Sol-gel processing of ZrO2 and polymer doped-ZrO2 monolayer reflective films with high laser damage threshold

Liang Li-Ping; Xu Yao; Zhang Lei; Wu Dong; Sun Yu-Han; Li Zhi-Hong; Wu Zhong-Hua

doi:10.7498/aps.55.4371

Abstract
A series of ZrO2 and polymer doped-ZrO2 sols have been synthesized by the controlled hydrolysis of zirconium n-propoxide. Acetic acid was used as the chelating agent. Poly(ethylene glycol)(PEG) 200 and polyvinylpyrrolidone(PVP) were introduced to produce the hybrid sols. ZrO2 and the polymer doped-ZrO2 optical thin films were then prepared by spin-coating the stable sols on K9 glass substrates. Effects of various synthetic parameters were studied, on the sol stability, the microstructure of colloidal system, the structural and optical properties of the films, as well as the laser damage resistance. In our reaction systems, both hydrolysis and chelation coexist. The preference for any of the two reactions strongly depends on the system composition and ultimately determines the stability and microstructure of the colloidal system. Besides, the addition of a proper amount of PEG200 and PVP, which probably acts as the competitive ligands, particle surface protective polymers and structure directive agents, can modify the hydrolysis-condensation process, thus producing more stable, uniform sols with mass fractal structure (fm=2.33—2.46) and average particle diameter of 19.1—23.7nm. Benefiting from the precursor sol structure, the polymer doped-films exhibit excellent surface planarity and uniform inner structure, which endows the films with good optical property and excellent laser damage resistance. For instance, the hybrid film with 10% PEG200 and 15% PVP (mass fractions) showed a high laser damage threshold of 24.5J/cm2 (for 1ns pulse duration) and a reflectivity increase of about 2% than that of the substrate at wavelength of about 1000nm.

Keywords:
zirconium dioxide /

sol-gel /

reflective coating /

laser damage
Authors and contacts
Liang Li-Ping³,

Xu Yao²,

Zhang Lei⁴,

Wu Dong²,

Sun Yu-Han²,

Li Zhi-Hong¹,

Wu Zhong-Hua¹

(1)中国科学院高能物理研究所,北京 100049; (2)中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原 030001; (3)中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原 030001；太原科技大学材料科学与工程学院,太原 030024；中国科学院研究生院,北京 100049; (4)中国科学院山西煤炭化学研究所煤转化国家重点实验室,太原 030001；中国科学院研究生院,北京 100049;中国工程物理研究院激光聚变研究中心，绵阳 621900
References

