铌酸钾钠基无铅压电陶瓷的高压电活性研究进展

邢洁; 谭智; 郑婷; 吴家刚; 肖定全; 朱建国

doi:10.7498/aps.69.20200288

摘要

以Pb(Zr_1–xTi_x)O₃ (PZT)为代表的铅基压电陶瓷因为具有良好的压电性能和机电耦合性能已被广泛应用于科技、工业、军事以及日常生活中. 但是, PZT基陶瓷中Pb的含量超过了60% (质量比), 在生产、使用及废弃处理过程中都会给人类生态环境造成严重损害. 因此, 发展无铅压电陶瓷已成为世界压电陶瓷研究的热点之一. 铌酸钾钠 (K_0.5Na_0.5)NbO₃ (KNN)无铅压电陶瓷因为具有较为优异的压电性能以及较高的居里温度, 被认为是最可能取代铅基压电陶瓷的材料体系之一. 经过研究者们的努力工作, 改性后的KNN基无铅压电陶瓷压电性能已经接近或超过了某些铅基压电陶瓷的性能. 本文综合介绍了具有高压电活性的KNN基无铅压电陶瓷国内外的研究进展, 重点阐述了高性能铌酸钾钠基无铅压电陶瓷制备工艺及相关理论基础的研究进展, 并就今后铌酸钾钠基无铅压电陶瓷研究发展的方向及前景提出建议.

关键词:

Abstract

Due to excellent piezoelectric properties and electromechanical coupling properties, lead-based piezoelectric ceramics represented by lead zirconate titanate Pb(Zr_xTi_1–x)O₃ (PZT) are widely used in science and technology, industry, military and daily life. However, the content of Pb in PZT-based ceramics exceeds 60% (mass ratio), which will cause serious damage to human ecological environment in the process of their production, use and waste treatment. Therefore, the development of lead-free piezoelectric ceramics has become one of the hot research spots. Potassium sodium niobate (K_0.5Na_0.5)NbO₃ (KNN) lead-free piezoelectric ceramics are considered as one of the most promising material systems to substitute for lead-based piezoelectric ceramics because of their good piezoelectric properties and higher Curie temperature. Through many years of researches, the piezoelectric properties of modified KNN based lead-free piezoelectric ceramics have approached to or even exceeded those of some lead-based piezoelectric ceramics. Combining with our relevant work, we comprehensively review the research progress of high piezoelectric activity of KNN based lead-free piezoelectric ceramics, especially focus on the research progress of high-performance potassium sodium niobate lead-free piezoelectric ceramics, preparation technology and related theoretical mechanisms. The future research direction and prospect of KNN-based lead-free piezoelectric ceramics are also presented.

Keywords:

作者及机构信息

四川大学材料科学与工程学院, 成都　610064

通信作者: 朱建国, nic0400@scu.edu.cn

基金项目: 国家级-国家自然科学基金(51932010)

Authors and contacts

College of Materials Science and Engineering, Sichuan University, Chengdu 610064, China

