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本文介绍了一种确定聚合物太阳能电池功能层光学常数和厚度的方法. 该方法借助于特定的色散模型拟合透射率测试曲线以获得功能层光学常数和厚度值. 文中比较了Forouhi-Bloomer和Lorentz-Oscillator模型在体异质结薄膜的透射率拟合计算中的适用性, 计算了poly(3-hexylthiophene)(P3HT)/[6,6]-phenylC61-butyric acid methyl ester (PCBM)和 poly[2-methoxy-5-5(2'-ethyl-hexyloxy)-1,4-phenylenevinylene](MEH-PPV)/PCBM体异质结薄膜的光学常数和厚度. 拟合得到的曲线与实验曲线符合良好, 厚度计算的结果与台阶仪测量结果保持一致, 误差小于4%. 进一步分析得到的热退火和加入高沸点溶剂添加剂后P3HT/PCBM薄膜的光学常数和光学禁带值与相应器件伏安特性相符. 该方法适用于所有体异质结的功能层, 可用于聚合物太阳能电池的膜系优化和在线检测.
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关键词:
- 聚合物太阳能电池 /
- 光学常数 /
- 透过率曲线 /
- Forouhi-Bloomer模型
We present a simple and accurate method of determininy the optical constant and physical thickness of the photoactive layer in a polymer solar cell. The applicabilities of the physics models including Forouhi-Bloomer and Lorentz-Oscillator models in transmission curve fitting are compared. This method is used to calculate the optical constants and film thicknesses of poly(3-hexylthiophene) (P3HT) /[6,6]-phenyl C61-butyric acid methyl ester (PCBM) and poly[2- methoxy-5-5(2'-ethyl-hexyloxy)-1,4-phenylenevinylene](MEH-PPV)/PCBM bulk heterojunction, The calculated transmission curves fit to the experimental ones well. The results accord with those reported in the literature and from the step profiler, and their error is less than 4%. The optical constant and the physical thickness of polymer solar cell after the optimization process including thermal annealing and adding high-boiling-point additive are studied, and the results are consistent with the voltage-current characteristics of the cell. This method is suited for bulk heterojunction films and can be used in polymer solar cell optimization and detection system.-
Keywords:
- polymer solar cells /
- optical constants /
- transmission curve /
- Forouhi-Bloomer model
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[2] Chen H Y, Hou J H, Zhang S Q, Liang Y Y, Yang G W, Yang Y, Yu L P, Wu Y, Li G 2009 Nature Photonics 3 649
[3] Chen H Y, Yang H C, Yang G W, Sista S, Zadoyan R, Li G, Yang Y 2009 J. Phys. Chem. C 113 7946
[4] van Bavel S S, Sourty E, deWith G, Loos J 2009 Nano Lett. 9 507
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[7] Li R H, Meng W M, Peng Y Q, Ma C Z, Wang R S, Xie H W, Wang Y, Ye Z C 2010 Acta Phys. Sin. 59 2126 (in Chinese) [李荣华, 孟卫民, 彭应全, 马朝柱, 汪润生, 谢宏伟, 王颖, 叶早晨 2010 59 2126]
[8] Liu R, Xu S, Zhao S L, Zhang F J, Cao X N, Kong C, Cao W Z, Gong W 2011 Acta Phys. Sin. 60 058801 (in Chinese) [刘瑞, 徐征, 赵谡玲, 张福俊, 曹晓宁, 孔超, 曹文喆, 龚伟 2011 60 058801]
[9] Zhao D W, Tan S T, Ke L, Liu P, Kyaw A K K, Sun X W, Lo G Q, Kwong D L 2010 Solar Energy Materials & Solar Cells 94 985
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[11] Persson N K, 2005 J. Chem. Phys. 123 204718
[12] Mariano C Q, Heliotis G, Xia R, Ariu M, Pintani M, Etchegoin P, Bradley D D C 2005 Adv. Funct Mater 15 925
[13] Weber J W, Calado V E, van de Sanden M C M2010 Appl. Phys. Lett. 97 091904
