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Optical properties of nanoparticles are related to their surface plasmon resonance. In this work, we use Mie theory to compute the extinction, absorption, and scattering properties of noble metal nanoparticles. The calculated results agree well with the experimental values. With increasing particle size, particle dipole absorption peak will be red-shifted; and the peak position and the size of the nanoparticles have a linear relationship. It is found that the ratio of core to shell size determines the absorption properties of spherical Au/Ag core/shell nanoparticles. When the Au shell is thin, the optical properties vary with the adjustable shell. When the Au shell is thick, its optical properties are similar to the pure Au nanoparticle. Through the calculation and analysis we made, the Mie theory can be generalized to nanocavity structures when the shell thickness reaches a certain value. Furthermore, it is found that the absorption peaks of alloy nanoparticles have a linear relationship with the alloy composition.
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Keywords:
- Mie theory /
- surface plasmon resonance /
- core-shell structure /
- UV-Vis spectrum
[1] Zheng J J, Sun G 2005 Acta. Phys. Sin. 54 2757 (in Chinese)[郑俊娟, 孙 刚 2005 54 2757]
[2] Wang W T, Yang G, Guan Y, Wu W D, Chen Z H 2004 Acta. Phys. Sin. 53 932 (in Chinese)[王伟田, 杨光, 陈正豪 2004 53 932]
[3] Wang C, Peng S, Chan R, Sun S H 2009 Small 5 67
[4] Hong X, Du D D, Qiu Z R, Zhang G X 2007 Acta. Phys. Sin. 56 7219 (in Chinese)[洪昕, 杜丹丹, 裘祖荣, 张国雄 2007 56 7219]
[5] Zhu J, Wang Y C, Yan S N 2004 Chin. Phys. Lett. 21 559
[6] Chen Z, Zhan P, Zhang J H, Wang Z L 2003 Chin. Phys. Lett. 20 1369
[7] Kim J H, Chung H W, Lee T R 2006 Chem. Mater. 18 4115
[8] Zhang T H, Yin M R, Fang Z Y 2005 Physics 34 909 (in Chinese) [张天浩, 尹美荣, 方哲宇 2005 物理 34 909]
[9] Graf C, Blaaderen V A 2002 Langmuir 18 524
[10] Rao H Z 2012 Modern Atmospheric Optics (Beijing: Science Press) p219
[11] Bohren C F, Huffman D R 1983 Absorption and Scattering of Light by Small Particles (New York: Wiley Interscience) p83
[12] Li Q, Wang L Z, Lu G Q, Huang J, Zhu X F, 2011 Acta Optical Sinica 31 0726001 (in Chinese) [李强, 王连洲, 逯高清, 黄娆, 朱贤方 2011 光学学报 31 0726001]
[13] Mätzler C 2002 MATLAB Functions for Mie Scattering and Absorption. (Research report, Institute of Applied Physics, University of Bern) p2
[14] Papavassiliou G C 1979 Prog.Solid. State. Ch. 12 185
[15] Michael Q 2011 Optical Properties of Nanoparticle System (Germany: Wileyvch) p128
[16] Li L L, Yang X C, Huang M, Zhao J F, Hou J W 2011 J. Funct. Mater. Devic. 12 14 (in Chinese) [李玲玲, 杨修春, 黄敏, 赵建富, 侯军伟 2011 功能材料与器件学报 12 14]
[17] Johnson P B, Christy R W 1972 Phys. Rev. B 6 4370