Corresponding author: Zhu Jian-Guo, nic0400@scu.edu.cn

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参考文献

[1]	Xiao D Q 2011 J. Adv. Dielectr. 01 33 Google Scholar
[2]	Aksel E, Jones J L 2010 Sensors 10 1935 Google Scholar
[3]	Rödel J, Webber K G, Dittmer R, Jo W, Kimura M, Damjanovic D 2015 J. Eur Ceram. Soc. 35 1659 Google Scholar
[4]	Vats G, Vaish R 2014 Int. J. Appl. Ceram. Tec. 11 883 Google Scholar
[5]	Thong H C, Zhao C L, Zhou Z, Wu C F, Liu Y X, Du Z Z, Li J F, Gong W, Wang K 2019 Mater. Today 29 37 Google Scholar
[6]	Wang K, Malič B, Wu J G 2018 MRS Bull. 43 607 Google Scholar
[7]	Lv X., Zhu J G, Xiao D Q, Zhang X X, Wu J G 2020 Chem. Soc. Rev. 49 671 Google Scholar
[8]	Wu J G, Xiao D Q, Zhu J G 2015 Chem. Rev. 115 2559 Google Scholar
[9]	Gou Q, Wu J G, Li A Q, Wu B, Xiao D Q, Zhu J G 2012 J. Alloy. Comp. 521 4 Google Scholar
[10]	Saito Y, Takao H, Tani T, Nonoyama T, Takatori K, Homma T, Nagaya T, Nakamura M 2004 Nature 432 84 Google Scholar
[11]	Li P, Zhai J W, Shen Bo, Zhang S J, Li X L, Zhu F Y, Zhang X M 2018 Adv. Mater. 30 1705171 Google Scholar
[12]	Tao H, Wu H J, Liu Y, Zhang Y, Wu J G, Li F, Lyu X, Zhao C L, Xiao D Q, Zhu J G, Pennycook S J 2019 J. Am. Chem. Soc. 141 13987 Google Scholar
[13]	Egerton L, Dillond D M 1959 J. Am. Chem. Soc. 42 5 Google Scholar
[14]	Qin Y L, Zhang J L, Yao W Z, Lu C J, Zhang S J 2016 ACS Appl. Mater. Interfaces 8 7257 Google Scholar
[15]	Wang Y Y, Wu J G, Xiao D Q, Wu W J, Zhang B, Wu L, Zhu J G 2008 J. Am. Ceram. Soc. 91 2772 Google Scholar
[16]	Tan C K I, Shannigrahi S, Yao K, Ma J 2015 J. Electroceram. 35 19 Google Scholar
[17]	Pang X M, Qiu J H, Zhu K J 2014 J. Adv. Ceram. 3 147 Google Scholar
[18]	Wang Y Y, Wu J G, Xiao D Q, Zhu J M, Jin Y, Zhu J G, Yu P, Wu L, Li X 2007 J. Appl. Phys. 102 054101 Google Scholar
[19]	Wu W J, Wang Z, Xiao D Q, Ma J, Wu J G, Li J, Liang W F, Zhu J G 2013 Integr. Ferroelectr. 141 82 Google Scholar
[20]	Wu W J, Xiao D Q, Wu J G, Liang W F, Li J, Zhu J G 2011 J. Alloy. Comp. 509 L284 Google Scholar
[21]	Wu J G, Xiao D Q, Wang Y Y, Zhu J G, Yu P 2008 J. Appl. Phys. 103 024102 Google Scholar
[22]	Wu B, Ma J, Wu W J, Chen M, Ding Y C 2018 Ceram. Inter. 44 1172 Google Scholar
[23]	Wen Y, Fan G F, Hao M M, Wang Y J, Chen X, Zhang Q W, Lv W Z 2019 J. Electron. Mater. 49 931 Google Scholar
[24]	Xing J, Tan Z, Yuan J, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 RSC Adv. 6 57210 Google Scholar
[25]	Tang X, Chen T, Liu Y H, Zhang J W, Zhang T, Wang G C, Zhou J F 2016 J. Alloy. Comp. 672 277 Google Scholar
[26]	Yang Y, Wang H, Li Y, Zheng Q J, Liao J, Jie W J, Lin D M 2019 Dalton Trans. 48 10676 Google Scholar
[27]	Wu W J, Chen M, Wu B, Ding Y C, Liu C Q 2017 J. Alloy. Comp. 695 1175 Google Scholar
[28]	Lv X, Wu J G, Xiao D Q, Tao H, Yuan Y, Zhu J G, Wang X J, Lou X J 2015 Dalton Trans. 44 4440 Google Scholar
[29]	Zhong H Y, Xiao HNY, Jiao N, Guo Y P 2019 J. Am. Ceram. Soc. 102 6422 Google Scholar
[30]	Li F L, Tan Z, Xing J, Jiang L M, Wu B, Wu J G, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 8803 Google Scholar
[31]	Li F L, Gou Q, Xing J, Tan Z, Jiang L M, Xie L X, Wu J G, Zhang W, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 18090 Google Scholar
[32]	Lv X, Li Z Y, Wu J G, Xi J W, Gong M, Xiao D Q, Zhu J G 2016 Mater. Design 109 609 Google Scholar
[33]	Lv X, Wu J G, Yang S, Xiao D Q, Zhu J G 2016 ACS Appl. Mater. Interfaces 8 18943 Google Scholar
[34]	Zhou C M, Zhang J L, Yao W Z, Liu D K, He G H 2020 J. Alloy. Comp. 820 153411 Google Scholar
[35]	Wu B, Ma J, Gou Q, Wu W J, Chen M 2019 J. Am. Ceram. Soc. 103 1698 Google Scholar
[36]	Shi C Y, Ma J, Wu J, Chen K, Wu B 2020 Ceram. Inter. 46 7 Google Scholar
[37]	Wang X P, Wu J G, Xiao D Q, Zhu J G, Cheng X J, Zheng T, Zhang B Y, Lou X J, Wang X J 2014 J. Am. Chem. Soc. 136 2905 Google Scholar
[38]	Wang X P, Wu J G, Xiao D Q, Cheng X J, Zheng T, Zhang B Y, Lou X J, Zhu J G 2014 J. Mater. Chem. A 2 4122 Google Scholar
[39]	Tao H, Wu J G, Zheng T, Wang X J, Lou X J 2015 J. Appl. Phys. 118 044102 Google Scholar
[40]	Zhou J S, Wang K, Yao F Z, Zheng T, Wu J G, Xiao D Q, Zhu J G, Li J F 2015 J. Mater. Chem. C 3 8780 Google Scholar
[41]	Xing J, Tan Z, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 J. Appl. Phys. 119 034101 Google Scholar
[42]	Zheng T, Wu H J, Yuan Y, Lv X, Li Q, Men T L, Zhao C L, Xiao D Q, Wu J G, Wang K, Li J F, Gu Y L, Zhu J G, Pennycook S J 2017 Energy Environ. Sci. 10 528 Google Scholar
[43]	Wu B, Wu H J, Wu J G, Xiao D Q, Zhu J G, Pennycook S J 2016 J. Am. Chem. Soc. 138 15459 Google Scholar
[44]	Yang W W, Li P, Li F, Liu X, Shen B, Zhai J W 2019 Ceram. Inter. 45 2275 Google Scholar
[45]	Xu K, Li J, Lv X, Wu J G, Zhang X X, Xiao D Q, Zhu J G 2016 Adv. Mater. 28 8519 Google Scholar
[46]	Wu B, Ma J, Wu W J, Chen M 2020 J. Mater. Chem. C 8 2838 Google Scholar
[47]	Yang W W, Li P, Wu S H, Li F, Shen B, Zhai J W 2020 Ceram. Inter. 46 6 Google Scholar
[48]	Liu Q, Zhang Y C, Gao J, Zhou Z, Wang H, Wang K, Zhang X W, Li L T, Li J F 2018 Energy Environ. Sci. 11 3531 Google Scholar
[49]	Feng W, Cen Z Y, Liang S Y, Luo B C, Zhang Y, Zhen Y C, Wang X H, Li L T 2019 J. Alloy. Comp. 786 498 Google Scholar
[50]	Hreščak J, Dražić G, Deluca M, Arčon I, Kodre A, Dapiaggi M, Rojac T, Malič B, Bencan A 2017 J. Eur Ceram. Soc. 37 2073 Google Scholar
[51]	Cen Z Y, Yu Y, Zhao P Y, Chen L L, Zhu C Q, Li L T, Wang X H 2019 J. Mater. Chem. C 7 1379 Google Scholar
[52]	Sun X X, Zhang J W, Lv X, Zhang X X, Liu Y, Li F, Wu J G 2019 J. Mater. Chem. A 7 16803 Google Scholar
[53]	Qin Y L, Zhang J L, Tan Y Q, Yao W Z, Wang C L, Zhang S J 2014 J. Eur Ceram. Soc. 34 4177 Google Scholar
[54]	Yao W Z, Zhang J L, Wang X M, Zhou C M, Sun X, Zhan J 2019 J. Eur Ceram. Soc. 39 287 Google Scholar
[55]	Zhou C M, Zhang J L, Yao W Z, Wang X M, Liu D K, Sun X 2018 J. Appl. Phys. 124 164101 Google Scholar
[56]	López-Juárez R, Novelo-Peralta O, González-García F, Rubio-Marcos F, Villafuerte-Castrejón M-E 2011 J. Eur Ceram. Soc. 31 1861 Google Scholar
[57]	Xing J, Tan Z, Chen X Y, Jiang L M, Wang W W, Deng X, Wu B, Wu J G, Xiao D Q, Zhu J G 2019 Inorg. Chem. 58 428 Google Scholar
[58]	Huan Y, Wei T, Wang Z X, Lei Y C, Chen F L, Wang X H 2019 J. Eur Ceram. Soc. 39 1002 Google Scholar
[59]	Ding Y, Zheng T, Zhao C L, Wu J G 2019 J. Appl. Phys. 126 124101 Google Scholar
[60]	Zhao C L, Wu B, Wang K, Li J F, Xiao D Q, Zhu J G, Wu J G 2018 J. Mater. Chem. A 6 23736 Google Scholar
[61]	Qin Y L, Zhang J L, Gao Y, Tan Y Q, Wang C L 2013 J. Appl. Phys. 113 204107 Google Scholar
[62]	Liu Q, Zhang Y C, Zhao L, Gao J, Zhou Z, Wang K, Zhang X W, Li L T, Li J F 2018 J. Mater. Chem. C 6 10618 Google Scholar
[63]	Liu Q, Li J F, Zhao L, Zhang Y C, Gao J, Sun W, Wang K, Li L T 2018 J. Mater. Chem. C 6 1116 Google Scholar
[64]	Fu J, Zuo R Z, Qi H, Zhang C, Li J F, Li L T 2014 Appl. Phys. Lett. 105 242903 Google Scholar
[65]	Zhou C M, Zhang J L, Yao W Z, Liu D K, Su W B 2019 Scripta Mater. 162 86 Google Scholar
[66]	Li P, Huan Y, Yang W W, Zhu F Y, Li X L, Zhang X M, Shen B, Zhai J W 2019 Acta Mater. 165 486 Google Scholar
[67]	Liu D K, Zhang X C, Su W B, Wang X M, Yao W Z, Zhou C M, Zhang J L 2019 J. Alloy. Comp. 779 800 Google Scholar
[68]	Lv X, Wu J G 2019 J. Mater. Chem. C 7 2037 Google Scholar
[69]	Zhang N, Zhao C, Wu J G 2019 Ceram. Inter. 45 24827 Google Scholar
