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本文提出一种基于微纳结构及金属纳米层的颜色调控方法. 通过理论分析研究, 建立了基于多孔氧化铝(PA) 微纳结构与金属纳米层的颜色调控物理模型. 以此为基础, 在孔深分别为250 nm和410 nm的PA模板表面磁控溅射铝(Al)金属纳米层, 对其反射干涉光谱分析可知, 通过控制PA模板的孔深可实现可见光谱范围内的颜色调控. 此外, 基于掩膜在孔深为410 nm的PA模板表面局域溅射铬(Cr)金属纳米层, 通过对其反射干涉光谱分析并与相同孔深的镀Al金属纳米层的PA颜色进行对比, 可以发现改变金属纳米层的材料和厚度同样可以实现颜色调控, 并通过局域颜色调控制备出彩色图案. 研究结果表明, 基于微纳结构及金属纳米层的颜色调控是一种切实可行和有效的方法.This article reports a novel color tuning technology based on micro-nano structure and metal nanolayer. On the basis of theoretical analysis, a color tuning model is established. Aluminum(Al) metal nanolayers are magnetron-sputtered on the surfaces of porour alumina (PA) templates with the pore-depths of 250 nm and 410 nm, and their pictures and reflective interference spectra show clearly green and red colors, respectively. These results indicate that different colors can be achieved just by controlling the pore-depth in PA templates. As comparison, a nanolayer of chromium(Cr) metal is magnetron-sputtered on the surface of PA template about 410 nm in pore-depth, the reflective interference spectra show that color tuning can also be achieved in the visible spectrum by changing the material and the thickness of the metal nanolayer. Moreover, a color pattern is further prepared based on mask and local sputtering method. Theoretical and experimental results validate the feasibility of this color tuning method.
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Keywords:
- micro nano structure /
- metal nanolayer /
- color tuning /
- porous alumina
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[16] Wang X L Q, Zhang D X, Zhang H J, Ma Y, Jiang J Z 2011 Nanotechnology 22 305306
[17] Wang X L Q, Zhang H J, Zhang D X, Ma Y, Fecht H J, Jiang J Z 2012 Microsc. Res. Tech. 75 698
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[19] Bragg W L 1912 Nature 90 410
[20] Bragg W H, Bragg W L 1913 P. Roy. Soc. A-Math. Phy. 88 428
[21] Zhang D X, Zhang H J, He Y L 2006 Microsc. Res. Tech. 69 267
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[1] Ghiradella H, Aneshansley D, Eisner T, Silberglied R E, Hinton H E 1972 Science 178 1214
[2] Nijhout H F 1991 Smithsonian Series in Comparative Evolutionary Biology (Washington, District of Columbia: Smithsonian Institutin Press)
[3] Nijhout H F 1994 Insect hormones (Princeton: Princeton University Press)
[4] Huang J, Wang X, Wang Z L 2006 Nano Lett. 6 2325
[5] Chen H M, Hsin C F, Liu R, Hu S F, Huang C Y 2007 J. Electrochem. Soc. 154 K11
[6] Yasui A, Iwasaki M, Kawahara T, Tada H, Ito S 2006 J. Colloid Interface Sci. 293 443
[7] Hu X, Pu Y J, Ling Z Y, Li Y 2009 Opt. Mater. 32 382
[8] Li Y, Wang C W, Tian J, Liu W M, Chen M, Li H L 2004 Acta Phys. Sin. 53 1594 (in Chinese) [李燕, 王成伟, 田军, 刘维民, 陈淼, 力虎林 2004 53 1594]
[9] Wang Y H, Mou J M, Cai W L, Xu Y Q 2001 Acta Phys. Sin. 50 1751 (in Chinese) [王银海, 牟季美, 蔡维理, 许彦旗 2001 50 1751]
[10] Vorobyev A Y, Guo C 2005 Phys. Rev. B 72 195422
[11] Vorobyev A Y, Guo C 2008 Appl. Phys. Lett. 92 041914
[12] Vorobyev A Y, Makin V, Guo C 2009 Phys. Rev. Lett. 102 234301
[13] Ge J, Hu Y, Yin Y 2007 Angew. Chem. 119 7572
[14] Ge J, Hu Y, Zhang T, Huynh T, Yin Y 2008 Langmuir 24 3671
[15] Ge J, Lee H, He L, Kim J, Lu Z, Kim H, Goebl J, Kwon S, Yin Y 2009 JACS 131 15687
[16] Wang X L Q, Zhang D X, Zhang H J, Ma Y, Jiang J Z 2011 Nanotechnology 22 305306
[17] Wang X L Q, Zhang H J, Zhang D X, Ma Y, Fecht H J, Jiang J Z 2012 Microsc. Res. Tech. 75 698
[18] Wang X L Q, Zhang H J, Zhang D X 2011 Acta Phys. Sin. 60 058104 (in Chinese) [王旭龙琦, 章海军, 张冬仙 2011 60 058104]
[19] Bragg W L 1912 Nature 90 410
[20] Bragg W H, Bragg W L 1913 P. Roy. Soc. A-Math. Phy. 88 428
[21] Zhang D X, Zhang H J, He Y L 2006 Microsc. Res. Tech. 69 267
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