全固态电池中界面的结构演化和物质输运

拱越; 谷林

doi:10.7498/aps.69.20201160

摘要

全固态电池中科学问题的本质在于引入的固态电解质的特性及全新的固-固界面的存在. 从构-效关系出发, 固-固界面和电解质自身的结构演化与物质输运过程决定了全固态电池的性能. 随着固态电解质材料研究的不断丰富, 目前全固态电池中的问题主要集中在固-固界面，界面处的组成和结构限制了全固态电池的性能. 根据固-固界面接触的情况不同, 本文按照固-固界面物理接触、化学接触和表面改性处理这三个层次总结与讨论全固态电池中固-固界面处的结构及其物质输运. 最后从功能材料功能性起源角度讨论局域对称性与宏观复杂体系下材料性能的关联.

关键词:

Abstract

The essence of the scientific problem in all solid-state batteries lies in the properties of the introduced solid electrolyte and the existence of a new solid-solid interface. Starting from the structure-property relationship, the structural evolution of the solid-solid interface and the electrolyte itself, and the matter transport process determine the performance of the all-solid-state battery. With the continuous enrichment of solid electrolyte materials, the current problems in all solid-state batteries are mainly concentrated on the solid-solid interface. The composition and structure at the interface limit the performance of all solid-state batteries. According to the different situations of solid-solid interface contact, this article summarizes and discusses the structure and matter transport at the solid-solid interface in all solid-state batteries according to the three levels of solid-solid interface physical contact, chemical contact and surface modification. Finally, the relationship between local symmetry and material properties under the macroscopic complex system is discussed from the perspective of the functional origin of functional materials.

Keywords:

作者及机构信息

拱越¹,
谷林^1,2,3

1.
中国科学院物理研究所, 先进材料与结构分析实验室, 北京　100190

2.
中国科学院大学，物理科学学院, 北京　100049

3.
松山湖材料实验室, 东莞　523808

通信作者: 谷林, l.gu@iphy.ac.cn

基金项目: 中国科学院前沿科学重点研究项目(批准号: QYZDB-SSW-JSC035)、国家自然科学基金(批准号: 51672307, 51421002)和博士后创新人才支持计划资助的课题

Authors and contacts

Gong Yue¹,
Gu Lin^1,2,3

1.
Laboratory of Advanced Materials & Electron Microscopy, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

2.
School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

3.
Songshan Lake Materials Laboratory, Dongguan 523808, China

Corresponding author: Gu Lin, l.gu@iphy.ac.cn

Funds: Project supported by the Key Research Program of Frontier Sciences, Chinese Academy of Sciens (Grant No. QYZDB-SSW-JSC035), the National Natural Science Foundation of China (Grant Nos. 51672307, 51421002), and the China National Postdoctoral Program for Innovative Talents

文章全文 : translate this paragraph

参考文献

[1]	Hu Y S 2016 Nat. Energy 1 16042 Google Scholar
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施引文献

图 1 全固态电池中存在的多种界面结构示意图^[5-8]

Fig. 1. Schematics of different interface structures in all-solid-state battery^[5-8].

下载: 全尺寸图片幻灯片

图 2 物理接触界面的结构和物质输运　(a) LCO正极在全固态电池中结构演化^[9]; (b) LNMO正极材料在全固态电池中的结构演化^[10]; (c) LCO/LLZO固-固接触界面结构和物质交换的调控^[12]; (d) NCM811/LGPS固-固接触界面在工作中的结构演化和物质交换^[13]

Fig. 2. Structure and material transport of the physical contact interface: (a) The structural evolution of the LCO positive electrode in an all-solid-state battery^[9]; (b) the structural evolution of LNMO cathode materials in all-solid-state batteries ^[10]; (c) regulation of LCO/LLZO solid-solid contact interface structure and material exchange^[12]; (d) structural evolution and material exchange of NCM811/LGPS solid-solid contact interface during operation^[13].

下载: 全尺寸图片幻灯片

图 3 化学接触界面的结构和物质输运　(a) Li/LAGP界面发生反应^[15]; (b) Li/LZPO界面反应^[16]; (c) Li/LLZO界面反应^[17]

Fig. 3. Structure and mater transport of the chemical contact interface: (a) Reaction at the Li/LAGP interface^[15]; (b) Li/LZPO interface reaction^[16]; (c) Li/LLZO interface reaction^[17].

下载: 全尺寸图片幻灯片

图 4 改善固-固界面物理接触　(a) 阴极支撑的固态电解质方案^[18]; (b) 电极表面原子尺度结构调控全固态电池的界面^[19]

Fig. 4. Improvement of the physical contact of the solid-solid interface: (a) A cathode-supported solid electrolyte membrane framework^[18]; (b) the surface structure of the electrode controlled by the interface of the all-solid-state battery^[19].

下载: 全尺寸图片幻灯片

图 5 电极和电解质的表面改性处理　(a) LAGP固态电解质的表面包覆处理^[20]; (b) LBH固态电解质的原位LiF表面修饰^[21]; (c) NCM523正极的表面包覆处理^[22]; (d) 金属锂负极的表面处理^[24].

Fig. 5. Surface modification treatment of electrode and electrolyte: (a) Surface treatment of LAGP solid electrolyte^[20]; (b) LBH solid electrolyte with in-situ LiF surface modification^[21]; (c) NCM523 positive electrode surface coating treatment^[22]; (d) Surface treatment of lithium metal anode^[24].