[70]	Xing J, Tan Z, Xie L X, Jiang L M, Yuan J, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2018 J. Am. Ceram. Soc. 101 1632 Google Scholar
[71]	Tao H, Wu J G, Wang H 2016 J. Alloy. Comp. 684 217 Google Scholar
[72]	Wang T, Wu C, Xing J, Wu J G, Li Chen B W, Xu X Y, Wang K, Zhu J G 2019 J. Am. Ceram. Soc. 102 6126 Google Scholar
[73]	Cen Z Y, Wang X H, Huan Y, Li L T 2018 J. Am. Ceram. Soc. 101 2391 Google Scholar
[74]	Jiang L M, Tan Z, Xing J, Wu J G, Chen Q, Zhang W, Xiao D Q, Zhu J G 2016 J. Mater. Sci.- Mater. El. 27 9812 Google Scholar
[75]	Wang X P, Wu J G, Lv X, Tao H, Cheng X J, Zheng T, Zhang B Y, Xiao D Q, Zhu J G 2014 J. Mater. Sci.- Mater. El. 25 3219 Google Scholar
[76]	Wang Z, Xiao D Q, Wu J G, Xiao M, Li F X, Zhu J G, Damjanovic D 2014 J. Am. Ceram. Soc. 97 688 Google Scholar
[77]	Feng S S, Xiao D Q, Wu J G, Xiao M, Zhu J G 2015 J. Alloy. Comp. 619 560 Google Scholar
[78]	Cheng X J, Wu J G, Wang X P, Zhang B Y, Lou X J, Wang X J, Xiao D Q, Zhu J G 2013 ACS Appl. Mater. Interfaces 5 10409 Google Scholar
[79]	Gou Q, Zhu J G, Wu J G, Li F L, Jiang L M, Xiao D Q 2018 J. Alloy. Comp. 730 311 Google Scholar
[80]	Cheng X J, Wu J G, Lou X J, Wang X J, Wang X P, Xiao D Q, Zhu J G 2014 ACS Appl. Mater. Interfaces 6 750 Google Scholar
[81]	Gou Q, Xiao D Q, Wu B, Xiao M, Feng S S, Ma Zhao D D, Wu J G, Zhu J G 2015 RSC Adv. 5 30660 Google Scholar
[82]	Ma Q, Wan B B, Cheng L J, Liu S J, Liu F S 2016 J. Electroceram. 36 30 Google Scholar
[83]	Kim J H, Kim J S, Han S H, Kang H W, Lee H G, Cheon C I 2016 Ceram. Inter. 42 5226 Google Scholar
[84]	Sumang R, Wicheanrat C, Bongkarn T, Maensiri S 2015 Ceram. Inter. 41 S136 Google Scholar
[85]	Zhang S J, Xia R, Hao H, Liu H X, Shrout T R 2008 Appl. Phys. Lett. 92 152904 Google Scholar
[86]	Yao F Z, Wang K, Jo W, Webber K G, Comyn T P, Ding J X, Xu B, Cheng L Q, Zheng M P, Hou Y D, Li J F 2016 Adv. Funct. Mater. 26 1217 Google Scholar
[87]	Lv X, Wu J G, Zhu J G, Xiao D Q 2018 Phys. Chem. Chem. Phys. 20 20149 Google Scholar
[88]	Zhang M H, Wang K, Du Y J, Dai G, Sun W, Li G, Hu D, Thong H C, Zhao C L, Xi X Q, Yue Z X, Li J F 2017 J. Am. Chem. Soc. 139 3889 Google Scholar
[89]	Tao H, Zhao C L, Zhang R, Wu J G 2019 J. Alloy. Comp. 795 401 Google Scholar
[90]	Cen Z Y, Feng W, Zhao P Y, Chen L L, Zhu C Q, Yu Y, Li L T, Wang X H 2018 J. Am. Ceram. Soc. 102 2675 Google Scholar
[91]	Huang Y L, Zhao C L, Wu B, Wu J G 2019 J. Am. Ceram. Soc. 102 2648 Google Scholar
[92]	Zheng T, Wu J G 2020 Acta Mater. 182 1 Google Scholar
[93]	Ramajo L, Rubio-Marcos F, Del Campo A, Fernández J F, Castro M S, Parra R 2015 J. Mater. Sci.- Mater. El. 26 9402 Google Scholar
[94]	Liu W L, Tan G Q, Xiong P, Xue X, Hao H F, Ren H J 2014 J. Mater. Sci.- Mater. El. 25 2348 Google Scholar
[95]	Hao H F, Tan G Q, Ren H J, Xia A, Xiong P 2014 Ceram. Inter. 40 9485 Google Scholar
[96]	Gu Q L, Sun Q M, Zhu K J, Liu J S, Qiu J H 2017 Ceram. Inter. 43 1135 Google Scholar
[97]	Cheng L Q, Wang K, Li J F 2015 Mater. Lett. 138 128 Google Scholar
[98]	Li Y M, Wang J S, Liao R H, Huang D, Jiang X P 2010 J. Alloy. Compd. 496 282 Google Scholar
[99]	Kumar P, Pattanaik M, Sonia 2013 Ceram. Inter. 39 65 Google Scholar
[100]	Haugen A B, Madaro F, Bjørkeng L-P, Grande T, Einarsrud M A 2015 J. Eur Ceram. Soc. 35 1449 Google Scholar
[101]	Jiang C Y, Tian X X, Shi G D 2016 Adv. Intell. Sys. Res. 136 7 Google Scholar
[102]	Yokouchi Y, Maeda T, Bornmann P, Hemsel T, Morita T 2013 Jpn. J. Appl. Phys. 52 07HB03 Google Scholar
[103]	Wang C, Fang B J, Qu Y H, Chen Z H, Zhang S, Ding J N 2020 J. Alloy. Compd. 832 153043 Google Scholar
[104]	Jaeger R E, Egerton L 1962 J. Am. Ceram. Soc. 45 5 Google Scholar
[105]	Li M Y, Chan N Y, Wang D Y 2017 J. Am. Ceram. Soc. 100 2984 Google Scholar
[106]	Feizpour M, Barzegar Bafrooei H, Hayati R, Ebadzadeh T 2014 Ceram. Inter. 40 871 Google Scholar
[107]	Ma J Z, Li H Y, Wang H J, Lin C, Wu X, Lin T F, Zheng X H, Yu X 2019 J. Eur Ceram. Soc. 39 986 Google Scholar
[108]	Chi M S, Ma W B, Guo J D, Wu J Q, Li T T, Wang S H, Zhang P F 2019 J. Mater. Sci.- Mater. El. 39 986 Google Scholar
[109]	Yu Z D, Chen X M, Su Y L, Lian H L, Lu J B, Zhou J P, Liu P 2019 J. Mater. Sci. 54 13457 Google Scholar
[110]	Li J F, Wang K, Zhang B P, Zhang L M 2006 J. Am. Ceram. Soc. 89 706 Google Scholar
[111]	Cen Z Y, Li L T, Wang X H 2019 J. Alloy. Comp. 797 1115 Google Scholar
[112]	Li H, Gong D W, Yang W L, Zhou Z X 2012 J. Mater. Sci. 48 1396 Google Scholar
[113]	Liao Y, Wang D M, Wang H, Wang T, Wei X H, Zheng Q J, Jie W J, Lin D M 2019 Ceram. Inter. 45 2644 Google Scholar
[114]	Wu B, Yin J, Lv X, Xiao D Q, Zhu J G, Wu J G 2019 J. Appl. Phys. 125 082526 Google Scholar
[115]	Liao Y, Wang D M, Wang H, Zhou L X, Zheng Q J, Lin D M 2020 Dalton Trans. 49 1311 Google Scholar
[116]	Comes R, Lambert M, Guinier A 1968 Solid State Commun. 6 715 Google Scholar
[117]	Cohen R E 1992 Nature 358 136 Google Scholar
[118]	Atern E A, Yacoby Y 1996 J. Phys. Chem. Solids 57 1449 Google Scholar
[119]	Rytz D, Höchli U T, Bilz H 1980 Phys. Rev. B 22 359 Google Scholar
[120]	Shuvaeva V A, Yanagi K, Yagi K, Sakaue K, Terauchi H 1998 Solid State Commun 106 335 Google Scholar
[121]	Devonshire A F 1949 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 40 1040 Google Scholar
[122]	Devonshire A F 1951 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 42 1065 Google Scholar
[123]	Cochran W 1959 Phys. Rev. Lett. 3 412 Google Scholar
[124]	Damjanovic D, Demartin 1997 J. Phys.-Condens. Mat. 9 4943 Google Scholar
[125]	谭智 2019 博士学位论文 (成都: 四川大学) Tan Z 2019 Ph. D. Dissertation (Chengdu: Sichuan University) (in Chinese)
[126]	Tellier J, Malic B, Dkhil B, Jenko D, Cilensek J, Kosec M 2009 Solid State Sci. 11 320 Google Scholar
[127]	Baker D W, Thomas P A, Zhang N, Glazer A M 2009 Appl. Phys. Lett. 95 091903 Google Scholar
[128]	Guo Y P, Kakimoto K, Ohsato H 2004 Appl. Phys. Lett. 85 4121 Google Scholar
[129]	Yang D, Wei L L, Chao X L, Yang Z P, Zhou X Y 2016 Phys. Chem. Chem. Phys. 18 7702 Google Scholar
[130]	Wu Z G, Cohen R E 2005 Phys. Rev. Lett. 95 037601 Google Scholar
[131]	Shannon R D 1976 Acta Crystallogra. A 32 751 Google Scholar
[132]	Tan Z, Xing J, Jiang L M, Zhu J G, Wu B 2017 Front. Mater. Sci. 11 344 Google Scholar
[133]	Ke S M, Huang H T, Fan H Q, Lee H K, Zhou L M, Mai Y M 2012 Appl. Phys. Lett. 101 082901 Google Scholar
[134]	Fu H X, Cohen R E 2000 Nature 403 281 Google Scholar
[135]	Suewattana M, Singh D J 2010 Phys. Rev. B 82 014114 Google Scholar
[136]	Voas B K, Usher T M, Liu X, Li S, Jones J L, Tan X, Cooper V R, Beckman S P 2014 Phys. Rev. B 90 024105 Google Scholar
[137]	Matsumoto K, Hiruma Y, Nagata H, Takenaka T 2008 Ceram. Inter. 34 787 Google Scholar
[138]	Tan Z, Peng Y T, An J, Zhang Q M, Zhu J G 2019 J. Am. Ceram. Soc. 102 5262 Google Scholar
[139]	Peng Y, T Tan Z, An J, Zhu J G, Zhang Q M 2019 J. Eur. Ceram. Soc. 39 5252 Google Scholar
[140]	Li C W, Xu X, Gao Q, Lu Z L 2019 Ceram. Int. 45 11092 Google Scholar
[141]	Liu S Y, Liu S, Li D J, Shen Y, Dang H, Liu Y, Xue W, Wang S 2014 J. Am. Ceram. Soc 97 4019 Google Scholar
[142]	Li Q, Zhang R, Lv T Q, Zheng L M 2015 Chin. Phys. B 24 053101 Google Scholar
[143]	Yang D, Chai Q Z, Wei L L, Chao X L, Yang Z P 2017 Phys. Chem. Chem. Phys. 19 27368 Google Scholar

