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Rubidium (Rb) isotope analysis has important applications in geological exploration and environmental detection. Based on tunable laser atom absorption spectroscopy technology combined with thermal decomposition of the sample, a Rb isotope absorption spectroscopy measurement device is built to detect the Rb isotope ratio stability. And the atomic generator is designed by a new micro-channel array structure, which enhances atomic beam collimation capability, effectively suppresses the doppler effect of the spectrum, and improves the resolution of Rb isotope absorption spectrum. The device adopts tantalum metal to make the atomic generator with a diameter of 6 mm, and the micro-channel array with a diameter of 1 mm is stacked inside the atomic generator which can be heated resistively to 3000 ℃. In this experiment, the Rb carbonate sample is catalyzed to release Rb atom beam at a high temperature of 600 ℃, while a probe laser is used to obtain high resolution Rb absorption spectrum. The Rb isotope ratio (85Rb∶87Rb) of natural abundance Rb carbonate samples is 2.441±0.02 by combining the inversion of the spectral line parameters, the detection error is 5.9%, and the detection limit of 87Rb is 1.76‰ (3σ). The experimental results show that the multi-microchannel structure reduces the linewidth of Rb atoms by 450 MHz (half height full width) compared with the counterparts of the single-channel structure, which can effectively distinguish the absorption characteristics of Rb isotopes. The device has a high detection accuracy and a high spectral resolution, which provides a possibility for the metal isotope abundance analysis, and has a broad application prospect.
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Keywords:
- Rb isotope /
- absorption spectroscopy /
- multi-microchannel array
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Li J, Tang S H, Ma J X, Zhu X K 2021 Rock and Mineral Analysis 40 627
Google Scholar
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Zhang Z Y, Ma J L, Zhang L, Zeng P, Liu Y, Wei G J 2020 Earth Science Frontiers 27 123
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Deng A M, Chen X, Zhang C H, Dong L 2004 J. Time Frequency 27 138
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[5] Waight T, Baker J, Willigers B 2002 Chemical Geology 186 99
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[6] Zhang Z Y, Ma J L, Le Zhang L, Liu Y, Wei G J 2018 J. Analy. Atomic Spectro. 33 322
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[7] Harilal S S, Brumfield B E, LaHaye N L, Hartig K C, Phillips M C 2018 Appl. Phys. Rev. 5 21301
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[8] 叶浩, 黄印博, 王琛, 刘国荣, 卢兴吉, 曹振松, 黄尧, 齐刚, 梅海平 2021 70 163201
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Peking Normal University, Central China Normal University, Nanjing Normal University 2020 Inorganic Chemistry (Vol. 1) (Beijing: Higher Education Press) p233 (in Chinese)
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[16] 陶雷刚 2018 博士学位论文 (合肥: 中国科学技术大学)
Tao L G 2018 Ph. D. Dissertation (Hefei: University of Science and Technology of China) (in Chinese)
[17] Senaratne R, Rajagopal S V, Geiger Z A, Fujiwara K M, Lebedev V, Weld D M 2015 Rev. Sci. Instrum. 86 023105
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[20] Steck D A 2021 Rubidium 87 D Line Data [2021-7-9]
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图 1 Rb同位素比测量实验装置
Figure 1. Experimental layout for Rb isotope ratio measurement.
图 2 (a) 真空电极腔结构示意图; (b) 双端子电极结构示意图
Figure 2. (a) Schematic diagram of vacuum electrode chamber structure; (b) schematic diagram of double terminal electrode structure.
图 3 (a) 原子发生器结构图; (b) 20 A下原子发生器温度时间变化曲线
Figure 3. (a) Structure of the atomic generator; (b) time variation curve of the atomic generator temperature at 20 A.
图 4 高温下Rb2CO3的分解过程
Figure 4. Reaction process of Rb2CO3 at high temperature.
图 5 (a) 不同口径原子发生器温度随电流变化趋势; (b) 不同口径原子发生器在600 ℃的吸收信号对比
Figure 5. (a) Trend of temperature of the atomic generator with current for different diameters; (b) comparison of absorption signal of the atomic generator with different diameters at 600 ℃.
图 6 (a) 87Rb吸收信号随温度的变化曲线; (b) Rb饱和蒸气压随温度的变化曲线
Figure 6. (a) The variation curve of 87Rb absorption signal with temperature; (b) the variation curve of Rb saturated vapor pressure with temperature.
图 7 (a) 单通道发散角结构示意图; (b) 多微管发散角结构示意图
Figure 7. (a) Schematic diagram of single-channel divergence angle structure; (b) schematic diagram of multi-microchannel divergence angle structure.
图 8 多微管与单通道结构Rb的吸收光谱展宽对比
Figure 8. Comparison of absorption spectrum broadening of Rb in multi-microchannel and single-channel.
