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利用非线性光学(NLO)晶体材料和变频技术, 可以把波长范围有限的激光光源扩展到紫外、深紫外区, 这已成为深紫外光源的热点研究方向. 然而, 目前限制深紫外全固态激光器发展和应用的关键问题是缺乏能够在该波段进行频率转换并且产业化应用的NLO晶体材料. 因此, 该领域的各国科学家都在积极探索并发展新一代的深紫外NLO晶体材料. 目前仅有KBe2BO3F2 (KBBF)晶体能够实现Nd:YAG的直接六倍频深紫外激光(波长为177.3 nm)输出. 然而, KBBF晶体存在严重的层状生长习性, 并且其原料氧化铍有剧毒, 从而极大地制约了其商业化生产和应用进程. 根据阴离子基团理论, 以BO3基团为基本结构单元形成的类[Be2BO3F]层状结构特征仍然是目前最有利于产生深紫外谐波的适宜结构之一, 因此, 基于KBBF层状结构进行分子工程设计, 并开发类KBBF结构的硼酸盐可能是探索新材料的优选策略. 本文通过回顾类KBBF结构硼酸盐深紫外NLO晶体的发展历程, 系统梳理该类晶体材料层状结构特点、不同层间连接方式和光学性能, 分析限制深紫外NLO晶体发展的主要因素, 讨论目前发展类KBBF结构硼酸盐深紫外NLO晶体材料的主要矛盾和解决策略, 以期对未来新材料的创新探索提供借鉴.The use of nonlinear optical crystal materials to extend the limited range of laser sources to the deep-ultraviolet (deep-UV, λ < 200 nm) regions by various frequency conversion techniques, has become an attractive field for generating deep-UV light. However, the lack of nonlinear optics (NLO) crystal materials capable of frequency conversion in the deep-UV light range, limits the development and application of deep-UV all-solid-state lasers. Therefore, scientists all over the world are actively exploring the new generation of deep-UV NLO crystal materials. At present, only the KBe2BO3F2 (KBBF) crystal is capable of generating deep-UV light through the direct sixth harmonic generation of the Nd:YAG laser. The infinite ∞[Be2BO3F2]− single layers, as the brilliant building blocks in the crystal structures of KBBF family, provide a relatively large second harmonic generation coefficient (d11 = 0.47 pm/V) and a sufficient birefringence (Δn = 0.07@1064 nm). However, the KBBF crystals have insurmountable intrinsic defects, such as the usage of high toxic beryllium oxide, and the serious layer growth habit, which greatly restrict its commercialization process. Since the layered structure of the KBBF crystal is still one of the most brilliant structures for generating deep-UV laser, an effective strategy is to change the interlayer connection mode and develop new NLO materials based on KBBF with less layering growth habit. In this paper, by reviewing the development history of borate deep-UV NLO crystals and the derivatives of KBBF, the relationship between layered structure and optical properties of different interlaminar connections of crystal materials is systematically analyzed. We discuss the main contradictions and solutions of the development of deep-UV NLO crystal materials which are similar to the KBBF structure. In order to provide a reference for the innovative exploration of new materials in the future, several design strategies are also proposed.
[1] Maiman T H 1960 Nature 187 493
Google Scholar
[2] Franken P A, Hill A E, Peters C W, Weinreich G 1961 Phys. Rev. Lett. 7 118
Google Scholar
[3] Zernike F, Berman P R 1966 Phys. Rev. Lett. 16 117
Google Scholar
[4] Rao K S, Yoon K H 2003 J. Mater. Sci. 38 391
Google Scholar
[5] Cyranoski D 2009 Nature 457 953
Google Scholar
[6] Yao W J, He R, Wang X Y, Lin Z S, Chen C T 2014 Adv. Opt. Mater. 2 411
Google Scholar
[7] 陈创天, 刘丽娟, 王晓洋 2014 物理 43 520
Google Scholar
Chen C T, Liu L J, Wang X Y 2014 Physics 43 520
Google Scholar
[8] Tressaud A, Poeppelmeier K R 2016 Photonic and Electronic Properties of Fluoride Materials: Progress in Fluorine Science Series (Amsterdam: Elsevier)
[9] Tran T T, Yu H W, Rondinelli J M, Poeppelmeier K R, Halasyamani P S 2016 Chem. Mater. 28 5238
Google Scholar
[10] Halasyamani P S, Zhang W G 2017 Inorg. Chem. 56 12077