施引文献

图 1 (a) KNN基无铅压电陶瓷d₃₃的历史演变图; (b) KNN基无铅压电陶瓷与铅基陶瓷d₃₃对比图^{[11,12,34,37,43,45]}

Fig. 1. (a) Historical evolution in d₃₃ values of KNN-based ceramics as a function of time; (b) comparison of d₃₃ values among KNN-based ceramics and PZT materials^{[11,12,34,37,43,45]}.

下载: 全尺寸图片幻灯片

图 2 (a)正交相(K_0.5Na_0.5NbO₃陶瓷^[56,61]); (b)室温下O-T相界(KNNL-BZ-BNT陶瓷体系^[62], KNNSL-BNZ-BZ-MnO₂陶瓷体系^[63]); (c)室温下R-T/R-O-T相界KNN基陶瓷的畴结构(KNNS-BF-BNZ陶瓷体系^[43], KNNS-BNZ-BZ陶瓷体系^[34])

Fig. 2. Domain structures of KNN-based ceramcis with different phase boundaries at room temperature: (a) Orthorhombic (K_0.5Na_0.5NbO₃ ceramics^[56,61]); (b) O-T phase boundaries (KNNL-BZ-BNT ceramics^[62], KNNSL-BNZ-BZ-MnO₂ ceramics^[63]); (c) R-T/R-O-T phase boundaries (KNNS-BF-BNZ ceramics^[43], KNNS-BNZ-BZ ceramics^[34]).

下载: 全尺寸图片幻灯片

图 3 KNN基无铅压电陶瓷d₃₃与T_C对比图^[12,15-47]

Fig. 3. Comparison of d₃₃ and T_C values of KNN-based ceramics^[12,15-47].

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图 4 根据文献[120]重画的KNbO₃中Nb原子位置在(001)平面的投影示意图

Fig. 4. Projections of real Nb off-center displacements on the (001) plane redrawn from the Ref. [120].

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图 5 B位原子在单四方相与两相共存时沿[$ \overline{1} 01$]方向的能量分布示意图^[125]

Fig. 5. Energy distribution for B-site atom in single tetragonal phase and two-phase coexistence along [$ \overline{1} 01$] direction^[125].

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表 1 室温下具有O-T相界的KNN压电陶瓷性能

Table 1. Properties of KNN ceramics with O-T phase boundary at room temperature.

Material system	d₃₃/pC·N^–1	k_p	T_C/℃
KNLANT^[15]	252	0.454	438
KNLN-BCZT^[16]	180	0.34	425
KNN-KLN^[17]	121	0.39	—
KNLN-AS^[18]	230	0.39	430
KNLN-BNCT^[19]	262	0.36	～400
KNN-BC^[20]	165	0.40	～390
KNN-LS^[21]	280	0.494	364
KNN-BLZ^[22]	265	0.365	364
KNN-BC-BNH^[23]	272	0.47	333

下载: 导出CSV

表 2 室温下具有R-O-T相界的KNN压电陶瓷的性能

Table 2. Properties of KNN ceramics with R-O-T phase boundary at room temperature.

Material system	d₃₃/pC·N^–1	k_p	T_C /℃
KNN-BNZ-BG^[24]	312	0.44	341
KNN-BZ-BNZ^[25]	345	0.50	～260
KNN-NS-BNKZH^[26]	452	0.63	～270
KNNS-BNCZ^[27]	415	0.46	245
KNNTS-BNKZ^[28]	400	0.46	240
KNN-BNZN^[29]	318 ± 10	—	360
KNNS-BKZH^[30]	451	0.52	258
KNNS-BLKZ^[31]	385	—	245
KNNS-SZ-BNH^[32]	470 ± 5	0.51 ± 0.02	244
KNNS-BS-BNZ^[33]	～480	—	～225
KNNS-BNZ-BZ^[34]	610	0.58	241
KNNS-BNKZ-Fe-AS^[12]	650	—	～180

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表 3 室温下具有R-T相界的KNN压电陶瓷的性能

Table 3. Properties of KNN ceramics with R-T phase boundary at room temperature.

