金属催化制备石墨烯的研究进展

于海玲; 朱嘉琦; 曹文鑫; 韩杰才

doi:10.7498/aps.62.028201

摘要

石墨烯作为一种新兴的碳素材料, 从一出现就引起了众多学者的关注. 石墨烯具有许多新奇的特性, 使得石墨烯在光电领域及微电子工业等有极大的应用潜力. 但是目前难以实现大尺寸、高质量、宏量石墨烯的可控制备, 限制了石墨烯的广泛应用. 本文分析了各种石墨烯制备方法的利弊, 重点从层数控制及大面积制备等方面对金属催化法进行了阐述, 固态碳源金属催化法可以实现宏量制备大尺寸、高质量、薄且均匀的石墨烯. 综述了金属催化制备石墨烯的相关机理研究, 指出了目前研究的局限, 并对石墨烯相变机理的下一步研究方向进行了展望.

关键词:

Abstract

Graphene, which is regarded as a new carbon material, has attracted much attention of scientists. Graphene holds the promise for applications in optoelectronics and microelectronics, owing to many unique physical and chemical properties. The large-scale applications are restricted by controllable synthesis of large-size graphene. In this paper we present the advantages and disadvantages of preparation processes of graphene. The recent advances in the process of metal-catalyzed graphene in terms of lay number control and large area synthesis are discussed. The graphene prepared by metal-catalyzed solid carbon source has large area and high quality and is thin and homogeneous. We review the latest progress in graphene transformation mechanism, point out the limitations of current study and prospect the future development in the graphene transformation mechanism.

Keywords:

作者及机构信息

1.
哈尔滨工业大学复合材料与结构研究所, 哈尔滨 150080

基金项目: 国家自然科学基金(批准号: 51222205, 51072039)、教育部新世纪人才支持计划(批准号: NCET-10-0070)和教育部博士点基金(批准号: 20122302110035)资助的课题.

Authors and contacts

1.
Center for Composite Materials and Structures, Harbin Institute of Technology, Harbin 150080, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51222205, 51072039), the Program for New Century Excellent Talents in University (Grant No. NCET-10-0070), and the Ph.D. Programs Foundation of Ministry of Education of China (Grant No. 20122302110035).

