掺铋离子BaO-B2O3玻璃的制备及其近红外发光性能的研究

刘军芳; 苏良碧; 唐慧丽; 徐军

doi:10.7498/aps.61.127806

摘要

采用高温熔融法制备了掺Bi离子的BaO-B2O3玻璃, 测定了样品玻璃的近红外以及可见光区的激发、发射谱、荧光衰减曲线以及Raman光谱. 在808 nm波长光的激发下, 在掺Bi离子的BaO-B2O3玻璃中发现了近红外发光现象, 且存在多个发光峰, 讨论了玻璃网络结构对Bi离子发光的影响, 对其发光机理进行了初步的探讨.

关键词:

Bi-doped BaO-B2O3 glasses are prepared by the melting method. Visible and infrared luminescence spectra, fluorescence decay curve and Raman scattering spectra are measured. NIR emissions, not only one broadband emission peak but also several emission peaks, appear in Bi-doped BaO-B2O3 glass under 808 nm LD pumping. The effect of the network structure of BaO-B2O3 glass on the NIR emission is discussed, and the mechanism for the emission is investigated preliminarily.

Keywords:

作者及机构信息

1.
同济大学材料科学与工程学院, 上海 200092;

2.
同济大学先进土木工程材料教育部重点实验室, 上海 200092;

3.
中国科学院上海硅酸盐研究所透明与光功能无机材料重点实验室, 上海 201800

基金项目: 国家自然科学基金青年科学基金(批准号: 61008045)资助的课题.

Authors and contacts

1.
College of Materials Science and Engineering, Tongji University, Shanghai 200092, China;

2.
Key Laboratory of Advanced Civil Engineering Materials (Tongji University), Ministry of Education, Shanghai 200092, China;

3.
Key Laboratory of Transparent and Opto-Functional Inorganic Materials, Shanghai Institute if Ceramics, Chinese Academy of Sciences, Shanghai 201800, China

Funds: Project supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 61008045) and the Fundamental Research Funds for the Central Universities.