Material system	d₃₃ /pC·N^–1	k_p	T_C/℃
KNNS-BNZSn^[35]	465	0.51	240
KNNS-BZH^[36]	410	—	255
KNNS-BNKZ^[37]	490	0.46	227
KNNTS-BNKZ^[38]	460	0.40	～220
KNNS-BNH^[39]	419	0.45	242
KNNS-BKZS^[40]	430	—	243
KNNS-BNLCZ^[41]	485	0.48	227
KNNS-BNKH^[42]	525	—	～210
KNNS-BF-BNZ^[43]	550	—	237
KNNS-CZ-BKHT-MnO₂^[44]	425	0.49	215
KNNS-BZ-BKH^[45]	570 ± 10	—	～190
KNNS-BNZ-BF^[46]	511	0.515	269
KNANS-BNZ^[47]	440	0.50	250

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表 4 KNN基无铅压电陶瓷压电常数与畴结构尺寸

Table 4. Piezoelectric constant of KNN ceramics with domain size.

Material system	d₃₃ or $ {d}_{33}^{*} $	Domain size
KNNS-SZ-BAZ^[52]	487 pC/N	30—65 nm, 65—160 nm, 30—45 nm
KNNS-BZ-BNH^[48]	600 pm/V	10—100 nm
KNNS-BNKH^[42]	525 pC/N	10—30 nm
KNNS-BNKZ-Fe-AS^[12]	(650 ± 20) pC/N	2 nm
KNNS-BNZ-BZ^[34]	610 pC/N	50—70 nm
KNNT-BNKZ-CZ^[51]	482 pm/V	60 nm
KNNS-BZ-BNZ^[65]	300 pC/N	150 nm—1.0 μm
KNNS-CZ-BKH^[66]	550 pC/N	30—230 nm
KNNS-BNH^[67]	512 pC/N	100 nm
KNNS-SZ-BNZ^[68]	450 pC/N	50—200 nm
KNLNTS^[54]	455 pC/N	110—310 nm
KNNS-BNZ-BF^[46]	510 pC/N	< 1 μm
KNN-BNZ-MnO₂-Sb₂O₃^[69]	318 pC/N	< 1 μm
KNN-BI-BNZ^[57]	317 pC/N	～200 nm
KNNdNS-BNZ^[70]	400 pC/N	～ 1 μm

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表 5 同时具有高压电性能和高居里温度的KNN陶瓷体系

Table 5. The KNN-based ceramics with high piezoelectric constant and high Curie temperature.

Material system	d₃₃ /pC·N^–1	T_C/℃
KNN-BNH^[71]	385	315
KNN-BNZ-LF^[72]	345	314
KNN-BNZ-MnO₂^[73]	300	345
KNN-BNZ-BG^[24]	312	341
KNN-BNZ-BA^[74]	355	335
KNN-BAZ^[75]	347	318
KNN-BNZ^[76]	360	329
KNN-BKZ-BZ^[77]	305	～300
KNLNS-BS^[78]	325	358
KNN-BNZS^[79]	350	315
KNN-BS-BNKLZ^[80]	366	335
KNN-BNT-BNZ^[81]	318	326
KNN-BNZ-BI^[57]	317	336

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表 6 温度稳定性高的KNN陶瓷体系的压电常数以及变化量

Table 6. Comparison of piezoelectric constant and variation among KNN-based ceramics.

	d₃₃/pC·N^–1	d₃₃ variation/%	$ {d}_{33}^{*} $/pm·V^–1	$ {d}_{33}^{*} $ variation/%
KNLNT-CZ^[86]	—	—	—	almost unchanged @140 ℃
KNN-BNZ-LF^[72]	345	—	420	8%@100 ℃
KNNT-BNKZ-SZ-MnO₂^[49]	—	—	400	10%@180 ℃
KNNT-BNKZ-CZ-MnO₂^[51]	—	—	482	10%@120 ℃
KNNS-BNZ-SZ^[87]	390	—	—	13%@180 ℃
KNN-BLT-BZ-MnO₂^[88]	—	—	470	8.5%@100 ℃, 21.2%@170 ℃
KNNS-BZ-BNZ^[65]	300	10@100 ℃	—	—
KNNS-(BHo)NHf^[89]	—	—	～386	almost unchanged @140 ℃
KNNT-BNZ-CZ^[90]	—	—	502	10%@135 ℃
KNNS-BNKH^[42]	525	—	460	10%@80 ℃
KNN-BZ-BNH-MnO₂^[91]	300	15@120 ℃	540 ± 10	5%@100 ℃
KNN-BNH-BF-MnO₂^[92]	450	—	—	28%@160 ℃
KNN-BNZ-MnO₂-Sb₂O₃^[69]	318	—	—	9%@170 ℃
KNNS-BZH-BNZ^[36]	410	—	441	2.5%@100 ℃, 16.1%@180 ℃
注: 16.1%@180 ℃表示到180 ℃性能下降16.1%.

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表 7 处于6配位时的离子半径表^[131]

Table 7. The ionic radii in six-fold coordination^[131].

	Nb⁵⁺	Ta⁵⁺	Zr⁴⁺	Hf⁴⁺	Sn⁴⁺	Ti⁴⁺	Sb⁵⁺	Sb³⁺	Ga³⁺
离子半径/Å	0.64	0.64	0.72	0.71	0.69	0.605	0.60	0.76	0.62

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表 8 不同结构下原子内坐标随应变的梯度, 注意O_I位于Bmm2不包含Nb原子的(010)平面, KNN中O_I,1和O_I,2沿a方向分别靠近K和Na原子^[138]

Table 8. Internal atomic coordinate gradients as a function of strains in different structure, noted that O_I is located at the (010) plane without Nb atoms in Bmm2, O_I,1 and O_I,2 are close to K and Na along a axis, respectively^[139].

		K	Nb		O_Ⅱ		O_Ⅰ
KN	∂u₃/∂η₃	0.108	0.166		–0.092		–0.091
KN	∂u₁/∂η₅	0.115	0.210		–0.151		–0.024

		K	Na	Nb	O_Ⅱ	O_I,1	O_I,2
KNN	∂u₃/∂η₃	0.103	0.542	0.125	–0.158	–0.125	–0.135
KNN	∂u₁/∂η₅	0.094	0.828	0.194	–0.235	–0.061	–0.309

