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The polycrystalline samples of La0.45Ca0.55Mn1-xVxO3(x=0.00, 0.10) have been prepared by the solid-phase reaction. Efects of V5+ substitution for Mn3+/Mn4+ on charge ordering and spin-glass state are studied by X-ray diffraction spectrum, temperature dependence of magnetization, and electron spin resonance spectra. The results indicate that charge ordering of the original system is almost destroyed, and spin-glass state at about 40 K is melted by 10% of V substitution for Mn. The charge ordering phase is destroyed mainly because of V5+ ions substitution for Mn3+/Mn4+, which increases the ratio of Mn3+ to Mn4+ and so causes ferromagnetic double-exchange to be superior to antiferromagnetic super-exchange. In addition, the spin-glass state is melted because V substitution for Mn destroys the formation condition of spin-glass state that a small quantity of ferromagnetic components exist under the antiferromagnetic backgrornd.
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Keywords:
- charge ordering /
- spin-glass state /
- perovskite manganite
[1] Jin S, Tiefel T H, McConmack M, Fastnacht R A, Ramesh R, Chen L H, Rao C N R, Raveau B 1994 Science 264 413
[2] Autret C, Gervais M, Gervais F, Raimboux N, Simon P 2004 Solid State Sci. 6 815
[3] Salamon M B, Jaime M 2001 Rev. Mod. Phys. 73 583
[4] Zener C 1951 Phys. Rev. 82 403
[5] Millis A J, Littlewoo P B, Shraiman B I 1995 Phys. Rev. Lett. 74 5144
[6] Yu J, Zhang J C, Cao G X, Wang S P, Jing C, Cao S X 2006 Acta Phys. Sin. 55 5190 (in Chinese) [俞 坚、 张金仓、 曹桂新、 王仕鹏、 敬 超、 曹世勋 2006 55 5190]
[7] Peng Z S, Guo H Y, Cai Z R, Wang G Y 2008 Chin. J. Low Temp. Phys. 30 298 (in Chinese) [彭振生、 郭焕银、 蔡之让、 王桂英 2008 低温 30 298]
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[11] Chen C H, Cheong S W 1996 Phys. Rev. Lett. 76 4042
[12] Mori S, Chen C H, Cheong S W 1998 Nature 392 473
[13] Peng Z S 2004 J. Rare Earths 22 232
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[16] Liang Y, Peng Z S, Yan G Q, Guo H Y, Cai Z R 2005 J. Rare Metals 28 513 (in Chinese) [梁 燕、 彭振生、 严国清、 郭焕银、 蔡之让 2005 稀有金属 28 513]
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[19] Liu N, Yan G Q, Cai Z R, Guo H Y, Peng Z S, Qu Z, Zhang Y H 2005 Chin. Sci. Bull. 50 1492 (in Chinese) [刘 宁、 严国清、 蔡之让、 郭焕银、 彭振生、 曲 哲、 张裕恒 2005 科学通报 50 1492]
[20] Rivadulla F, Freita-Alvite M, Lopez-Quinteal M A 2002 J. Appl. Phys. 91 785
[21] Kuwahara H, Tomioka Y, Asamitsu A, Moritomo Y, Tokura Y 1995 Science 270 961
[22] Asamitsu A, TomiokaY, Kuwahara H, Tokura Y 1997 Nature 388 55
[23] Tokunaga M, Miura N , TomikaY, Tokura Y 1998 Phys. Rev. B 57 5259
[24] Damay F, Maignan A, Martin C, Raveah B 1997 J. Appl. Phys. 82 1458
[25] Li R W, Sun J R, Wang Z H, Zhang S Y, Tong N, Shen B G 2000 J. Appl. Phys. 88 7041
[26] Damay F, Martin C, Maignan A, Hervien M, Raveah B 1998 Appl. Phys. Lett. 73 3772
[27] Zhu Y W, Fang J, Huang Z, Gao B J 2003 Chin. J. Low Temp. Phys. 25 151 (in Chinese) [朱永文、 方 军、 黄 真、 高秉钧 2003 低温 25 151]
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[29] Wang S P, Zhang J C, Cao G X, Yu J, Jing C, Cao S X 2006 Acta Phys. Sin. 55 367 (in Chinese) [王仕鹏、 张金仓、 曹桂新、 俞 坚、 敬 超、 曹世勋 2006 55 367]