参考文献

[1]	Novoselov K 2011 Rev. Mod. Phys. 83 837
[2]	Novoselov K 2004 Science 306 66
[3]	Peierls R 1935 Annals de l'I. H. P. 5 p177
[4]	Landau L 1937 Phys. Z. Sowjetunion 11 p26
[5]	Stoller M D, Park S, Zhu Y, An J, Ruoff R S 2008 Nano Lett. 8 3498
[6]	Nair R R, Blake P, Grigorenko A N, Novoselov K S, Booth T J, Stauber T, Peres N M R, Geim A K 2008 Science 320 1308
[7]	Stauber T, Peres N M R, Geim A K 2008 Phys. Rev. B 78 085418
[8]	Lee C, Wei X, Kysar J W, Hone J 2008 Science 321 385
[9]	Balandin A A, Ghosh S, Bao W Z, Calizo I, Teweldebrhan D, Miao F, Lau C N 2008 Nano Lett. 8 902
[10]	Areshkin D A, White C T 2007 Nano Lett. 7 3253
[11]	Geim A K, Novoselov K S 2007 Nat. Mater. 6 183
[12]	Wei D, Liu Y 2010 Adv. Mater. 22 3225
[13]	Geim A K 2009 Science 324 1530
[14]	Singh V, Joung D, Zhai L, Das S, Khondaker S I, Seal S 2011 Prog. Mater Sci. 56 1178
[15]	Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y, Wu Y, Nguyen S T, Ruoff R S 2007 Carbon 45 1558
[16]	Park S, Ruoff R S 2009 Nat. Nanotechnol. 4 217
[17]	Yang X Y, Dou X, Rouhanipour A, Zhi L J, Rader H J, Mullen K 2008 JACS 130 4216
[18]	Berger C 2006 Science 312 1191
[19]	Weatherup R S, Bayer B C, Blume R, Ducati C, Baehtz C, Schlögl R, Hofmann S 2011 Nano Lett. 11 4154
[20]	Huang H, Chen W, Chen S, Wee A T S 2008 Acs Nano 2 2513
[21]	Berger C, Song Z M, Li T B, Li X B, Ogbazghi A Y, Feng R, Dai Z T, Marchenkov A N, Conrad E H, First P N, de Heer W A 2004 J. Phys. Chem. B 108 19912
[22]	Emtsev K V, Bostwick A, Horn K, Jobst J, Kellogg G L, Ley L, McChesney J L, Ohta T, Reshanov S A, Rohrl J, Rotenberg E, Schmid A K, Waldmann D, Weber H B, Seyller T 2009 Nat. Mater. 8 203
[23]	Pan Y, Zhang H G, Shi D X, Sun J T, Du S X, Liu F, Gao H J 2009 Adv. Mater. 21 2739
[24]	Zhang H, Fu Q, Cui Y, Tan D L, Bao X H 2009 Chin. Sci. Bull. 1860 (in Chinese) [张辉, 傅强, 崔义, 谭大力, 包信和 2009 科学通报 1860]
[25]	Sutter P W, Flege J I, Sutter E A 2008 Nat. Mater. 7 406
[26]	Campos-Delgado J, Romo-Herrera J M, Jia X T, Cullen D A, Muramatsu H, Kim Y A, Hayashi T, Ren Z F, Smith D J, Okuno Y, Ohba T, Kanoh H, Kaneko K, Endo M, Terrones H, Dresselhaus M S, Terrones M 2008 Nano Lett. 8 2773
[27]	Di C A, Wei D C, Yu G, Liu Y Q, Guo Y L, Zhu D B 2008 Adv. Mater. 20 3289
[28]	Shang N G, Papakonstantinou P, McMullan M, Chu M, Stamboulis A, Potenza A, Dhesi S S, Marchetto H 2008 Adv. Funct. Mater. 18 3506
[29]	Li X, Cai W, An J, Kim S, Nah J, Yang D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L, Ruoff R S 2009 Science 324 1312
[30]	Bae S, Kim H, Lee Y, Xu X F, Park J S, Zheng Y, Balakrishnan J, Lei T, Kim H R, Song Y I, Kim Y J, Kim K S, Ozyilmaz B, Ahn J H, Hong B H, Iijima S 2010 Nat. Nanotechnol. 5 574
[31]	Chen Z P, Ren W C, Liu B L, Gao L B, Pei S F, Wu Z S, Zhao J P, Cheng H M 2010 Carbon 48 3543
[32]	Wei D C, Liu Y Q, Zhang H L, Huang L P, Wu B, Chen J Y, Yu G 2009 JACS 131 11147
[33]	Ren W C, Gao L B, Ma L P, Cheng H M 2011 New Carbon Mater. 71 (in Chinese) [任文才高力波, 马来鹏, 成会明 2011 新型炭材料 71]
[34]	Juang Z Y, Wu C Y, Lo C W, Chen W Y, Huang C F, Hwang J C, Chen F R, Leou K C, Tsai C H 2009 Carbon 47 2026
[35]	Hofrichter J, Szafranek B u N, Otto M, Echtermeyer T J, Baus M, Majerus A, Geringer V, Ramsteiner M, Kurz H 2010 Nano Lett. 10 36
[36]	Fujita J I, Ueki R, Miyazawa Y, Ichihashi T 2009 J. Vac. Sci. Technol. B 27 3063
[37]	Zheng M, Takei K, Hsia B, Fang H, Zhang X, Ferralis N, Ko H, Chueh Y L, Zhang Y, Maboudian R, Javey A 2010 Appl. Phys. Lett. 96 063110
