通过AC-HVAF方法制备铁基非晶合金涂层的结构分析

叶凤霞; 陈燕; 余鹏; 罗强; 曲寿江; 沈军

doi:10.7498/aps.63.078101

摘要

本研究通过活性燃烧高速燃气喷涂（AC-HVAF）方法制备出了均匀致密的铁基非晶化合金涂层. 通过调制AC-HVAF喷涂过程的工艺参数，研究了喷涂枪长、喷涂距离和送粉率对涂层非晶化程度的影响，得出控制枪长是形成高质量非晶化涂层的关键，而喷涂距离和送粉率决定了涂层的厚度和形成速率. 制备出的铁基非晶合金与基体结合致密，孔隙率较低，完全的非晶化结构有效的保持了铁基非晶合金优异的力学性能，可以对基体材料进行很好的防护.

关键词:

Abstract

The uniform and compact Fe-based amorphous alloy coating was prepared by active combustion high velocity air fuel (AC-HVAF) spray method. By tuning the parameters of AC-HVAF spray process, the influence of the spraying gun length, spraying distance, and powder feed rate on non-crystallization has been studied carefully. Results indicate that spraying gun length is the key factor in forming perfect amorphous coating. Spraying distance and powder feed rate may determine the thickness and formation rate of the coating. The prepared coatings have a tight adhesion with the substrate, low porosity, and good non-crystallization, which would effectively maintain the excellent mechanical properties of the Fe-based amorphous alloy. The coating can provide a good protection for the substrate material.

Keywords:

作者及机构信息

1.
光电功能材料重庆市重点实验室, 重庆师范大学物理与电子工程学院, 重庆 401331;

2.
材料科学与工程学院, 同济大学, 上海 201804

基金项目: 国家自然科学基金（批准号：51101178，51274151）、重庆市基础与前沿研究计划杰青项目（批准号：cstc2013jcyjjq50002）和重庆市教委自然科学基金（批准号：KJ120610）资助的课题.

Authors and contacts

1.
Chongqing Key Laboratory of Photo-Electric Functional Materials, College of Physics and Electronic Engineering, Chongqing Normal University, Chongqing 401331, China;

2.
School of Materials Science and Engineering, Tongji University, Shanghai 201804, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51101178, 51274151), the Outstanding Youth Project of the Basic and Frontier Research Program of Chongqing, China (Grant No. cstc2013jcyjjq50002), and the Natural Science Foundation of Chongqing Municipal Education Commission, China (Grant No. KJ120610).

参考文献

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施引文献

[1]	Pang S J, Zhang T, Asami A, Inoue A 2002 Acta Mater. 50 489
[2]	Telford M 2004 Mater. Today 3 36
[3]	Lu Z P, Liu C T, Thompson J R, Porter W D 2004 Phys. Rev. Lett. 92 245503
[4]	Wang W H 2012 Prog. Mater. Sci. 57 487
[5]	Yu P, Bai H Y, Tang M B, Wang W L, Wang W H 2005 Acta Phys. Sin. 54 3284 (in Chinese)[余鹏, 白海洋, 汤美波, 王万录, 汪卫华2005 54 3284]
[6]	Chen M W 2011 NPG Asia Mater. 3 82
[7]	Schroers J 2005 JOM 57 35
[8]	Zhang B, Zhao D Q, Pan M X, Wang W H, Greer A L 2005 Phys. Rev. Lett. 94 205502
[9]	Trexler M M, Thadhani N N 2010 Prog. Mater. Sci. 55 759
[10]	Rong C B, Zhao Y H, Xu M, Zhao H H, Cheng L Z, He K Y 2001 Acta Phys. Sin. 50 2235 (in Chinese)[荣传兵, 赵玉华, 徐民, 赵恒和, 程力智, 何开元2001 50 2235]
[11]	Nassima S, Badis B, Gabriel L, Alberto C, Marcello B 2012 Chin. Phys. Lett. 29 118102
[12]	Chen Q J, Shen J, Fan H B, Sun J F, Huang Y J, Mccartney D G 2005 Chin. Phys. Lett. 22 1736
[13]	Koutsky J 2004 J. Mater. Process Techn. 157-158 557
[14]	Wielage B, Wank A, Pokmurska H, Grund T, Rupprecht C, Reisel G, Friesen E 2006 Surf. Coat. Techn. 201 2032
[15]	Chen Z G, Zhu X R, Tang X L, Kong D J, Wang L 2007 Acta Phys. Sin. 56 7320 (in Chinese)[陈志刚, 朱小蓉, 汤小丽, 孔德军, 王玲2007 56 7320]
[16]	Guo R Q, Zhang C, Chen Q, Yang Y, Li N, Liu L 2011 Corr. Sci. 53 2351
[17]	Zhou Z, Wang L, Wang F C, Liu Y B 2009 Trans. Nonferr. Mater. Soc. Chin. 19 s634
[18]	Zhang C, Wu Y, Liu L 2012 Appl. Phys. Lett. 101 121603
[19]	Heimann R B, Lehmann H D 2008 Rec. Pat. Mater. Sci. 1 41
[20]	Stoica V, Ahmed R, Itsukaichi T, Tobe S 2004 Wear 257 1103
[21]	Qiao Y F, Fischer T E, Dent A 2003 Surf. Coat. Techn. 172 24
[22]	Liu X Q, Zheng Y G, Chang X C, Hou W L, Wang J Q, Tang Z, Burgess A 2009 J. Alloy. Comp. 484 300
[23]	Pierlot C, Pawlowski L, Bigan M, Chagnon P 2008 Surf. Coat. Techn. 202 4483
[24]	Wang T G, Zhao S S, Hua W G, Gong J, Sun C 2009 Surf. Coat. Techn. 203 1637
[25]	Otsubo F, Kishitake K 2005 Mater. Trans. 46 80
[26]	Zhang F G, Zhou H Q, Hu J, Shao J L, Zhang G C, Hong T, He B 2012 Chin. Phys. B 21 094601
[27]	Zhang C, Chan K C, Wu Y, Liu L 2012 Acta Mater. 60 4152

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