HT-7装置液态锂限制器实验中锂的腐蚀与沉积特性的研究

孟献才; 左桂忠; 任君; 孙震; 徐伟; 黄明; 李美姮; 邓辉球; 胡建生; 胡望宇

doi:10.7498/aps.64.212801

摘要

在磁约束聚变等离子体装置中, 面对等离子体的第一壁将直接影响高温等离子体性能及第一壁寿命, 具有表面自我修复的、能有效抑制边界粒子再循环的液态金属锂第一壁越来越被重视, 其中液态锂第一壁与等离子体相互作用的研究尤其重要. 本文研究了HT-7装置液态锂限制器实验中锂的表面腐蚀及在装置内沉积特性、及其对等离子体性能影响. 实验表明, 当锂与等离子体相互作用较弱时, 锂以微弱的蒸发及溅射形式从表面腐蚀并进入等离子体, 表现为锂的线辐射有所增强, 等离子体内杂质水平降低, 氢再循环降低, 有利于等离子体约束性能提高; 当锂与等离子体间的相互作用比较强时, 锂主要以锂滴形式直接进入等离子体, 引起锂的辐射爆发, 最终引发等离子体放电破裂. 通过对锂斑及样品的分析发现, 锂主要沉积在限制器周围, 并且在低场侧及沿着等离子体电流方向沉积居多, 表现为极向和环向分布不均匀, 这也导致边界粒子再循环分布的不均匀. 这些实验为研究液态锂第一壁与等离子体相互作用, 分析液态锂第一壁在托卡马克装置上应用具有重要参考意义.

关键词:

HT-7托卡马克 /
液态锂 /
第一壁 /
腐蚀

Abstract

In the magnetic confinement fusion device, the first wall as plasma facing components will directly affect the performance of high temperature plasma. And the interaction of plasma and materials also affect the life of the first wall. Liquid lithium first wall receives more and more attention due to the properties of repairing itself and effectively inhibiting boundary particle recycling. So the research of the interaction between liquid lithium wall and plasma is particularly important. Erosion and deposition characteristics of lithium and its influence on the performance of plasma during lithium limiter experiment in HT-7 device are studied in-depth in this paper. Experimental results show that when the interaction between Li and plasma is weak, Li enters into the plasma mainly by weak surface evaporation and sputtering. During this process, Li line emission is strengthened, impurity and hydrogen recycling is decreased resulting in the improvement of plasma performance. When the interaction between Li and plasma becomes extremely strong, it is found so many big scale Li droplets ejected from liquid lithium surface to cause intense Li efflux into plasma, leading to plasma discharge disruption. Li atoms coming from Li limiter are ionized in the scrape-off layer (SOL), and entered into hot plasma column as ions (Li+, Li2+, Li3+) and transported in plasma. After the experiment, it can be found that a lot of white spots distributed in the vacuum chamber wall, with its main composition being Li2CO3 by XPS analysis. Through observing Li spot distribution and analyzing the lithium film thickness by scanning electron microscopy (SEM) in different samples, it is observed that the lithium is primarily deposited around the limiter, but the number of Li spots is more at the low field side than that at the high field side of the device, and the Li film gradually becomes thinner along the toroidal direction of the HT-7 device, leading to the non-uniformity of impurity and hydrogen recycling. The experiment may provide a reference for studying the interaction of plasma and liquid lithium first wall and the application of liquid lithium first wall in future tokamak device.

Keywords:

作者及机构信息

1.
湖南大学物理与微电子科学学院应用物理系, 长沙 410082;

2.
中国科学院等离子体物理研究所, 合肥 230031

通信作者: 胡建生, hujs@ipp.ac.cn;wyuhu@hnu.edu.cn ; 胡望宇, hujs@ipp.ac.cn;wyuhu@hnu.edu.cn

基金项目: 国家磁约束核聚变能研究专项(批准号: 2013 GB114004, 2014 GB124006)和国家自然科学基金(批准号: 11405210, 11105181)资助的课题.

