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It is shown by means of electron diffraction and high resolution lattice imaging that there are 9R, 10H, 16H, 20H, 21R, 44H and 2H structures in cast Ni3(Tix,V1-x) alloys. These phases have the following orientation relationships with primary phases Ni3Ti and Ni3V: {001}L.P∥{001}(Ni3Ti)∥{112}(Ni3V);〈100〉L.P.∥〈100〉(Ni3Ti)∥〈110〉(Ni3V) After prolonged annealingat high temperature these phases would transform into 9R.
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