Google Scholar
[11] Wu C, Yang G, Humphrey M G, Zhang C 2018 Coord. Chem. Rev. 375 459
Google Scholar
[12] Shen Y G, Zhao S G, Luo J H 2018 Coord. Chem. Rev. 366 1
Google Scholar
[13] Yang Y, Jiang X X, Lin Z S, Wu Y C 2017 Crystals (Basel)
7 951 [14] Eimerl D, Davis L, Velsko S, Graham E, Zalkin A 1987 J. Appl. Phys. 62 1968
Google Scholar
[15] Chen C T, Wu Y C, Jiang A D, Wu B C, You G M, Li R K, Lin S J 1989 J. Opt. Soc. Am. B 6 616
Google Scholar
[16] 卢嘉锡, 吴新涛, 陈长章, 程文旦, 梁敬魁 1997 科学通报 42 561
Google Scholar
Lu J X, Wu X T, Chen C Z, Chen W D, Liang J K 1997 Chin. Sci. Bull. 42 561
Google Scholar
[17] Krogh-Moe J 1960 Acta Crystallogr. 13 889
Google Scholar
[18] Mori Y, Kuroda I, Nakajima S, Sasaki T, Nakai S 1995 Appl. Phys. Lett. 67 1818
Google Scholar
[19] 陈创天, 姚文娇 2011 光学学报 31 82
Chen C T, Yao W J 2011 Acta Opt. Sin. 31 82
[20] Mei L F, Wang Y B, Chen C T, Wu B 1993 J. Appl. Phys. 74 7014
Google Scholar
[21] Chen C T, Luo S Y, Wang X Y, Wang G L, Wen X H, Wu H X, Zhang X, Xu Z Y 2009 J. Opt. Soc. Am. B 26 1519
Google Scholar
[22] Huang H W, Chen C T, Wang X Y, Zhu Y, Wang G L, Zhang X, Wang L R, Yao J Y 2011 J. Opt. Soc. Am. B: Opt. Phys. 28 2186
Google Scholar
[23] Jones-Bey H 1998 Laser Focus World 34 127
[24] 陈创天, 许祖彦 2002 人工晶体学报 31 224
Google Scholar
Chen C T, Xu Z Y 2002 J. Synth. Cryst. 31 224
Google Scholar
[25] 刘丽娟, 陈创天 2010 中国材料进展 29 16
Liu L J, Chen C T 2010 Mater. Chin. 29 16
[26] Tran T T, Young J, Rondinelli J M, Halasyamani P S 2017 J. Am. Chem. Soc. 139 1285
Google Scholar
[27] Tran T T, He J G, Rondinelli J M, Halasyamani P S 2015 J. Am. Chem. Soc. 137 10504
Google Scholar
[28] Zhao S G, Gong P F, Luo S Y, Bai L, Lin Z S, Tang Y Y, Zhou Y L, Hong M C, Luo J H 2015 Angew. Chem. Int. Ed. 127 4291
Google Scholar
[29] Zhao S G, Gong P F, Luo S Y, Lei B, Lin Z S, Ji C M, Chen T L, Hong M C, Luo J H 2014 J. Am. Chem. Soc. 136 8560
Google Scholar
[30] Li L, Wang Y, Lei B H, Han S J, Yang Z H, Poeppelmeier K R, Pan S L 2016 J. Am. Chem. Soc. 138 9101
Google Scholar
[31] Shen Y G, Yang Y, Zhao S G, Zhao B Q, Lin Z S, Ji C M, Li L N, Fu P, Hong M C, Luo J H 2016 Chem. Mater. 28 7110
Google Scholar
[32] Zhou Z Y, Qiu Y, Liang F, Palatinus L, Poupon M, Yang T, Cong R H, Lin Z S, Sun J L 2018 Chem. Mater. 30 2203
Google Scholar
[33] Song J L, Hu C L, Xu X, Kong F, Mao J G 2015 Angew. Chem. Int. Ed. 46 3679
[34] Wu H P, Pan S L, Poeppelmeier K R, Li H Y, Jia D Z, Chen Z H, Fan X Y, Yang Y, Rondinelli J M, Luo H S 2011 J. Am. Chem. Soc. 133 7786
Google Scholar
[35] Wang Z J, Qiao H M, Su R B, Hu B, Yang X, He C, Long X 2018 Adv. Funct. Mater. 28 1804089
Google Scholar
[36] Sun Y Z, Li Z, Lee M H, Yang Z H, Pan S L, Sadeh B 2017 J. Phys. Soc. Jpn. 86 044401
Google Scholar
[37] Zhang B B, Han G P, Wang Y, Chen X L, Yang Z H, Pan S L 2018 Chem. Mater. 30 5397
Google Scholar
[38] Xiong L, Chen J, Lu J, Pan C Y, Wu L M 2018 Chem. Mater. 30 7823
Google Scholar
[39] Chen C T, Wang Y B, Wu B C, Wu K, Zeng W, Yu L 1995 Nature 373 322
Google Scholar
[40] Qi H, Chen C T 2001 Inorg. Chem. Commun. 4 565
Google Scholar
[41] Huang H W, Yao J Y, Lin Z S, Wang X Y, He R, Yao W J, Zhai N X, Chen C T 2011 Chem. Mater. 23 5457
Google Scholar
[42] Huang H W, Yao J Y, Lin Z S, Wang X Y, He R, Yao W J, Zhai N X, Chen C T 2011 Angew. Chem. Int. Ed. 123 9307
Google Scholar
[43] Guo S, Liu L J, Xia M J, Kang L, Huang Q, Li C, Wang X Y, Lin Z S, Chen C T 2016 Inorg. Chem. 47 6586