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[1]	Xiao D Q 2011 J. Adv. Dielectr. 01 33 Google Scholar
[2]	Aksel E, Jones J L 2010 Sensors 10 1935 Google Scholar
[3]	Rödel J, Webber K G, Dittmer R, Jo W, Kimura M, Damjanovic D 2015 J. Eur Ceram. Soc. 35 1659 Google Scholar
[4]	Vats G, Vaish R 2014 Int. J. Appl. Ceram. Tec. 11 883 Google Scholar
[5]	Thong H C, Zhao C L, Zhou Z, Wu C F, Liu Y X, Du Z Z, Li J F, Gong W, Wang K 2019 Mater. Today 29 37 Google Scholar
[6]	Wang K, Malič B, Wu J G 2018 MRS Bull. 43 607 Google Scholar
[7]	Lv X., Zhu J G, Xiao D Q, Zhang X X, Wu J G 2020 Chem. Soc. Rev. 49 671 Google Scholar
[8]	Wu J G, Xiao D Q, Zhu J G 2015 Chem. Rev. 115 2559 Google Scholar
[9]	Gou Q, Wu J G, Li A Q, Wu B, Xiao D Q, Zhu J G 2012 J. Alloy. Comp. 521 4 Google Scholar
[10]	Saito Y, Takao H, Tani T, Nonoyama T, Takatori K, Homma T, Nagaya T, Nakamura M 2004 Nature 432 84 Google Scholar
[11]	Li P, Zhai J W, Shen Bo, Zhang S J, Li X L, Zhu F Y, Zhang X M 2018 Adv. Mater. 30 1705171 Google Scholar
[12]	Tao H, Wu H J, Liu Y, Zhang Y, Wu J G, Li F, Lyu X, Zhao C L, Xiao D Q, Zhu J G, Pennycook S J 2019 J. Am. Chem. Soc. 141 13987 Google Scholar
[13]	Egerton L, Dillond D M 1959 J. Am. Chem. Soc. 42 5 Google Scholar
[14]	Qin Y L, Zhang J L, Yao W Z, Lu C J, Zhang S J 2016 ACS Appl. Mater. Interfaces 8 7257 Google Scholar
[15]	Wang Y Y, Wu J G, Xiao D Q, Wu W J, Zhang B, Wu L, Zhu J G 2008 J. Am. Ceram. Soc. 91 2772 Google Scholar
[16]	Tan C K I, Shannigrahi S, Yao K, Ma J 2015 J. Electroceram. 35 19 Google Scholar
[17]	Pang X M, Qiu J H, Zhu K J 2014 J. Adv. Ceram. 3 147 Google Scholar
[18]	Wang Y Y, Wu J G, Xiao D Q, Zhu J M, Jin Y, Zhu J G, Yu P, Wu L, Li X 2007 J. Appl. Phys. 102 054101 Google Scholar
[19]	Wu W J, Wang Z, Xiao D Q, Ma J, Wu J G, Li J, Liang W F, Zhu J G 2013 Integr. Ferroelectr. 141 82 Google Scholar
[20]	Wu W J, Xiao D Q, Wu J G, Liang W F, Li J, Zhu J G 2011 J. Alloy. Comp. 509 L284 Google Scholar
[21]	Wu J G, Xiao D Q, Wang Y Y, Zhu J G, Yu P 2008 J. Appl. Phys. 103 024102 Google Scholar
[22]	Wu B, Ma J, Wu W J, Chen M, Ding Y C 2018 Ceram. Inter. 44 1172 Google Scholar
[23]	Wen Y, Fan G F, Hao M M, Wang Y J, Chen X, Zhang Q W, Lv W Z 2019 J. Electron. Mater. 49 931 Google Scholar
[24]	Xing J, Tan Z, Yuan J, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 RSC Adv. 6 57210 Google Scholar
[25]	Tang X, Chen T, Liu Y H, Zhang J W, Zhang T, Wang G C, Zhou J F 2016 J. Alloy. Comp. 672 277 Google Scholar
[26]	Yang Y, Wang H, Li Y, Zheng Q J, Liao J, Jie W J, Lin D M 2019 Dalton Trans. 48 10676 Google Scholar
[27]	Wu W J, Chen M, Wu B, Ding Y C, Liu C Q 2017 J. Alloy. Comp. 695 1175 Google Scholar
[28]	Lv X, Wu J G, Xiao D Q, Tao H, Yuan Y, Zhu J G, Wang X J, Lou X J 2015 Dalton Trans. 44 4440 Google Scholar
[29]	Zhong H Y, Xiao HNY, Jiao N, Guo Y P 2019 J. Am. Ceram. Soc. 102 6422 Google Scholar
[30]	Li F L, Tan Z, Xing J, Jiang L M, Wu B, Wu J G, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 8803 Google Scholar
[31]	Li F L, Gou Q, Xing J, Tan Z, Jiang L M, Xie L X, Wu J G, Zhang W, Xiao D Q, Zhu J G 2017 J. Mater. Sci.- Mater. El. 28 18090 Google Scholar
[32]	Lv X, Li Z Y, Wu J G, Xi J W, Gong M, Xiao D Q, Zhu J G 2016 Mater. Design 109 609 Google Scholar
[33]	Lv X, Wu J G, Yang S, Xiao D Q, Zhu J G 2016 ACS Appl. Mater. Interfaces 8 18943 Google Scholar
[34]	Zhou C M, Zhang J L, Yao W Z, Liu D K, He G H 2020 J. Alloy. Comp. 820 153411 Google Scholar
[35]	Wu B, Ma J, Gou Q, Wu W J, Chen M 2019 J. Am. Ceram. Soc. 103 1698 Google Scholar
[36]	Shi C Y, Ma J, Wu J, Chen K, Wu B 2020 Ceram. Inter. 46 7 Google Scholar
[37]	Wang X P, Wu J G, Xiao D Q, Zhu J G, Cheng X J, Zheng T, Zhang B Y, Lou X J, Wang X J 2014 J. Am. Chem. Soc. 136 2905 Google Scholar
[38]	Wang X P, Wu J G, Xiao D Q, Cheng X J, Zheng T, Zhang B Y, Lou X J, Zhu J G 2014 J. Mater. Chem. A 2 4122 Google Scholar
[39]	Tao H, Wu J G, Zheng T, Wang X J, Lou X J 2015 J. Appl. Phys. 118 044102 Google Scholar
[40]	Zhou J S, Wang K, Yao F Z, Zheng T, Wu J G, Xiao D Q, Zhu J G, Li J F 2015 J. Mater. Chem. C 3 8780 Google Scholar
[41]	Xing J, Tan Z, Jiang L M, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2016 J. Appl. Phys. 119 034101 Google Scholar
[42]	Zheng T, Wu H J, Yuan Y, Lv X, Li Q, Men T L, Zhao C L, Xiao D Q, Wu J G, Wang K, Li J F, Gu Y L, Zhu J G, Pennycook S J 2017 Energy Environ. Sci. 10 528 Google Scholar
[43]	Wu B, Wu H J, Wu J G, Xiao D Q, Zhu J G, Pennycook S J 2016 J. Am. Chem. Soc. 138 15459 Google Scholar
[44]	Yang W W, Li P, Li F, Liu X, Shen B, Zhai J W 2019 Ceram. Inter. 45 2275 Google Scholar
[45]	Xu K, Li J, Lv X, Wu J G, Zhang X X, Xiao D Q, Zhu J G 2016 Adv. Mater. 28 8519 Google Scholar
[46]	Wu B, Ma J, Wu W J, Chen M 2020 J. Mater. Chem. C 8 2838 Google Scholar
[47]	Yang W W, Li P, Wu S H, Li F, Shen B, Zhai J W 2020 Ceram. Inter. 46 6 Google Scholar