图 9 (a) Rb原子吸收光谱信噪比随平均次数的变化; (b) 平衡探测前后基线波动对比
Figure 9. (a) The variation curve of SNR of Rb absorption spectrum with average times; (b) comparison of baseline fluctuations before and after balance detection.
图 10 (a) 600 ℃时Rb原子吸收光谱; (b) 85Rb∶87Rb吸收光谱信号稳定性
Figure 10. (a) Absorption spectrum of Rb at 600 ℃; (b) the stability of 85Rb∶87Rb absorption spectrum signal.
表 1 部分高熔点材料特性
Table 1. Characteristics of several high melting point materials.
金属 钽 钨 钼 钛 熔点/℃ 3000 3420 2600 1660 电阻率/(Ω·m) 13.10 0.05 5.34 45.20 断面收缩率/% 86 10 60 64 
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[1] 李津, 唐索寒, 马健雄, 朱祥坤 2021 岩矿测试 40 627
Google Scholar
Li J, Tang S H, Ma J X, Zhu X K 2021 Rock and Mineral Analysis 40 627
Google Scholar
[2] 张卓盈, 马金龙, 张乐, 曾提, 刘颖, 韦刚健 2020 地学前缘 27 123
Google Scholar
Zhang Z Y, Ma J L, Zhang L, Zeng P, Liu Y, Wei G J 2020 Earth Science Frontiers 27 123
Google Scholar
[3] 邓爱民, 陈循, 张春华, 董理 2004 时间频率学报 27 138
Google Scholar
Deng A M, Chen X, Zhang C H, Dong L 2004 J. Time Frequency 27 138
Google Scholar
[4] King L A, Gornushkin I B, Pappas D, Smith B W, Winefordner J D 1999 Spectrochim. Acta Part B 54 1771
Google Scholar
[5] Waight T, Baker J, Willigers B 2002 Chemical Geology 186 99
Google Scholar
[6] Zhang Z Y, Ma J L, Le Zhang L, Liu Y, Wei G J 2018 J. Analy. Atomic Spectro. 33 322
Google Scholar
[7] Harilal S S, Brumfield B E, LaHaye N L, Hartig K C, Phillips M C 2018 Appl. Phys. Rev. 5 21301
Google Scholar
[8] 叶浩, 黄印博, 王琛, 刘国荣, 卢兴吉, 曹振松, 黄尧, 齐刚, 梅海平 2021 70 163201
Google Scholar
Ye H, Huang Y B, Wang C, Liu G R, Lu X J, Cao Z S, Huang Y, Qi G, Mei H P 2021 Acta Phys. Sin. 70 163201
Google Scholar
[9] Lebedev V, Bartlett J H, Castro A 2018 J. Analy. Atomic Spectrom. 33 1862
Google Scholar
[10] Majumder A, Jana B, Kathar R T, Das A K, Mago V K 2009 Vacuum 83 989
Google Scholar
[11] 北京师范大学, 华中师范大学, 南京师范大学 2020 无机化学 (上卷) (北京: 高等教育出版社) 第233页
Peking Normal University, Central China Normal University, Nanjing Normal University 2020 Inorganic Chemistry (Vol. 1) (Beijing: Higher Education Press) p233 (in Chinese)
[12] Shpilrai E, Nikanoro E 1971 High Temperature 9 393
[13] Jana B, Majumder A, Thakur K B, Das A K 2013 Rev. Sci. Instrum. 84 106113
Google Scholar
[14] Haynes W M 2016 CRC Handbook of Chemistry and Physics (97th Ed.) (Boca Raton: CRC Press) pp2005–2006
[15] Gupta M, Randhawa B S 2012 J. Analy. Appl. Pyroly. 95 25
Google Scholar
[16] 陶雷刚 2018 博士学位论文 (合肥: 中国科学技术大学)
Tao L G 2018 Ph. D. Dissertation (Hefei: University of Science and Technology of China) (in Chinese)
[17] Senaratne R, Rajagopal S V, Geiger Z A, Fujiwara K M, Lebedev V, Weld D M 2015 Rev. Sci. Instrum. 86 023105
Google Scholar
[18] 孙明国, 马宏亮, 刘强, 曹振松, 王贵师, 刘锟, 黄印博, 高晓明, 饶瑞中 2018 67 064206
Google Scholar
Sun M G, Ma H L, Liu Q, Cao Z S, Wang G S, Liu K, Huang Y B, Gao X M, Rao R Z 2018 Acta Phys. Sin. 67 064206
Google Scholar
[19] Steck D A 2021 Rubidium 85 D Line Data [2021-7-9]
[20] Steck D A 2021 Rubidium 87 D Line Data [2021-7-9]
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