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采用熔融冷却法制备了系列Ho3+/Pr3+共掺的Ge25Ga10Se65玻璃样品,测试了样品的吸收光谱以及908 nm激光抽运下的中红外荧光光谱和Ho3+离子5I7能级寿命.计算了Ho3+:5I7→5I8发射截面和Pr3+:3H4→3F2吸收截面,讨论了Ho3+,Pr3+离子之间的能量转移效率及Pr3+离子浓度的影响.通过拟合Ho3+离子2.0 μm荧光衰减曲线判断能量转移机理.结果表明,Ho3+掺杂Ge25Ga10Se65玻璃中引入Pr3+离子可以有效提高Ho3+离子的2.9 μm荧光强度.
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关键词:
- 中红外发光 /
- 硫系玻璃 /
- Ho3+/Pr3+共掺
A series of chalcogenide glasses based on Ge25Ga10Se65 system co-doped with Ho3+/Pr3+ ions of different ratios were synthesized by melt-quenching technique. The absorption spectra,mid-infrared fluorescence and lifetime of glass samples under 908 nm laser excitation were measured. The emission cross section of Ho3+:5I7→5I8 and absorption cross section of Pr3+:3H4→3F2 were calculated. The energy transfer efficiency between Ho3+ and Pr3+ ions with different Pr3+ ion concentrations have been discussed. Through fitting the 2.0 μm fluorescence decay curves of Ho3+ ions,the energy transfer regime was judged. The results prove thatTm3+ is an efficient sensitizer which enhances the Ho3+: 2.9 μm fluorescence intensity significantly.-
Keywords:
- mid-infrared luminescence /
- chalcogenide glass /
- Pr3+/Ho3+ codoped
[1] Moizan V,Nazabal V,Troles J,Houizot P,Adam J L,Doualan J L,Moncorge R,Smektala F,Gadret G,Pitoisc S,Canat G 2008 Opt. Mater. 31 39
[2] Ma J Y,Fang X,Kamran M,Zhao H Y,Bi C Z,Zhao B R,Qiu X G 2008 Chin. Phys. B17 3313
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[4] Nemec P,Frumar M 2008 Mater. Lett. 62 2799
[5] Munzar M,Koughia C,Tonchev D,Maeda K,Ikari T,Haugen C,Decorby R,McMullin J N,Kasap S O 2006 Opt. Mater. 28 225
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[8] Lee T H,Heo J,Choi Y G,Park B J,Kim K H 2004 Chem. Phys. Lett. 384 16
[9] Choi Y G,Park B J,Kim K H 2003 Opt. Lett. 28 622
[10] Shaw L B,Harbison B B,Cole B,Sanghera J S,Aggarwal I D 1997 Opt. Express 1 87
[11] Jackson S D 2009 Opt. Lett. 34 2327
[12] Dexter D L 1953 J. Chem. Phys. 21 836
[13] McCumber D E 1964 Phys. Rev. 134A299
[14] Yang Z Y,Luo L,Chen W 2006 J. Opt. Soc. Am. B23 358
[15] Weber M J 1971 Phys. Rev. B 4 2932
[16] Dai S X,Xu T F,Nie Q H,Shen X,Zhang J J,Hu L L 2006 Acta Phys. Sin. 55 1479 (in Chinese)[戴世勋、徐铁峰、聂秋华、沈 祥、张军杰、胡丽丽 2006 55 1479]
[17] Jackson S D 2004 Opt. Lett. 29 334
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[1] Moizan V,Nazabal V,Troles J,Houizot P,Adam J L,Doualan J L,Moncorge R,Smektala F,Gadret G,Pitoisc S,Canat G 2008 Opt. Mater. 31 39
[2] Ma J Y,Fang X,Kamran M,Zhao H Y,Bi C Z,Zhao B R,Qiu X G 2008 Chin. Phys. B17 3313
[3] Cai C F,Wu H Z,Si J X,Sun Y,Dai N 2009 Acta Phys. Sin. 58 3560(in Chinese)[蔡春锋、吴惠桢、斯剑霄、孙 艳、戴 〖4] Calvez L,Lucas P,Roze M,Ma H L,Lucas J,Zhang X H 2007 Appl. Phys. A 89 183
[4] Nemec P,Frumar M 2008 Mater. Lett. 62 2799
[5] Munzar M,Koughia C,Tonchev D,Maeda K,Ikari T,Haugen C,Decorby R,McMullin J N,Kasap S O 2006 Opt. Mater. 28 225
[6] Park B J,Seo H S,Ahn J T,Choi Y G,Jeon D Y,Chung W J 2008 J. Lumin. 128 1617
[7] Schweizer T,Samson B N,Hector J R,Brocklesby W S,Hewak D W,Payne D N 1999 Infrared Phys. Technol. 40 329
[8] Lee T H,Heo J,Choi Y G,Park B J,Kim K H 2004 Chem. Phys. Lett. 384 16
[9] Choi Y G,Park B J,Kim K H 2003 Opt. Lett. 28 622
[10] Shaw L B,Harbison B B,Cole B,Sanghera J S,Aggarwal I D 1997 Opt. Express 1 87
[11] Jackson S D 2009 Opt. Lett. 34 2327
[12] Dexter D L 1953 J. Chem. Phys. 21 836
[13] McCumber D E 1964 Phys. Rev. 134A299
[14] Yang Z Y,Luo L,Chen W 2006 J. Opt. Soc. Am. B23 358
[15] Weber M J 1971 Phys. Rev. B 4 2932
[16] Dai S X,Xu T F,Nie Q H,Shen X,Zhang J J,Hu L L 2006 Acta Phys. Sin. 55 1479 (in Chinese)[戴世勋、徐铁峰、聂秋华、沈 祥、张军杰、胡丽丽 2006 55 1479]
[17] Jackson S D 2004 Opt. Lett. 29 334
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