Authors and contacts

1.
Department of Applied Physics, School of Physics and Electronics, Hunan University, Changsha 410082, China;

2.
Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, China

Corresponding author: Hu Jian-Sheng, hujs@ipp.ac.cn;wyuhu@hnu.edu.cn ; Hu Wang-Yu, hujs@ipp.ac.cn;wyuhu@hnu.edu.cn

Funds: Project supported by the National Magnetic Confinement Fusion Science Program (Grant Nos.2013 GB114004, 2014 GB124006), and the National Natural Science Foundation of China (Grant Nos. 11405210, 11105181).

参考文献

[1]	Krasheninnikov S I, Smirnov R D, Rudakov D L 2011 Plasma Phys. Controlled Fusion 53 083001
[2]	Huang Z H, Yan L W, Yukihiro T, Feng Z, Cheng J, Hong W Y, Pan Y D, Yang Q W, Duan X R 2015 Chin. Phys. B 24 7
[3]	Huang Y, Sun J Z, Sang C F, Ding F, Wang D Z 2014 Acta Phys. Sin. 63 035204 (in Chinese) [黄艳, 孙继忠,桑超峰, 丁芳, 王德真 2014 63 035204]
[4]	Hu J S, Sun Z, Zuo G Z, Wu J H, Li J H, Chen Y, Wang H Y, Wang X M, Li J G 2012 Chinese Vacuum Society 2012 Annual Conference Lan Zhou, China, September 21, 2012, p149
[5]	Li J H, Hu J S, Wang X M, Yu Y W, Wu J H, Chen Y,Wang H Y 2012 Acta Phys. Sin. 61 205203 (in Chinese) [李加宏, 胡建生, 王小明,余耀伟, 吴金华, 陈跃, 王厚银 2012 61 205203]
[6]	Zheng X W, Li J G, Hu J S, Li H, Cao B, Wu J H 2013 Acta Phys. Sin. 62 155202 (in Chinese) [郑星炜, 李建刚, 胡建生, 李加宏, 曹斌, 吴金华 2013 62 155202]
[7]	Sun Z, Hu J S, Zuo G Z, Ren J, Cao B, Li J G, Mansfield D K 2014 Fusion Eng. Des. 89 2886
[8]	Kaita R, Majeski R, Boaz M, Efthimion P, Gettelfinger G, Gray T, Hoffman D, Jardin S, Kugel H, Marfuta P, Munsat T, Neumeyer C, Raftopoulos S, Soukhanovskii V, Spaleta J, Taylor G, Timberlake J, Woolley R, Zakharov L, Finkenthal M, Stutman D, Delgado A L, Seraydarian R P, Antar G, Doerner R, Luckhardt S, Baldwin M, Conn R W, Maingi R, Menon M, Causey R, Buchenauer D, Ulrickson M, Jones B, Rodgers D 2005 J. Nucl. Mater 337 872
[9]	Majeski R, Jardin S, Kaita R, Gray T, Marfuta P, Spaleta J, Timberlake J, Zakharov L, Antar G, Doerner R, Luckhardt S, Seraydarian R, Soukhanovskii V, Maingi R, Finkenthal M, Stutman D, Rodgers D, Angelini S 2005 Nucl. Fusion 45 519
[10]	Vertkov A, Luyblinski I, Evtikhin V, Mazzitelli G, Apicella M L, Lazarev V, Alekseyev A, Khonlyakov S 2007 Fusion Eng. Des. 82 1627
