全固态锂离子电池内部热输运研究前沿

吴成伟; 谢国锋; 周五星

doi:10.7498/aps.71.20211887

摘要

本文简要阐述了全固态锂离子电池的特点及其内部热输运研究的意义. 介绍并总结了国内外与正极材料、负极材料、固态电解质, 以及电极与电解质界面热输运性质相关的实验和理论工作. 针对脱嵌锂过程对电极材料热导率的影响机理尚不明确, 非晶态转变对电极材料热输运研究的挑战, 界面热输运模型与方法不足等问题, 系统梳理了全固态锂离子电池内部热输运的重要前沿科学问题.

关键词:

This paper briefly describes the characteristics of all-solid-state lithium-ion battery and the significance of investigation on the internal thermal transport. The related experimental and theoretical works on the thermal transport properties of cathode materials, anode materials, solid-state electrolytes, and electrode-electrolyte interfaces are introduced and summarized. In view of the unclear mechanism of the influence of lithium insertion and extraction process on the thermal conductivity of electrode materials, the challenge of solid-state amorphization to the research of thermal transport, and the limitation of models and methods in heat transport across the interface, we systematically sort out the important scientific issues of thermal transport in all-solid-state lithium-ion battery.

Keywords:

作者及机构信息

1.
湖南科技大学材料科学与工程学院, 湘潭　411201

2.
新能源储存与转换先进材料湖南省重点实验室, 湘潭　411201

通信作者: 谢国锋, xieguofeng@hnust.cn ; 周五星, wuxingzhou@hnu.edu.cn

基金项目: 国家自然科学基金(批准号: 12074115, 11874145)资助的课题.

Authors and contacts

1.
School of Materials Science and Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

2.
Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, Xiangtan 411201, China

Corresponding author: Xie Guo-Feng, xieguofeng@hnust.cn ; Zhou Wu-Xing, wuxingzhou@hnu.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 12074115, 11874145).

文章全文 : translate this paragraph

参考文献

[1]	余启, 刘琦, 王自强, 李宝华 2020 69 228805 Google Scholar Yu Q, Liu Q, Wang Z Q, Li B H 2020 Acta Phys. Sin. 69 228805 Google Scholar
[2]	拱越, 谷林 2020 69 226801 Google Scholar Gong Y, Gu L 2020 Acta Phys. Sin. 69 226801 Google Scholar
[3]	Kantharaj R, Marconnet A M 2019 Nanosci. Microsc. Therm. 23 128 Google Scholar
[4]	Koo B, Goli P, Sumant A V, dos Santos Claro P C, Rajh T, Johnson C S, Balandin A A, Shevchenko E V 2014 ACS Nano 8 7202 Google Scholar
[5]	Lee E, Salgado R A, Lee B, Sumant A V, Rajh T, Johnson C, Balandin A A, Shevchenko E V 2018 Carbon 129 702 Google Scholar
[6]	Vishwakarma V, Jain A 2017 J. Power Sources 362 219 Google Scholar
[7]	Meng H, Yu X X, Feng H, Xue Z G, Yang N 2019 Int. J. Heat Mass Transf. 137 1241 Google Scholar
[8]	Little W A 1959 Can. J. Phys. 37 334 Google Scholar
[9]	Swartz E T, Pohl R O 1987 Appl. Phys. Lett. 51 2200 Google Scholar
[10]	Young D A, Maris H J 1989 Phys. Rev. B 40 3685 Google Scholar
[11]	Tian Z, Esfarjani K, Chen G 2012 Phys. Rev. B 86 235304 Google Scholar
[12]	Ong Z Y, Zhang G 2015 Phys. Rev. B 91 174302 Google Scholar
[13]	Zhang W, Fisher T S, Mingo N 2006 J. Heat Transfer 129 483
[14]	Feng T, Yao W, Wang Z, Shi J, Li C, Cao B, Ruan X 2017 Phys. Rev. B 95 195202 Google Scholar
[15]	Feng T, Zhong Y, Shi J, Ruan X 2019 Phys. Rev. B 99 045301 Google Scholar
[16]	Sadasivam S, Waghmare U V, Fisher T S 2015 J. Appl. Phys. 117 134502 Google Scholar
[17]	Polanco C A, Lindsay L 2019 Phys. Rev. B 99 075202 Google Scholar
[18]	Dhakane A, Varshney V, Liu J, Heinz H, Jain A 2020 Surf. Interfaces 21 10067
[19]	Cho J, Losego M D, Zhang H G, Kim H, Zuo J, Petrov I, Cahill D G, Braun P V 2014 Nat. Commun. 5 4035 Google Scholar
[20]	Hu S, Zhang Z, Wang Z, Zeng K, Cheng Y, Chen J, Zhang G 2018 ES Energy Environ. 1 74
[21]	Qian X, Gu X, Dresselhaus M S, Yang R 2016 J. Phys. Chem. Lett. 7 4744 Google Scholar
[22]	Li H, Huang X J, Chen L Q, Zhou G W, Zhang Z, Yu D P, Mo Y J, Pei N, 2000 Solid State Ionics 135 181 Google Scholar
[23]	Hatchard T D, Dahn J R 2004 J. Electrochem. Soc. 151 A838 Google Scholar
[24]	Limthongkul P, Jang Y I, Dudney N J, Chiang Y M 2003 Acta Mater. 51 1103 Google Scholar
[25]	Reimers J N 1992 J. Electrochem. Soc. 139 2091 Google Scholar