参考文献

[1]	Yamada M, Ono H, Ohishi Y 1998 Electron. Lett. 34 1490
[2]	Fujimoto Y, Nakatsuka M 2001 Jpn. J. Appl. Phys. 40 L279
[3]	Dvoyrin V V, Mashinsky V M, Bulatov L I 2006 Opt. Lett. 31 2966
[4]	Arai Y, Suzuki T, Ohishi Y 2007 Appl. Phys. Lett. 90 261110
[5]	Sun H T, Miwa Y, Shimaoka F 2009 Opt. Lett. 34 1219
[6]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett. 33 1488
[7]	Peng M Y, Qiu J R, Cheng D P 2004 Opt. Lett. 29 1998
[8]	Peng M Y, Qiu J R, Cheng D P 2005 Opt. Lett. 30 2433
[9]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1628
[10]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1635
[11]	Ren J, Wu B, Jiang X 2007 Appl. Phys. B 88 363
[12]	Ren J, Qiu J R, Cheng D P 2008 J. of Alloys and Compounds 463 L5
[13]	Zhou S F, Dong H F, Zeng H P 2007 Appl. Phys. Lett. 91 061919
[14]	Peng M Y, Wu B T, Da N 2008 Journal of Non-Crystalline Solids 354 1221
[15]	Qiu J R, PengMY, Ren J J 2008 Journal of Non-Crystalline Solids 354 1235
[16]	Zhou S F, Jiang N, Zhu B 2008 Advanced Functional Materials 18 1407
[17]	Peng M Y, Zhao Q Z, Qiu J R 2009 J. Am. Ceram. Soc. 92 542
[18]	Zhou S F, Jiang N, Zhu B 2009 Advanced Functional Materials 192081
[19]	Xia H P Wang X J 2006 Appl. Phys. Lett. 89 051917
[20]	Xia H P, Wang X J 2008 Spectrochimica Acta A 70 122
[21]	Xia H P, Wang X J 2006 Optics Communications 268 75
[22]	Wang X J, Xia H P 2006 Acta Phys. Sin. 55 5263 (in Chinese)[王雪俊, 夏海平 2006 55 5263]
[23]	Su L B, Xu J, Zhou P 2009 Opt. Lett. 34 2504
[24]	Ruan J, Su L B, Qiu J R 2009 Optical Express 17 5163
[25]	Su L B, Zhou P, Xu J 2009 Optical Express 17 13554
[26]	Xu J, Zhao H Y, Su L B 2010 Optical Express 18 3385
[27]	Fujimoto Y, Nakatsuka M 2003 Appl. Phys. Lett. 82 3325
[28]	Khonthon S, Morinoto S, Arai Y 2007 J. Ceramic Society Jap. 115 259
[29]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett. 33 1488
[30]	Sharonov M Y, Bykov A B, Petricevic V 2008 Opt. Lett. 33 2131
[31]	Blasse G, Bril A 1968 J. Chem. Phys. 48 217
[32]	Srivastava A 1998 J. Lumin. 78 239
[33]	Andrey N, Akira Y, Martin M 2006 J. Cryst. Growth. 92 236
[34]	Zhang H J, Su Q 1998 Chinese J. Lumin. 9 231 (in Chinese)[张洪杰, 苏锵 1988 发光学报 9 231]
[35]	Blasse G, Meijerink A, Nomes M, Zuidema J 1994 J. Phys. Chem. Solids. 55 171
[36]	Mariska A. Hamastra, Hilda F. Folkerts, Geroge Blasse 1994 J. Mater. Chem. 4 1349
[37]	Chi G W, Zhou D C, Song Z G 2009 Optical Materials 31 945
[38]	Guo F Q 1997 Materials Science Engineering 15 39 (in Chinese) [郭凤岐 1997 材料科学与工程 15 39]
[39]	Guo F Q, Le X J, Cui W Q 1987 J. Wuhan University of Technology 1 61 (in Chinese)[郭凤岐, 乐雄军, 崔万秋 1987 武汉工业大学学报 1 61]
[40]	Huang P N, Jin Y F, Huang X H 1984 Acta Phys. Sin. 33 523 (in Chinese)[黄彭年, 金宜芬, 黄熙怀 1984 33 523]
[41]	Jin Y F, Ji Y S, Chen X S, Huo G Q, Huang X H 1985 Acta Phys. Sin. 34 1174 (in Chinese)[金宜芬, 季允送, 陈祥生, 霍根泉, 黄熙怀 1985 34 1174]
[42]	Santos C N, Menses D D S, Echegut P, Neuville D R, Hernandes A C, Ibanez A 2009 Appl. Phys. Lett. 94 151901
[43]	Zhou L F, Lin H X, Chen W Luo L 2008 Journal of Physics and Chemistry of Solids 69 2499

