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Polymer photovoltaic cells with organic polymer materials as the active layers for an increasing power conversion efficiency have become a research hotspot in the field of photovoltaic devices in recent years. In this paper, Internal mechanism of polymer/fullerene solar cells are elaborated exhaustively, including light absorption, exciton diffusion and dissociation and charge carrier transport as well as extraction. Furthermore, the optimization of device structure, morphology control and interface modification are introduced to improve performance of polymer/fullerene solar cells. Power conversion efficiency and the various structures which can be achieved are discussed in detail. The future prospects of polymer photovoltaic cells are also expected.
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Keywords:
- bulk-heterojunction /
- polymer /
- fullerene /
- inverted solar cells
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[11] Yu G, Gao J, Hummelen J C 1995 Science 270 1789
[12] Shaheen,S E ,Brabec,C J Sariciftci, 2001 Applied Physics Letters 78 841
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[14] Ma,W L,Yang C Y,Gong,X 2005 Advanced Functional Materials 15 1617
[15] Kim,J Y ,Kim,S H ,Lee,H H 2006 Advanced Materials 18 572
[16] Wang E, Wang L, Lan L F 2008 Appl. Phys. Lett. 92 033307
[17] Wang M, Hu X W, Liu P 2011 Journal of the American Chemical Society 133 9638
[18] He Y J, Chen H Y, Hou J H 2010 Journal of the American Chemical Society 132 1377
[19] Zhao G J, He Y J, Li Y F 2010 Advanced Materials 22 4355
[20] Park S H, Roy A, Beaupré S, Heeger A J 2009 Nature Photonics 3 297
[21] Hou J,Chen H ,Zhang S, Yang Y 2009 Journal of the American Society 131 15586
[22] Chen H ,Hou J ,Zhang S, Yang Y 2009 Nature Photonics 3 649
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[25] Kim S Y, Hong K, Kim K 2008 Mater. Lett. 4 63
[26] Kim H, Shin M, Park J 2010 IEEE Trans Nanotechnol. 9 400
[27] deJong M P, vanIjzendoorn L J A, deVoigt M J 2000 Appl. Phys. Lett. 77 255
[28] Xu Z, Chen L M, Yang G W 2009 Adv. Funct. Mater. 19 1227
[29] Waldauf C , Morana M, Denk P 2006 Applied Physics Letters 89 233517
[30] Liao H H, Chen L M , Xu Z, Yang Y 2008 Appl. Phys. Lett. 92 173303
[31] Jiang Ch Y, Sun X W, Zhao D W 2010 Solar Energy Materials & Solar Cells 94 1618
[32] Zhu Y X, Xu X F, Zhang L J 2011 Solar Energy Materials & Solar Cells 97 83
[33] Lin Y H, Yang P C, Huang J S 2011 Solar Energy Materials & Solar Cells 95 2511
[34] Cheng Y J, Hsieh Ch H, Li Y F 2010 J. Am. Chem. Soc. 132 17381
[35] Chu T Y, Tsang S W, Zhou J Y 2012 Solar Energy Materials & Solar Cells 96 155
[36] Amb C M,Amb, Chen S, Graham K R. 2011 J. Am. Chem. Soc. 133 10062
[37] Kim C S, Tinker L L, DiSalle B F 2009 Adv .Mater. 21 3110
[38] Reyes-Reyes M, López-Sandoval R, Arenas-Alatorre J 2007 Thin Solid Films 516 52
[39] Savenije T J, Kroeze J E, Yang X 2005 Adv. Funct. Mater. 15 1260
[40] Nguyen L H, Hoppe H, Erb T 2007 Adv. Funct. Mater. 17 1071
[41] Erb T, Zhokhavets U, Gobsch G 2005 Adv. Funct .Mater. 15 1193
[42] Inoue K, Ulbricht R, Madaka P C 2005 Synth .Met. 154 41
[43] Ayzner A L, Wanger D D, Tassone C J 2008 J. Phys. Chem. C 112 18711
[44] Yun J J, Peet J, Cho N S 2008 Appl .Phys. Lett. 92 251912
[45] Mihailetchi V D, Xie H X, de-Boer B 2006 Adv. Funct. Mater. 16 699
[46] Li G, Shrotriya V, Yang Y 2005 J. Appl. Phys. 98 043704
[47] Ma W, Yang C, Heeger A J 2007 Adv. Mater. 19 1387
[48] Goh C, Scully S R, McGehee M D 2007 J. Appl. Phys. 101 114503