施引文献

图 1 全固态锂离子电池结构以及充放电过程锂离子传输示意图

Fig. 1. All-solid-state lithium-ion battery structure and schematic diagram of lithium-ion transmission during charging and discharging.

下载: 全尺寸图片幻灯片

map

[1]	余启, 刘琦, 王自强, 李宝华 2020 69 228805 Google Scholar Yu Q, Liu Q, Wang Z Q, Li B H 2020 Acta Phys. Sin. 69 228805 Google Scholar
[2]	拱越, 谷林 2020 69 226801 Google Scholar Gong Y, Gu L 2020 Acta Phys. Sin. 69 226801 Google Scholar
[3]	Kantharaj R, Marconnet A M 2019 Nanosci. Microsc. Therm. 23 128 Google Scholar
[4]	Koo B, Goli P, Sumant A V, dos Santos Claro P C, Rajh T, Johnson C S, Balandin A A, Shevchenko E V 2014 ACS Nano 8 7202 Google Scholar
[5]	Lee E, Salgado R A, Lee B, Sumant A V, Rajh T, Johnson C, Balandin A A, Shevchenko E V 2018 Carbon 129 702 Google Scholar
[6]	Vishwakarma V, Jain A 2017 J. Power Sources 362 219 Google Scholar
[7]	Meng H, Yu X X, Feng H, Xue Z G, Yang N 2019 Int. J. Heat Mass Transf. 137 1241 Google Scholar
[8]	Little W A 1959 Can. J. Phys. 37 334 Google Scholar
[9]	Swartz E T, Pohl R O 1987 Appl. Phys. Lett. 51 2200 Google Scholar
[10]	Young D A, Maris H J 1989 Phys. Rev. B 40 3685 Google Scholar
[11]	Tian Z, Esfarjani K, Chen G 2012 Phys. Rev. B 86 235304 Google Scholar
[12]	Ong Z Y, Zhang G 2015 Phys. Rev. B 91 174302 Google Scholar
[13]	Zhang W, Fisher T S, Mingo N 2006 J. Heat Transfer 129 483
[14]	Feng T, Yao W, Wang Z, Shi J, Li C, Cao B, Ruan X 2017 Phys. Rev. B 95 195202 Google Scholar
[15]	Feng T, Zhong Y, Shi J, Ruan X 2019 Phys. Rev. B 99 045301 Google Scholar
[16]	Sadasivam S, Waghmare U V, Fisher T S 2015 J. Appl. Phys. 117 134502 Google Scholar
[17]	Polanco C A, Lindsay L 2019 Phys. Rev. B 99 075202 Google Scholar
[18]	Dhakane A, Varshney V, Liu J, Heinz H, Jain A 2020 Surf. Interfaces 21 10067
[19]	Cho J, Losego M D, Zhang H G, Kim H, Zuo J, Petrov I, Cahill D G, Braun P V 2014 Nat. Commun. 5 4035 Google Scholar
[20]	Hu S, Zhang Z, Wang Z, Zeng K, Cheng Y, Chen J, Zhang G 2018 ES Energy Environ. 1 74
[21]	Qian X, Gu X, Dresselhaus M S, Yang R 2016 J. Phys. Chem. Lett. 7 4744 Google Scholar
[22]	Li H, Huang X J, Chen L Q, Zhou G W, Zhang Z, Yu D P, Mo Y J, Pei N, 2000 Solid State Ionics 135 181 Google Scholar
[23]	Hatchard T D, Dahn J R 2004 J. Electrochem. Soc. 151 A838 Google Scholar
[24]	Limthongkul P, Jang Y I, Dudney N J, Chiang Y M 2003 Acta Mater. 51 1103 Google Scholar
[25]	Reimers J N 1992 J. Electrochem. Soc. 139 2091 Google Scholar

