Magnetic and anisotropic magnetocaloric effects of HoCoSi fast quenching ribbons

Zhang Yan; Zong Shuo-Tong; Sun Zhi-Gang; Liu Hong-Xia; Chen Feng-Hua; Zhang Ke-Wei; Hu Ji-Fan; Zhao Tong-Yun; Shen Bao-Gen

doi:10.7498/aps.71.20220683

Abstract

The performance of magnetocaloric effect materials is one of the key factors restricting the development of magnetic refrigeration technology. Materials with anisotropic magnetocaloric effect can be used in the rotary magnetic refrigeration technology, which is beneficial to the simplification of refrigeration devices. In this work, the magnetic properties, magnetocaloric effects, and magnetic anisotropies of rapidly quenched HoCoSi compounds are investigated. At low temperatures below T_t = 5.7 K, the HoCoSi ferromagnetism and helical magnetism coexist. With the increase of temperature, the HoCoSi undergoes a second-order phase transition from ferromagnetic (FM) to paramagnetic (PM) phase at T_C = 13.7 K. Both XRD and SEM show that the HoCoSi has a preferred orientation. In order to obtain a large magnetocaloric effect and to determine the effect of preferred orientation on magnetism and magnetocaloric effect, the isothermal magnetization curves of the 10 m/s–HoCoSi fast quenched belt in the directions of H parallel and perpendicular to texture around the Curie temperature are analyzed. The corresponding magnetic entropy change (–ΔS_M) and magnetic refrigeration capacity (RC) are calculated. Under the magnetic field changing from 0 to 5 T, the value of –ΔS_M is 22 J/(kg·K) in the direction of H parallel to the texture and 12 J/(kg·K) in the direction of H perpendicular to texture , and their corresponding values of RC(RCP)are 360 (393.8) J·kg^–1 and 160 (254.4) J/kg. The value of –ΔS_M reaches 12.5 J/(kg·K)even at μ₀H = 0–2 T in the direction of H parallel to the texture. It is obvious that the 10-m/s-HoCoSi fast quenching belt shows a large low-field magnetocaloric effect and obvious magnetic anisotropy, which is expected to be used to realize the magnetic refrigeration technology of rotating samples.

Keywords:

Authors and contacts

1.
School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China
2.
Laboratory of Magnetic and Electric Functional Materials and the Applications, The Key Laboratory of Shanxi Province, Taiyuan 030024, China
3.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Zong Shuo-Tong, zongshuotong@tyust.edu.cn

Funds: Project supported by the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi (Grant No. 2021 L304), the Taiyuan University of Science and Technology Scientific Research Initial Funding (Grant No. 20202022), the Funding for Outstanding Doctoral Research in Jin (Grant No. 20212002), the State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technology) (Grant No. 2022-KF-32).