[44] Wang S C, Ye N, Li W, Zhao D 2010 J. Am. Chem. Soc. 132 8779
Google Scholar
[45] Wang S C, Ye N 2011 J. Am. Chem. Soc. 133 11458
Google Scholar
[46] Huang H, Liu L, Jin S, Yao W, Zhang Y, Chen C 2013 J. Am. Chem. Soc. 135 18319
Google Scholar
[47] Guo S, Liang F, Liu L J, Xia M J, Fang Z, Wu R F, Wang X Y, Lin Z S, Chen C T 2017 New J. Chem. 41 4269
Google Scholar
[48] Peng G, Ye N, Lin Z S, Kang L, Pan S L, Zhang M, Lin C, Long X, Luo M, Chen Y 2018 Angew. Chem. Int. Ed. 57 8968
Google Scholar
[49] Guo S, Jiang X X, Xia M J, Liu L, Fang Z, Huang Q, Wu R, Wang X, Lin Z S, Chen C T 2017 Inorg. Chem. 56 11451
Google Scholar
[50] Hu Z G, Higashiyama T, Yoshimura M, Yap Y K, Mori Y, Sasaki T 1998 Jpn. J. Appl. Phys. 3 7
[51] Tran T T, Koocher N Z, Rondinelli J M, Halasyamani P S 2017 Angew. Chem. Int. Ed. 56 2969
Google Scholar
[52] Ye N, Zeng W R, Wu B C, Chen C T 1998 Proc. SPIE-Int. Soc. Opt. Eng. p21
[53] Hu Z G, Yoshimura M, Muramatsu K, Mori Y, Sasaki T 2002 Jpn. J. Appl. Phys. 41 1131
Google Scholar
[54] Zhao S G, Gong P F, Luo S Y, Liu S J, Li L N, Asghar M A, Khan T, Hong M, Lin Z S, Luo J H 2015 J. Am. Chem. Soc. 46 2207
[55] Zhao B Q, Bai L, Li B X, Zhao S G, Shen Y G, Li X F, Ding Q R, Ji C M, Lin Z S, Luo J H 2017 Cryst. Growth Des. 18 1168
[56] Yu H W, Young J, Wu H P, Zhang W, Rondinelli J M, Halasyamani S 2017 Adv. Opt. Mater. 5 1700840
Google Scholar
[57] Wu H P, Yu H W, Pan S L, Halasyamani P S 2017 Inorg. Chem. 56 8755
Google Scholar
[58] Zou G, Lin C, Jo H, Nam G, You T S, Ok K M 2016 Angew. Chem. Int. Ed. 55 12078
Google Scholar
[59] Luo M, Song Y X, Liang F, Ye N, Lin Z S 2018 Inorg. Chem. Front. 5 916
Google Scholar
[60] Yu H W, Koocher N, Rondinelli J, Halasyamani P S 2018 Angew. Chem. Int. Ed. 57 6100
Google Scholar
[61] Zhao S G, Zhang J, Zhang S Q, Sun Z H, Lin Z S, Wu Y C, Hong M C, Luo J H 2014 Inorg. Chem. 53 2521
Google Scholar
[62] Yu H W, Wu H P, Pan S L, Yang Z H, Hou X L, Su X, Jing Q, Poeppelmeier K R, Rondinelli J M 2014 J. Am. Chem. Soc. 136 1264
Google Scholar
[63] Yang G S, Gong P F, Lin Z S, Ye N 2016 Chem. Mater. 28 9122
Google Scholar
[64] Xia M J, Li R K 2016 J. Solid State Chem. 233 58
Google Scholar
[65] Chen Y N, Zhang M, Pan S L 2018 New J. Chem. 42 12365
Google Scholar
[66] Duan M H, Xia M J, Li R K 2018 Eur. J. Inorg. Chem. 2018 3686
Google Scholar
[67] Zhao S G, Gong P F, Bai L, Xu X, Zhang S Q, Sun Z H, Lin Z S, Hong M C, Chen C T, Luo J H 2014 Nat. Commun. 5 4019
Google Scholar
[68] Zhang B B, Shi G Q, Yang Z H, Zhang F F, Pan S L 2017 Angew. Chem. Int. Ed. 56 3916
Google Scholar
[69] Shi G Q, Wang Y, Zhang F F, Zhang B B, Yang Z H, Hou X L, Pan S L, Poeppelmeier K R 2017 J. Am. Chem. Soc. 139 10645
Google Scholar
[70] Wang Y, Zhang B B, Yang Z H, Pan S L 2018 Angew. Chem. Int. Ed. 57 2150
Google Scholar
[71] Wang X F, Wang Y, Zhang B B, Zhang F F, Yang Z H, Pan S L 2017 Angew. Chem. Int. Ed. 56 14119
Google Scholar
[72] Zhang Z Z, Wang Y, Zhang B B, Yang Z H, Pan S L 2018 Angew. Chem. Int. Ed. 57 6577
Google Scholar
[73] Qi H, Chen C T 2001 Chem. Lett. 30 352
Google Scholar
[74] 沈耀国 2017 民营科技 6 56
Google Scholar
Shen Y G 2017 Pri.Tech. 6 56
Google Scholar
[75] 陈创天 1976 25 146
Google Scholar
Chen C T 1976 Acta Phys. Sin. 25 146
Google Scholar
[76] 陈创天 1977 26 486
Google Scholar
Chen C T 1977 Acta Phys. Sin. 26 486
Google Scholar
[77] 陈创天 1977 26 124
Google Scholar
Chen C T 1977 Acta Phys. Sin. 26 124
Google Scholar
