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使用金属有机化学气相沉积技术，在4英寸GaAs衬底上获得了空间用GaInP/GaAs/In0.3Ga0.7As倒装三结太阳能电池.高分辨X射线衍射和阴极射线发光测试结果表明AlInGaAs应力渐变缓冲层的晶格弛豫度约100%，其整面平均穿透位错密度约5.4×106/cm2.与GaInP/InGaAs/Ge常规三结太阳能电池相比，在AM0光谱、25 ℃测试条件下，面积24 cm2的倒装三结太阳能电池转换效率达到32%，输出功率提高了5%.采用1 MeV高能电子对倒装三结电池进行粒子辐照测试，电池各项性能参数随不同辐照剂量发生改变，在1×1015/cm2辐照总剂量下电池转换效率衰降比例达到15%.In recent years, with the development of solar cell technology, the conversion efficiency of the lattice-matched Ga0.51In0.49P/In0.01Ga0.99As/Ge triple-junction solar cell has achieved 30% under AM0 spectrum. As is well known, it is difficult to further improve the efficiency due to the limited bandgap combination. Therefore, an inverted metamorphic triple-junction solar cell is designed by replacing the Ge subcell with a 1.0 eV InGaAs subcell. The efficiency could be increased with the open-circuit voltage increasing, while the short circuit current maintains a similar value.#br#In this paper, the inverted metamorphic GaInP/GaAs/In0.3Ga0.7As triple-junction solar cells are grown on 4-inch GaAs substrates via metal organic chemical vapor deposition. Optimizing the epitaxy process, AlInGaAs graded buffer shows nearly 100% relaxation by the reciprocal space mapping of the high-resolution X-ray diffraction and low average threading dislocation density~5.4×106/cm2 evaluated from the cathodoluminescence image. Finally, the inverted metamorphic triple-junction solar cell with 24 cm2 area shows a conversion efficiency of 32% with an open-circuit voltage of 3.045 V and a short-circuit current of 404.5 mA under one sun, AM0 spectrum, 25℃ conditions, which is 5% higher than the lattice-matched GaInP/InGaAs/Ge triple-junction solar cell. Under 1 MeV electron irradiation test, the degradations of the external quantum efficiency and I-V characteristics of inverted metamorphic triple-junction solar cell are exhibited each as a function of fluence, and finally the end-of-life efficiency is 27.2% with a degradation of 15% under 1×1015/cm2 fluence. More experiments mainly focusing on the lattice quality of AlInGaAs graded buffer and the structure of In0.3Ga0.7As subcell, will be carried out to improve the efficiency and enhance the radiation hardness.
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Keywords:
- inverted metamorphic /
- space solar cell /
- electron radiation
[1] Ficcadenti M, Campesato R, Casale M, Gabetta G, Gori G, Kagan M, Kholev B A, Ivanov V 2014 10th European Space Power Conference Noordwijkerhout, Netherlands, April 13-17, 2014 p1
[2] Guter W, Schöne J, Philipps S, Steiner M, Siefer G, Wekkeli A, Welser E, Oliva E, Bett A, Dimroth F 2009 Appl. Phys. Lett. 94 223504
[3] Fuhrmann D, Meusel M, Ebel L, Guter W, Kubera T, Köstler W, Strobl G 2013 9 th International Conference on Concentrator Photovoltaics Miyazaki, Japan, April 15-17, 2013 p1
[4] Wanlass M W, Albin D S 2004 AIP Conf. Proc. 738 462
[5] Wanlass M W, Ahrenkiel S P, Ahrenkiel R K, Albin D S, Carapella J J, Duda A, Geisz J F, Kurtz S, Moriarty T, Wehrer R J, Wernsman B 2005 31st IEEE Photovoltaics Specialists Conference Florida, USA, January 3-7, 2005 p530
[6] Geisz J F, Sarah Kurtz, Wanlass M W, Ward J S, Duda A, Friedman D J, Olson J M, McMahon W E, Moriaty T E, Kiehl J T 2007 Appl. Phys. Lett. 91 023502
[7] Cornfeld A B, Stan M, Varghese T, Diaz J, Ley A V, Cho B, Korostyshevsky A, Aiken D J, Sharps P R 2008 33rd IEEE Photovoltaic Specialists Conference California, USA, May 11-16, 2008 p1
[8] Patel P, Aiken D, Boca A, Cho B, Chumney D, Clevenger M B, Cornfeld A, Fatemi N, Lin Y, McCarty J, Newman F, Sharps P, Spann J, Stan M, Steinfeldt J, Strautin C, Varghese T 2012 38th IEEE Photovoltaic Specialists Conference Austin, Texas, June 3-8, 2012 p110