[38]	Rodriguez Manzo J A, Pham Huu C, Banhart F 2011 Acs Nano 5 1529
[39]	Orofeo C M, Ago H, Hu B, Tsuji M 2011 Nano Research 4 531
[40]	Ji H X, Hao Y F, Ren Y J, Charlton M, Lee W H, Wu Q Z, Li H F, Zhu Y W, Wu Y P, Piner R, Ruoff R S 2011 Acs Nano 5 7656
[41]	Liu N, Fu L, Dai B, Yan K, Liu X, Zhao R, Zhang Y, Liu Z 2011 Nano Lett. 11 297
[42]	Sun Z, Yan Z, Yao J, Beitler E, Zhu Y, Tour J M 2010 Nature 468 549
[43]	Perdigão L S M A, Sabki S N, Garfitt J M, Capiod P, Beton P H 2011 J. Phys. Chem. C 115 7472
[44]	Garaj S, Hubbard W, Golovchenko J A 2010 Appl. Phys. Lett. 97 183103
[45]	Kaplas T, Sharma D, Suirko, Y 2012 Carbon 50 1503
[46]	Sun J, Cole M, Ahmad S, Backe O, Ive T, Loffler M, Lindvall N, Olsson E, Teo K, Liu J, Larsson A, Yurgens A, Haglund A 2011 IEEE T. Semiconduct. M 99 1
[47]	Sun J, Lindvall N, Cole M, Teo K, Yurgens A 2011 Appl. Phys. Lett. 98 252107
[48]	Jerng S K, Lee J H, Yu D S, Kim Y S, Ryou J, Hong S, Kim C, Yoon S, Chun S H 2012 J. Phys. Chem. C 116 7380
[49]	Tang J, Kang C Y, Li L M, Yan W S, Wei S Q, Xu P S 2011 Physica E 43 1415
[50]	Chen J Y, Wen Y G, Guo Y L, Wu B, Huang L P, Xue Y Z, Geng D C, Wang D, Yu G, Liu Y Q 2011 J. Am. Chem. Soc. 133 17548
[51]	Li X S, Cai W W, Colombo L, Ruoff R S 2009 Nano Lett. 9 4268
[52]	Shahil K M F, Balandin A A 2012 Nano Lett. 12 861
[53]	Katsnelson M I 2007 Mater. Today 10 20
[54]	Rao C N R, Biswas K, Subrahmanyam K S, Govindaraj A 2009 J. Mater. Chem. 19 2457
[55]	Seyller T, Bostwick A, Emtsev K V, Horn K, Ley L, McChesney J L, Ohta T, Riley J D, Rotenberg E, Speck F 2008 Phys. Status Solidi B 245 1436
[56]	Hass J, de Heer W A, Conrad E H 2008 J. Phys. Condensed Matter 20 323202
[57]	Unarunotai S, Murata Y, Chialvo C E, Kim H S, MacLaren S, Mason N, Petrov I, Rogers J A 2009 Appl. Phys. Lett. 95 202101
[58]	Rollings E, Gweon G, Zhou S, Mun B, McChesney J, Hussain B, Fedorov A, First P, Deheer W, Lanzara A 2006 J. Phys. Chem. Solids 67 2172
[59]	Camara N, Rius G, Huntzinger J R, Tiberj A, Mestres N, Godignon P, Camassel J 2008 Appl. Phys. Lett. 93 123503
[60]	Kim K J, Lee H, Choi J H, Lee H K, Kang T H, Kim B, Kim S J 2008 Phys. Condens Mat. 20 225017
[61]	Sutter E, Acharya D P, Sadowski J T, Sutter P 2009 Appl. Phys. Lett. 94 133101
[62]	Sutter E, Albrecht P, Sutter P 2009 Appl. Phys. Lett. 95 133109
[63]	Moritz W, Wang B, Bocquet M L, Brugger T, Greber T, Wintterlin J, Gunther S 2010 Phys. Rev. Lett. 104 136102
[64]	Kaplas T, Sharma D, Suirko Y 2012 Carbon 50 1503
[65]	Kim K S, Zhao Y, Jang H, Lee S Y, Kim J M, Kim K S, Ahn J H, Kim P, Choi J Y, Hong B H 2009 Nature 457 706
[66]	Li X S, Zhu Y W, Cai W W, Borysiak M, Han B Y, Chen D, Piner R D, Colombo L, Ruoff R S 2009 Nano Lett. 9 4359
[67]	Gao L, Ren W, Zhao J, Ma L-P, Chen Z, Cheng H-M 2010 Appl. Phys. Lett. 97 183109
[68]	Bhaviripudi S, Jia X T, Dresselhaus M S, Kong J 2010 Nano Lett. 10 4128
[69]	Cai W W, Zhu Y W, Li X S, Piner R D, Ruoff R S 2009 Appl. Phys. Lett. 95 123115
[70]	Reina A, Jia X T, Ho J, Nezich D, Son H B, Bulovic V, Dresselhaus M S, Kong J 2009 Nano Lett. 9 30
[71]	Wintterlin J, Bocquet M L 2009 Surf. Sci. 603 1841
[72]	Dreyer D R, Ruoff R S, Bielawski C W 2010 Angew. Chem. Int. Edit. 49 9336
[73]	Compton O C, Nguyen S T 2010 Small 6 711
[74]	Becerril H A, Mao J, Liu Z, Stoltenberg R M, Bao Z, Chen Y 2008 Acs Nano 2 463
[75]	Dato A, Radmilovic V, Lee Z, Phillips J, Frenklach M 2008 Nano Lett. 8 2012
[76]	Wu Z S, Ren W, Gao L, Liu B, Jiang C, Cheng H M 2009 Carbon 47 493
[77]	Schneider J J 2011 Chemcatchem 3 1119