施引文献

[1]	Yamada M, Ono H, Ohishi Y 1998 Electron. Lett. 34 1490
[2]	Fujimoto Y, Nakatsuka M 2001 Jpn. J. Appl. Phys. 40 L279
[3]	Dvoyrin V V, Mashinsky V M, Bulatov L I 2006 Opt. Lett. 31 2966
[4]	Arai Y, Suzuki T, Ohishi Y 2007 Appl. Phys. Lett. 90 261110
[5]	Sun H T, Miwa Y, Shimaoka F 2009 Opt. Lett. 34 1219
[6]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett. 33 1488
[7]	Peng M Y, Qiu J R, Cheng D P 2004 Opt. Lett. 29 1998
[8]	Peng M Y, Qiu J R, Cheng D P 2005 Opt. Lett. 30 2433
[9]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1628
[10]	Meng X G, Qiu J R, Peng M Y 2005 Opt. Express 13 1635
[11]	Ren J, Wu B, Jiang X 2007 Appl. Phys. B 88 363
[12]	Ren J, Qiu J R, Cheng D P 2008 J. of Alloys and Compounds 463 L5
[13]	Zhou S F, Dong H F, Zeng H P 2007 Appl. Phys. Lett. 91 061919
[14]	Peng M Y, Wu B T, Da N 2008 Journal of Non-Crystalline Solids 354 1221
[15]	Qiu J R, PengMY, Ren J J 2008 Journal of Non-Crystalline Solids 354 1235
[16]	Zhou S F, Jiang N, Zhu B 2008 Advanced Functional Materials 18 1407
[17]	Peng M Y, Zhao Q Z, Qiu J R 2009 J. Am. Ceram. Soc. 92 542
[18]	Zhou S F, Jiang N, Zhu B 2009 Advanced Functional Materials 192081
[19]	Xia H P Wang X J 2006 Appl. Phys. Lett. 89 051917
[20]	Xia H P, Wang X J 2008 Spectrochimica Acta A 70 122
[21]	Xia H P, Wang X J 2006 Optics Communications 268 75
[22]	Wang X J, Xia H P 2006 Acta Phys. Sin. 55 5263 (in Chinese)[王雪俊, 夏海平 2006 55 5263]
[23]	Su L B, Xu J, Zhou P 2009 Opt. Lett. 34 2504
[24]	Ruan J, Su L B, Qiu J R 2009 Optical Express 17 5163
[25]	Su L B, Zhou P, Xu J 2009 Optical Express 17 13554
[26]	Xu J, Zhao H Y, Su L B 2010 Optical Express 18 3385
[27]	Fujimoto Y, Nakatsuka M 2003 Appl. Phys. Lett. 82 3325
[28]	Khonthon S, Morinoto S, Arai Y 2007 J. Ceramic Society Jap. 115 259
[29]	Sokolov V O, Plotnichenko V G, Dianov E M 2008 Opt. Lett. 33 1488
[30]	Sharonov M Y, Bykov A B, Petricevic V 2008 Opt. Lett. 33 2131
[31]	Blasse G, Bril A 1968 J. Chem. Phys. 48 217
[32]	Srivastava A 1998 J. Lumin. 78 239
[33]	Andrey N, Akira Y, Martin M 2006 J. Cryst. Growth. 92 236
[34]	Zhang H J, Su Q 1998 Chinese J. Lumin. 9 231 (in Chinese)[张洪杰, 苏锵 1988 发光学报 9 231]
[35]	Blasse G, Meijerink A, Nomes M, Zuidema J 1994 J. Phys. Chem. Solids. 55 171
[36]	Mariska A. Hamastra, Hilda F. Folkerts, Geroge Blasse 1994 J. Mater. Chem. 4 1349
[37]	Chi G W, Zhou D C, Song Z G 2009 Optical Materials 31 945
[38]	Guo F Q 1997 Materials Science Engineering 15 39 (in Chinese) [郭凤岐 1997 材料科学与工程 15 39]
[39]	Guo F Q, Le X J, Cui W Q 1987 J. Wuhan University of Technology 1 61 (in Chinese)[郭凤岐, 乐雄军, 崔万秋 1987 武汉工业大学学报 1 61]
[40]	Huang P N, Jin Y F, Huang X H 1984 Acta Phys. Sin. 33 523 (in Chinese)[黄彭年, 金宜芬, 黄熙怀 1984 33 523]
[41]	Jin Y F, Ji Y S, Chen X S, Huo G Q, Huang X H 1985 Acta Phys. Sin. 34 1174 (in Chinese)[金宜芬, 季允送, 陈祥生, 霍根泉, 黄熙怀 1985 34 1174]
[42]	Santos C N, Menses D D S, Echegut P, Neuville D R, Hernandes A C, Ibanez A 2009 Appl. Phys. Lett. 94 151901
[43]	Zhou L F, Lin H X, Chen W Luo L 2008 Journal of Physics and Chemistry of Solids 69 2499