[78] 陈创天 1978 27 41
Google Scholar
Chen C T 1978 Acta Phys. Sin. 27 41
Google Scholar
[79] Kang L, Luo S Y, Peng G, Ye N, Wu Y C, Chen C T, Lin Z S 2015 Inorg. Chem. 54 10533
Google Scholar
[80] Bian Q, Yang Z H, Wang Y C, Mutailipu M, Ma Y, Pan S 2018 Inorg. Chem. 57 5716
Google Scholar
[81] Huang Q, Liu L J, Wang X Y, Li R K, Chen C T 2016 Inorg. Chem. Commun. 55 12496
Google Scholar
[82] Atuchin V V, Bazarov B G, Gavrilova T A, Grossman V G, Molokeev M S, Bazarova Z G 2012 J. Alloys Compd. 515 119
Google Scholar
[83] Huang Q, Liu L J, Xia M J, Yang Y, Guo S, Wang X Y, Lin Z S, Chen C T 2017 Crystals 7 104
Google Scholar
[84] Hu Z G, Yoshimura M, Muramatsu K, Mori Y, Sasaki T 2002 Jpn. J. Appl. Phys., Part 2 41
[85] Hu Z G, Yue Y C, Chen X A, Yao J Y, Wang J N, Lin Z S 2011 Solid State Sci. 13 875
Google Scholar
[86] Li R K, Chen P 2010 Inorg. Chem. 49 1561
Google Scholar
[87] Mutailipu M, Zhang M, Wu H P, Yang Z H, Shen Y H, Sun J L, Pan S L 2018 Nat. Commun. 9 3089
Google Scholar
[88] He M, Chen X L, Okudera H, Simon A 2005 Chem. Mater. 17 2193
Google Scholar
[89] Shen Y G, Zhao S G, Yang Y, Cao L L, Wang Z J, Zhao B Q, Sun Z H, Lin Z S, Luo J H 2017 Cryst. Growth Des. 17 4422
Google Scholar
[90] Fang Z, Jiang X X, Duan M H, Hou Z Y, Tang C C, Xia M J, Liu L J, Lin Z S, Fan F D, Bai L, Chen C T 2018 Chem. - Eur. J. 24 7856
Google Scholar
[91] 盖敏强, 王颖, 潘世烈 2018 科学通报 63 998
Gai M Q, Wang Y, Pan S L 2018 Chin. Sci. Bull. 63 998
[92] Han G P, Wang Y, Zhang B B, Pan S L 2018 Chem.- Eur. J. 24 17638
Google Scholar
[93] Wang Y, Pan S L 2016 Coord. Chem. Rev. 323 15
Google Scholar
[94] Cakmak G, Nuss J, Jansen M 2009 Z. Anorg. Allg. Chem. 635 631
Google Scholar
[95] Pilz T, Jansen M 2011 Z. Anorg. Allg. Chem. 637 2148
Google Scholar
[96] Pilz T, Nuss H, Jansen M 2012 J. Solid State Chem. 186 104
Google Scholar
[97] Zhang Z Z, Wang Y, Zhang B B, Yang Z H, Pan S L 2018 Inorg. Chem. 57 4820
Google Scholar
[98] Mutailipu M, Zhang M, Zhang B B, Wang L Y, Yang Z H, Zhou X, Pan S L 2018 Angew. Chem. Int. Ed. 57 6095
Google Scholar
[99] Luo M, Liang F, Song Y X, Zhao D, Xu F, Ye N, Lin Z S 2018 J. Am. Chem. Soc. 140 3884
Google Scholar
[100] Mutailipu M, Zhang M, Zhang B B, Yang Z H, Pan S L 2018 Chem. Commun. 54 6308
Google Scholar
[101] Tang C C, Jiang X X, Yin W L, Liu L J, Xia M J, Huang Q, Song G M, Wang X Y, Lin Z S, Chen C T 2019 Dalton Trans. 48 21
Google Scholar
[102] 史国强 2017 硕士学位论文 (北京: 中国科学院大学)
Shi G Q 2017 M.S. Thesis(Beijing: University of Chinese Academy of Sciences) (in Chinese)
[103] Luo M, Liang F, Song Y X, Zhao D, Ye N, Lin Z S 2018 J. Am. Chem. Soc. 140 6814
Google Scholar
[104] Kang L, Lin Z S, Liu F, Huang B 2018 Inorg. Chem. 57 11146
Google Scholar
[105] Kang L, Liang F, Gong P F, Lin Z S, Liu F, Huang B 2018 Phys. Status Solidi RRL 12 1800276
Google Scholar
-
图 2 从KBBF 到Pb2BO3I的倍频效应演进
Fig. 2. Second harmonic generation evolution from KBBF to Pb2BO3I.
图 7 Sr2Be2B2O7和BaAl2B2O7晶体结构模型
Fig. 7. Ball-and-stick representations of Sr2Be2B2O7 and BaAl2B2O7.
图 8 K3Sr3Li2Al4B6O20F和K3Ba3Li2Al4B6O20F (KBLABF)的晶体结构模型
Fig. 8. Ball-and-stick representations of K3Sr3Li2Al4B6O20F and K3Ba3Li2Al4B6O20F (KBLABF).
图 11 层间由B—O共价键连接的系列硼酸盐晶体结构
Fig. 11. Crystal structures of the series borates contain B—O covalent bond.
表 1 层间含有离子键和氢键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
Table 1. Cmparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by ionic bond and hydrogen bond.
