Sol-gel deposition of highly reflective multilayer coatings from PVP-ZrO2 hybrid systems

Liang Li-Ping; Zhang Lei; Xu Yao; Zhang Bin; Wu Dong; Sun Yu-Han; Jiang Xiao-Dong; Wei Xiao-Feng; Li Zhi-Hong; Wu Zhong-Hua

doi:10.7498/aps.55.6175

Abstract
A series of ZrO2 and polyvinylpyrrolidone (PVP) doped-ZrO2 sols have been synthesized by the controlled hydrolysis and condensation of zirconium n-propoxide, with diethanolamine (DEA) as the chelating agent. PVP-ZrO2 hybrid monolayers and highly reflective (HR) multilayer coatings were then prepared by spin-coating the stable sols on K9 glass substrates. The fabrication of the HR coatings involves alternate depositions of PVP-ZrO2 (as the high-index material) and SiO2 (as the low-index material) layers. The microstructures of the sols, the structural and optical properties, as well as the laser damage resistance of the films were thoroughly characterized. By virtue of the small angle X-ray scattering (SAXS) analysis, the sol-gel processing parameters were successfully optimized, endowing the as-prepared films with good optical properties and high laser damage resistance. SAXS studies also offer the possibility to a good knowledge of the microstructure of the sols. In our hybrid system, the unhydrolyzed DEA ligands, which become anchored in the inorganic network, may considerably weaken the effects of PVP on the formation and growth of ZrO2 particles. Hence, the incorporation of a proper amount of PVP gives rise to negligible change of the sol structure and only a slight variation in refractive index and laser damage resistance of the films. However, at the slight expense of the refractive index and laser damage resistance, the incorporation of PVP can easily alleviate the stress incompatibility between different layers and facilitate the fabrication of the multilayer coatings. As the mass fraction of PVP reaches 15%—20%, a perfect match between different layers can be achieved, which ensures the successful deposition of 21-layer, nearly full-reflection coatings with the minimum transmittance of about 1.6%—2.1% (at 1064nm) and high laser damage threshold of 16.4—18.2J/cm2 (at 1064nm, 1ns pulse duration and R/1 mode).

Keywords:
sol-gel /

PVP-ZrO2 /

highly reflective coating /

laser-induced damage
Authors and contacts
Liang Li-Ping⁴,

Zhang Lei⁵,

Xu Yao³,

Zhang Bin³,

Wu Dong³,

Sun Yu-Han³,

Jiang Xiao-Dong¹,

Wei Xiao-Feng¹,

Li Zhi-Hong²,

Wu Zhong-Hua²

(1)中国工程物理研究院激光聚变研究中心，绵阳 621900; (2)中国科学院高能物理研究所同步辐射实验室,北京 100049; (3)中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原 030001; (4)中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原 030001；太原科技大学材料科学与工程学院,太原 030024；中国科学院研究生院,北京 100049; (5)中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原 030001；中国科学院研究生院,北京 100049；中国工程物理研究院激光聚变研究中心，绵阳 621900
References