Cited By

[1]	Zhang Li-Juan, Zhang Chuan-Chao, Chen Jing, Bai Yang, Jiang Yi-Lan, Jiang Xiao-Long, Wang Hai-Jun, Luan Xiao-Yu, Yuan Xiao-Dong, Liao Wei. Formation and control of bubbles during the mitigation of laser-induced damage on fused silica surface. Acta Physica Sinica, 2018, 67(1): 016103. doi: 10.7498/aps.67.20171839
[2]	Liu Chong, Ji Lai-Lin, Zhu Bao-Qiang, Lin Zun-Qi. Numerical simulation analysis of high efficient SFG and color separation in far field in high power laser facility based on noncollinear phase matching by KDP crystal. Acta Physica Sinica, 2016, 65(14): 144202. doi: 10.7498/aps.65.144202
[3]	Shen Chao, Cheng Xiang-Ai, Tian Ye, Xu Zhong-Jie, Jiang Tian. Experimental and computational study of damage pocess induced by 1064 nm nanosecond laser pulse on the exit surface of fused silica. Acta Physica Sinica, 2016, 65(15): 155201. doi: 10.7498/aps.65.155201
[4]	Han Wei, Feng Bin, Zheng Kui-Xing, Zhu Qi-Hua, Zheng Wan-Guo, Gong Ma-Li. Laser-induced damage growth of fused silica at 351 nm on a large-aperture high-power laser facility. Acta Physica Sinica, 2016, 65(24): 246102. doi: 10.7498/aps.65.246102
[5]	Guo Zhao-Long, Zhao Hai-Xin, Zhao Wei. Preparation and characterization of self-cleaning and anti-reflection ZnO-SiO2 nanometric films. Acta Physica Sinica, 2016, 65(6): 064206. doi: 10.7498/aps.65.064206
[6]	Sun Xiao-Yan, Lei Ze-Min, Lu Xing-Qiang, Fan Dian-Yuan. Mechanism of original damage of thin optical components induced by surface particle contamination. Acta Physica Sinica, 2014, 63(13): 134201. doi: 10.7498/aps.63.134201
[7]	Liu Yi, Zhang Qing, Li Hai-Jin, Li Yong, Liu Hou-Tong. Temperature dependence of electrical resistivity for Sr-doped perovskite-type oxide Y1-xSrxCoO3 prepared by sol-gel process. Acta Physica Sinica, 2013, 62(4): 047202. doi: 10.7498/aps.62.047202
[8]	Liu Hong-Jie, Wang Feng-Rui, Luo Qing, Zhang Zhen, Huang Jin, Zhou Xin-Da, Jiang Xiao-Dong, Wu Wei-Dong, Zheng Wan-Guo. Experimental comparison of damage performance induced by nanosecond 1 laser between K9 and fused silica optics. Acta Physica Sinica, 2012, 61(7): 076103. doi: 10.7498/aps.61.076103
[9]	Wang Kun-Peng, Yan Shi. S substituting for P point defect-induced laser damage in KDP crystals. Acta Physica Sinica, 2011, 60(9): 097401. doi: 10.7498/aps.60.097401
[10]	Xia Zhi-Lin, Guo Pei-Tao, Xue Yi-Yu, Huang Cai-Hua, Li Zhan-Wang. Investigation of the plasma bursting process in short pulsed laser induced film damage. Acta Physica Sinica, 2010, 59(5): 3523-3530. doi: 10.7498/aps.59.3523
[11]	Zhao Xing-Hai, Hu Jian-Ping, Gao Yang, Pan Feng, Ma Ping. Laser induced damage and fracture of optical fiber in vacuum chamber. Acta Physica Sinica, 2010, 59(6): 3917-3923. doi: 10.7498/aps.59.3917
[12]	Liu Hong-Jie, Huang Jin, Wang Feng-Rui, Zhou Xin-Da, Jiang Xiao-Dong, Wu Wei-Dong. Effect of thermal stresses on fused silica surface on the laser induced damage. Acta Physica Sinica, 2010, 59(2): 1308-1313. doi: 10.7498/aps.59.1308
[13]	Wang De-Yi, Gao Shu-Xia, Li Gang, Zhao Ming. The structure，optical and electrical properties of Li-N dual-acceptor doped p-type ZnO thin films prepared by sol-gel method. Acta Physica Sinica, 2010, 59(5): 3473-3480. doi: 10.7498/aps.59.3473
[14]	Wang Xiao-Dong, Shen Jun, Wang Sheng-Zhao, Zhang Zhi-Hua. Optical constants of sol-gel derived TiO2 films characterized by spectroscopic ellipsometry. Acta Physica Sinica, 2009, 58(11): 8027-8032. doi: 10.7498/aps.58.8027
[15]	Liang Li-Ping, Zhang Lei, Sheng Yong-Gang, Xu Yao, Wu Dong, Sun Yu-Han, Jiang Xiao-Dong, Wei Xiao-Feng. Studies on the laser-induced damage resistance of sol-gel derived ZrO2-TiO2 composite high refractive index films. Acta Physica Sinica, 2007, 56(6): 3596-3601. doi: 10.7498/aps.56.3596
[16]	Liang Li-Ping, Zhang Lei, Xu Yao, Zhang Bin, Wu Dong, Sun Yu-Han, Jiang Xiao-Dong, Wei Xiao-Feng, Li Zhi-Hong, Wu Zhong-Hua. Sol-gel deposition of highly reflective multilayer coatings from PVP-ZrO2 hybrid systems. Acta Physica Sinica, 2006, 55(11): 6175-6184. doi: 10.7498/aps.55.6175
[17]	Zhao Ming-Lei, Wang Chun-Lei, Wang Jin-Feng, Chen Hong-Cun, Zhong Wei-Lie. Enhanced piezoelectric properties of (Bi0.5Na0.5)1－xBax TiO3 lead-free ceramics by sol-gel method. Acta Physica Sinica, 2004, 53(7): 2357-2362. doi: 10.7498/aps.53.2357
[18]	Liu Huang-Qing, Wang Ling-Ling, Qin Wei-Ping. Luminescence of Eu3+ Ions in nanocrystalline zirconia. Acta Physica Sinica, 2004, 53(1): 282-285. doi: 10.7498/aps.53.282
[19]	He Zhi-Wei, Zhen Cong-Mian, Lan Wei, Wang Yin-Yue. Deposition of nanoporous silica thin films by sol-gel. Acta Physica Sinica, 2003, 52(12): 3130-3134. doi: 10.7498/aps.52.3130
[20]	Zhao Ming-Lei, Wang Chun-Lei, Zhong Wei-Lie, Wang Jin-Feng, Chen Hong-Cun. Electrical properties of (Bi05Na05)TiO3 ceramic prepared by sol-gel method. Acta Physica Sinica, 2003, 52(1): 229-232. doi: 10.7498/aps.52.229

Catalog

Vol. 55, Issue 8 - 2006-04-20

Metrics

Abstract views: 8947
PDF Downloads: 1281
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板

Sol-gel processing of ZrO2 and polymer doped-ZrO2 monolayer reflective films with high laser damage threshold

Abstract

Authors and contacts

References

Cited By

Catalog

Metrics

Authors

Referees

About Journal

About

Search

Article

留言板

Sol-gel processing of ZrO2 and polymer doped-ZrO2 monolayer reflective films with high laser damage threshold

Abstract

Authors and contacts

References

Cited By

Catalog

Metrics

Publishing process

Authors

Referees

About Journal

About