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碲化镉薄膜太阳能电池电学特性参数分析

赵守仁 黄志鹏 孙雷 孙朋超 张传军 邬云华 曹鸿 王善力 褚君浩

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碲化镉薄膜太阳能电池电学特性参数分析

赵守仁, 黄志鹏, 孙雷, 孙朋超, 张传军, 邬云华, 曹鸿, 王善力, 褚君浩

Analysis of electrical property parameters of CdS/CdTe solar cells fabricated by close space-sublimation

Zhao Shou-Ren, Huang Zhi-Peng, Sun Lei, Sun Peng-Chao, Zhang Chuan-Jun, Wu Yun-Hua, Cao Hong, Wang Shan-Li, Chu Jun-Hao
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  • 用inline方式全部近空间升华方法制备n-CdS/p-CdTe取得了~11%的转换效率(AM1.5). 把其中n-CdS层采用磁控溅射方法取得了~10%的转换效率(AM1.5). 基于其电流密度-电压(J-V)曲线和外量子效率曲线, 分析了其拟合关键参数对于电池性能的影响程度, 并从理论分析上把目前器件性能参数与当今前沿性能参数以及其理论值进行比较, 指出了如何提高电池转换效率(η)的方法: 提高开路电压(Voc)、短路电流(Jsc)和填充因子(FF).
    CdS/CdTe Thin film solar cells are grown in a homemade close-space sublimation system where the cell fabrication of p-n junction is carried out in a continuous, in-line process. The best efficiency achieved is about 11% (AM1.5). Another cell is prepared with the same procedure except for the n-CdS layer coated by sputtering(SP), achieving an efficiency of about 10% (AM1.5). Current density-voltage and external quantum efficiency measurements are analyzed and the solar cell performances are characterized. By the comparison between the practical fitted data and theoretical calculations, the method of improving CdS/CdTe solar cell efficiency, i.e., increasing the open-circuit voltage (Voc), short circuit current (Jsc), and fill factor (FF), is proposed.
    • 基金项目: 中国科学院知识创新工程重要方向项目(批准号:KGCX2-YW-38,KGCX2-YW-384)和上海市2012年度"科技创新行动计划"节能减排领域项目(批准号:12dz1201000)资助的课题.
    • Funds: Project supported by the Important Initiatives In the Knowledge Innovation Project of Chinese Academy of Sciences (Grant Nos. KGCX2-YW-38, KGCX2-YW-384), and 2012-Shanghai, "Science and Technology Innovation Action Plan" Energy-Saving Emission Reduction Project, China (Grant No. 12dz1201000).
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    Ferekides C S, Ceekala V, Dugan K, Killian L, Oman D, Swaminathan R, Morel D 1996 AIP Conf. Proc. 353 39

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    Alan L. Fahrenbruch A L 1999 AIP Conf. Proc. 462 48

    [25]

    Kosyachenko L 2010 Solar Energy 6 105

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    Takamoto T, Agui T, Kurita H, Ohmori M 1997 Sol. Energy Mater. Sol. Cells 49 219

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    Green M A 1992 Solar Cells: Operating Principles, Technology and System Applications (1st Ed.) (Kensington: University of New South Wales, NSW) p96

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    Green M A 1981 Solid-State Electron 24 788

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    Marfaing Y 2001 Thin Solid Films 387 123

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    Fahrenbruch A L, Chien K F, Kim D, Lopez-Otero A, Sharps P, Rube R H 1989 Solar Cells 27 137

  • [1]

    Banai R, Blissett C, Buurma C, Colegrove E 2011 Photovoltaic Specialists Conference (PVSC), 37th IEEE Seattle, WA, June 19-24, 2011 p003410

    [2]

    Matin M A, Amin N, Zaharim A, Sopian K 2009 Proceedings of the 8th WSEAS International Conference on Non-linear Analysis, Non-linear Systems and Chaos Wisconsin, USA 2009 p338

    [3]

    Chegaar M, Ouennoughi Z, Guechi F, Langueur H 2003 J. Electron Dev. 2 p17

    [4]

    Kaminski A, Marchand J J, Fave A 1997 Photovoltaic Specialists Conference, Conference Record of the Twenty-Sixth IEEE Anaheim, CA, September 29-October 3, 1997 p203

    [5]

    Rajkanan K, Shewchun J 1979 Solid State Electron 22 193

    [6]

    Chen Y F, Wang X M, Li D, Hong R J, Shen H 2001 Appl. Energy 88 2239

    [7]

    Ferekides C S, Morel D L 2011 Subcontract Report NREL/SR-5200-51605

    [8]