[78]	Saenger K L, Tsang J C, Bol A A, Chu J O, Grill A, Lavoie C 2010 Appl. Phys. Lett. 96 153105
[79]	Somani P R, Somani S P, Umeno M 2006 Chem. Phys. Lett. 430 56
[80]	Andersson O E, Prasad B L V, Sato H, Enoki T, Hishiyama Y, Kaburagi Y, Yoshikawa M, Bandow S 1998 Phys. Rev. B 58 16387
[81]	Cai W W, Piner R D, Stadermann F J, Park S, Shaibat M A, Ishii Y, Yang D X, Velamakanni A, An S J, Stoller M, An J H, Chen D M, Ruoff R S 2008 Science 321 1815
[82]	Chae S J, Gunes F, Kim K K, Kim E S, Han G H, Kim S M, Shin H J, Yoon S M, Choi J Y, Park M H, Yang C W, Pribat D, Lee Y H 2009 Adv. Mater. 21 2328
[83]	Terasawa T, Saiki K 2012 Carbon 50 869
[84]	Gao J H, Fujita D, Xu M S, Onishi K, Miyamoto S 2010 Acs Nano 4 1026
[85]	Rummeli M H, Bachmatiuk A, Scott A, Borrnert F, Warner J H, Hoffman V, Lin J H, Cuniberti G, Buchner B 2010 Acs Nano 4 4206
[86]	Gao L, Guest J R, Guisinger N P 2010 Nano Lett. 10 3512
[87]	Yazyev O V, Louie S G 2010 Nat. Mater. 9 806
[88]	Meng L, Sun Q, Wang J, Ding F 2012 J. Phys. Chem. C 116 6097
[89]	Nakajima T, Shintani K 2009 J. Appl. Phys. 106 114305
[90]	Giovannetti G, Khomyakov P A, Brocks G, Karpan V M, van den Brink J, Kelly P J 2008 Phys. Rev. Lett. 101 026803
[91]	Saadi S, Abild-Pedersen F, Helveg S, Sehested J, Hinnemann B, Appel C C, Norskov J K 2010 J. Phys. Chem. C 114 11221
[92]	Xu Z, Buehler M J 2010 J. Phys. Condensed Matter 22 485301
[93]	Yu Q K, Jauregui L A, Wu W, Colby R, Tian J F, Su Z H, Cao H L, Liu Z H, Pandey D, Wei D G, Chung T F, Peng P, Guisinger N P, Stach E A, Bao J M, Pei S S, Chen Y P 2011 Nat. Mater. 10 443
[94]	Li X, Magnuson C W, Venugopal A, Tromp R M, Hannon J B, Vogel E M, Colombo L, Ruoff R S 2011 J. Am. Chem. Soc. 133 2816
[95]	Gao L, Ren W, Xu H, Jin L, Wang Z, Ma T, Ma L P, Zhang Z, Fu Q, Peng L M, Bao X, Cheng H M 2012 Nat. Comms. 3 699
[96]	Pan Y, Zhang H G, Shi D X, Sun J T, Du S X, Liu F, Gao H J 2009 Adv. Mater. 21 2777
[97]	Chen X, Liu S, Liu L, Liu X, Liu X, Wang L 2012 Appl. Phys. Lett. 100 163106
[98]	Allen M J, Tung V C, Kaner R B 2010 Chem. Rev. 110 132
[99]	Fu Q, Bao X H 2009 Chin. Sci. Bull. 2657 (in Chinese) [傅强, 包信和 2009 科学通报 2657]
[100]	Yang Q H 2011 New Carbon Mater. 1 (in Chinese) [杨全红 2011 新型炭材料 1]
[101]	Tan C L, Tan Z B, Ma L, Chen J, Yang F, Qu F M, Liu G T, YangH F, Yang C L, Lv L 2009 Acta Phys. Sin. 58 5726 (in Chinese) [谭长玲, 谭振兵, 马丽, 陈军, 杨帆, 屈凡明, 刘广同, 杨海方, 杨昌黎, 吕力 2009 58 5726]
[102]	Wang L, Tian L H, Wei G D, Gao F M, Zheng J J, Yang W Y 2011 J. Inorg. Mater. 1009 (in Chinese) [王霖, 田林海, 尉国栋, 高凤梅, 郑金桔, 杨为佑 2011 无机材料学报 1009]
[103]	Hu H X, Zhang Z H, Liu X H, Qiu M, Ding K H 2010 Acra Phys. Sin. 59 7156 (in Chinese) [胡海鑫, 张振华, 刘新海, 邱明, 丁开和 2010 59 7156]
[104]	Hu Y J, Jin J, Zhang H, Wu P, Cai C X 2010 Acta Phys. Chim. Sin. 26 2073 (in Chinese) [胡耀娟, 金娟, 张卉, 吴萍, 蔡称心 2010 物理化学学报 26 2073]
[105]	Xu X J, Qin J G, Li Z 2009 Prog. Chem. 79 (in Chinese) [徐秀娟, 秦金贵, 李振 2009 化学进展 79]
[106]	Huang H R, Chen J 2009 Carbon techniques 35 (in Chinese) [黄桂荣, 陈建 2009 炭素技术 35]
[107]	Ma S Q, Pei L Z, Kang Y J 2009 Modern Physics 44 (in Chinese) [马圣乾, 裴立振, 康英杰 2009 现代物理知识 44]
[108]	Yang Q G, Lv W, Yang Y G, Wang M Z 2008 New Carbon Mater. 97 (in Chinese) [杨全红, 吕伟, 杨永岗, 王茂章 2008 新型炭材料 97]
[109]	Li X, Zhao W F, Chen G H 2008 Materials Review 48 (in Chinese) [李旭, 赵卫峰, 陈国华 2008 材料导报 48]
[110]	Gu Z B, Ji G H, Lu M H 2010 J. Nanjing University of Technology (Natural Science Edition) 105 (in Chinese) [顾正彬, 季根华, 卢明辉 2010 南京工业大学学报 (自然科学版) 105]