[9] Patel P, Aiken D, Chumney D, Cornfeld A, Lin Y, Mackos C, McCarty J, Miller N, Sharps P, Stan M 2012 38th IEEE Photovoltaic Specialists Conference Austin, Texas, June 3-8, 2012 p1
[10] Takamoto T, Washio H, Juso H 2014 40th IEEE Photovoltaic Specialists Conference Denver, USA, June 8-13, 2014 p1
[11] Chumney D, Aiken D, Cho B, Cornfeld A, Diaz J, Ley V, Mittman J, Newman F, Sharps P, Stan M, Varghese T 2010 35th IEEE Photovoltaic Specialists Conference Hawaii, USA, June 20-25, 2010 p113
[12] Boisvert J, Law D, King R, Rehder E, Chiu P, Bhusari D, Fetzer C, Liu X, Hong W 2013 39th IEEE Photovoltaic Specialists Conference Florida, USA, June 16-21, 2013 p2790
[13] Stan M, Aiken D, Cho B, Cornfeld A, Ley V, Patel P, Sharps P, Varghese T 2010 J. Cryst. Growth 312 1370
[14] Wang D X, Song M H, Bi J F, Chen W J, Li S L, Liu G Z, Li M Y, Wu C Y 2017 Chin. Phys. Lett. 34 068801
[15] Walters R J, Messenger S R, Cotal H R, Xapsos M A, Wojtczuk S J, Serreze H B, Summers G P 1997 J. Appl. Phys. 82 2164
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[1] Ficcadenti M, Campesato R, Casale M, Gabetta G, Gori G, Kagan M, Kholev B A, Ivanov V 2014 10th European Space Power Conference Noordwijkerhout, Netherlands, April 13-17, 2014 p1
[2] Guter W, Schöne J, Philipps S, Steiner M, Siefer G, Wekkeli A, Welser E, Oliva E, Bett A, Dimroth F 2009 Appl. Phys. Lett. 94 223504
[3] Fuhrmann D, Meusel M, Ebel L, Guter W, Kubera T, Köstler W, Strobl G 2013 9 th International Conference on Concentrator Photovoltaics Miyazaki, Japan, April 15-17, 2013 p1
[4] Wanlass M W, Albin D S 2004 AIP Conf. Proc. 738 462
[5] Wanlass M W, Ahrenkiel S P, Ahrenkiel R K, Albin D S, Carapella J J, Duda A, Geisz J F, Kurtz S, Moriarty T, Wehrer R J, Wernsman B 2005 31st IEEE Photovoltaics Specialists Conference Florida, USA, January 3-7, 2005 p530
[6] Geisz J F, Sarah Kurtz, Wanlass M W, Ward J S, Duda A, Friedman D J, Olson J M, McMahon W E, Moriaty T E, Kiehl J T 2007 Appl. Phys. Lett. 91 023502
[7] Cornfeld A B, Stan M, Varghese T, Diaz J, Ley A V, Cho B, Korostyshevsky A, Aiken D J, Sharps P R 2008 33rd IEEE Photovoltaic Specialists Conference California, USA, May 11-16, 2008 p1
[8] Patel P, Aiken D, Boca A, Cho B, Chumney D, Clevenger M B, Cornfeld A, Fatemi N, Lin Y, McCarty J, Newman F, Sharps P, Spann J, Stan M, Steinfeldt J, Strautin C, Varghese T 2012 38th IEEE Photovoltaic Specialists Conference Austin, Texas, June 3-8, 2012 p110
[9] Patel P, Aiken D, Chumney D, Cornfeld A, Lin Y, Mackos C, McCarty J, Miller N, Sharps P, Stan M 2012 38th IEEE Photovoltaic Specialists Conference Austin, Texas, June 3-8, 2012 p1
[10] Takamoto T, Washio H, Juso H 2014 40th IEEE Photovoltaic Specialists Conference Denver, USA, June 8-13, 2014 p1
[11] Chumney D, Aiken D, Cho B, Cornfeld A, Diaz J, Ley V, Mittman J, Newman F, Sharps P, Stan M, Varghese T 2010 35th IEEE Photovoltaic Specialists Conference Hawaii, USA, June 20-25, 2010 p113
[12] Boisvert J, Law D, King R, Rehder E, Chiu P, Bhusari D, Fetzer C, Liu X, Hong W 2013 39th IEEE Photovoltaic Specialists Conference Florida, USA, June 16-21, 2013 p2790
[13] Stan M, Aiken D, Cho B, Cornfeld A, Ley V, Patel P, Sharps P, Varghese T 2010 J. Cryst. Growth 312 1370
[14] Wang D X, Song M H, Bi J F, Chen W J, Li S L, Liu G Z, Li M Y, Wu C Y 2017 Chin. Phys. Lett. 34 068801
[15] Walters R J, Messenger S R, Cotal H R, Xapsos M A, Wojtczuk S J, Serreze H B, Summers G P 1997 J. Appl. Phys. 82 2164
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