[11]	Pericoli R V, Alekseyev A, Angelini B, Annibaldi S V, Apicella M L, Apruzzese G, Barbato E, Berrino J, Bertocchi A, Bin W, Bombarda F, Bracco G, Bruschi A, Buratti P, Calabro G, Cardinali A, Carraro L, Castaldo C, Centioli C, Cesario R, Cirant S, Cocilovo V, Crisanti F D, Antona G D, Angelis R D, Benedetti M D, Marco F, Esposito B, Frigione D, Gabellieri L, Gandini F, Giovannozzi E, Granucci G, Gravanti F, Grossetti G, Grosso G, Lannone F, Kroegler H, Lazarev V, Lazzaro E, Leigheb M, Lyublinski I E, Lubyako L, Maddaluno G, Marinucci M, Marocco D, Martin J R, Mazzitelli G, Mazzotta C, Mellera V, Mirizzi F, Monari G, Moro A, Muzzini V, Nowak S, Orsitto F P, Panaccione L, Panella M, Pieroni L, Podda S, Puiatti M E, Ravera G, Regnoli G, Romanelli F, Romanelli M, Shalashov A, Simonetto A, Smeulders P, Sozzi C, Sternini E, Tartari U, Tilia B, Tuccillo A A, Tudisco O, Valisa M, Vertkov A, Vitale V, Vlad G, Zagorski R, Zonca F 2007 Nucl. Fusion 47 S608
[12]	Apicella M L, Mazzitelli G, Lazarev V B, Azizov E A, Mirnov S V, Petrov V G, Evtikhin V A, Lyublinski I E, Vertkov A V, Lucca F D, Ferdinando E, Mazzone G, Ramogida G, Roccella M 2005 Fusion Eng. Des. 75 351
[13]	Mirnov S V, Azizov E A, Evtikhin V A, Lazarev V B, Lyublinski I E, Vertkov A V, Prokhorov D Y 2006 Plasma Phys. Control. Fusion 48 821
[14]	Mirnov SV, Lazarev V B 2011 J. Nucl.Mater 415 S417
[15]	Zuo G Z, Hu J S, Li J G, Luo N C Zakharov L E, Zhang L, Ti A 2011 J. Nucl. Mater 415 1062
[16]	Hu J S, Zuo G Z, Li J G, Luo N C, Zakharov L E, Zhang L, Zhang W, Xu P 2010 Fusion Eng. Des. 85 930
[17]	Sun Z, Hu J S, Zuo G Z, Ren J, Li J G, Zakharov L E, Mansfield D K 2013 J. Nucl. Mater 438 899
[18]	Ren J, Hu J S, Zuo G Z, Sun Z, Li J G, Ruzic D N, Zakharov L E 2014 Phys. Scr. T159
[19]	Hu J S, Ren J, Sun Z, Zuo G Z, Yang Q X, Li J G, Mansfield D K, Zakharov L E, Ruzic D N 2014 Fusion Eng. Des. 89 2875
[20]	Ren J, Zuo G Z, Hu J S, Sun Z, Yang Q X, Li J G, Zakharov L, Xie H, Chen Z X 2015 Rev. Sci. Instrum. 82 23504
[21]	Zuo G Z, Ren J, Hu JS, Sun Z, Yang Q X, Li J G, Zakharov L E, Ruzic D N 2014 Fusion Eng. Des. 89 2845
[22]	Mansfield D K, Roquemore A L, Schneider H, Timberlake J, Kugel H, Bell M G 2010 Fusion Eng. Des. 85 896
[23]	Deng B Q, Yan J C, Huang J H 2000 Chinese Journal of Nuclear Science and Engineering 20 373 [邓柏权, 严建成, 黄锦华 2000 核科学与工程 20 373]
[24]	Stotler D P, Skinner C H, Blanchard W R, Krstic P S, Kugel H W, Schneider H, Zakharov L E 2011 J. Nucl. Mater 415 S1058
[25]	Stotler D P, Skinner C H, Blanchard W R, Krstic P S, Kugel H W, Schneider H, Zakharov L E 2011 J. Nucl. Mater 415 S1058