施引文献

[1]	Novoselov K 2011 Rev. Mod. Phys. 83 837
[2]	Novoselov K 2004 Science 306 66
[3]	Peierls R 1935 Annals de l'I. H. P. 5 p177
[4]	Landau L 1937 Phys. Z. Sowjetunion 11 p26
[5]	Stoller M D, Park S, Zhu Y, An J, Ruoff R S 2008 Nano Lett. 8 3498
[6]	Nair R R, Blake P, Grigorenko A N, Novoselov K S, Booth T J, Stauber T, Peres N M R, Geim A K 2008 Science 320 1308
[7]	Stauber T, Peres N M R, Geim A K 2008 Phys. Rev. B 78 085418
[8]	Lee C, Wei X, Kysar J W, Hone J 2008 Science 321 385
[9]	Balandin A A, Ghosh S, Bao W Z, Calizo I, Teweldebrhan D, Miao F, Lau C N 2008 Nano Lett. 8 902
[10]	Areshkin D A, White C T 2007 Nano Lett. 7 3253
[11]	Geim A K, Novoselov K S 2007 Nat. Mater. 6 183
[12]	Wei D, Liu Y 2010 Adv. Mater. 22 3225
[13]	Geim A K 2009 Science 324 1530
[14]	Singh V, Joung D, Zhai L, Das S, Khondaker S I, Seal S 2011 Prog. Mater Sci. 56 1178
[15]	Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y, Wu Y, Nguyen S T, Ruoff R S 2007 Carbon 45 1558
[16]	Park S, Ruoff R S 2009 Nat. Nanotechnol. 4 217
[17]	Yang X Y, Dou X, Rouhanipour A, Zhi L J, Rader H J, Mullen K 2008 JACS 130 4216
[18]	Berger C 2006 Science 312 1191
[19]	Weatherup R S, Bayer B C, Blume R, Ducati C, Baehtz C, Schlögl R, Hofmann S 2011 Nano Lett. 11 4154
[20]	Huang H, Chen W, Chen S, Wee A T S 2008 Acs Nano 2 2513
[21]	Berger C, Song Z M, Li T B, Li X B, Ogbazghi A Y, Feng R, Dai Z T, Marchenkov A N, Conrad E H, First P N, de Heer W A 2004 J. Phys. Chem. B 108 19912
[22]	Emtsev K V, Bostwick A, Horn K, Jobst J, Kellogg G L, Ley L, McChesney J L, Ohta T, Reshanov S A, Rohrl J, Rotenberg E, Schmid A K, Waldmann D, Weber H B, Seyller T 2009 Nat. Mater. 8 203
[23]	Pan Y, Zhang H G, Shi D X, Sun J T, Du S X, Liu F, Gao H J 2009 Adv. Mater. 21 2739
[24]	Zhang H, Fu Q, Cui Y, Tan D L, Bao X H 2009 Chin. Sci. Bull. 1860 (in Chinese) [张辉, 傅强, 崔义, 谭大力, 包信和 2009 科学通报 1860]
[25]	Sutter P W, Flege J I, Sutter E A 2008 Nat. Mater. 7 406
[26]	Campos-Delgado J, Romo-Herrera J M, Jia X T, Cullen D A, Muramatsu H, Kim Y A, Hayashi T, Ren Z F, Smith D J, Okuno Y, Ohba T, Kanoh H, Kaneko K, Endo M, Terrones H, Dresselhaus M S, Terrones M 2008 Nano Lett. 8 2773
[27]	Di C A, Wei D C, Yu G, Liu Y Q, Guo Y L, Zhu D B 2008 Adv. Mater. 20 3289
[28]	Shang N G, Papakonstantinou P, McMullan M, Chu M, Stamboulis A, Potenza A, Dhesi S S, Marchetto H 2008 Adv. Funct. Mater. 18 3506
[29]	Li X, Cai W, An J, Kim S, Nah J, Yang D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L, Ruoff R S 2009 Science 324 1312
[30]	Bae S, Kim H, Lee Y, Xu X F, Park J S, Zheng Y, Balakrishnan J, Lei T, Kim H R, Song Y I, Kim Y J, Kim K S, Ozyilmaz B, Ahn J H, Hong B H, Iijima S 2010 Nat. Nanotechnol. 5 574