[1]	张袆柔, 曾晓淇, 李家星, 任怡茂, 吴伟雄. 锂离子电池颗粒尺度下电化学-热-力过充模型. , 2025, 74(3): 038201. doi: 10.7498/aps.74.20240984
[2]	申开波, 刘英光, 李鑫, 李亨宣. 石墨烯纳米网中的声子干涉效应. , 2023, 72(12): 123102. doi: 10.7498/aps.72.20230361
[3]	余泽浩, 张力发, 吴靖, 赵云山. 二维层状热电材料研究进展. , 2023, 72(5): 057301. doi: 10.7498/aps.72.20222095
[4]	谢忠祥, 喻霞, 贾聘真, 陈学坤, 邓元祥, 张勇, 周五星. 并苯分子结的热电性质. , 2023, 72(12): 124401. doi: 10.7498/aps.72.20230354
[5]	罗天麟, 丁亚飞, 韦宝杰, 杜建迎, 沈翔瀛, 朱桂妹, 李保文. 低维微纳尺度体系声子热传导和热调控: 来自芯片散热的非平衡统计物理问题. , 2023, 72(23): 234401. doi: 10.7498/aps.72.20231546
[6]	华彪, 孙宝珍, 王靖轩, 石晶, 徐波. Li含量对Li_3xLa_(2/3)–x†_(1/3)–2xTiO₃固态电解质表面稳定性、电子结构及Li离子输运性质的影响. , 2023, 72(2): 028201. doi: 10.7498/aps.72.20221808
[7]	何兵, 练宇翔, 吴木生, 罗文崴, 杨慎博, 欧阳楚英. 阳离子调控对卤化物固态电解质性能的改善. , 2022, 71(20): 208201. doi: 10.7498/aps.71.20221050
[8]	周逸凡, 杨慕紫, 佘峰权, 龚力, 张晓琪, 陈建, 宋树芹, 谢方艳. X射线光电子能谱在固态锂离子电池界面研究中的应用. , 2021, 70(17): 178801. doi: 10.7498/aps.70.20210180
[9]	余启鹏, 刘琦, 王自强, 李宝华. 全固态金属锂电池负极界面问题及解决策略. , 2020, 69(22): 228805. doi: 10.7498/aps.69.20201218
[10]	拱越, 谷林. 全固态电池中界面的结构演化和物质输运. , 2020, 69(22): 226801. doi: 10.7498/aps.69.20201160
[11]	曾建邦, 郭雪莹, 刘立超, 沈祖英, 单丰武, 罗玉峰. 基于电化学-热耦合模型研究隔膜孔隙结构对锂离子电池性能的影响机制. , 2019, 68(1): 018201. doi: 10.7498/aps.68.20181726
[12]	赵宁, 钟毅, 黄明亮, 马海涛, 刘小平. 热迁移对Cu/Sn/Cu焊点液-固界面Cu6Sn5生长动力学的影响. , 2015, 64(16): 166601. doi: 10.7498/aps.64.166601
[13]	马昊, 刘磊, 路雪森, 刘素平, 师建英. 锂离子电池正极材料Li2FeSiO4的电子结构与输运特性. , 2015, 64(24): 248201. doi: 10.7498/aps.64.248201
[14]	李娟, 汝强, 胡社军, 郭凌云. 锂离子电池SnSb/C复合负极材料的热碳还原法制备及电化学性能研究. , 2014, 63(16): 168201. doi: 10.7498/aps.63.168201
[15]	周化光, 林鑫, 王猛, 黄卫东. Cu固液界面能的分子动力学计算. , 2013, 62(5): 056803. doi: 10.7498/aps.62.056803
[16]	葛宋, 陈民. 接触角与液固界面热阻关系的分子动力学模拟. , 2013, 62(11): 110204. doi: 10.7498/aps.62.110204
[17]	鲍志刚, 陈元平, 欧阳滔, 杨凯科, 钟建新. L型石墨纳米结的热输运. , 2011, 60(2): 028103. doi: 10.7498/aps.60.028103
[18]	韩庆邦, 钱梦騄, 朱昌平. 激光超声方法研究固-固界面波传播特性. , 2007, 56(1): 313-320. doi: 10.7498/aps.56.313
[19]	陈存礼, 李建年, 华文玉. 钛-硅系快速热退火固相反应机制的研究. , 1990, 39(7): 127-133. doi: 10.7498/aps.39.127
[20]	金蔚青, 小松启. 固液界面温度的一种测量方法. , 1985, 34(9): 1166-1172. doi: 10.7498/aps.34.1166

计量

文章访问数: 6690
PDF下载量: 312
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板

全固态锂离子电池内部热输运研究前沿