化合物 空间群 结构 层间连接 紫外截止边/nm deff (KDP)或dij/pm·V—1 NaBe2BO3F2[20] C2 [Be2BO3F2]∞ Na+—F− 155 deff = 1.7 × deff (NH4H2PO4) KBe2BO3F2[20] R32 [Be2BO3F2]∞ K+—F− 147 d11 = 0.47 ± 0.01 RbBe2BO3F2[21] R32 [Be2BO3F2]∞ Rb+—F− 160 d11 = 0.45 ± 0.01 CsBe2BO3F2[22] R32 [Be2 BO3F2]∞ Cs+—F− 151 d11 = 0.5 NH4Be2BO3F2[48] R32 [Be2BO3F2]∞ N—H·F 153 1.2 $\gamma $-Be2BO3F[48] R32 [Be2BO3F2]∞ Be2+—F− 144.8 2.3 RbZn2BO3Cl2[63,81] R32 [Zn2BO3Cl2]∞ Rb+—Cl− 198 2.9 KZn2BO3Cl2[63,81] R32 [Zn2BO3Cl2]∞ K+—Cl− 193 3.0 NH4Zn2BO3Cl2[63] R32 [Zn2BO3Cl2]∞ N—H·Cl 186 2.8 Be2(BO3)F[43] C2 [Be2BO3F2]∞ Be2+—F− 150 a 0.25 BaBe2BO3F3[43] P63 [Be2BO3F2]∞ Ba2+—F− < 185 0.1 K2Al2B2O7[50,52] P321 [Al3B3O6]∞ Al3+—O2− 180 0.45 K2(1-x)Na2xAl2BO7[88](0 < x < 0.6) P321 [Al3B3O6]∞ Al3+—O2− 180 0.45 K2(1−x)Rb2xAl2B2O7[82] (0 < x < 0.75) P321 [Al3B3O6]∞ Al3+—O2− — 0.7 K0.67Rb1.33Al2B2O7[83] P321 [Al3B3O6]∞ Al3+—O2− 188 0.9 $\beta$-Rb2Al2B2O7[51] P321 [Al3B3O6]∞ Al3+—O2− < 200 2.0 BaAlBO3F2[84] $ P{\overline 6}2c$ [AlBO3F2]∞ Ba2+—F− 165 2.0 Rb3Al3B3O10F[54] P31c [Al3(BO3)OF]∞ Al3+—F−Al3+—O2− < 200 1.2 BaZnBO3F[64] $ P{\overline 6}$ [ZnBO3F]∞ Zn2+—O2− — 3 × deff Ba3Mg3(BO3)3F3[87] Pna21 [Mg3O2F3(BO3)2]∞ Ba2+—F− 184 d33 = 0.51 注: 上标a为计算值. 
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表 2 SBBO型硼酸盐深紫外NLO材料的结构和光学性能比较
Table 2. Comparison of structural and optical properties of some deep-UV NLO materials of SBBO family.
化合物 空间群 结构 层间连接 紫外截止边/nm 倍频效应(KDP)或dij//pm·V−1 Sr2Be2B2O7[39] $ P{\overline 6}c2$ [Be2(BO3)2O]∞ Sr2+—O2− 155 2.5 Ba2Be2B2O7[40,73] $ P{\overline 6}2c$ [Be2(BO3)2O]∞ Ba2+—O2− 215 2.0 BaAl2B2O7[52] R32 [Al6B6O12]∞ Al3+—O2− — d11 = 0.75 NaCaBe2B2O6F[41] Cc [Be3B3O6F3]∞ Ca2+—O2− 190 0.3 K3Ba3Li2Al4B6O20F[55] $ P{\overline 6}2c$ [Li2Al4B6O20F]∞ Ba2+—O2− 190 1.5 Rb3Ba3Li2Al4B6O20F[89] $ P{\overline 6}2c$ [Li2Al4B6O20F]∞ Ba2+—O2− 195 1.4 K3Sr3Li2Al4B6O20F[57] R32 [Li2Al4B6O20F]∞ Sr2+—O2− 190 1.7 (0.9) Cs2Al2(B3O6)2O[90] P63 [Al2(B3O6)2O] Al3+—O2− 185 d31 = 0.032
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表 3 部分氟化硼酸盐深紫外NLO材料的结构和光学性能比较
Table 3. Comparison of structural and optical properties of some fluorooxoborates deep-UV NLO materials.
化合物 空间群 结构 层间连接方式 紫外截止边/nm 倍频效应(KDP) NH4B4O6F[69] Pna21 [B4O6F]∞ N—H·F 156 3.0 CsB4O6F[71] Pna21 [B4O6F]∞ Cs+—F− 155 1.9 RbB4O6F[70] Pna21 [B4O6F]∞ Rb+—F− < 190 0.8 CsKB8O12F2[70] P321 [B4O6F]∞ Cs/K+—F− < 190 1.9 CsRbB8O12F2[70] $ P{\overline 6}2c$ [B4O6F]∞ Cs/K+—F− < 190 1.1 NaB4O6F[72] C2 [B4O6F]∞ Na+—F− < 180 0.9 SrB5O7F3[98] Cmc21 [B5O7F3]∞ Sr2+—F− < 180 1.6 Sr2B10O14F6[99] < 200 2.5 CaB5O7F3[97] Cmc21 [B5O7F3]∞ Ca2+—F− < 180 2.0 Ca2B10O14F6[99] < 200 2.3
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表 4 层间含有B—O共价键连接的类KBBF结构硼酸盐深紫外NLO材料的结构和光学性能比较
Table 4. Comparison of structural and optical properties of some deep-UV NLO materials of KBBF family with adjacent layers connected by rigid B—O groups.