[49] Roy A, Park S H, Cowan S 2009 Appl. Phys. Lett. 95 013302
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[1] Li G, Shrotriya V, Yang Y 2005 Nat. Mater. 4 864
[2] Koster L J A, Mihailetchi V D, Blom P W M 2006 Appl. Phys. Lett. 88 093511
[3] Green M A, Emery K, Hishikawa Y 2011 Res. Appl. 19 565
[4] Wang E G, Wang L, Cao Y 2008 Appl. Phys. Lett. 92 033307
[5] Liang Y, Feng D, Wu Y 2009 J. Am. Chem. Soc. 1317792
[6] Liang Y Y, Yu L P, 2010 Accounts of Chemical Research 43 1227
[7] Huo L J, Zhang Sh Q, Guo Xi 2011 Angew. Chem. Int. Ed. 50 9697
[8] He Z C, Zhong C M , Huang X, Cao Y 2011 Advanced Materials 22 4636
[9] Luhman W A, Holmes R J 2009 Appl. Phys. Lett. 94 153304
[10] Yu G, Pakbaz K, Heeger A J 1994 Appl. Phys. Lett. 64 3422
[11] Yu G, Gao J, Hummelen J C 1995 Science 270 1789
[12] Shaheen,S E ,Brabec,C J Sariciftci, 2001 Applied Physics Letters 78 841
[13] Padinger,F ,Rittberger R S ,Sariciftci 2003 Advanced Functional Materials 13 85
[14] Ma,W L,Yang C Y,Gong,X 2005 Advanced Functional Materials 15 1617
[15] Kim,J Y ,Kim,S H ,Lee,H H 2006 Advanced Materials 18 572
[16] Wang E, Wang L, Lan L F 2008 Appl. Phys. Lett. 92 033307
[17] Wang M, Hu X W, Liu P 2011 Journal of the American Chemical Society 133 9638
[18] He Y J, Chen H Y, Hou J H 2010 Journal of the American Chemical Society 132 1377
[19] Zhao G J, He Y J, Li Y F 2010 Advanced Materials 22 4355
[20] Park S H, Roy A, Beaupré S, Heeger A J 2009 Nature Photonics 3 297
[21] Hou J,Chen H ,Zhang S, Yang Y 2009 Journal of the American Society 131 15586
[22] Chen H ,Hou J ,Zhang S, Yang Y 2009 Nature Photonics 3 649
[23] Chu T Y , Lu J P, Beaupr, Tao Y 2011 J. S. Am. Chem. Soc. 133 4250
[24] Jorgensen M, Norrman K, Krebs F C 2008 Sol. Energy Materials & Sol. Cells 92 686
[25] Kim S Y, Hong K, Kim K 2008 Mater. Lett. 4 63
[26] Kim H, Shin M, Park J 2010 IEEE Trans Nanotechnol. 9 400
[27] deJong M P, vanIjzendoorn L J A, deVoigt M J 2000 Appl. Phys. Lett. 77 255
[28] Xu Z, Chen L M, Yang G W 2009 Adv. Funct. Mater. 19 1227
[29] Waldauf C , Morana M, Denk P 2006 Applied Physics Letters 89 233517
[30] Liao H H, Chen L M , Xu Z, Yang Y 2008 Appl. Phys. Lett. 92 173303
[31] Jiang Ch Y, Sun X W, Zhao D W 2010 Solar Energy Materials & Solar Cells 94 1618
[32] Zhu Y X, Xu X F, Zhang L J 2011 Solar Energy Materials & Solar Cells 97 83
[33] Lin Y H, Yang P C, Huang J S 2011 Solar Energy Materials & Solar Cells 95 2511
[34] Cheng Y J, Hsieh Ch H, Li Y F 2010 J. Am. Chem. Soc. 132 17381
[35] Chu T Y, Tsang S W, Zhou J Y 2012 Solar Energy Materials & Solar Cells 96 155
[36] Amb C M,Amb, Chen S, Graham K R. 2011 J. Am. Chem. Soc. 133 10062
[37] Kim C S, Tinker L L, DiSalle B F 2009 Adv .Mater. 21 3110
[38] Reyes-Reyes M, López-Sandoval R, Arenas-Alatorre J 2007 Thin Solid Films 516 52
[39] Savenije T J, Kroeze J E, Yang X 2005 Adv. Funct. Mater. 15 1260
[40] Nguyen L H, Hoppe H, Erb T 2007 Adv. Funct. Mater. 17 1071
[41] Erb T, Zhokhavets U, Gobsch G 2005 Adv. Funct .Mater. 15 1193
[42] Inoue K, Ulbricht R, Madaka P C 2005 Synth .Met. 154 41
[43] Ayzner A L, Wanger D D, Tassone C J 2008 J. Phys. Chem. C 112 18711
[44] Yun J J, Peet J, Cho N S 2008 Appl .Phys. Lett. 92 251912
[45] Mihailetchi V D, Xie H X, de-Boer B 2006 Adv. Funct. Mater. 16 699
[46] Li G, Shrotriya V, Yang Y 2005 J. Appl. Phys. 98 043704
[47] Ma W, Yang C, Heeger A J 2007 Adv. Mater. 19 1387
[48] Goh C, Scully S R, McGehee M D 2007 J. Appl. Phys. 101 114503
[49] Roy A, Park S H, Cowan S 2009 Appl. Phys. Lett. 95 013302
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