[14] Macleod H A 2001 Thin-Film Optical Filters 3rd edn (Bristol: Institute of Physics Publishing) p34
[15] Zhu D X, Shen W D, Ye H, Liu X, Zhen H Y 2008 J. Phys. D: Appl. Phys. 41 235104
[16] ShenWD, Liu X, Zhu Y, Zou T, Ye H, Gu P F 2005 Chinese Journal of Semiconductors 26 155 (in Chinese) [沈伟东, 刘旭, 朱勇, 邹桐, 叶辉, 顾培夫 2005 半导体学报 26 155]
[17] Su W T, Li B, Liu D q, Zhang F S 2006 Optical Instruments 28 150 (in Chinese) [苏伟涛, 李斌, 刘定权, 张凤山 2006 光学仪器 28 150]
[18] Laidani N, Bartali R, Gottardi G, Anderle M, Cheyssac P 2008 J. Phys.: Condens Matter 20 015216
[19] Moulé A J, Meerholz K 2007 Appl. Phys. Lett. 91 061901
[20] Moulé A J, Bonekamp J B, Meerholz K 2006 J. Appl. Phys. 100 094503
[21] Koster L J A, Smits E C P, Mihailetchi V D, Blom P W M 2005 Physical Review B 72 085205
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[1] Oosterhout S D, Wienk M M, van BavelS S, ThiedmannR, Koster L J A, Gilot J, Loos J, Schmidt V, Janssen R A J 2011 Nature Materials 8 818
[2] Chen H Y, Hou J H, Zhang S Q, Liang Y Y, Yang G W, Yang Y, Yu L P, Wu Y, Li G 2009 Nature Photonics 3 649
[3] Chen H Y, Yang H C, Yang G W, Sista S, Zadoyan R, Li G, Yang Y 2009 J. Phys. Chem. C 113 7946
[4] van Bavel S S, Sourty E, deWith G, Loos J 2009 Nano Lett. 9 507
[5] Miao X, Peng J B 2010 Acta Phys. Sin. 59 2131 (in Chinese) [徐苗, 彭俊彪 2010 59 2131]
[6] Yu H Z, Wen Y X 2011 Acta Phys. Sin. 60 038401 (in Chinese) [於黄忠, 温源鑫 2011 60 038401]
[7] Li R H, Meng W M, Peng Y Q, Ma C Z, Wang R S, Xie H W, Wang Y, Ye Z C 2010 Acta Phys. Sin. 59 2126 (in Chinese) [李荣华, 孟卫民, 彭应全, 马朝柱, 汪润生, 谢宏伟, 王颖, 叶早晨 2010 59 2126]
[8] Liu R, Xu S, Zhao S L, Zhang F J, Cao X N, Kong C, Cao W Z, Gong W 2011 Acta Phys. Sin. 60 058801 (in Chinese) [刘瑞, 徐征, 赵谡玲, 张福俊, 曹晓宁, 孔超, 曹文喆, 龚伟 2011 60 058801]
[9] Zhao D W, Tan S T, Ke L, Liu P, Kyaw A K K, Sun X W, Lo G Q, Kwong D L 2010 Solar Energy Materials & Solar Cells 94 985
[10] Kim J Y, KimS H, Lee H H, Lee K, Ma W L, Gong X, Heeger A L 2006 Adv. Mater 18 572
[11] Persson N K, 2005 J. Chem. Phys. 123 204718
[12] Mariano C Q, Heliotis G, Xia R, Ariu M, Pintani M, Etchegoin P, Bradley D D C 2005 Adv. Funct Mater 15 925
[13] Weber J W, Calado V E, van de Sanden M C M2010 Appl. Phys. Lett. 97 091904
[14] Macleod H A 2001 Thin-Film Optical Filters 3rd edn (Bristol: Institute of Physics Publishing) p34
[15] Zhu D X, Shen W D, Ye H, Liu X, Zhen H Y 2008 J. Phys. D: Appl. Phys. 41 235104
[16] ShenWD, Liu X, Zhu Y, Zou T, Ye H, Gu P F 2005 Chinese Journal of Semiconductors 26 155 (in Chinese) [沈伟东, 刘旭, 朱勇, 邹桐, 叶辉, 顾培夫 2005 半导体学报 26 155]
[17] Su W T, Li B, Liu D q, Zhang F S 2006 Optical Instruments 28 150 (in Chinese) [苏伟涛, 李斌, 刘定权, 张凤山 2006 光学仪器 28 150]
[18] Laidani N, Bartali R, Gottardi G, Anderle M, Cheyssac P 2008 J. Phys.: Condens Matter 20 015216
[19] Moulé A J, Meerholz K 2007 Appl. Phys. Lett. 91 061901
[20] Moulé A J, Bonekamp J B, Meerholz K 2006 J. Appl. Phys. 100 094503
[21] Koster L J A, Smits E C P, Mihailetchi V D, Blom P W M 2005 Physical Review B 72 085205
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