化合物 空间群 结构 层间连接方式 紫外截止边/nm 倍频效应(KDP) $ \beta $-KBe2B3O7[44] Pmn21 [Be2BO5]∞ [BO2]∞ < 200 0.75 $\gamma $-KBe2B3O7[44] P21 [Be2BO5]∞ [B3O6] < 200 0.68 RbBe2B3O7[44] Pmn21 [Be2BO5]∞ [BO2]∞ < 200 0.79 Na2CsBe6B5O15[45] C2 [Be2BO5]∞ [BO3] < 200 1.17 Na2Be4B4O11[46] P1 [Be2BO5]∞ [B2O5] 171 1.30 LiNa5Be12B12O23[46] Pc [Be2BO5]∞ [B2O5] 169 1.40 Li4Sr(BO3)2[67] Cc [SrBO3]∞ [B2O3] 186 2.00
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[1] Maiman T H 1960 Nature 187 493
Google Scholar
[2] Franken P A, Hill A E, Peters C W, Weinreich G 1961 Phys. Rev. Lett. 7 118
Google Scholar
[3] Zernike F, Berman P R 1966 Phys. Rev. Lett. 16 117
Google Scholar
[4] Rao K S, Yoon K H 2003 J. Mater. Sci. 38 391
Google Scholar
[5] Cyranoski D 2009 Nature 457 953
Google Scholar
[6] Yao W J, He R, Wang X Y, Lin Z S, Chen C T 2014 Adv. Opt. Mater. 2 411
Google Scholar
[7] 陈创天, 刘丽娟, 王晓洋 2014 物理 43 520
Google Scholar
Chen C T, Liu L J, Wang X Y 2014 Physics 43 520
Google Scholar
[8] Tressaud A, Poeppelmeier K R 2016 Photonic and Electronic Properties of Fluoride Materials: Progress in Fluorine Science Series (Amsterdam: Elsevier)
[9] Tran T T, Yu H W, Rondinelli J M, Poeppelmeier K R, Halasyamani P S 2016 Chem. Mater. 28 5238
Google Scholar
[10] Halasyamani P S, Zhang W G 2017 Inorg. Chem. 56 12077
Google Scholar
[11] Wu C, Yang G, Humphrey M G, Zhang C 2018 Coord. Chem. Rev. 375 459
Google Scholar
[12] Shen Y G, Zhao S G, Luo J H 2018 Coord. Chem. Rev. 366 1
Google Scholar
[13] Yang Y, Jiang X X, Lin Z S, Wu Y C 2017 Crystals (Basel)
7 951 [14] Eimerl D, Davis L, Velsko S, Graham E, Zalkin A 1987 J. Appl. Phys. 62 1968
Google Scholar
[15] Chen C T, Wu Y C, Jiang A D, Wu B C, You G M, Li R K, Lin S J 1989 J. Opt. Soc. Am. B 6 616
Google Scholar
[16] 卢嘉锡, 吴新涛, 陈长章, 程文旦, 梁敬魁 1997 科学通报 42 561
Google Scholar
Lu J X, Wu X T, Chen C Z, Chen W D, Liang J K 1997 Chin. Sci. Bull. 42 561
Google Scholar
[17] Krogh-Moe J 1960 Acta Crystallogr. 13 889
Google Scholar
[18] Mori Y, Kuroda I, Nakajima S, Sasaki T, Nakai S 1995 Appl. Phys. Lett. 67 1818
Google Scholar
[19] 陈创天, 姚文娇 2011 光学学报 31 82
Chen C T, Yao W J 2011 Acta Opt. Sin. 31 82
[20] Mei L F, Wang Y B, Chen C T, Wu B 1993 J. Appl. Phys. 74 7014
Google Scholar
[21] Chen C T, Luo S Y, Wang X Y, Wang G L, Wen X H, Wu H X, Zhang X, Xu Z Y 2009 J. Opt. Soc. Am. B 26 1519
Google Scholar
[22] Huang H W, Chen C T, Wang X Y, Zhu Y, Wang G L, Zhang X, Wang L R, Yao J Y 2011 J. Opt. Soc. Am. B: Opt. Phys. 28 2186
Google Scholar
[23] Jones-Bey H 1998 Laser Focus World 34 127
[24] 陈创天, 许祖彦 2002 人工晶体学报 31 224
Google Scholar
Chen C T, Xu Z Y 2002 J. Synth. Cryst. 31 224
Google Scholar
[25] 刘丽娟, 陈创天 2010 中国材料进展 29 16
Liu L J, Chen C T 2010 Mater. Chin. 29 16
[26] Tran T T, Young J, Rondinelli J M, Halasyamani P S 2017 J. Am. Chem. Soc. 139 1285
Google Scholar
[27] Tran T T, He J G, Rondinelli J M, Halasyamani P S 2015 J. Am. Chem. Soc. 137 10504
Google Scholar
[28] Zhao S G, Gong P F, Luo S Y, Bai L, Lin Z S, Tang Y Y, Zhou Y L, Hong M C, Luo J H 2015 Angew. Chem. Int. Ed. 127 4291
Google Scholar
[29] Zhao S G, Gong P F, Luo S Y, Lei B, Lin Z S, Ji C M, Chen T L, Hong M C, Luo J H 2014 J. Am. Chem. Soc. 136 8560
Google Scholar
[30] Li L, Wang Y, Lei B H, Han S J, Yang Z H, Poeppelmeier K R, Pan S L 2016 J. Am. Chem. Soc. 138 9101
Google Scholar
[31] Shen Y G, Yang Y, Zhao S G, Zhao B Q, Lin Z S, Ji C M, Li L N, Fu P, Hong M C, Luo J H 2016 Chem. Mater. 28 7110
Google Scholar
[32] Zhou Z Y, Qiu Y, Liang F, Palatinus L, Poupon M, Yang T, Cong R H, Lin Z S, Sun J L 2018 Chem. Mater. 30 2203
Google Scholar
[33] Song J L, Hu C L, Xu X, Kong F, Mao J G 2015 Angew. Chem. Int. Ed. 46 3679