下载: 全尺寸图片幻灯片

map

[1]	Hu Y S 2016 Nat. Energy 1 16042 Google Scholar
[2]	Ma C, Chen K, Liang C, Nan C W, Ishikawa R, More K, Chi M 2014 Energy Environ. Sci. 7 1638 Google Scholar
[3]	Xiao D, Gu L 2020 Nano Sel. 1
[4]	Liu X Z, Tang Z X, Li Q H, Zhang Q H, Yu X Q, Gu L 2020 Cell Rep. Phys. Sci. 1 100066 Google Scholar
[5]	Nie K, Hong Y, Qiu J, Li Q, Yu X, Li H, Chen L 2018 Front. Chem. 6 1 Google Scholar
[6]	Xu L, Tang S, Cheng Y, Wang K, Liang J, Liu C, Cao Y C, Wei F, Mai L 2018 Joule 2 1991 Google Scholar
[7]	Xiao Y, Wang Y, Bo S H, Kim J C, Miara L J, Ceder G 2020 Nat. Rev. Mater. 5 105 Google Scholar
[8]	Banerjee A, Wang X, Fang C, Wu E A, Meng Y S 2020 Chem. Rev. acs.chemrev.0 c00101
[9]	Gong Y, Zhang J, Jiang L, Shi J A, Zhang Q, Yang Z, Zou D, Wang J, Yu X, Xiao R, Hu Y S, Gu L, Li H, Chen L 2017 J. Am. Chem. Soc. 139 4274 Google Scholar
[10]	Gong Y, Chen Y, Zhang Q, Meng F, Shi J A, Liu X, Liu X, Zhang J, Wang H, Wang J, Yu Q, Zhang Z, Xu Q, Xiao R, Hu Y S, Gu L, Li H, Huang X, Chen L 2018 Nat. Commun. 9 3341 Google Scholar
[11]	Ohta S, Kobayashi T, Seki J, Asaoka T 2012 J. Power Sources 202 332 Google Scholar
[12]	Vardar G, Bowman W J, Lu Q, Wang J, Chater R J, Aguadero A, Seibert R, Terry J, Hunt A, Waluyo I, Fong D D, Jarry A, Crumlin E J, Hellstrom S L, Chiang Y M, Yildiz B 2018 Chem. Mater. 30 6259 Google Scholar
[13]	Li X, Ren Z, Norouzi Banis M, Deng S, Zhao Y, Sun Q, Wang C, Yang X, Li W, Liang J, Li X, Sun Y, Adair K, Li R, Hu Y, Sham T K, Huang H, Zhang L, Lu S, Luo J, Sun X 2019 ACS Energy Lett. 4 2480 Google Scholar
[14]	Qiu J, Liu X, Chen R, Li Q, Wang Y, Chen P, Gan L, Lee S J, Nordlund D, Liu Y, Yu X, Bai X, Li H, Chen L 2020 Adv. Funct. Mater. 30 1909392 Google Scholar
[15]	Hartmann P, Leichtweiss T, Busche M R, Schneider M, Reich M, Sann J, Adelhelm P, Janek J 2013 J. Phys. Chem. C 117 21064 Google Scholar
[16]	Li Y, Zhou W, Chen X, Lü X, Cui Z, Xin S, Xue L, Jia Q, Goodenough J B 2016 Proc. Natl. Acad. Sci. 113 13313 Google Scholar
[17]	Ma C, Cheng Y, Yin K, Luo J, Sharafi A, Sakamoto J, Li J, More K L, Dudney N J, Chi M 2016 Nano Lett. 16 7030 Google Scholar
[18]	Chen X, He W, Ding L X, Wang S, Wang H 2019 Energy Environ. Sci. 12 938 Google Scholar
[19]	Shiraki S, Shirasawa T, Suzuki T, Kawasoko H, Shimizu R, Hitosugi T 2018 ACS Appl. Mater. Interfaces 10 41732 Google Scholar
[20]	Liu Y, Sun Q, Zhao Y, Wang B, Kaghazchi P, Adair K R, Li R, Zhang C, Liu J, Kuo L Y, Hu Y, Sham T K, Zhang L, Yang R, Lu S, Song X, Sun X 2018 Appl. Mater. Interfaces 10 31240 Google Scholar
[21]	Shi X, Pang Y, Wang B, Sun H, Wang X, Li Y, Yang J, Li H W, Zheng S 2020 Mater. Today Nano 10 1
[22]	Zhang Y, Tian Y, Xiao Y, Miara L J, Aihara Y, Tsujimura T, Shi T, Scott M C, Ceder G 2020 Adv. Energy Mater. 10 1903778 Google Scholar
[23]	Zhang L, Yang T, Du C, Liu Q, Tang Y, Zhao J, Wang B, Chen T, Sun Y, Jia P, Li H, Geng L, Chen J, Ye H, Wang Z, Li Y, Sun H, Li X, Dai Q, Tang Y, Peng Q, Shen T, Zhang S, Zhu T, Huang J 2020 Nat. Nanotechnol. 15 94 Google Scholar
[24]	Su Y, Ye L, Fitzhugh W, Wang Y, Gil-González E, Kim I, Li X 2020 Energy Environ. Sci. 13 908 Google Scholar

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