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The dynamical potentials of highly excited vibrational states of HOCl in the bending and OCl stretching coordinates with anharmonicity and Fermi coupling are studied. The result shows that HO stretching vibration mode has significantly different effects on OCl stretching mode and HOCl bending mode under different polyad numbers. The dynamical potentials and the corresponding phase space trajectories are studied in the case that the polyad number is 24 and it is found that the quantal vibrational energy levels could be classified by the fixed points of dynamical potentials and the quantum environments could be identified by the numerical values of action integrals.
[1] Leu M T 1988 Geophys. Res. Lett. 15 17
[2] Jost R, Joyeux M, Skokov S, Bowman J 1999 J. Chem. Phys. 1116807
[3] Peterson K A, Skokov S, Bowman J M 1999 J. Chem. Phys. 1117446
[4] Joyeux M, Sugny D, Lombardi M, Jost R, Schinke R, Skokov S,Bowman J 2000 J. Chem. Phys. 113 9610
[5] Weiss J, Hauschildt J, Grebenshchikov S Y, Duren R, Schinke R,Koput J, Stamatiadis S, Farantos S C 2000 J. Chem. Phys. 112 77
[6] Joyeux M, Grebenshchikov S Y, Bredenbeck J, Schinke R , FarantosS C 2005 Geometric Structures of Phase Space in MultidimensionalChaos: a special volume of advances in Chemical Physics,part A, 130 chapter 5
[7] Zheng D S, Wu G Z 2002 Acta Phys. Sin. 51 2229 (in Chinese)[郑敦胜, 吴国祯 2002 51 2229
[8] Zheng D S, Guo X K 2004 Acta Phys. Sin. 53 3347 (in Chinese)[郑敦胜, 郭锡坤 2004 53 3347
[9] Fang C, Wu G Z 2009 J. Mol. Struct.: Theo. Chem. 910 147
[10] Fang C, Wu G Z 2009 Chin. Phys. B 18 0130
[11] Fang C, Wu G Z 2010 Chin. Phys. B 19 010509
[12] Fang C, Wu G Z 2010 Chin. Phys. B 19 110513
[13] Zhang W M , Feng D H , Gilmore, R 1990 Rev. Modern Phys. 62867
[14] Gilmore R 1974 Lie Algebras and Some of Their Applications(New York: Wiley)
[15] Biczysko M, Tarroni R 2002 Phys. Chem. Chem. Phys. 4 708
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[1] Leu M T 1988 Geophys. Res. Lett. 15 17
[2] Jost R, Joyeux M, Skokov S, Bowman J 1999 J. Chem. Phys. 1116807
[3] Peterson K A, Skokov S, Bowman J M 1999 J. Chem. Phys. 1117446
[4] Joyeux M, Sugny D, Lombardi M, Jost R, Schinke R, Skokov S,Bowman J 2000 J. Chem. Phys. 113 9610
[5] Weiss J, Hauschildt J, Grebenshchikov S Y, Duren R, Schinke R,Koput J, Stamatiadis S, Farantos S C 2000 J. Chem. Phys. 112 77
[6] Joyeux M, Grebenshchikov S Y, Bredenbeck J, Schinke R , FarantosS C 2005 Geometric Structures of Phase Space in MultidimensionalChaos: a special volume of advances in Chemical Physics,part A, 130 chapter 5
[7] Zheng D S, Wu G Z 2002 Acta Phys. Sin. 51 2229 (in Chinese)[郑敦胜, 吴国祯 2002 51 2229
[8] Zheng D S, Guo X K 2004 Acta Phys. Sin. 53 3347 (in Chinese)[郑敦胜, 郭锡坤 2004 53 3347
[9] Fang C, Wu G Z 2009 J. Mol. Struct.: Theo. Chem. 910 147
[10] Fang C, Wu G Z 2009 Chin. Phys. B 18 0130
[11] Fang C, Wu G Z 2010 Chin. Phys. B 19 010509
[12] Fang C, Wu G Z 2010 Chin. Phys. B 19 110513
[13] Zhang W M , Feng D H , Gilmore, R 1990 Rev. Modern Phys. 62867
[14] Gilmore R 1974 Lie Algebras and Some of Their Applications(New York: Wiley)
[15] Biczysko M, Tarroni R 2002 Phys. Chem. Chem. Phys. 4 708
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