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The Raman vibrational spectra of water inside mesoporous silicate are measured in a temperature range of 100 T 303 K. It is found that the Raman spectrum of confined water becomes more different from that of bulk water with the decrease of water content in pores. For samples with high water content in pore, the main peak position of the Raman spectrum of water changes abruptly in a narrow temperature range. However, when water content decreases down to 20%, the red shift of the main peak of the Raman spectrum is continuous with temperature decreasing. At the same time, its temperature-dependence is the same as that of bulk amorphous ice.
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Keywords:
- confined water /
- vibrational property /
- low temperature Raman spectrum /
- interfacial effect
[1] Moilanen D E, Fenn E E., Wong D, Fayer M D 2009 J. Chem. Phys. 131 014704
[2] Soprunyuk V, Wallacher D, Huber P, Knorr K, Kityk A 2003 Phys. Rev. B 67 144105
[3] [4] Binder K, Horbach J, Vink R, De Virgiliis A 2008 Soft Matter 4 1555
[5] [6] Alcoutlabi M, Mckenna G B 2005 J. Phys.: Condens. Matter 17 R461
[7] [8] [9] Alba-Simionesco C, Coasne B, Dosseh G, Dudziak G, Gubbins K E, Radhakrishnan R, Sliwinska-Bartkowiak M 2006 J. Phys.: Condens. Matter 18 R15
[10] [11] Dvoyashkin M, Khokhlov A, Valiullin R, Krger J 2008 J. Chem. Phys. 129 154702
[12] Liu X X, Wang Q, Huang X F, Yang S H, Li C X, Niu X J, Shi Q F, Sun G, Lu K Q 2010 J. Phys. Chem. B 114 4145
[13] [14] [15] Huang X F, Wang Q, Liu X X, Yang S H, Li C X, Sun G, Pan L Q, Lu K Q 2009 J. Phys. Chem. C 113 18768
[16] [17] Fayer M D, Levinger N E 2010 Ann. Rev. Anal. Chem. 3 89
[18] [19] Moore E B, de la Llave E, Welke K, Scherlis D A, Molinero V 2010 Phys. Chem. Chem. Phys. 12 4124
[20] Jhnert S, Vaca Ch醰ez F, Schaumann G E, Schreiber A, Schnhoff M, Findenegg G H 2008 Phys. Chem. Chem. Phys. 10 6039
[21] [22] Kittaka S, Ishimaru S, Kuranishi M, Matsuda T, Yamaguchi T 2006 Phys. Chem. Chem. Phys. 8 3223
[23] [24] [25] Seyed-Yazdi J, Farman H, Dore J C, Webber J B W, Findenegg G H, Hansen T 2008 J. Phys.: Condens. Matter 20 205107
[26] [27] Tombari E, Salvetti G, Ferrari C, Johari G P 2005 J. Chem. Phys. 122 104712
[28] Morishige K 2011 J. Phys. Chem. C 115 12158
[29] [30] [31] Duricković I, Claverie R, Bourson P, Marchetti M, Chassot J M, Fontana M D 2011 J. Raman Spectrosc. 42 1408
[32] Wong P T T, Whalley E 1975 J. Chem. Phys. 62 2418
[33] [34] [35] Grunberg B, Emmler T, Gedat E, Shenderovich I, Findenegg G H, Limbach H H, Buntkowsky G 2004 Chem. Eur. J. 10 5689
[36] Furić K, Volovsek V 2010 J. Mol. Struct. 976 174
[37] [38] Sivakumar T C, Rice S A, Sceats M G 1978 J. Chem. Phys. 69 3468
[39] -
[1] Moilanen D E, Fenn E E., Wong D, Fayer M D 2009 J. Chem. Phys. 131 014704
[2] Soprunyuk V, Wallacher D, Huber P, Knorr K, Kityk A 2003 Phys. Rev. B 67 144105
[3] [4] Binder K, Horbach J, Vink R, De Virgiliis A 2008 Soft Matter 4 1555
[5] [6] Alcoutlabi M, Mckenna G B 2005 J. Phys.: Condens. Matter 17 R461
[7] [8] [9] Alba-Simionesco C, Coasne B, Dosseh G, Dudziak G, Gubbins K E, Radhakrishnan R, Sliwinska-Bartkowiak M 2006 J. Phys.: Condens. Matter 18 R15
[10] [11] Dvoyashkin M, Khokhlov A, Valiullin R, Krger J 2008 J. Chem. Phys. 129 154702
[12] Liu X X, Wang Q, Huang X F, Yang S H, Li C X, Niu X J, Shi Q F, Sun G, Lu K Q 2010 J. Phys. Chem. B 114 4145
[13] [14] [15] Huang X F, Wang Q, Liu X X, Yang S H, Li C X, Sun G, Pan L Q, Lu K Q 2009 J. Phys. Chem. C 113 18768
[16] [17] Fayer M D, Levinger N E 2010 Ann. Rev. Anal. Chem. 3 89
[18] [19] Moore E B, de la Llave E, Welke K, Scherlis D A, Molinero V 2010 Phys. Chem. Chem. Phys. 12 4124
[20] Jhnert S, Vaca Ch醰ez F, Schaumann G E, Schreiber A, Schnhoff M, Findenegg G H 2008 Phys. Chem. Chem. Phys. 10 6039
[21] [22] Kittaka S, Ishimaru S, Kuranishi M, Matsuda T, Yamaguchi T 2006 Phys. Chem. Chem. Phys. 8 3223
[23] [24] [25] Seyed-Yazdi J, Farman H, Dore J C, Webber J B W, Findenegg G H, Hansen T 2008 J. Phys.: Condens. Matter 20 205107
[26] [27] Tombari E, Salvetti G, Ferrari C, Johari G P 2005 J. Chem. Phys. 122 104712
[28] Morishige K 2011 J. Phys. Chem. C 115 12158
[29] [30] [31] Duricković I, Claverie R, Bourson P, Marchetti M, Chassot J M, Fontana M D 2011 J. Raman Spectrosc. 42 1408
[32] Wong P T T, Whalley E 1975 J. Chem. Phys. 62 2418
[33] [34] [35] Grunberg B, Emmler T, Gedat E, Shenderovich I, Findenegg G H, Limbach H H, Buntkowsky G 2004 Chem. Eur. J. 10 5689
[36] Furić K, Volovsek V 2010 J. Mol. Struct. 976 174
[37] [38] Sivakumar T C, Rice S A, Sceats M G 1978 J. Chem. Phys. 69 3468
[39]
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