[48]	Liu Q, Zhang Y C, Gao J, Zhou Z, Wang H, Wang K, Zhang X W, Li L T, Li J F 2018 Energy Environ. Sci. 11 3531 Google Scholar
[49]	Feng W, Cen Z Y, Liang S Y, Luo B C, Zhang Y, Zhen Y C, Wang X H, Li L T 2019 J. Alloy. Comp. 786 498 Google Scholar
[50]	Hreščak J, Dražić G, Deluca M, Arčon I, Kodre A, Dapiaggi M, Rojac T, Malič B, Bencan A 2017 J. Eur Ceram. Soc. 37 2073 Google Scholar
[51]	Cen Z Y, Yu Y, Zhao P Y, Chen L L, Zhu C Q, Li L T, Wang X H 2019 J. Mater. Chem. C 7 1379 Google Scholar
[52]	Sun X X, Zhang J W, Lv X, Zhang X X, Liu Y, Li F, Wu J G 2019 J. Mater. Chem. A 7 16803 Google Scholar
[53]	Qin Y L, Zhang J L, Tan Y Q, Yao W Z, Wang C L, Zhang S J 2014 J. Eur Ceram. Soc. 34 4177 Google Scholar
[54]	Yao W Z, Zhang J L, Wang X M, Zhou C M, Sun X, Zhan J 2019 J. Eur Ceram. Soc. 39 287 Google Scholar
[55]	Zhou C M, Zhang J L, Yao W Z, Wang X M, Liu D K, Sun X 2018 J. Appl. Phys. 124 164101 Google Scholar
[56]	López-Juárez R, Novelo-Peralta O, González-García F, Rubio-Marcos F, Villafuerte-Castrejón M-E 2011 J. Eur Ceram. Soc. 31 1861 Google Scholar
[57]	Xing J, Tan Z, Chen X Y, Jiang L M, Wang W W, Deng X, Wu B, Wu J G, Xiao D Q, Zhu J G 2019 Inorg. Chem. 58 428 Google Scholar
[58]	Huan Y, Wei T, Wang Z X, Lei Y C, Chen F L, Wang X H 2019 J. Eur Ceram. Soc. 39 1002 Google Scholar
[59]	Ding Y, Zheng T, Zhao C L, Wu J G 2019 J. Appl. Phys. 126 124101 Google Scholar
[60]	Zhao C L, Wu B, Wang K, Li J F, Xiao D Q, Zhu J G, Wu J G 2018 J. Mater. Chem. A 6 23736 Google Scholar
[61]	Qin Y L, Zhang J L, Gao Y, Tan Y Q, Wang C L 2013 J. Appl. Phys. 113 204107 Google Scholar
[62]	Liu Q, Zhang Y C, Zhao L, Gao J, Zhou Z, Wang K, Zhang X W, Li L T, Li J F 2018 J. Mater. Chem. C 6 10618 Google Scholar
[63]	Liu Q, Li J F, Zhao L, Zhang Y C, Gao J, Sun W, Wang K, Li L T 2018 J. Mater. Chem. C 6 1116 Google Scholar
[64]	Fu J, Zuo R Z, Qi H, Zhang C, Li J F, Li L T 2014 Appl. Phys. Lett. 105 242903 Google Scholar
[65]	Zhou C M, Zhang J L, Yao W Z, Liu D K, Su W B 2019 Scripta Mater. 162 86 Google Scholar
[66]	Li P, Huan Y, Yang W W, Zhu F Y, Li X L, Zhang X M, Shen B, Zhai J W 2019 Acta Mater. 165 486 Google Scholar
[67]	Liu D K, Zhang X C, Su W B, Wang X M, Yao W Z, Zhou C M, Zhang J L 2019 J. Alloy. Comp. 779 800 Google Scholar
[68]	Lv X, Wu J G 2019 J. Mater. Chem. C 7 2037 Google Scholar
[69]	Zhang N, Zhao C, Wu J G 2019 Ceram. Inter. 45 24827 Google Scholar
[70]	Xing J, Tan Z, Xie L X, Jiang L M, Yuan J, Chen Q, Wu J G, Zhang W, Xiao D Q, Zhu J G 2018 J. Am. Ceram. Soc. 101 1632 Google Scholar
[71]	Tao H, Wu J G, Wang H 2016 J. Alloy. Comp. 684 217 Google Scholar
[72]	Wang T, Wu C, Xing J, Wu J G, Li Chen B W, Xu X Y, Wang K, Zhu J G 2019 J. Am. Ceram. Soc. 102 6126 Google Scholar
[73]	Cen Z Y, Wang X H, Huan Y, Li L T 2018 J. Am. Ceram. Soc. 101 2391 Google Scholar
[74]	Jiang L M, Tan Z, Xing J, Wu J G, Chen Q, Zhang W, Xiao D Q, Zhu J G 2016 J. Mater. Sci.- Mater. El. 27 9812 Google Scholar
[75]	Wang X P, Wu J G, Lv X, Tao H, Cheng X J, Zheng T, Zhang B Y, Xiao D Q, Zhu J G 2014 J. Mater. Sci.- Mater. El. 25 3219 Google Scholar
[76]	Wang Z, Xiao D Q, Wu J G, Xiao M, Li F X, Zhu J G, Damjanovic D 2014 J. Am. Ceram. Soc. 97 688 Google Scholar
[77]	Feng S S, Xiao D Q, Wu J G, Xiao M, Zhu J G 2015 J. Alloy. Comp. 619 560 Google Scholar
[78]	Cheng X J, Wu J G, Wang X P, Zhang B Y, Lou X J, Wang X J, Xiao D Q, Zhu J G 2013 ACS Appl. Mater. Interfaces 5 10409 Google Scholar
[79]	Gou Q, Zhu J G, Wu J G, Li F L, Jiang L M, Xiao D Q 2018 J. Alloy. Comp. 730 311 Google Scholar
[80]	Cheng X J, Wu J G, Lou X J, Wang X J, Wang X P, Xiao D Q, Zhu J G 2014 ACS Appl. Mater. Interfaces 6 750 Google Scholar
[81]	Gou Q, Xiao D Q, Wu B, Xiao M, Feng S S, Ma Zhao D D, Wu J G, Zhu J G 2015 RSC Adv. 5 30660 Google Scholar
[82]	Ma Q, Wan B B, Cheng L J, Liu S J, Liu F S 2016 J. Electroceram. 36 30 Google Scholar
[83]	Kim J H, Kim J S, Han S H, Kang H W, Lee H G, Cheon C I 2016 Ceram. Inter. 42 5226 Google Scholar
[84]	Sumang R, Wicheanrat C, Bongkarn T, Maensiri S 2015 Ceram. Inter. 41 S136 Google Scholar
[85]	Zhang S J, Xia R, Hao H, Liu H X, Shrout T R 2008 Appl. Phys. Lett. 92 152904 Google Scholar
[86]	Yao F Z, Wang K, Jo W, Webber K G, Comyn T P, Ding J X, Xu B, Cheng L Q, Zheng M P, Hou Y D, Li J F 2016 Adv. Funct. Mater. 26 1217 Google Scholar
[87]	Lv X, Wu J G, Zhu J G, Xiao D Q 2018 Phys. Chem. Chem. Phys. 20 20149 Google Scholar
[88]	Zhang M H, Wang K, Du Y J, Dai G, Sun W, Li G, Hu D, Thong H C, Zhao C L, Xi X Q, Yue Z X, Li J F 2017 J. Am. Chem. Soc. 139 3889 Google Scholar
[89]	Tao H, Zhao C L, Zhang R, Wu J G 2019 J. Alloy. Comp. 795 401 Google Scholar
[90]	Cen Z Y, Feng W, Zhao P Y, Chen L L, Zhu C Q, Yu Y, Li L T, Wang X H 2018 J. Am. Ceram. Soc. 102 2675 Google Scholar
[91]	Huang Y L, Zhao C L, Wu B, Wu J G 2019 J. Am. Ceram. Soc. 102 2648 Google Scholar