[31]	Chen Z P, Ren W C, Liu B L, Gao L B, Pei S F, Wu Z S, Zhao J P, Cheng H M 2010 Carbon 48 3543
[32]	Wei D C, Liu Y Q, Zhang H L, Huang L P, Wu B, Chen J Y, Yu G 2009 JACS 131 11147
[33]	Ren W C, Gao L B, Ma L P, Cheng H M 2011 New Carbon Mater. 71 (in Chinese) [任文才高力波, 马来鹏, 成会明 2011 新型炭材料 71]
[34]	Juang Z Y, Wu C Y, Lo C W, Chen W Y, Huang C F, Hwang J C, Chen F R, Leou K C, Tsai C H 2009 Carbon 47 2026
[35]	Hofrichter J, Szafranek B u N, Otto M, Echtermeyer T J, Baus M, Majerus A, Geringer V, Ramsteiner M, Kurz H 2010 Nano Lett. 10 36
[36]	Fujita J I, Ueki R, Miyazawa Y, Ichihashi T 2009 J. Vac. Sci. Technol. B 27 3063
[37]	Zheng M, Takei K, Hsia B, Fang H, Zhang X, Ferralis N, Ko H, Chueh Y L, Zhang Y, Maboudian R, Javey A 2010 Appl. Phys. Lett. 96 063110
[38]	Rodriguez Manzo J A, Pham Huu C, Banhart F 2011 Acs Nano 5 1529
[39]	Orofeo C M, Ago H, Hu B, Tsuji M 2011 Nano Research 4 531
[40]	Ji H X, Hao Y F, Ren Y J, Charlton M, Lee W H, Wu Q Z, Li H F, Zhu Y W, Wu Y P, Piner R, Ruoff R S 2011 Acs Nano 5 7656
[41]	Liu N, Fu L, Dai B, Yan K, Liu X, Zhao R, Zhang Y, Liu Z 2011 Nano Lett. 11 297
[42]	Sun Z, Yan Z, Yao J, Beitler E, Zhu Y, Tour J M 2010 Nature 468 549
[43]	Perdigão L S M A, Sabki S N, Garfitt J M, Capiod P, Beton P H 2011 J. Phys. Chem. C 115 7472
[44]	Garaj S, Hubbard W, Golovchenko J A 2010 Appl. Phys. Lett. 97 183103
[45]	Kaplas T, Sharma D, Suirko, Y 2012 Carbon 50 1503
[46]	Sun J, Cole M, Ahmad S, Backe O, Ive T, Loffler M, Lindvall N, Olsson E, Teo K, Liu J, Larsson A, Yurgens A, Haglund A 2011 IEEE T. Semiconduct. M 99 1
[47]	Sun J, Lindvall N, Cole M, Teo K, Yurgens A 2011 Appl. Phys. Lett. 98 252107
[48]	Jerng S K, Lee J H, Yu D S, Kim Y S, Ryou J, Hong S, Kim C, Yoon S, Chun S H 2012 J. Phys. Chem. C 116 7380
[49]	Tang J, Kang C Y, Li L M, Yan W S, Wei S Q, Xu P S 2011 Physica E 43 1415
[50]	Chen J Y, Wen Y G, Guo Y L, Wu B, Huang L P, Xue Y Z, Geng D C, Wang D, Yu G, Liu Y Q 2011 J. Am. Chem. Soc. 133 17548
[51]	Li X S, Cai W W, Colombo L, Ruoff R S 2009 Nano Lett. 9 4268
[52]	Shahil K M F, Balandin A A 2012 Nano Lett. 12 861
[53]	Katsnelson M I 2007 Mater. Today 10 20
[54]	Rao C N R, Biswas K, Subrahmanyam K S, Govindaraj A 2009 J. Mater. Chem. 19 2457
[55]	Seyller T, Bostwick A, Emtsev K V, Horn K, Ley L, McChesney J L, Ohta T, Riley J D, Rotenberg E, Speck F 2008 Phys. Status Solidi B 245 1436
[56]	Hass J, de Heer W A, Conrad E H 2008 J. Phys. Condensed Matter 20 323202
[57]	Unarunotai S, Murata Y, Chialvo C E, Kim H S, MacLaren S, Mason N, Petrov I, Rogers J A 2009 Appl. Phys. Lett. 95 202101
