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Helical formation is fairly ubiquitous in nature. Under certain circumstances, entropy may induce polymer chains to form helical structures. In this article, molecular dynamics is applied to illustrate the conformation behaviors of a polymer bottle brush adsorbed onto the surface of a cylinder with infinite length. The helical conformation of a polymer bottle brush is closely related to the number of branch chains as well as the adsorption energy between the polymer bottle brush and the cylinder. Once the adsorption energy is weak, the polymer bottle brush with enough branch chains may form an entropy-induced complete helical structure. Our results may give a deeper insight into polymer helical structural studies.
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Keywords:
- entropy-induced /
- polymer bottle brush /
- helical structure /
- molecular dynamics
[1] Watson J D, Crick F H C 1953 Nature 171 4356
[2] Sussman J L, Harel M, Frolow F 1991 Science 253 5022
[3] Snir Y, Kamien R 2005 Science 307 1067
[4] Gurevitch I, Srebnik S 2007 Chem. Phys. Lett. 444 96
[5] Gurevitch I, Srebnik S 2008 J. Chem. Phys. 128 144901
[6] Yang Z Y, Zhang D, Zhang L X 2011 Soft Matter 7 6836
[7] Tong H P, Zhang L X, 2012 Acta Phys. Sin. 61 058701 (in Chinese) [仝焕平, 章林溪 2012 61 058701]
[8] Rossi M, Scheffler M, Blum V 2013 J. Phys. Chem. B 18 5574
[9] Tkatchenko A, Scheffler M 2009 Phys. Rev. Lett. 102 073005
[10] Bela, Mulder M 2012 Phys. Rev. Lett. 108 268305
[11] Swope W C, Andersen H C, Berens P H, Wilson K R 1982 J. Chem. Phys. 76 637
[12] Chai A H, Ran S Y, Zhang D, Jiang Y W, Yang G C, Zhang L X, 2013 Chin. Phys. 22 098701
[13] Nap R, Szleifer I 2005 Langmuri 21 12072
[14] Chen Y Y, Zhang Q, Ding J D 2006 J. Chem. Phys. 124 184903
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[1] Watson J D, Crick F H C 1953 Nature 171 4356
[2] Sussman J L, Harel M, Frolow F 1991 Science 253 5022
[3] Snir Y, Kamien R 2005 Science 307 1067
[4] Gurevitch I, Srebnik S 2007 Chem. Phys. Lett. 444 96
[5] Gurevitch I, Srebnik S 2008 J. Chem. Phys. 128 144901
[6] Yang Z Y, Zhang D, Zhang L X 2011 Soft Matter 7 6836
[7] Tong H P, Zhang L X, 2012 Acta Phys. Sin. 61 058701 (in Chinese) [仝焕平, 章林溪 2012 61 058701]
[8] Rossi M, Scheffler M, Blum V 2013 J. Phys. Chem. B 18 5574
[9] Tkatchenko A, Scheffler M 2009 Phys. Rev. Lett. 102 073005
[10] Bela, Mulder M 2012 Phys. Rev. Lett. 108 268305
[11] Swope W C, Andersen H C, Berens P H, Wilson K R 1982 J. Chem. Phys. 76 637
[12] Chai A H, Ran S Y, Zhang D, Jiang Y W, Yang G C, Zhang L X, 2013 Chin. Phys. 22 098701
[13] Nap R, Szleifer I 2005 Langmuri 21 12072
[14] Chen Y Y, Zhang Q, Ding J D 2006 J. Chem. Phys. 124 184903
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