施引文献

[1]	Krasheninnikov S I, Smirnov R D, Rudakov D L 2011 Plasma Phys. Controlled Fusion 53 083001
[2]	Huang Z H, Yan L W, Yukihiro T, Feng Z, Cheng J, Hong W Y, Pan Y D, Yang Q W, Duan X R 2015 Chin. Phys. B 24 7
[3]	Huang Y, Sun J Z, Sang C F, Ding F, Wang D Z 2014 Acta Phys. Sin. 63 035204 (in Chinese) [黄艳, 孙继忠,桑超峰, 丁芳, 王德真 2014 63 035204]
[4]	Hu J S, Sun Z, Zuo G Z, Wu J H, Li J H, Chen Y, Wang H Y, Wang X M, Li J G 2012 Chinese Vacuum Society 2012 Annual Conference Lan Zhou, China, September 21, 2012, p149
[5]	Li J H, Hu J S, Wang X M, Yu Y W, Wu J H, Chen Y,Wang H Y 2012 Acta Phys. Sin. 61 205203 (in Chinese) [李加宏, 胡建生, 王小明,余耀伟, 吴金华, 陈跃, 王厚银 2012 61 205203]
[6]	Zheng X W, Li J G, Hu J S, Li H, Cao B, Wu J H 2013 Acta Phys. Sin. 62 155202 (in Chinese) [郑星炜, 李建刚, 胡建生, 李加宏, 曹斌, 吴金华 2013 62 155202]
[7]	Sun Z, Hu J S, Zuo G Z, Ren J, Cao B, Li J G, Mansfield D K 2014 Fusion Eng. Des. 89 2886
[8]	Kaita R, Majeski R, Boaz M, Efthimion P, Gettelfinger G, Gray T, Hoffman D, Jardin S, Kugel H, Marfuta P, Munsat T, Neumeyer C, Raftopoulos S, Soukhanovskii V, Spaleta J, Taylor G, Timberlake J, Woolley R, Zakharov L, Finkenthal M, Stutman D, Delgado A L, Seraydarian R P, Antar G, Doerner R, Luckhardt S, Baldwin M, Conn R W, Maingi R, Menon M, Causey R, Buchenauer D, Ulrickson M, Jones B, Rodgers D 2005 J. Nucl. Mater 337 872
[9]	Majeski R, Jardin S, Kaita R, Gray T, Marfuta P, Spaleta J, Timberlake J, Zakharov L, Antar G, Doerner R, Luckhardt S, Seraydarian R, Soukhanovskii V, Maingi R, Finkenthal M, Stutman D, Rodgers D, Angelini S 2005 Nucl. Fusion 45 519
[10]	Vertkov A, Luyblinski I, Evtikhin V, Mazzitelli G, Apicella M L, Lazarev V, Alekseyev A, Khonlyakov S 2007 Fusion Eng. Des. 82 1627
[11]	Pericoli R V, Alekseyev A, Angelini B, Annibaldi S V, Apicella M L, Apruzzese G, Barbato E, Berrino J, Bertocchi A, Bin W, Bombarda F, Bracco G, Bruschi A, Buratti P, Calabro G, Cardinali A, Carraro L, Castaldo C, Centioli C, Cesario R, Cirant S, Cocilovo V, Crisanti F D, Antona G D, Angelis R D, Benedetti M D, Marco F, Esposito B, Frigione D, Gabellieri L, Gandini F, Giovannozzi E, Granucci G, Gravanti F, Grossetti G, Grosso G, Lannone