GeS2-In2S3硫系玻璃的物化性质与晶化行为研究

林常规; 翟素敏; 李卓斌; 屈国顺; 顾少轩; 陶海征; 戴世勋

doi:10.7498/aps.64.054208

摘要

认识玻璃组成-性能-结构之间关系是玻璃科学中经久不衰的研究课题之一. 在制得(100-x) GeS2-xIn2S3 (x=10, 15, 20, 25或30 mol%) 系列玻璃和玻璃陶瓷样品的基础上, 利用可见-近红外透过光谱, DSC, XRD和Raman光谱等测试技术表征了随组份变化的光学带隙, 玻璃转变温度以及晶化行为等, 并结合GeS2-Ga2S3玻璃研究结果探讨了Ga, In 元素及其形成的网络结构对玻璃性质的影响.研究发现, 在硫系玻璃中In比Ga对光学带隙和玻璃转变温度等性质的影响要大. 它们所形成玻璃的晶化行为也截然不同, 但与其各自的材料相图有着密切的联系. 利用偏振拉曼光谱获得玻璃网络中的基本结构单元信息.最后, 结合材料相图, 玻璃随组成变化的物化性质和晶化行为以及基本网络结构单元的认识, 探讨了玻璃的化学拓扑与网络拓扑之间的联系, 为今后研究提供一种新的研究思路.

关键词:

Abstract

Relationship among the composition, properties, and structure of glasses are one of the long standing topics in glass science. In this paper, (100-x) GeS2-xIn2S3 (x=10, 15, 20, 25 or 30 mol%) glasses and glass-ceramics are prepared by melt-quenching and subsequent heat treatments. Their composition dependence of optical bandgap, glass transition temperature, and crystallization behavior is measured by various techniques, and the effect of Ga or In element and the related structural units on their properties is discussed with the help of the previous researches on the GeS2-Ga2S3 glass system. Results show that In has a much bigger influence than Ga on the optical bandgap and glass transition temperature of chalcogenide glasses, while the crystallization behavior of the two kinds of glasses containing Ga and In is totally different, but has a close connection with the respective phase diagram. Their structural motifs can be realized by employing polarized Raman spectra. Consequently, combined with the recognition of their phase diagrams, the composition dependence of physiochemical properties and crystallization behavior, as well as the structural motifs, the correlation between chemical and structural topology is briefly discussed, which may provide a new insight into the glass topological structure.

Keywords:

作者及机构信息

1.
武汉理工大学硅酸盐建筑材料国家重点实验室, 武汉 430070;

2.
宁波大学高等技术研究院红外材料及器件实验室, 宁波 315211

基金项目: 国家自然科学基金(批准号: 61108057)、浙江省自然科学基金(批准号: LY14E020001)、武汉理工大学硅酸盐建筑材料国家重点实验室开放基金(批准号: SYSJJ2013-03)、教育部留学回国人员科研启动基金和宁波大学王宽诚幸福基金资助的课题.

Authors and contacts

1.
State Key Laboratory of Silicate Materials for Architecture (Wuhan University of Technology), Wuhan 430070, China;

2.
Laboratory of Infrared Materials and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China

Funds: Project supported by the National Natural Science Foundation of China (Grant No. 61108057), the Natural Science Foundation of Zhejiang Province, China (Grant No. LY14E020001), the State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology), China (Grant No. SYSJJ2013-03), and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, the State Education Ministry. It was also sponsored by K.C. Wong Magna Fund in Ningbo University.

参考文献

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[7]	Lin C, Calvez L, Rozé M, Tao H, Zhang X, Zhao X 2009 Appl. Phys. A 97 713
[8]	Calvez L, Ma H L, Lucas J, Zhang X H 2007 Adv. Mater. 19 129
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[14]	Lin C, Calvez L, Li Z, Dai S, Tao H, Ma H, Zhang X, Moine B, Zhao X 2013 J. Am. Ceram. Soc. 96 816
[15]	Dong G, Tao H, Chu S, Wang S, Zhao X, Gong Q, Xiao X, Lin C 2007 Opt. Commun. 270 373
[16]	Dong G, Tao H, Xiao X, Lin C, Zhao X, Mao S 2007 J. Phys. Chem. Solids 68 158
[17]	Xu Y, Chen D, Zhang Q, Wang W, Zeng H, Shen C, Chen G 2009 Chem. Phys. Lett. 472 104
[18]	Xu Y, Chen D, Zhang Q, Zeng H, Shen C, Adam J-l, Zhang X, Chen G 2009 J. Phys. Chem. C 113 9911
[19]	Tao H, Lin C, Chu S, Mao S, Gong Y, Zhao X, Wang S, Gong Q 2008 J. Non-Cryst. Solids 354 1303
[20]	Tao H, Lin C, Gong Y, Mao S, Zhao X 2008 Optoelectron. Adv. Mater. 2 29
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[22]	Li Z, Lin C, Nie Q, Dai S 2013 J. Am. Ceram. Soc. 96 125
[23]	Li Z, Lin C, Nie Q, Dai S 2013 Appl. Phys. A 112 939
[24]	Loireau-Lozac'h A M, Guittard M 1975 Ann. Chim. 10 101
[25]	Sarkisov E S, Lidin R A 1969 Inorg. Mater. 5 839
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[27]	Tao H, Mao S, Dong G, Xiao H, Zhao X 2006 Solid State Commun. 137 408
[28]	Gasanly N M, Özkan H, Aydinli A, Yilmaz Ī 1999 Solid State Commun. 110 231