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[31] Chen Z P, Wang C M, Li Y F, Su Y L, Liu D W, Li T, Zhang J C 2009 Cryo. Supercond. 37 76 (in Chinese) [陈镇平、 王春梅、 李越峰、 苏玉玲、 刘德伟、 李 涛、 张金仓 2009 低温与超导 37 76]
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[1] Jin S, Tiefel T H, McConmack M, Fastnacht R A, Ramesh R, Chen L H, Rao C N R, Raveau B 1994 Science 264 413
[2] Autret C, Gervais M, Gervais F, Raimboux N, Simon P 2004 Solid State Sci. 6 815
[3] Salamon M B, Jaime M 2001 Rev. Mod. Phys. 73 583
[4] Zener C 1951 Phys. Rev. 82 403
[5] Millis A J, Littlewoo P B, Shraiman B I 1995 Phys. Rev. Lett. 74 5144
[6] Yu J, Zhang J C, Cao G X, Wang S P, Jing C, Cao S X 2006 Acta Phys. Sin. 55 5190 (in Chinese) [俞 坚、 张金仓、 曹桂新、 王仕鹏、 敬 超、 曹世勋 2006 55 5190]
[7] Peng Z S, Guo H Y, Cai Z R, Wang G Y 2008 Chin. J. Low Temp. Phys. 30 298 (in Chinese) [彭振生、 郭焕银、 蔡之让、 王桂英 2008 低温 30 298]
[8] Xu M X, Jiao Z K 1998 Acta Phys. Sin. 47 1007 (in Chinese) [徐明祥、 焦正宽1998 47 1007]
[9] Kiryukhin V, Casa D, Hill J P, Keimer B, Vigliante A, Tomioka Y, Tokura Y 1997 Nature 386 813
[10] Li X J, Wang Q 2009 Acta Phys. Sin. 58 6482 (in Chinese) [李晓娟、 王 强 2009 58 6482]
[11] Chen C H, Cheong S W 1996 Phys. Rev. Lett. 76 4042
[12] Mori S, Chen C H, Cheong S W 1998 Nature 392 473
[13] Peng Z S 2004 J. Rare Earths 22 232
[14] Vanitha P V, Singh R S, Natarajan S, Rao C N R 1998 J. Solid State Chem. 137 365
[15] Wang G Y, Yan G Q, Mao Q, Liu N, Peng Z S, Guo H Y 2009 Chin. Rare Earths 30 10 (in Chinese) [王桂英、 严国清、 毛 强、 刘 宁、 彭振生、 郭焕银 2009 稀土 30 10]
[16] Liang Y, Peng Z S, Yan G Q, Guo H Y, Cai Z R 2005 J. Rare Metals 28 513 (in Chinese) [梁 燕、 彭振生、 严国清、 郭焕银、 蔡之让 2005 稀有金属 28 513]
[17] Qu Z, Pi L, Fan J Y, Zhang B, Zhang T, Tan S, Zhang B, Zhang M, Zhang Y H 2007 Chin. Phys. 16 258
[18] Shu M M, Cao S X, Gao T, Yuan S J, Kang B J, Yu L M, Zhang J C 2009 Acta Phys. Sin. 58 3309 (in Chinese) [舒苗苗、 曹世勋、 高 湉、 袁淑娟、 康保娟、 郁黎明、 张金仓 2009 58 3309]
[19] Liu N, Yan G Q, Cai Z R, Guo H Y, Peng Z S, Qu Z, Zhang Y H 2005 Chin. Sci. Bull. 50 1492 (in Chinese) [刘 宁、 严国清、 蔡之让、 郭焕银、 彭振生、 曲 哲、 张裕恒 2005 科学通报 50 1492]
[20] Rivadulla F, Freita-Alvite M, Lopez-Quinteal M A 2002 J. Appl. Phys. 91 785
[21] Kuwahara H, Tomioka Y, Asamitsu A, Moritomo Y, Tokura Y 1995 Science 270 961
[22] Asamitsu A, TomiokaY, Kuwahara H, Tokura Y 1997 Nature 388 55
[23] Tokunaga M, Miura N , TomikaY, Tokura Y 1998 Phys. Rev. B 57 5259
[24] Damay F, Maignan A, Martin C, Raveah B 1997 J. Appl. Phys. 82 1458
[25] Li R W, Sun J R, Wang Z H, Zhang S Y, Tong N, Shen B G 2000 J. Appl. Phys. 88 7041
[26] Damay F, Martin C, Maignan A, Hervien M, Raveah B 1998 Appl. Phys. Lett. 73 3772
[27] Zhu Y W, Fang J, Huang Z, Gao B J 2003 Chin. J. Low Temp. Phys. 25 151 (in Chinese) [朱永文、 方 军、 黄 真、 高秉钧 2003 低温 25 151]
[28] Guo H Y, Liu N, Cai Z R, Zhang Y H 2006 Acta Phys. Sin. 55 865 (in Chinese) [郭焕银、 刘 宁、 蔡之让、 张裕恒 2006 55 865]
[29] Wang S P, Zhang J C, Cao G X, Yu J, Jing C, Cao S X 2006 Acta Phys. Sin. 55 367 (in Chinese) [王仕鹏、 张金仓、 曹桂新、 俞 坚、 敬 超、 曹世勋 2006 55 367]
[30] Kundaliya D C, Vij R, Kulkarni R G, Tulapurkar A A, Pinto R, Malik S K, Yelon W B 2003 J. Magn. Magn. Mater. 264 62
[31] Chen Z P, Wang C M, Li Y F, Su Y L, Liu D W, Li T, Zhang J C 2009 Cryo. Supercond. 37 76 (in Chinese) [陈镇平、 王春梅、 李越峰、 苏玉玲、 刘德伟、 李 涛、 张金仓 2009 低温与超导 37 76]
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