F, Kroegler H, Lazarev V, Lazzaro E, Leigheb M, Lyublinski I E, Lubyako L, Maddaluno G, Marinucci M, Marocco D, Martin J R, Mazzitelli G, Mazzotta C, Mellera V, Mirizzi F, Monari G, Moro A, Muzzini V, Nowak S, Orsitto F P, Panaccione L, Panella M, Pieroni L, Podda S, Puiatti M E, Ravera G, Regnoli G, Romanelli F, Romanelli M, Shalashov A, Simonetto A, Smeulders P, Sozzi C, Sternini E, Tartari U, Tilia B, Tuccillo A A, Tudisco O, Valisa M, Vertkov A, Vitale V, Vlad G, Zagorski R, Zonca F 2007 Nucl. Fusion 47 S608
[12]	Apicella M L, Mazzitelli G, Lazarev V B, Azizov E A, Mirnov S V, Petrov V G, Evtikhin V A, Lyublinski I E, Vertkov A V, Lucca F D, Ferdinando E, Mazzone G, Ramogida G, Roccella M 2005 Fusion Eng. Des. 75 351
[13]	Mirnov S V, Azizov E A, Evtikhin V A, Lazarev V B, Lyublinski I E, Vertkov A V, Prokhorov D Y 2006 Plasma Phys. Control. Fusion 48 821
[14]	Mirnov SV, Lazarev V B 2011 J. Nucl.Mater 415 S417
[15]	Zuo G Z, Hu J S, Li J G, Luo N C Zakharov L E, Zhang L, Ti A 2011 J. Nucl. Mater 415 1062
[16]	Hu J S, Zuo G Z, Li J G, Luo N C, Zakharov L E, Zhang L, Zhang W, Xu P 2010 Fusion Eng. Des. 85 930
[17]	Sun Z, Hu J S, Zuo G Z, Ren J, Li J G, Zakharov L E, Mansfield D K 2013 J. Nucl. Mater 438 899
[18]	Ren J, Hu J S, Zuo G Z, Sun Z, Li J G, Ruzic D N, Zakharov L E 2014 Phys. Scr. T159
[19]	Hu J S, Ren J, Sun Z, Zuo G Z, Yang Q X, Li J G, Mansfield D K, Zakharov L E, Ruzic D N 2014 Fusion Eng. Des. 89 2875
[20]	Ren J, Zuo G Z, Hu J S, Sun Z, Yang Q X, Li J G, Zakharov L, Xie H, Chen Z X 2015 Rev. Sci. Instrum. 82 23504
[21]	Zuo G Z, Ren J, Hu JS, Sun Z, Yang Q X, Li J G, Zakharov L E, Ruzic D N 2014 Fusion Eng. Des. 89 2845
[22]	Mansfield D K, Roquemore A L, Schneider H, Timberlake J, Kugel H, Bell M G 2010 Fusion Eng. Des. 85 896
[23]	Deng B Q, Yan J C, Huang J H 2000 Chinese Journal of Nuclear Science and Engineering 20 373 [邓柏权, 严建成, 黄锦华 2000 核科学与工程 20 373]
[24]	Stotler D P, Skinner C H, Blanchard W R, Krstic P S, Kugel H W, Schneider H, Zakharov L E 2011 J. Nucl. Mater 415 S1058
[25]	Stotler D P, Skinner C H, Blanchard W R, Krstic P S, Kugel H W, Schneider H, Zakharov L E 2011 J. Nucl. Mater 415 S1058