    Wu X Z, Dhere R G, Albin D S, Gessert T A, DeHart C, Keane J C, Duda A, Coutts T J, Asher S, Levi D H, Moutinho H R, Yan Y, Moriarty T, Johnston S, Emery K, Sheldon P 2001 To be Presented at the NCPV Program Review Meeting Lakewood Colorado, US, October 14-17, 2001 p14

    [9]

    Romeo N, Bosio A, Tedeschi R, Canevari V 1999 Sol. Energy Mater. Sol. Cells 58 209

    [10]

    Korevaar B A, Halverson A, Cao J, Choi J, Davila C, Huber W 2013 Thin Solid Films 535 229

    [11]

    Zhao S R, Huang Z P, Sun L, Sun P C, Zhang C J, Wu Y H, Cao H, Wang S L, Chu J H 2013 Acta Phys. Sin. 62 168801 (in Chinese) [赵守仁, 黄志鹏, 孙雷, 孙朋超, 张传军, 邬云华, 曹鸿, 王善力, 褚君浩 2013 62 168801]

    [12]

    Zhao S R, Huang Z P, Sun L, Sun P C, Zhang C J, Wu Y H, Cao H, Huang Z M, Wang S L, Chu J H 2013 Journal of Infrared and Millimeter Waves 32 444 (in Chinese) [赵守仁, 黄志鹏, 孙雷, 孙朋超, 张传军, 邬云华, 曹鸿, 黄志明, 王善力, 褚君浩 2013 红外与毫米波学报 32 444]

    [13]

    Sites J, Pan J 2007 Thin Solid Films 515 6099

    [14]

    Arturo M A 2006 Solar Energy 80 675

    [15]

    Luque A, Hegedus S 2003 Handbook of Photovoltaic Science and Engineering (England: John Wiley & Sons, Ltd) p617

    [16]

    Kosyachenko L A, Grushko E V 2010 Fizikai Tekhnika Poluprovodnikov 44 1422

    [17]

    Ferekides C S, Marinskiy D, Marinskaya S, Tetali B, Oman D, Morel D L 1996 25th PVSC Washington, D.C., USA, May 13-17, p751

    [18]

    Guo J, Kong C Y, Wang W L 2003 Proc. SPIE 5117 157

    [19]

    Siepchen B, Drost C, Späth B, Krishnakumar V, Richter H, Harr M, Bossert S, Grimm M, Häfner K, Modes T, Zywitzki O, Morgner H 2012 Thin Solid Films 535 224

    [20]

    Guo J, Wang W L, Liu G B, Feng L H 2003 J. Chongqing Univ. 26 34 (in Chinese) [郭江, 王万录, 刘高斌, 冯良桓 2003 重庆大学学报 26 34]

    [21]

    Mitchell K W, Fahrenbruch A L, Bube R H 1977 J. Appl. Phys. 48 4365

    [22]

    Oman D M, Dugan K M, Killian J L, Ceekala V, Ferekides C S, Morel D L 1995 Appl. Phys. Lett. 67 1896

    [23]

    Ferekides C S, Ceekala V, Dugan K, Killian L, Oman D, Swaminathan R, Morel D 1996 AIP Conf. Proc. 353 39

    [24]

    Alan L. Fahrenbruch A L 1999 AIP Conf. Proc. 462 48

    [25]

    Kosyachenko L 2010 Solar Energy 6 105

    [26]

    Reference Solar Spectral Irradiance at the Ground at Different Receiving Conditions, 9845-1, Standard of International Organization for Standardization ISO, 1992

    [27]

    Takamoto T, Agui T, Kurita H, Ohmori M 1997 Sol. Energy Mater. Sol. Cells 49 219

    [28]

    Green M A 1992 Solar Cells: Operating Principles, Technology and System Applications (1st Ed.) (Kensington: University of New South Wales, NSW) p96

    [29]

    Green M A 1981 Solid-State Electron 24 788

    [30]

    Marfaing Y 2001 Thin Solid Films 387 123

    [31]

    Hussain O M, Reddy P J 1991 J. Mater. Sci. Lett. 10 813

    [32]

    Gordillo G, Florez J M, Hernandez L C 1995 Sol. Energy Mater. Sol. Cells 37 273

    [33]

    Fahrenbruch A L, Chien K F, Kim D, Lopez-Otero A, Sharps P, Rube R H 1989 Solar Cells 27 137

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出版历程
  • 收稿日期:  2013-05-07
  • 修回日期:  2013-06-04
  • 刊出日期:  2013-09-05

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