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References

[1]	Shen B G, Sun J R, Hu F X, Zhang H W, Cheng Z H 2009 Adv. Mater. 21 4545 Google Scholar
[2]	Franco V, Blázquez J S, Ingale B, Conde A 2012 Annu. Rev. Mater. Sci. 42 305 Google Scholar
[3]	Zhang H, Shen B G, Xu Z Y, Shen J, Hu F X, Sun J R, Long Y 2013 Appl. Phys. Lett. 102 092401 Google Scholar
[4]	Gschneidner K A Jr, Pecharsky V K, Tsokol A O 2005 Rep. Prog. Phys. 68 1479 Google Scholar
[5]	Zhang H, Shen B G 2015 Chin. Phys. B 24 127504 Google Scholar
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[7]	Li L W, Yan M 2022 JMST
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[10]	Nikitin S A, Skokov K P, Koshkid'ko Y S, Pastushenkov Y G, Ivanova T I 2010 Phys. Rev. Lett. 105 137205 Google Scholar
[11]	Balli M, Mansouri S, Dimitrov D Z, Fournier P, Jandl S, Juang J Y 2020 Phys. Rev. Mater. 4 114411 Google Scholar
[12]	Nikitin S A, Ivanova T I, Zvonov A I, Koshkid'ko Y S, Ćwik J, Rogacki K 2018 Acta Mater. 161 331 Google Scholar
[13]	Liu Y, Petrovic C 2018 Phys. Rev. B 97 174418 Google Scholar
[14]	Liu Y, Petrovic C 2019 Phys Rev. Mater. 3 014001 Google Scholar
[15]	Zhang H, Li Y V, Liu E K, Ke Y J 2015 Sci. Rep. 5 11929 Google Scholar
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[18]	Welter R, Venturini G, Ressouche E, Malaman B 1994 J. Alloys Compd. 210 279 Google Scholar
[19]	Gupta S, Suresh K G 2013 Mater. Lett. 113 195 Google Scholar
[20]	Leciejewicz J, Stusser N, Kolenda M, Szytuta A, Zygmunt A 1996 J. Alloys Compd. 240 164 Google Scholar
[21]	Yuan F, Du J, Shen B L 2012 Appl. Phys. Lett. 101 032405 Google Scholar
[22]	Szytula A, Balanda M, Hofmann M, Leciejewicz J, Kolenda M, Penc B, Zygmunt A 2009 J. Appl. Phys. 105 023901 Google Scholar
[23]	Wang J L, Marquina C, Ibarra M R, Wu G H 2006 Phys. Rev. B 73 094436
[24]	Szytula A, Balanda M, Hofmann M, Leciejewicz J, Kolenda M, Penc B, Zygmunt A 1999 J. Magn. Magn. Mater. 191 122 Google Scholar
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[26]	Guo D, Zhang Y K, Wu B B, Wang H F, Guan R G, Li X, Ren Z M 2020 J. Alloy. Compd. 830 154666 Google Scholar
[27]	Ma Y, Dong X, Qi Y, 2019 J. Magn. Magn. Mater. 471 25 Google Scholar
[28]	Zhang Y, Zhu J, Li S, Zhang Z Q, Wang J, Ren Z M 2022 Sci. China Mater. 65 1345 Google Scholar
[29]	Li L W, Xu P, Ye S K, Li Y, Liu G D, Huo D X, Yan M 2020 Acta Mater. 194 354 Google Scholar
[30]	Wu B B, Guo D, Wang Y M, Zhang Y K 2020 Ceram. Int. 46 11988 Google Scholar
[31]	Zhang Y K, Zhang B, Li S, Zhu J, Wu B B, Wang J, Ren Z M 2021 Ceram. Int. 47 18205 Google Scholar

Cited By

图 1 (a)—(d)甩带速度为分别为5 m/s, 10 m/s, 15 m/s, 20 m/s的HoCoSi快淬带在自由面和贴辊面的XRD图(f代表自由面, n代表贴辊面)

Figure 1. (a)−(d) XRD patterns of the HoCoSi fast quenched belts at 5 m/s, 10 m/s, 15 m/s, and 20 m/s on the free surface and the roller surface (f represents the free surface and n represents the roll surface).

DownLoad: Full-Size Img PowerPoint

图 2 外场为0.1 T时, 10 m/s甩带速度下的HoCoSi在ZFC和FCC两种模式下的热磁曲线, ZFC的一阶导数曲线显示在下方; 内插图为ZFC模式的1/χ-T 曲线, 实线表示Curie-Weiss拟合

Figure 2. The temperature dependence of magnetization in ZFC and FC mode for HoCoSi of 10 m/s under the field of 0.01 T, and the corresponding ZFC first derivative curves are shown below. The 1/χ-T curve of ZFC was displayed in the insets. The solid line to inverse susceptibility shows the Curie-Weiss fit.

DownLoad: Full-Size Img PowerPoint

图 3 在5 m/s, 10 m/s, 15 m/s, 20 m/s甩带速度下HoCoSi快淬带的磁场//织构方向的等温磁化曲线　(a) T = 5 K, 插图为10 m/s的快淬带横截面的SEM图; (b) T = 17 K

Figure 3. The magnetization isotherms of 5 m/s, 10 m/s, 15 m/s, 20 m/s HoCoSi taken in the direction of H parallel to textures: (a) T = 5 K, the SEM image of the cross-section of 10 m/s HoCoSi was displayed in the inset; (b) T = 17 K.