[58]	Rollings E, Gweon G, Zhou S, Mun B, McChesney J, Hussain B, Fedorov A, First P, Deheer W, Lanzara A 2006 J. Phys. Chem. Solids 67 2172
[59]	Camara N, Rius G, Huntzinger J R, Tiberj A, Mestres N, Godignon P, Camassel J 2008 Appl. Phys. Lett. 93 123503
[60]	Kim K J, Lee H, Choi J H, Lee H K, Kang T H, Kim B, Kim S J 2008 Phys. Condens Mat. 20 225017
[61]	Sutter E, Acharya D P, Sadowski J T, Sutter P 2009 Appl. Phys. Lett. 94 133101
[62]	Sutter E, Albrecht P, Sutter P 2009 Appl. Phys. Lett. 95 133109
[63]	Moritz W, Wang B, Bocquet M L, Brugger T, Greber T, Wintterlin J, Gunther S 2010 Phys. Rev. Lett. 104 136102
[64]	Kaplas T, Sharma D, Suirko Y 2012 Carbon 50 1503
[65]	Kim K S, Zhao Y, Jang H, Lee S Y, Kim J M, Kim K S, Ahn J H, Kim P, Choi J Y, Hong B H 2009 Nature 457 706
[66]	Li X S, Zhu Y W, Cai W W, Borysiak M, Han B Y, Chen D, Piner R D, Colombo L, Ruoff R S 2009 Nano Lett. 9 4359
[67]	Gao L, Ren W, Zhao J, Ma L-P, Chen Z, Cheng H-M 2010 Appl. Phys. Lett. 97 183109
[68]	Bhaviripudi S, Jia X T, Dresselhaus M S, Kong J 2010 Nano Lett. 10 4128
[69]	Cai W W, Zhu Y W, Li X S, Piner R D, Ruoff R S 2009 Appl. Phys. Lett. 95 123115
[70]	Reina A, Jia X T, Ho J, Nezich D, Son H B, Bulovic V, Dresselhaus M S, Kong J 2009 Nano Lett. 9 30
[71]	Wintterlin J, Bocquet M L 2009 Surf. Sci. 603 1841
[72]	Dreyer D R, Ruoff R S, Bielawski C W 2010 Angew. Chem. Int. Edit. 49 9336
[73]	Compton O C, Nguyen S T 2010 Small 6 711
[74]	Becerril H A, Mao J, Liu Z, Stoltenberg R M, Bao Z, Chen Y 2008 Acs Nano 2 463
[75]	Dato A, Radmilovic V, Lee Z, Phillips J, Frenklach M 2008 Nano Lett. 8 2012
[76]	Wu Z S, Ren W, Gao L, Liu B, Jiang C, Cheng H M 2009 Carbon 47 493
[77]	Schneider J J 2011 Chemcatchem 3 1119
[78]	Saenger K L, Tsang J C, Bol A A, Chu J O, Grill A, Lavoie C 2010 Appl. Phys. Lett. 96 153105
[79]	Somani P R, Somani S P, Umeno M 2006 Chem. Phys. Lett. 430 56
[80]	Andersson O E, Prasad B L V, Sato H, Enoki T, Hishiyama Y, Kaburagi Y, Yoshikawa M, Bandow S 1998 Phys. Rev. B 58 16387
[81]	Cai W W, Piner R D, Stadermann F J, Park S, Shaibat M A, Ishii Y, Yang D X, Velamakanni A, An S J, Stoller M, An J H, Chen D M, Ruoff R S 2008 Science 321 1815
[82]	Chae S J, Gunes F, Kim K K, Kim E S, Han G H, Kim S M, Shin H J, Yoon S M, Choi J Y, Park M H, Yang C W, Pribat D, Lee Y H 2009 Adv. Mater. 21 2328
[83]	Terasawa T, Saiki K 2012 Carbon 50 869
[84]	Gao J H, Fujita D, Xu M S, Onishi K, Miyamoto S 2010 Acs Nano 4 1026
[85]	Rummeli M H, Bachmatiuk A, Scott A, Borrnert F, Warner J H, Hoffman V, Lin J H, Cuniberti G, Buchner B 2010 Acs Nano 4 4206
[86]	Gao L, Guest J R, Guisinger N P 2010 Nano Lett. 10 3512