施引文献

[1]	Zhou Y, Yu X, Xu X, Dai S 2012 Acta Phys. Sin. 61 157701 (in Chinese) [周亚训, 於杏燕, 徐星辰, 戴世勋 2012 61 157701]
[2]	Dong G, Xiao X, Ren J, Ruan J, Liu X, Qiu J, Lin C, Tao H, Zhao X 2008 Chin. Phys. Lett. 25 1891
[3]	Wei K, Machewirth D P, Wenzel J, Snitzer E, Sigel G H 1994 Opt. Lett. 19 904
[4]	Wei K, Machewirth DP, Wenzel J, Snitzer E, Sigel Jr GH. 1995 J. Non-Cryst. Solids 182 257
[5]	Kim Y S, Cho W Y, Shin Y B, Heo J 1996 J. Non-Cryst. Solids 203 176
[6]	Heo J, Min Yoon J, Ryou S Y 1998 J. Non-Cryst. Solids 238 115
[7]	Lin C, Calvez L, Rozé M, Tao H, Zhang X, Zhao X 2009 Appl. Phys. A 97 713
[8]	Calvez L, Ma H L, Lucas J, Zhang X H 2007 Adv. Mater. 19 129
[9]	Lin C, Calvez L, Tao H, Allix M, Moréac A, Zhang X, Zhao X 2011 J. Solid State Chem. 184 584
[10]	Lin C, Qu G, Li Z, Dai S, Ma H, Xu T, Nie Q, Zhang X 2013 J. Am. Ceram. Soc. 96 1779
[11]	Li Z, Lin C, Nie Q, Xu T, Dai S 2012 Acta Phys. Sin. 61 104207 (in Chinese) [李卓斌, 林常规, 聂秋华, 徐铁峰, 戴世勋 2012 61 104207]
[12]	Lin C, Li Z, Qian H, Ni W, Li Y, Dai S 2012 Acta Phys. Sin. 61 154212 (in Chinese) [林常规, 李卓斌, 覃海娇, 倪文豪, 李燕颖, 戴世勋 2012 61 154212]
[13]	Lin C, Dai S, Liu C, Song Ba, Xu Y, Chen F, Heo J 2012 Appl. Phys. Lett. 100 231910
[14]	Lin C, Calvez L, Li Z, Dai S, Tao H, Ma H, Zhang X, Moine B, Zhao X 2013 J. Am. Ceram. Soc. 96 816
[15]	Dong G, Tao H, Chu S, Wang S, Zhao X, Gong Q, Xiao X, Lin C 2007 Opt. Commun. 270 373
[16]	Dong G, Tao H, Xiao X, Lin C, Zhao X, Mao S 2007 J. Phys. Chem. Solids 68 158
[17]	Xu Y, Chen D, Zhang Q, Wang W, Zeng H, Shen C, Chen G 2009 Chem. Phys. Lett. 472 104
[18]	Xu Y, Chen D, Zhang Q, Zeng H, Shen C, Adam J-l, Zhang X, Chen G 2009 J. Phys. Chem. C 113 9911
[19]	Tao H, Lin C, Chu S, Mao S, Gong Y, Zhao X, Wang S, Gong Q 2008 J. Non-Cryst. Solids 354 1303
[20]	Tao H, Lin C, Gong Y, Mao S, Zhao X 2008 Optoelectron. Adv. Mater. 2 29
[21]	Ying L, Lin C, Nie Q, Li Z, Xu Y, Chen F, Dai S 2012 J. Am. Ceram. Soc. 95 1320
[22]	Li Z, Lin C, Nie Q, Dai S 2013 J. Am. Ceram. Soc. 96 125
[23]	Li Z, Lin C, Nie Q, Dai S 2013 Appl. Phys. A 112 939
[24]	Loireau-Lozac'h A M, Guittard M 1975 Ann. Chim. 10 101
[25]	Sarkisov E S, Lidin R A 1969 Inorg. Mater. 5 839
[26]	Vogel W 1994 Glass Chemistry (Second Edition) (Berlin: Springer-Verlag) pp92-109
[27]	Tao H, Mao S, Dong G, Xiao H, Zhao X 2006 Solid State Commun. 137 408
[28]	Gasanly N M, Özkan H, Aydinli A, Yilmaz Ī 1999 Solid State Commun. 110 231

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