全固态锂离子电池内部热输运研究前沿

吴成伟; 谢国锋; 周五星

doi:10.7498/aps.71.20211887

摘要

本文简要阐述了全固态锂离子电池的特点及其内部热输运研究的意义. 介绍并总结了国内外与正极材料、负极材料、固态电解质, 以及电极与电解质界面热输运性质相关的实验和理论工作. 针对脱嵌锂过程对电极材料热导率的影响机理尚不明确, 非晶态转变对电极材料热输运研究的挑战, 界面热输运模型与方法不足等问题, 系统梳理了全固态锂离子电池内部热输运的重要前沿科学问题.

关键词:

This paper briefly describes the characteristics of all-solid-state lithium-ion battery and the significance of investigation on the internal thermal transport. The related experimental and theoretical works on the thermal transport properties of cathode materials, anode materials, solid-state electrolytes, and electrode-electrolyte interfaces are introduced and summarized. In view of the unclear mechanism of the influence of lithium insertion and extraction process on the thermal conductivity of electrode materials, the challenge of solid-state amorphization to the research of thermal transport, and the limitation of models and methods in heat transport across the interface, we systematically sort out the important scientific issues of thermal transport in all-solid-state lithium-ion battery.

Keywords:

作者及机构信息

1.
湖南科技大学材料科学与工程学院, 湘潭　411201

2.
新能源储存与转换先进材料湖南省重点实验室, 湘潭　411201

通信作者: 谢国锋, xieguofeng@hnust.cn ; 周五星, wuxingzhou@hnu.edu.cn

基金项目: 国家自然科学基金(批准号: 12074115, 11874145)资助的课题.

Authors and contacts

1.
School of Materials Science and Engineering, Hunan University of Science and Technology, Xiangtan 411201, China

2.
Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, Xiangtan 411201, China

Corresponding author: Xie Guo-Feng, xieguofeng@hnust.cn ; Zhou Wu-Xing, wuxingzhou@hnu.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 12074115, 11874145).

文章全文 : translate this paragraph

参考文献

[1]	余启, 刘琦, 王自强, 李宝华 2020 69 228805 Google Scholar Yu Q, Liu Q, Wang Z Q, Li B H 2020 Acta Phys. Sin. 69 228805 Google Scholar
[2]	拱越, 谷林 2020 69 226801 Google Scholar Gong Y, Gu L 2020 Acta Phys. Sin. 69 226801 Google Scholar
[3]	Kantharaj R, Marconnet A M 2019 Nanosci. Microsc. Therm. 23 128 Google Scholar
[4]	Koo B, Goli P, Sumant A V, dos Santos Claro P C, Rajh T, Johnson C S, Balandin A A, Shevchenko E V 2014 ACS Nano 8 7202 Google Scholar
[5]	Lee E, Salgado R A, Lee B, Sumant A V, Rajh T, Johnson C, Balandin A A, Shevchenko E V 2018 Carbon 129 702 Google Scholar
[6]	Vishwakarma V, Jain A 2017 J. Power Sources 362 219 Google Scholar
[7]	Meng H, Yu X X, Feng H, Xue Z G, Yang N 2019 Int. J. Heat Mass Transf. 137 1241 Google Scholar
[8]	Little W A 1959 Can. J. Phys. 37 334 Google Scholar
[9]	Swartz E T, Pohl R O 1987 Appl. Phys. Lett. 51 2200 Google Scholar
[10]	Young D A, Maris H J 1989 Phys. Rev. B 40 3685 Google Scholar
[11]	Tian Z, Esfarjani K, Chen G 2012 Phys. Rev. B 86 235304 Google Scholar
[12]	Ong Z Y, Zhang G 2015 Phys. Rev. B 91 174302 Google Scholar
[13]	Zhang W, Fisher T S, Mingo N 2006 J. Heat Transfer 129 483
[14]	Feng T, Yao W, Wang Z, Shi J, Li C, Cao B, Ruan X 2017 Phys. Rev. B 95 195202 Google Scholar
[15]	Feng T, Zhong Y, Shi J, Ruan X 2019 Phys. Rev. B 99 045301 Google Scholar
[16]	Sadasivam S, Waghmare U V, Fisher T S 2015 J. Appl. Phys. 117 134502 Google Scholar
[17]	Polanco C A, Lindsay L 2019 Phys. Rev. B 99 075202 Google Scholar
[18]	Dhakane A, Varshney V, Liu J, Heinz H, Jain A 2020 Surf. Interfaces 21 10067
[19]	Cho J, Losego M D, Zhang H G, Kim H, Zuo J, Petrov I, Cahill D G, Braun P V 2014 Nat. Commun. 5 4035 Google Scholar
[20]	Hu S, Zhang Z, Wang Z, Zeng K, Cheng Y, Chen J, Zhang G 2018 ES Energy Environ. 1 74
[21]	Qian X, Gu X, Dresselhaus M S, Yang R 2016 J. Phys. Chem. Lett. 7 4744 Google Scholar
[22]	Li H, Huang X J, Chen L Q, Zhou G W, Zhang Z, Yu D P, Mo Y J, Pei N, 2000 Solid State Ionics 135 181 Google Scholar
[23]	Hatchard T D, Dahn J R 2004 J. Electrochem. Soc. 151 A838 Google Scholar
[24]	Limthongkul P, Jang Y I, Dudney N J, Chiang Y M 2003 Acta Mater. 51 1103 Google Scholar
[25]	Reimers J N 1992 J. Electrochem. Soc. 139 2091 Google Scholar