[1]	张小安, 梅策香, 张颖, 梁昌慧, 周贤明, 曾利霞, 李耀宗, 柳钰, 向前兰, 孟惠, 王益军. ¹²⁹Xe^q⁺离子入射Cu靶表面激发的近红外光谱线和X射线谱. , 2020, 69(21): 213301. doi: 10.7498/aps.69.20200500
[2]	耿俊娴, 李少强, 王诗琪, 黄春, 吕云杰, 胡睿, 屈军乐, 刘丽炜. 近红外光刺激神经细胞钙离子光激活. , 2020, 69(15): 158701. doi: 10.7498/aps.69.20200489
[3]	王兴生, 马彦明, 高勋, 林景全. 纳秒脉冲激光诱导空气等离子体的近红外辐射特性. , 2020, 69(2): 029502. doi: 10.7498/aps.69.20190753
[4]	盖敏强, 王颖, 潘世烈. 类KBe₂BO₃F₂结构硼酸盐深紫外非线性光学材料的研究进展. , 2019, 68(2): 024208. doi: 10.7498/aps.68.20182145
[5]	马文君, 由芳田, 彭洪尚, 黄世华. 小粒径同质/异质壳层结构NaGdF4:3%Nd3+纳米颗粒的近红外发光特性. , 2017, 66(10): 107801. doi: 10.7498/aps.66.107801
[6]	熊中龙, 吴妍, 景锐平, 马冲, 龙蔚辉, 张超军, 程永进. 掺Yb硅酸盐玻璃的热漂白性能研究. , 2016, 65(4): 044208. doi: 10.7498/aps.65.044208
[7]	张喆, 柳倩, 祁志美. 基于金银合金薄膜的近红外表面等离子体共振传感器研究. , 2013, 62(6): 060703. doi: 10.7498/aps.62.060703
[8]	李永进, 宋志国, 李臣, 万荣华, 邱建备, 杨正文, 尹兆益, 王雪, 王齐, 周大成, 杨勇. 结构自还原效应对铋掺碱土金属硅磷铝硼玻璃超宽带近红外发光的影响. , 2013, 62(11): 117801. doi: 10.7498/aps.62.117801
[9]	刘军芳, 苏良碧, 徐军. Bi2O3-B2O3-BaO玻璃的制备及其近红外发光性能的研究. , 2013, 62(3): 037804. doi: 10.7498/aps.62.037804
[10]	周大成, 刘志亮, 宋志国, 杨正文, 何禧佳, 王荣飞, 焦清, 邱建备. 铋离子掺杂RO-Al2O3-SiO2玻璃近红外超宽带发光性质. , 2012, 61(12): 127802. doi: 10.7498/aps.61.127802
[11]	赵鹤玲, 夏海平, 罗彩香, 徐军. 掺Bi离子锗铌酸盐红外发光玻璃的研究. , 2012, 61(8): 086102. doi: 10.7498/aps.61.086102
[12]	赵衡煜, 俞平胜, 郭鑫, 苏良碧, 李欣年, 方晓明, 杨秋红, 徐军. 电子束辐照诱导Bi:α-BaB2O4 单晶近红外宽带发光的研究. , 2011, 60(9): 097802. doi: 10.7498/aps.60.097802
[13]	罗彩香, 夏海平, 虞灿, 徐军. 掺Bi钨酸镉单晶体发光特性的研究. , 2011, 60(7): 077806. doi: 10.7498/aps.60.077806
[14]	喻军, 周朋, 赵衡煜, 吴锋, 夏海平, 苏良碧, 徐军. γ射线辐照诱导Bi:α-BaB2O4单晶近红外宽带发光的研究. , 2010, 59(5): 3538-3541. doi: 10.7498/aps.59.3538
[15]	周朋, 苏良碧, 李红军, 喻军, 郑丽和, 杨秋红, 徐军. 掺铋BaF2晶体的制备及其近红外发光研究. , 2010, 59(4): 2827-2830. doi: 10.7498/aps.59.2827
[16]	陈飞, 张晓丹, 赵颖, 魏长春, 孙建. 硅薄膜沉积过程中等离子发光基团的一维空间分布研究. , 2008, 57(5): 3276-3280. doi: 10.7498/aps.57.3276
[17]	王雪俊, 夏海平. GeO2-Bi2O3-MOx(MOx=WO3, BaO)玻璃近红外超宽带发光的研究. , 2007, 56(5): 2725-2730. doi: 10.7498/aps.56.2725
[18]	叶晓岚, 邓文杰, 梁二军. 卤酸根离子的近红外表面增强Raman散射. , 1997, 46(11): 2130-2137. doi: 10.7498/aps.46.2130
[19]	黄彭年, 黄熙怀. MO2,M2O5和MO3氧化物对锂硼酸盐玻璃离子导电性的影响. , 1989, 38(10): 1628-1633. doi: 10.7498/aps.38.1628
[20]	郑海兴, 吴光照, 干福熹. 氟化物、氟磷酸盐和磷酸盐玻璃中Er3+离子的发光研究. , 1985, 34(12): 1582-1594. doi: 10.7498/aps.34.1582

计量

文章访问数: 7348
PDF下载量: 973
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板