DownLoad: Full-Size Img PowerPoint

图 4 甩带速度10 m/s时HoCoSi快淬带在磁场平行　(a)和垂直(b)织构方向的等温磁化曲线; (c) T = 5 K, μ₀H = 2 T下的转角磁化曲线

Figure 4. The magnetization isotherms of 10 m/s HoCoSi taken in the direction of H parallel to textures (a) and H perpendicular to textures (b); (c) the magnetization as a function of rotation angle at 5 K in the magnetic field of 2 T.

DownLoad: Full-Size Img PowerPoint

图 5 10 m/s的HoCoSi快淬带的$\Delta {S}_{\mathrm{M}}\text-T$变化曲线　(a)磁场平行⊥织构方向; (b)磁场垂直织构方向; 内插图为制冷能力RC随外场变化关系

Figure 5. The$\Delta {S}_{\mathrm{M}}\text-T$ curves of 10 m/s HoCoSi: (a) In the direction of H parallel to textures; (b) in the direction of H perpendicular to textures. The corresponding magnetic refrigeration capacity RC were showed in the insets.

DownLoad: Full-Size Img PowerPoint

图 6 10 m/s下HoCoSi快淬带在磁场垂直织构方向的M-T曲线(a)和M-H曲线放大图(b)

Figure 6. The curves of M-T (a) and M-H curve enlarged view(b)of 10 m/s HoCoSi taken in the direction of H perpendicular to the texture.

DownLoad: Full-Size Img PowerPoint

表 1 10 m/s下HoCoSi化合物的磁热参数和一些最近报道的 Δμ₀H = 5 T 的有前景的低温磁制冷材料

Table 1. Magnetocaloric parameters for the 10 m/s HoCoSi compounds and some recently reported promising cryogenic magnetic refrigerants for Δμ₀H = 5 T.

Compound	T_M /K	$ \left\| {\Delta S_{\text{M}}^{{\max}}} \right\| $/(J·(kg·K)^–1)	δTFWHM/K	RCP/(J·kg^–1)	Refs.
Compound	T_M /K		δTFWHM/K	RCP/(J·kg^–1)	Refs.	HoCoSi(parallel)	13.7	22	17.9	393.8	This study
HoCoSi(perpendicular)	13.7	12	21.2	266.4	This study
Er₂Ni_1.5Ga_2.5	4.1	15.7	18.3	254.4	[26]
PrFe₂Si₂	8.5	6.4	17	~100.8	[27]
NdFe₂Si₂	15.5	12.4	11	~116.3	[27]
GdFe₂Si₂	8.6	23.25	9	276.56	[28]
Gd₂ZnMnO₆	6.4	15.2	14.9	226.2	[29]
Ho₂ZnMnO₆	6.8	13.2	18.7	246.5	[29]
Ho₂CrMnO₆	6.1	8.8	22.0	193.7	[30]
Er₂CrMnO₆	5.2	10.3	14.2	146.0	[30]
Er₂CuMnO₆	3.6	9.9	19.7	195.9	[31]