施引文献

图 1 全固态锂离子电池结构以及充放电过程锂离子传输示意图

Fig. 1. All-solid-state lithium-ion battery structure and schematic diagram of lithium-ion transmission during charging and discharging.

下载: 全尺寸图片幻灯片

map

[1]	余启, 刘琦, 王自强, 李宝华 2020 69 228805 Google Scholar Yu Q, Liu Q, Wang Z Q, Li B H 2020 Acta Phys. Sin. 69 228805 Google Scholar
[2]	拱越, 谷林 2020 69 226801 Google Scholar Gong Y, Gu L 2020 Acta Phys. Sin. 69 226801 Google Scholar
[3]	Kantharaj R, Marconnet A M 2019 Nanosci. Microsc. Therm. 23 128 Google Scholar
[4]	Koo B, Goli P, Sumant A V, dos Santos Claro P C, Rajh T, Johnson C S, Balandin A A, Shevchenko E V 2014 ACS Nano 8 7202 Google Scholar
[5]	Lee E, Salgado R A, Lee B, Sumant A V, Rajh T, Johnson C, Balandin A A, Shevchenko E V 2018 Carbon 129 702 Google Scholar
[6]	Vishwakarma V, Jain A 2017 J. Power Sources 362 219 Google Scholar
[7]	Meng H, Yu X X, Feng H, Xue Z G, Yang N 2019 Int. J. Heat Mass Transf. 137 1241 Google Scholar
[8]	Little W A 1959 Can. J. Phys. 37 334 Google Scholar
[9]	Swartz E T, Pohl R O 1987 Appl. Phys. Lett. 51 2200 Google Scholar
[10]	Young D A, Maris H J 1989 Phys. Rev. B 40 3685 Google Scholar
[11]	Tian Z, Esfarjani K, Chen G 2012 Phys. Rev. B 86 235304 Google Scholar
[12]	Ong Z Y, Zhang G 2015 Phys. Rev. B 91 174302 Google Scholar
[13]	Zhang W, Fisher T S, Mingo N 2006 J. Heat Transfer 129 483
[14]	Feng T, Yao W, Wang Z, Shi J, Li C, Cao B, Ruan X 2017 Phys. Rev. B 95 195202 Google Scholar
[15]	Feng T, Zhong Y, Shi J, Ruan X 2019 Phys. Rev. B 99 045301 Google Scholar
[16]	Sadasivam S, Waghmare U V, Fisher T S 2015 J. Appl. Phys. 117 134502 Google Scholar
[17]	Polanco C A, Lindsay L 2019 Phys. Rev. B 99 075202 Google Scholar
[18]	Dhakane A, Varshney V, Liu J, Heinz H, Jain A 2020 Surf. Interfaces 21 10067
[19]	Cho J, Losego M D, Zhang H G, Kim H, Zuo J, Petrov I, Cahill D G, Braun P V 2014 Nat. Commun. 5 4035 Google Scholar
[20]	Hu S, Zhang Z, Wang Z, Zeng K, Cheng Y, Chen J, Zhang G 2018 ES Energy Environ. 1 74
[21]	Qian X, Gu X, Dresselhaus M S, Yang R 2016 J. Phys. Chem. Lett. 7 4744 Google Scholar
[22]	Li H, Huang X J, Chen L Q, Zhou G W, Zhang Z, Yu D P, Mo Y J, Pei N, 2000 Solid State Ionics 135 181 Google Scholar
[23]	Hatchard T D, Dahn J R 2004 J. Electrochem. Soc. 151 A838 Google Scholar
[24]	Limthongkul P, Jang Y I, Dudney N J, Chiang Y M 2003 Acta Mater. 51 1103 Google Scholar
[25]	Reimers J N 1992 J. Electrochem. Soc. 139 2091 Google Scholar

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全固态锂离子电池内部热输运研究前沿