂O₃/Ru异质结原子层分辨的投影电子态密度及对应的能带示意图, (a), (b)异质结中QL-Al₂O₃极化分别指向和远离石墨烯; (c) 基于石墨烯/QL-M₂O₃ (M = Al, Y)/Ru异质结的功能器件示意图^[23]

Fig. 9. (a), (b) Layer-resolved projected density of states and corresponding band diagram of graphene/QL-Al₂O₃/Ru heterostructure when polarization points to (a) and away from (b) graphene; (c) schematics of functional devices based on graphene/QL-M₂O₃ (M = Al, Y)/Ru heterostructure^[23].

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map

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[2]	Kim J Y, Choi M J, Jang H W 2021 APL Mater. 9 021102 Google Scholar
[3]	Martin L W, Rappe A M 2016 Nat. Rev. Mater. 2 16087
[4]	Paillard C, Bai X, Infante I C, Guennou M, Geneste G, Alexe M, Kreisel J, Dkhil B 2016 Adv. Mater. 28 5153 Google Scholar
[5]	Cui C, Xue F, Hu W J, Li L J 2018 npj 2D Mater. Appl. 2 18 Google Scholar
[6]	Guan Z, Hu H, Shen X, Xiang P, Zhong N, Chu J, Duan C 2020 Adv. Electron. Mater. 6 1900818 Google Scholar
[7]	Qi L, Ruan S, Zeng Y J 2021 Adv. Mater. 33 2005098 Google Scholar
[8]	Wu M 2021 ACS Nano 15 9229 Google Scholar
[9]	Xue F, He J H, Zhang X 2021 Appl. Phys. Rev. 8 021316 Google Scholar
[10]	Yasuda K, Wang X, Watanabe K, Taniguchi T, Jarillo-Herrero P 2021 Science 372 1458 Google Scholar
[11]	Vizner Stern M, Waschitz Y, Cao W, Nevo I, Watanabe K, Taniguchi T, Sela E, Urbakh M, Hod O, Ben Shalom M 2021 Science 372 1462 Google Scholar
[12]	Li L, Wu M 2017 ACS Nano 11 6382 Google Scholar
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