[87]	Yazyev O V, Louie S G 2010 Nat. Mater. 9 806
[88]	Meng L, Sun Q, Wang J, Ding F 2012 J. Phys. Chem. C 116 6097
[89]	Nakajima T, Shintani K 2009 J. Appl. Phys. 106 114305
[90]	Giovannetti G, Khomyakov P A, Brocks G, Karpan V M, van den Brink J, Kelly P J 2008 Phys. Rev. Lett. 101 026803
[91]	Saadi S, Abild-Pedersen F, Helveg S, Sehested J, Hinnemann B, Appel C C, Norskov J K 2010 J. Phys. Chem. C 114 11221
[92]	Xu Z, Buehler M J 2010 J. Phys. Condensed Matter 22 485301
[93]	Yu Q K, Jauregui L A, Wu W, Colby R, Tian J F, Su Z H, Cao H L, Liu Z H, Pandey D, Wei D G, Chung T F, Peng P, Guisinger N P, Stach E A, Bao J M, Pei S S, Chen Y P 2011 Nat. Mater. 10 443
[94]	Li X, Magnuson C W, Venugopal A, Tromp R M, Hannon J B, Vogel E M, Colombo L, Ruoff R S 2011 J. Am. Chem. Soc. 133 2816
[95]	Gao L, Ren W, Xu H, Jin L, Wang Z, Ma T, Ma L P, Zhang Z, Fu Q, Peng L M, Bao X, Cheng H M 2012 Nat. Comms. 3 699
[96]	Pan Y, Zhang H G, Shi D X, Sun J T, Du S X, Liu F, Gao H J 2009 Adv. Mater. 21 2777
[97]	Chen X, Liu S, Liu L, Liu X, Liu X, Wang L 2012 Appl. Phys. Lett. 100 163106
[98]	Allen M J, Tung V C, Kaner R B 2010 Chem. Rev. 110 132
[99]	Fu Q, Bao X H 2009 Chin. Sci. Bull. 2657 (in Chinese) [傅强, 包信和 2009 科学通报 2657]
[100]	Yang Q H 2011 New Carbon Mater. 1 (in Chinese) [杨全红 2011 新型炭材料 1]
[101]	Tan C L, Tan Z B, Ma L, Chen J, Yang F, Qu F M, Liu G T, YangH F, Yang C L, Lv L 2009 Acta Phys. Sin. 58 5726 (in Chinese) [谭长玲, 谭振兵, 马丽, 陈军, 杨帆, 屈凡明, 刘广同, 杨海方, 杨昌黎, 吕力 2009 58 5726]
[102]	Wang L, Tian L H, Wei G D, Gao F M, Zheng J J, Yang W Y 2011 J. Inorg. Mater. 1009 (in Chinese) [王霖, 田林海, 尉国栋, 高凤梅, 郑金桔, 杨为佑 2011 无机材料学报 1009]
[103]	Hu H X, Zhang Z H, Liu X H, Qiu M, Ding K H 2010 Acra Phys. Sin. 59 7156 (in Chinese) [胡海鑫, 张振华, 刘新海, 邱明, 丁开和 2010 59 7156]
[104]	Hu Y J, Jin J, Zhang H, Wu P, Cai C X 2010 Acta Phys. Chim. Sin. 26 2073 (in Chinese) [胡耀娟, 金娟, 张卉, 吴萍, 蔡称心 2010 物理化学学报 26 2073]
[105]	Xu X J, Qin J G, Li Z 2009 Prog. Chem. 79 (in Chinese) [徐秀娟, 秦金贵, 李振 2009 化学进展 79]
[106]	Huang H R, Chen J 2009 Carbon techniques 35 (in Chinese) [黄桂荣, 陈建 2009 炭素技术 35]
[107]	Ma S Q, Pei L Z, Kang Y J 2009 Modern Physics 44 (in Chinese) [马圣乾, 裴立振, 康英杰 2009 现代物理知识 44]
[108]	Yang Q G, Lv W, Yang Y G, Wang M Z 2008 New Carbon Mater. 97 (in Chinese) [杨全红, 吕伟, 杨永岗, 王茂章 2008 新型炭材料 97]
[109]	Li X, Zhao W F, Chen G H 2008 Materials Review 48 (in Chinese) [李旭, 赵卫峰, 陈国华 2008 材料导报 48]
[110]	Gu Z B, Ji G H, Lu M H 2010 J. Nanjing University of Technology (Natural Science Edition) 105 (in Chinese) [顾正彬, 季根华, 卢明辉 2010 南京工业大学学报 (自然科学版) 105]

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