[92]	Zheng T, Wu J G 2020 Acta Mater. 182 1 Google Scholar
[93]	Ramajo L, Rubio-Marcos F, Del Campo A, Fernández J F, Castro M S, Parra R 2015 J. Mater. Sci.- Mater. El. 26 9402 Google Scholar
[94]	Liu W L, Tan G Q, Xiong P, Xue X, Hao H F, Ren H J 2014 J. Mater. Sci.- Mater. El. 25 2348 Google Scholar
[95]	Hao H F, Tan G Q, Ren H J, Xia A, Xiong P 2014 Ceram. Inter. 40 9485 Google Scholar
[96]	Gu Q L, Sun Q M, Zhu K J, Liu J S, Qiu J H 2017 Ceram. Inter. 43 1135 Google Scholar
[97]	Cheng L Q, Wang K, Li J F 2015 Mater. Lett. 138 128 Google Scholar
[98]	Li Y M, Wang J S, Liao R H, Huang D, Jiang X P 2010 J. Alloy. Compd. 496 282 Google Scholar
[99]	Kumar P, Pattanaik M, Sonia 2013 Ceram. Inter. 39 65 Google Scholar
[100]	Haugen A B, Madaro F, Bjørkeng L-P, Grande T, Einarsrud M A 2015 J. Eur Ceram. Soc. 35 1449 Google Scholar
[101]	Jiang C Y, Tian X X, Shi G D 2016 Adv. Intell. Sys. Res. 136 7 Google Scholar
[102]	Yokouchi Y, Maeda T, Bornmann P, Hemsel T, Morita T 2013 Jpn. J. Appl. Phys. 52 07HB03 Google Scholar
[103]	Wang C, Fang B J, Qu Y H, Chen Z H, Zhang S, Ding J N 2020 J. Alloy. Compd. 832 153043 Google Scholar
[104]	Jaeger R E, Egerton L 1962 J. Am. Ceram. Soc. 45 5 Google Scholar
[105]	Li M Y, Chan N Y, Wang D Y 2017 J. Am. Ceram. Soc. 100 2984 Google Scholar
[106]	Feizpour M, Barzegar Bafrooei H, Hayati R, Ebadzadeh T 2014 Ceram. Inter. 40 871 Google Scholar
[107]	Ma J Z, Li H Y, Wang H J, Lin C, Wu X, Lin T F, Zheng X H, Yu X 2019 J. Eur Ceram. Soc. 39 986 Google Scholar
[108]	Chi M S, Ma W B, Guo J D, Wu J Q, Li T T, Wang S H, Zhang P F 2019 J. Mater. Sci.- Mater. El. 39 986 Google Scholar
[109]	Yu Z D, Chen X M, Su Y L, Lian H L, Lu J B, Zhou J P, Liu P 2019 J. Mater. Sci. 54 13457 Google Scholar
[110]	Li J F, Wang K, Zhang B P, Zhang L M 2006 J. Am. Ceram. Soc. 89 706 Google Scholar
[111]	Cen Z Y, Li L T, Wang X H 2019 J. Alloy. Comp. 797 1115 Google Scholar
[112]	Li H, Gong D W, Yang W L, Zhou Z X 2012 J. Mater. Sci. 48 1396 Google Scholar
[113]	Liao Y, Wang D M, Wang H, Wang T, Wei X H, Zheng Q J, Jie W J, Lin D M 2019 Ceram. Inter. 45 2644 Google Scholar
[114]	Wu B, Yin J, Lv X, Xiao D Q, Zhu J G, Wu J G 2019 J. Appl. Phys. 125 082526 Google Scholar
[115]	Liao Y, Wang D M, Wang H, Zhou L X, Zheng Q J, Lin D M 2020 Dalton Trans. 49 1311 Google Scholar
[116]	Comes R, Lambert M, Guinier A 1968 Solid State Commun. 6 715 Google Scholar
[117]	Cohen R E 1992 Nature 358 136 Google Scholar
[118]	Atern E A, Yacoby Y 1996 J. Phys. Chem. Solids 57 1449 Google Scholar
[119]	Rytz D, Höchli U T, Bilz H 1980 Phys. Rev. B 22 359 Google Scholar
[120]	Shuvaeva V A, Yanagi K, Yagi K, Sakaue K, Terauchi H 1998 Solid State Commun 106 335 Google Scholar
[121]	Devonshire A F 1949 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 40 1040 Google Scholar
[122]	Devonshire A F 1951 The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 42 1065 Google Scholar
[123]	Cochran W 1959 Phys. Rev. Lett. 3 412 Google Scholar
[124]	Damjanovic D, Demartin 1997 J. Phys.-Condens. Mat. 9 4943 Google Scholar
[125]	谭智 2019 博士学位论文 (成都: 四川大学) Tan Z 2019 Ph. D. Dissertation (Chengdu: Sichuan University) (in Chinese)
[126]	Tellier J, Malic B, Dkhil B, Jenko D, Cilensek J, Kosec M 2009 Solid State Sci. 11 320 Google Scholar
[127]	Baker D W, Thomas P A, Zhang N, Glazer A M 2009 Appl. Phys. Lett. 95 091903 Google Scholar
[128]	Guo Y P, Kakimoto K, Ohsato H 2004 Appl. Phys. Lett. 85 4121 Google Scholar
[129]	Yang D, Wei L L, Chao X L, Yang Z P, Zhou X Y 2016 Phys. Chem. Chem. Phys. 18 7702 Google Scholar
[130]	Wu Z G, Cohen R E 2005 Phys. Rev. Lett. 95 037601 Google Scholar
[131]	Shannon R D 1976 Acta Crystallogra. A 32 751 Google Scholar
[132]	Tan Z, Xing J, Jiang L M, Zhu J G, Wu B 2017 Front. Mater. Sci. 11 344 Google Scholar
[133]	Ke S M, Huang H T, Fan H Q, Lee H K, Zhou L M, Mai Y M 2012 Appl. Phys. Lett. 101 082901 Google Scholar
[134]	Fu H X, Cohen R E 2000 Nature 403 281 Google Scholar
[135]	Suewattana M, Singh D J 2010 Phys. Rev. B 82 014114 Google Scholar
[136]	Voas B K, Usher T M, Liu X, Li S, Jones J L, Tan X, Cooper V R, Beckman S P 2014 Phys. Rev. B 90 024105 Google Scholar
[137]	Matsumoto K, Hiruma Y, Nagata H, Takenaka T 2008 Ceram. Inter. 34 787 Google Scholar
[138]	Tan Z, Peng Y T, An J, Zhang Q M, Zhu J G 2019 J. Am. Ceram. Soc. 102 5262 Google Scholar
[139]	Peng Y, T Tan Z, An J, Zhu J G, Zhang Q M 2019 J. Eur. Ceram. Soc. 39 5252 Google Scholar
[140]	Li C W, Xu X, Gao Q, Lu Z L 2019 Ceram. Int. 45 11092 Google Scholar
[141]	Liu S Y, Liu S, Li D J, Shen Y, Dang H, Liu Y, Xue W, Wang S 2014 J. Am. Ceram. Soc 97 4019 Google Scholar
[142]	Li Q, Zhang R, Lv T Q, Zheng L M 2015 Chin. Phys. B 24 053101 Google Scholar
[143]	Yang D, Chai Q Z, Wei L L, Chao X L, Yang Z P 2017 Phys. Chem. Chem. Phys. 19 27368 Google Scholar

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