Cited By

[1]	Zhang Li-Juan, Zhang Chuan-Chao, Chen Jing, Bai Yang, Jiang Yi-Lan, Jiang Xiao-Long, Wang Hai-Jun, Luan Xiao-Yu, Yuan Xiao-Dong, Liao Wei. Formation and control of bubbles during the mitigation of laser-induced damage on fused silica surface. Acta Physica Sinica, 2018, 67(1): 016103. doi: 10.7498/aps.67.20171839
[2]	Guo Zhao-Long, Zhao Hai-Xin, Zhao Wei. Preparation and characterization of self-cleaning and anti-reflection ZnO-SiO2 nanometric films. Acta Physica Sinica, 2016, 65(6): 064206. doi: 10.7498/aps.65.064206
[3]	Liu Chong, Ji Lai-Lin, Zhu Bao-Qiang, Lin Zun-Qi. Numerical simulation analysis of high efficient SFG and color separation in far field in high power laser facility based on noncollinear phase matching by KDP crystal. Acta Physica Sinica, 2016, 65(14): 144202. doi: 10.7498/aps.65.144202
[4]	Han Wei, Feng Bin, Zheng Kui-Xing, Zhu Qi-Hua, Zheng Wan-Guo, Gong Ma-Li. Laser-induced damage growth of fused silica at 351 nm on a large-aperture high-power laser facility. Acta Physica Sinica, 2016, 65(24): 246102. doi: 10.7498/aps.65.246102
[5]	Sun Xiao-Yan, Lei Ze-Min, Lu Xing-Qiang, Fan Dian-Yuan. Mechanism of original damage of thin optical components induced by surface particle contamination. Acta Physica Sinica, 2014, 63(13): 134201. doi: 10.7498/aps.63.134201
[6]	Liu Yi, Zhang Qing, Li Hai-Jin, Li Yong, Liu Hou-Tong. Temperature dependence of electrical resistivity for Sr-doped perovskite-type oxide Y1-xSrxCoO3 prepared by sol-gel process. Acta Physica Sinica, 2013, 62(4): 047202. doi: 10.7498/aps.62.047202
[7]	Liu Hong-Jie, Wang Feng-Rui, Luo Qing, Zhang Zhen, Huang Jin, Zhou Xin-Da, Jiang Xiao-Dong, Wu Wei-Dong, Zheng Wan-Guo. Experimental comparison of damage performance induced by nanosecond 1 laser between K9 and fused silica optics. Acta Physica Sinica, 2012, 61(7): 076103. doi: 10.7498/aps.61.076103
[8]	Zhuang Xiao-Bo, Xia Hai-Ping. Nonlinear absorption properties of Cu(II)meso-tetra(4-sulfonatopheny1) porphine in TiO2/SiO2 organic-inorganic gel using Z-scan technique. Acta Physica Sinica, 2012, 61(18): 184213. doi: 10.7498/aps.61.184213
[9]	Wang Kun-Peng, Yan Shi. S substituting for P point defect-induced laser damage in KDP crystals. Acta Physica Sinica, 2011, 60(9): 097401. doi: 10.7498/aps.60.097401
[10]	Xia Zhi-Lin, Guo Pei-Tao, Xue Yi-Yu, Huang Cai-Hua, Li Zhan-Wang. Investigation of the plasma bursting process in short pulsed laser induced film damage. Acta Physica Sinica, 2010, 59(5): 3523-3530. doi: 10.7498/aps.59.3523
[11]	Zhao Xing-Hai, Hu Jian-Ping, Gao Yang, Pan Feng, Ma Ping. Laser induced damage and fracture of optical fiber in vacuum chamber. Acta Physica Sinica, 2010, 59(6): 3917-3923. doi: 10.7498/aps.59.3917
[12]	Liu Hong-Jie, Huang Jin, Wang Feng-Rui, Zhou Xin-Da, Jiang Xiao-Dong, Wu Wei-Dong. Effect of thermal stresses on fused silica surface on the laser induced damage. Acta Physica Sinica, 2010, 59(2): 1308-1313. doi: 10.7498/aps.59.1308
[13]	Wang De-Yi, Gao Shu-Xia, Li Gang, Zhao Ming. The structure，optical and electrical properties of Li-N dual-acceptor doped p-type ZnO thin films prepared by sol-gel method. Acta Physica Sinica, 2010, 59(5): 3473-3480. doi: 10.7498/aps.59.3473
[14]	Yang Chang-Hu, Ma Zhong-Quan, Xu Fei, Zhao Lei, Li Feng, He Bo. Raman spectral analysis of TiO2 thin films doped with rare-earth yttrium and lanthanum. Acta Physica Sinica, 2010, 59(9): 6549-6555. doi: 10.7498/aps.59.6549
[15]	Wang Xiao-Dong, Shen Jun, Wang Sheng-Zhao, Zhang Zhi-Hua. Optical constants of sol-gel derived TiO2 films characterized by spectroscopic ellipsometry. Acta Physica Sinica, 2009, 58(11): 8027-8032. doi: 10.7498/aps.58.8027
[16]	Liang Li-Ping, Zhang Lei, Sheng Yong-Gang, Xu Yao, Wu Dong, Sun Yu-Han, Jiang Xiao-Dong, Wei Xiao-Feng. Studies on the laser-induced damage resistance of sol-gel derived ZrO2-TiO2 composite high refractive index films. Acta Physica Sinica, 2007, 56(6): 3596-3601. doi: 10.7498/aps.56.3596
[17]	Liang Li-Ping, Xu Yao, Zhang Lei, Wu Dong, Sun Yu-Han, Li Zhi-Hong, Wu Zhong-Hua. Sol-gel processing of ZrO2 and polymer doped-ZrO2 monolayer reflective films with high laser damage threshold. Acta Physica Sinica, 2006, 55(8): 4371-4382. doi: 10.7498/aps.55.4371
[18]	Zhao Ming-Lei, Wang Chun-Lei, Wang Jin-Feng, Chen Hong-Cun, Zhong Wei-Lie. Enhanced piezoelectric properties of (Bi0.5Na0.5)1－xBax TiO3 lead-free ceramics by sol-gel method. Acta Physica Sinica, 2004, 53(7): 2357-2362. doi: 10.7498/aps.53.2357
[19]	Zhao Ming-Lei, Wang Chun-Lei, Zhong Wei-Lie, Wang Jin-Feng, Chen Hong-Cun. Electrical properties of (Bi05Na05)TiO3 ceramic prepared by sol-gel method. Acta Physica Sinica, 2003, 52(1): 229-232. doi: 10.7498/aps.52.229
[20]	He Zhi-Wei, Zhen Cong-Mian, Lan Wei, Wang Yin-Yue. Deposition of nanoporous silica thin films by sol-gel. Acta Physica Sinica, 2003, 52(12): 3130-3134. doi: 10.7498/aps.52.3130

Catalog

Vol. 55, Issue 11 - 2006-06-05

Metrics

Abstract views: 9506
PDF Downloads: 1322
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板

Sol-gel deposition of highly reflective multilayer coatings from PVP-ZrO2 hybrid systems

Abstract

Authors and contacts

References

Cited By

Catalog

Metrics

Authors

Referees

About Journal

About

Search

Article

留言板

Sol-gel deposition of highly reflective multilayer coatings from PVP-ZrO2 hybrid systems

Abstract

Authors and contacts

References

Cited By

Catalog

Metrics

Publishing process

Authors

Referees

About Journal

About