[18] Mallin M P, Murphy C J 2002 Nano. Lett. 11 235
[19] Yang J, Jim Y L, Heng P T 2005 J. Phys. Chem. B 109 19208
[20] Tsuji M, Hikinol S, Tanabe R, Yamaguchi D 2010 Chem. Lett. 4 334
[21] Bruzzone S, Arrighini G P, Guidotti C 2003 Mater. Sci. Eng. C 12 965
[22] Anderson T S, Magruder R H, Wittigc J E, Kinser D L, Zuhr R A 2000 Nucl. Instum. Methods Phys. Res. Sec. B 11 401
[23] Yan S N, Wang Y C 2006 T. Nonferr. Metal. Soc. 12 284 (in Chinese) [闫仕农, 王永昌 2006 中国有色金属学报 12 284]
[24] Yan S N, Zhu J 2006 Rare. Metal. Mat. Eng. 1 161 (in Chinese) [闫世农, 朱键 2006 稀有金属材料与工程 1 161]
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[1] Zheng J J, Sun G 2005 Acta. Phys. Sin. 54 2757 (in Chinese)[郑俊娟, 孙 刚 2005 54 2757]
[2] Wang W T, Yang G, Guan Y, Wu W D, Chen Z H 2004 Acta. Phys. Sin. 53 932 (in Chinese)[王伟田, 杨光, 陈正豪 2004 53 932]
[3] Wang C, Peng S, Chan R, Sun S H 2009 Small 5 67
[4] Hong X, Du D D, Qiu Z R, Zhang G X 2007 Acta. Phys. Sin. 56 7219 (in Chinese)[洪昕, 杜丹丹, 裘祖荣, 张国雄 2007 56 7219]
[5] Zhu J, Wang Y C, Yan S N 2004 Chin. Phys. Lett. 21 559
[6] Chen Z, Zhan P, Zhang J H, Wang Z L 2003 Chin. Phys. Lett. 20 1369
[7] Kim J H, Chung H W, Lee T R 2006 Chem. Mater. 18 4115
[8] Zhang T H, Yin M R, Fang Z Y 2005 Physics 34 909 (in Chinese) [张天浩, 尹美荣, 方哲宇 2005 物理 34 909]
[9] Graf C, Blaaderen V A 2002 Langmuir 18 524
[10] Rao H Z 2012 Modern Atmospheric Optics (Beijing: Science Press) p219
[11] Bohren C F, Huffman D R 1983 Absorption and Scattering of Light by Small Particles (New York: Wiley Interscience) p83
[12] Li Q, Wang L Z, Lu G Q, Huang J, Zhu X F, 2011 Acta Optical Sinica 31 0726001 (in Chinese) [李强, 王连洲, 逯高清, 黄娆, 朱贤方 2011 光学学报 31 0726001]
[13] Mätzler C 2002 MATLAB Functions for Mie Scattering and Absorption. (Research report, Institute of Applied Physics, University of Bern) p2
[14] Papavassiliou G C 1979 Prog.Solid. State. Ch. 12 185
[15] Michael Q 2011 Optical Properties of Nanoparticle System (Germany: Wileyvch) p128
[16] Li L L, Yang X C, Huang M, Zhao J F, Hou J W 2011 J. Funct. Mater. Devic. 12 14 (in Chinese) [李玲玲, 杨修春, 黄敏, 赵建富, 侯军伟 2011 功能材料与器件学报 12 14]
[17] Johnson P B, Christy R W 1972 Phys. Rev. B 6 4370
[18] Mallin M P, Murphy C J 2002 Nano. Lett. 11 235
[19] Yang J, Jim Y L, Heng P T 2005 J. Phys. Chem. B 109 19208
[20] Tsuji M, Hikinol S, Tanabe R, Yamaguchi D 2010 Chem. Lett. 4 334
[21] Bruzzone S, Arrighini G P, Guidotti C 2003 Mater. Sci. Eng. C 12 965
[22] Anderson T S, Magruder R H, Wittigc J E, Kinser D L, Zuhr R A 2000 Nucl. Instum. Methods Phys. Res. Sec. B 11 401
[23] Yan S N, Wang Y C 2006 T. Nonferr. Metal. Soc. 12 284 (in Chinese) [闫仕农, 王永昌 2006 中国有色金属学报 12 284]
[24] Yan S N, Zhu J 2006 Rare. Metal. Mat. Eng. 1 161 (in Chinese) [闫世农, 朱键 2006 稀有金属材料与工程 1 161]
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