[34] Wu H P, Pan S L, Poeppelmeier K R, Li H Y, Jia D Z, Chen Z H, Fan X Y, Yang Y, Rondinelli J M, Luo H S 2011 J. Am. Chem. Soc. 133 7786
Google Scholar
[35] Wang Z J, Qiao H M, Su R B, Hu B, Yang X, He C, Long X 2018 Adv. Funct. Mater. 28 1804089
Google Scholar
[36] Sun Y Z, Li Z, Lee M H, Yang Z H, Pan S L, Sadeh B 2017 J. Phys. Soc. Jpn. 86 044401
Google Scholar
[37] Zhang B B, Han G P, Wang Y, Chen X L, Yang Z H, Pan S L 2018 Chem. Mater. 30 5397
Google Scholar
[38] Xiong L, Chen J, Lu J, Pan C Y, Wu L M 2018 Chem. Mater. 30 7823
Google Scholar
[39] Chen C T, Wang Y B, Wu B C, Wu K, Zeng W, Yu L 1995 Nature 373 322
Google Scholar
[40] Qi H, Chen C T 2001 Inorg. Chem. Commun. 4 565
Google Scholar
[41] Huang H W, Yao J Y, Lin Z S, Wang X Y, He R, Yao W J, Zhai N X, Chen C T 2011 Chem. Mater. 23 5457
Google Scholar
[42] Huang H W, Yao J Y, Lin Z S, Wang X Y, He R, Yao W J, Zhai N X, Chen C T 2011 Angew. Chem. Int. Ed. 123 9307
Google Scholar
[43] Guo S, Liu L J, Xia M J, Kang L, Huang Q, Li C, Wang X Y, Lin Z S, Chen C T 2016 Inorg. Chem. 47 6586
[44] Wang S C, Ye N, Li W, Zhao D 2010 J. Am. Chem. Soc. 132 8779
Google Scholar
[45] Wang S C, Ye N 2011 J. Am. Chem. Soc. 133 11458
Google Scholar
[46] Huang H, Liu L, Jin S, Yao W, Zhang Y, Chen C 2013 J. Am. Chem. Soc. 135 18319
Google Scholar
[47] Guo S, Liang F, Liu L J, Xia M J, Fang Z, Wu R F, Wang X Y, Lin Z S, Chen C T 2017 New J. Chem. 41 4269
Google Scholar
[48] Peng G, Ye N, Lin Z S, Kang L, Pan S L, Zhang M, Lin C, Long X, Luo M, Chen Y 2018 Angew. Chem. Int. Ed. 57 8968
Google Scholar
[49] Guo S, Jiang X X, Xia M J, Liu L, Fang Z, Huang Q, Wu R, Wang X, Lin Z S, Chen C T 2017 Inorg. Chem. 56 11451
Google Scholar
[50] Hu Z G, Higashiyama T, Yoshimura M, Yap Y K, Mori Y, Sasaki T 1998 Jpn. J. Appl. Phys. 3 7
[51] Tran T T, Koocher N Z, Rondinelli J M, Halasyamani P S 2017 Angew. Chem. Int. Ed. 56 2969
Google Scholar
[52] Ye N, Zeng W R, Wu B C, Chen C T 1998 Proc. SPIE-Int. Soc. Opt. Eng. p21
[53] Hu Z G, Yoshimura M, Muramatsu K, Mori Y, Sasaki T 2002 Jpn. J. Appl. Phys. 41 1131
Google Scholar
[54] Zhao S G, Gong P F, Luo S Y, Liu S J, Li L N, Asghar M A, Khan T, Hong M, Lin Z S, Luo J H 2015 J. Am. Chem. Soc. 46 2207
[55] Zhao B Q, Bai L, Li B X, Zhao S G, Shen Y G, Li X F, Ding Q R, Ji C M, Lin Z S, Luo J H 2017 Cryst. Growth Des. 18 1168
[56] Yu H W, Young J, Wu H P, Zhang W, Rondinelli J M, Halasyamani S 2017 Adv. Opt. Mater. 5 1700840
Google Scholar
[57] Wu H P, Yu H W, Pan S L, Halasyamani P S 2017 Inorg. Chem. 56 8755
Google Scholar
[58] Zou G, Lin C, Jo H, Nam G, You T S, Ok K M 2016 Angew. Chem. Int. Ed. 55 12078
Google Scholar
[59] Luo M, Song Y X, Liang F, Ye N, Lin Z S 2018 Inorg. Chem. Front. 5 916
Google Scholar
[60] Yu H W, Koocher N, Rondinelli J, Halasyamani P S 2018 Angew. Chem. Int. Ed. 57 6100
Google Scholar
[61] Zhao S G, Zhang J, Zhang S Q, Sun Z H, Lin Z S, Wu Y C, Hong M C, Luo J H 2014 Inorg. Chem. 53 2521
Google Scholar
[62] Yu H W, Wu H P, Pan S L, Yang Z H, Hou X L, Su X, Jing Q, Poeppelmeier K R, Rondinelli J M 2014 J. Am. Chem. Soc. 136 1264
Google Scholar
[63] Yang G S, Gong P F, Lin Z S, Ye N 2016 Chem. Mater. 28 9122
Google Scholar
[64] Xia M J, Li R K 2016 J. Solid State Chem. 233 58
Google Scholar
[65] Chen Y N, Zhang M, Pan S L 2018 New J. Chem. 42 12365
Google Scholar
[66] Duan M H, Xia M J, Li R K 2018 Eur. J. Inorg. Chem. 2018 3686
Google Scholar
[67] Zhao S G, Gong P F, Bai L, Xu X, Zhang S Q, Sun Z H, Lin Z S, Hong M C, Chen C T, Luo J H 2014 Nat. Commun. 5 4019
Google Scholar
[68] Zhang B B, Shi G Q, Yang Z H, Zhang F F, Pan S L 2017 Angew. Chem. Int. Ed. 56 3916
Google Scholar