DownLoad: CSV

map

[1]	Shen B G, Sun J R, Hu F X, Zhang H W, Cheng Z H 2009 Adv. Mater. 21 4545 Google Scholar
[2]	Franco V, Blázquez J S, Ingale B, Conde A 2012 Annu. Rev. Mater. Sci. 42 305 Google Scholar
[3]	Zhang H, Shen B G, Xu Z Y, Shen J, Hu F X, Sun J R, Long Y 2013 Appl. Phys. Lett. 102 092401 Google Scholar
[4]	Gschneidner K A Jr, Pecharsky V K, Tsokol A O 2005 Rep. Prog. Phys. 68 1479 Google Scholar
[5]	Zhang H, Shen B G 2015 Chin. Phys. B 24 127504 Google Scholar
[6]	郑新奇, 沈俊, 胡凤霞, 孙继荣, 沈保根王军民 2016 65 217502 Google Scholar Zheng X Q, Shen J, Hu F X, Sun J R, Shen B G 2016 Acta Phys. Sin. 65 217502 Google Scholar
[7]	Li L W, Yan M 2022 JMST
[8]	Zhang Y K 2019 J. Alloys Compd. 787 1173 Google Scholar
[9]	Li L W, Yan M 2020 J. Alloys Compd. 823 153810 Google Scholar
[10]	Nikitin S A, Skokov K P, Koshkid'ko Y S, Pastushenkov Y G, Ivanova T I 2010 Phys. Rev. Lett. 105 137205 Google Scholar
[11]	Balli M, Mansouri S, Dimitrov D Z, Fournier P, Jandl S, Juang J Y 2020 Phys. Rev. Mater. 4 114411 Google Scholar
[12]	Nikitin S A, Ivanova T I, Zvonov A I, Koshkid'ko Y S, Ćwik J, Rogacki K 2018 Acta Mater. 161 331 Google Scholar
[13]	Liu Y, Petrovic C 2018 Phys. Rev. B 97 174418 Google Scholar
[14]	Liu Y, Petrovic C 2019 Phys Rev. Mater. 3 014001 Google Scholar
[15]	Zhang H, Li Y V, Liu E K, Ke Y J 2015 Sci. Rep. 5 11929 Google Scholar
[16]	Zhang H, Xing C F, Zhou H, Zheng X Q, Miao X F, He L H, Chen J, Lu H L, Liu E K, Han W T, Zhang H G, Wang Y X, Long Y, Eijk L V, Brück E 2020 Acta Mater. 193 2020
[17]	Barua R, Lejeune B T, Ke L, Hadjipanayis G, Levin E M, McCallum R W, Kramer M J, Lewis L H 2018 J. Alloys. Compd. 745 505 Google Scholar
[18]	Welter R, Venturini G, Ressouche E, Malaman B 1994 J. Alloys Compd. 210 279 Google Scholar
[19]	Gupta S, Suresh K G 2013 Mater. Lett. 113 195 Google Scholar
[20]	Leciejewicz J, Stusser N, Kolenda M, Szytuta A, Zygmunt A 1996 J. Alloys Compd. 240 164 Google Scholar
[21]	Yuan F, Du J, Shen B L 2012 Appl. Phys. Lett. 101 032405 Google Scholar
[22]	Szytula A, Balanda M, Hofmann M, Leciejewicz J, Kolenda M, Penc B, Zygmunt A 2009 J. Appl. Phys. 105 023901 Google Scholar
[23]	Wang J L, Marquina C, Ibarra M R, Wu G H 2006 Phys. Rev. B 73 094436
[24]	Szytula A, Balanda M, Hofmann M, Leciejewicz J, Kolenda M, Penc B, Zygmunt A 1999 J. Magn. Magn. Mater. 191 122 Google Scholar
[25]	许志一 2012 博士学位论文 (北京: 中国科学院物理研究所) Xu Z Y 2012 Ph. D. Dissertation (Beijing: Institute of Physics, Chinese Academy of Sciences) (in Chinese)
[26]	Guo D, Zhang Y K, Wu B B, Wang H F, Guan R G, Li X, Ren Z M 2020 J. Alloy. Compd. 830 154666 Google Scholar
[27]	Ma Y, Dong X, Qi Y, 2019 J. Magn. Magn. Mater. 471 25 Google Scholar
[28]	Zhang Y, Zhu J, Li S, Zhang Z Q, Wang J, Ren Z M 2022 Sci. China Mater. 65 1345 Google Scholar
[29]	Li L W, Xu P, Ye S K, Li Y, Liu G D, Huo D X, Yan M 2020 Acta Mater. 194 354 Google Scholar
[30]	Wu B B, Guo D, Wang Y M, Zhang Y K 2020 Ceram. Int. 46 11988 Google Scholar
[31]	Zhang Y K, Zhang B, Li S, Zhu J, Wu B B, Wang J, Ren Z M 2021 Ceram. Int. 47 18205 Google Scholar

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