[1]	甘舒匀, 徐帅, 李炳生, 柴林江, 陈黎明, 何晓珣, 汪利, 刘思捷, 文春梅, 李佳奇, 伍忠政. 含铝强化奥氏体钢在550 ℃液态铅铋中的腐蚀行为. , 2024, 73(2): 026104. doi: 10.7498/aps.73.20231103
[2]	杨海林, 陈琦丽, 顾星, 林宁. 氧原子在氟化石墨烯上扩散的第一性原理计算. , 2023, 72(1): 016801. doi: 10.7498/aps.72.20221630
[3]	沈永青, 张志强, 廖斌, 吴先映, 张旭, 华青松, 鲍曼雨. 高功率脉冲磁控溅射技术制备掺氮类金刚石薄膜的磨蚀性能. , 2020, 69(10): 108101. doi: 10.7498/aps.69.20200021
[4]	陈淑年, 廖斌, 陈琳, 张志强, 沈永青, 王浩琦, 庞盼, 吴先映, 华青松, 何光宇. 基于磁过滤技术TiAlCN/TiAlN/TiAl复合体系腐蚀及摩擦学性能. , 2020, 69(10): 107202. doi: 10.7498/aps.69.20200012
[5]	佟曼, 范天伟, 陈云琳. 畴腐蚀掺镁铌酸锂可调阵列光分束器的研究. , 2016, 65(1): 014215. doi: 10.7498/aps.65.014215
[6]	唐琬婷, 肖时芳, 孙学贵, 胡望宇, 邓辉球. 液态锂在铜的微通道中的流动行为. , 2016, 65(10): 104705. doi: 10.7498/aps.65.104705
[7]	卢洪伟, 查学军, 胡立群, 林士耀, 周瑞杰, 罗家融, 钟方川. HT-7托卡马克slide-away放电充气对等离子体行为的影响. , 2012, 61(7): 075202. doi: 10.7498/aps.61.075202
[8]	卢洪伟, 胡立群, 林士耀, 钟国强, 周瑞杰, 张继宗. HT-7托卡马克等离子体slide-away放电研究. , 2010, 59(8): 5596-5601. doi: 10.7498/aps.59.5596
[9]	徐强, 高翔, 单家方, 胡立群, 赵君煜. HT-7托卡马克大功率低混杂波电流驱动的实验研究. , 2009, 58(12): 8448-8453. doi: 10.7498/aps.58.8448
[10]	刘贵立, 方戈亮. Sc在Al-Zn-Mg-Cu超高强铝合金中作用机理的电子理论研究. , 2009, 58(7): 4872-4877. doi: 10.7498/aps.58.4872
[11]	刘贵立. 钛的腐蚀与钝化机理电子理论研究. , 2008, 57(7): 4441-4445. doi: 10.7498/aps.57.4441
[12]	徐伟, 万宝年, 谢纪康. HT-6M托卡马克装置杂质输运. , 2003, 52(8): 1970-1978. doi: 10.7498/aps.52.1970
[13]	张谷令, 王久丽, 杨武保, 范松华, 刘赤子, 杨思泽. 内表面栅极等离子体源离子注入TiN薄膜及其特性研究. , 2003, 52(9): 2213-2218. doi: 10.7498/aps.52.2213
[14]	王文浩, 俞昌旋, 许宇鸿, 闻一之, 凌必利, 宋梅, 万宝年. HT-7超导托卡马克边界等离子体参量及其涨落的实验研究. , 2001, 50(8): 1521-1527. doi: 10.7498/aps.50.1521
[15]	张先梅, 万宝年, 阮怀林, 吴振伟. HT-7托卡马克等离子体欧姆放电时电子热扩散系数的研究. , 2001, 50(4): 715-720. doi: 10.7498/aps.50.715
[16]	王文浩, 许宇鸿, 俞昌旋, 闻一之, 凌必利, 宋梅, 万宝年. HT-7超导托卡马克边缘涨落谱特征及湍流输运研究. , 2001, 50(10): 1956-1963. doi: 10.7498/aps.50.1956
[17]	傅鹏, 刘正之, 罗家融, 夏海燕. HT-7铁芯超导托卡马克等离子体电流和水平位移多变量反馈控制. , 1999, 48(4): 685-691. doi: 10.7498/aps.48.685
[18]	邵其鋆, 陈建新, 吴士明, 潘正瑛, 霍裕昆, 高兴华. 聚变α粒子对第一壁辐照损伤的蒙特-卡罗研究(Ⅱ)——溅射. , 1991, 40(8): 1244-1252. doi: 10.7498/aps.40.1244
[19]	霍裕昆, 吴选红, 邵其鋆, 陈建新, 吴士明, 潘正瑛, 高兴华. 聚变α粒子对第一壁辐照损伤的蒙特-卡罗研究(Ⅰ)——轰击第一壁的α粒子能谱. , 1991, 40(8): 1236-1243. doi: 10.7498/aps.40.1236
[20]	郑少白, 杨宣宗, W. P. WEST, D. M. THOMAS. 利用高能锂束激光荧光法测量托卡马克中的角向磁场. , 1990, 39(4): 531-540. doi: 10.7498/aps.39.531

计量

文章访问数: 6362
PDF下载量: 174
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板