[69] Shi G Q, Wang Y, Zhang F F, Zhang B B, Yang Z H, Hou X L, Pan S L, Poeppelmeier K R 2017 J. Am. Chem. Soc. 139 10645
Google Scholar
[70] Wang Y, Zhang B B, Yang Z H, Pan S L 2018 Angew. Chem. Int. Ed. 57 2150
Google Scholar
[71] Wang X F, Wang Y, Zhang B B, Zhang F F, Yang Z H, Pan S L 2017 Angew. Chem. Int. Ed. 56 14119
Google Scholar
[72] Zhang Z Z, Wang Y, Zhang B B, Yang Z H, Pan S L 2018 Angew. Chem. Int. Ed. 57 6577
Google Scholar
[73] Qi H, Chen C T 2001 Chem. Lett. 30 352
Google Scholar
[74] 沈耀国 2017 民营科技 6 56
Google Scholar
Shen Y G 2017 Pri.Tech. 6 56
Google Scholar
[75] 陈创天 1976 25 146
Google Scholar
Chen C T 1976 Acta Phys. Sin. 25 146
Google Scholar
[76] 陈创天 1977 26 486
Google Scholar
Chen C T 1977 Acta Phys. Sin. 26 486
Google Scholar
[77] 陈创天 1977 26 124
Google Scholar
Chen C T 1977 Acta Phys. Sin. 26 124
Google Scholar
[78] 陈创天 1978 27 41
Google Scholar
Chen C T 1978 Acta Phys. Sin. 27 41
Google Scholar
[79] Kang L, Luo S Y, Peng G, Ye N, Wu Y C, Chen C T, Lin Z S 2015 Inorg. Chem. 54 10533
Google Scholar
[80] Bian Q, Yang Z H, Wang Y C, Mutailipu M, Ma Y, Pan S 2018 Inorg. Chem. 57 5716
Google Scholar
[81] Huang Q, Liu L J, Wang X Y, Li R K, Chen C T 2016 Inorg. Chem. Commun. 55 12496
Google Scholar
[82] Atuchin V V, Bazarov B G, Gavrilova T A, Grossman V G, Molokeev M S, Bazarova Z G 2012 J. Alloys Compd. 515 119
Google Scholar
[83] Huang Q, Liu L J, Xia M J, Yang Y, Guo S, Wang X Y, Lin Z S, Chen C T 2017 Crystals 7 104
Google Scholar
[84] Hu Z G, Yoshimura M, Muramatsu K, Mori Y, Sasaki T 2002 Jpn. J. Appl. Phys., Part 2 41
[85] Hu Z G, Yue Y C, Chen X A, Yao J Y, Wang J N, Lin Z S 2011 Solid State Sci. 13 875
Google Scholar
[86] Li R K, Chen P 2010 Inorg. Chem. 49 1561
Google Scholar
[87] Mutailipu M, Zhang M, Wu H P, Yang Z H, Shen Y H, Sun J L, Pan S L 2018 Nat. Commun. 9 3089
Google Scholar
[88] He M, Chen X L, Okudera H, Simon A 2005 Chem. Mater. 17 2193
Google Scholar
[89] Shen Y G, Zhao S G, Yang Y, Cao L L, Wang Z J, Zhao B Q, Sun Z H, Lin Z S, Luo J H 2017 Cryst. Growth Des. 17 4422
Google Scholar
[90] Fang Z, Jiang X X, Duan M H, Hou Z Y, Tang C C, Xia M J, Liu L J, Lin Z S, Fan F D, Bai L, Chen C T 2018 Chem. - Eur. J. 24 7856
Google Scholar
[91] 盖敏强, 王颖, 潘世烈 2018 科学通报 63 998
Gai M Q, Wang Y, Pan S L 2018 Chin. Sci. Bull. 63 998
[92] Han G P, Wang Y, Zhang B B, Pan S L 2018 Chem.- Eur. J. 24 17638
Google Scholar
[93] Wang Y, Pan S L 2016 Coord. Chem. Rev. 323 15
Google Scholar
[94] Cakmak G, Nuss J, Jansen M 2009 Z. Anorg. Allg. Chem. 635 631
Google Scholar
[95] Pilz T, Jansen M 2011 Z. Anorg. Allg. Chem. 637 2148
Google Scholar
[96] Pilz T, Nuss H, Jansen M 2012 J. Solid State Chem. 186 104
Google Scholar
[97] Zhang Z Z, Wang Y, Zhang B B, Yang Z H, Pan S L 2018 Inorg. Chem. 57 4820
Google Scholar
[98] Mutailipu M, Zhang M, Zhang B B, Wang L Y, Yang Z H, Zhou X, Pan S L 2018 Angew. Chem. Int. Ed. 57 6095
Google Scholar
[99] Luo M, Liang F, Song Y X, Zhao D, Xu F, Ye N, Lin Z S 2018 J. Am. Chem. Soc. 140 3884
Google Scholar
[100] Mutailipu M, Zhang M, Zhang B B, Yang Z H, Pan S L 2018 Chem. Commun. 54 6308
Google Scholar
[101] Tang C C, Jiang X X, Yin W L, Liu L J, Xia M J, Huang Q, Song G M, Wang X Y, Lin Z S, Chen C T 2019 Dalton Trans. 48 21
Google Scholar
[102] 史国强 2017 硕士学位论文 (北京: 中国科学院大学)
Shi G Q 2017 M.S. Thesis(Beijing: University of Chinese Academy of Sciences) (in Chinese)
[103] Luo M, Liang F, Song Y X, Zhao D, Ye N, Lin Z S 2018 J. Am. Chem. Soc. 140 6814
Google Scholar
[104] Kang L, Lin Z S, Liu F, Huang B 2018 Inorg. Chem. 57 11146
Google Scholar
[105] Kang L, Liang F, Gong P F, Lin Z S, Liu F, Huang B 2018 Phys. Status Solidi RRL 12 1800276
Google Scholar
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