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A new method to detect carbon isotope ratio of carbon dioxide is presented, which is developed based on Fourier transform infrared spectroscopy (FTIR)technique. The method to obtain the absorption coefficient from HITRAN is introduced in detail. The nonlinear least square algorithm to determine δ13CO2 value is studied. The total system and experimental procedure are shown in the paper. The temperature and pressure effect on δ13CO2 value determination are analyzed from both theory and experiment analysis. For the same CO2 standard gas, the δ13CO2 value is detected by both FTIR and IRMS technology, and the results are also comparatively analyzed and discussed. The difference in mean between both methods is only 0.25%. The experimental results show that the FTIR technique to detect carbon isotope ratio of carbon dioxide is viable.
[1] Esler M B, Griffith D WT, Wilson S R, Steele L P 2000 Anal. Chem. 72 216
[2] Yakir D, Silveira L da, Sternberg L 2000 Oecologia 123 297
[3] Oppenheimer C, Francis P, Burton M, Maciejewski A J H, Boardman L 1998 Appl. Phys. B 67 505
[4] Castrillo A, Casa G, Burgel V M, Tedesco D, Gianfrani L 2004 Opt. Express 12 6515
[5] Richter D, Erdelyi M, Curl R F, Tittel F K, Oppenheimer C, Duffell H J, Burton M 2002 Opt. Lasers Eng. 37 171
[6] Amorim L C A, Carneiro J P, Cardeal Z L2008 Journal of Chromatography B 865 141
[7] Cao Y C, Sun G Q, Han Y, Sun D L, Wang X 2008 Acta Pedologica Sinica 45 249 (in Chinese) [曹亚澄, 孙国庆, 韩勇, 孙德玲, 王曦 2008 土壤学报 45 249]
[8] Jäger F, Wagner G, Meijer H A J, Kerstel E R T 2005 Isotopes in Environmental and Health Studies 41 373
[9] Castrillo A, Casa G, Palmieri A, Gianfrani L 2006 Isotopes in Environmental and Health Studies 42 47
[10] Saleska S R, Shorter J H, Herndon S, Jimenez R, Mcmanus, J B, Munger J W, Nelson D D, Zahniser M S 2006 Isotopes in Environmental and Health Studies 42 115
[11] Bowling D R, Sargent S D, Tanner B D, Ehleringer J R 2003 Agr. Forest Meteorol. 118 1
[12] Liu Z M, Liu W Q, Gao M G, Tong J J, Zhang T S, Xu L, Wei X L, Jin L, Wang Y P, Chen J 2010 Acta Phys. Sin. 59 5397 (in Chinese) [刘志明, 刘文清, 高闽光, 童晶晶, 张天舒, 徐亮, 魏秀丽, 金岭, 王亚萍, 陈军 2010 59 5397]
[13] Liu Z M, Liu W Q, Gao M G, Tong J J, Zhang T S, Xu L, Wei X L 2008 Chin. Phys. B 17 4184
[14] Wu J G 1994 Techniques and Applications of Modern Fourier Transform Infrared Spectroscopy (Vol. 1) (Beijing: Science and Technology Literature Press) p156 (in Chinese) [吴瑾光 1994 近代傅里叶变换红外光谱技术与应用(上卷) (北京: 科学技术文献出版社) 第156页]
[15] Zhang S, Li Y X, Ma Q Y, Xu X W, Niu P J, Li Y Z, Niu S L, Li H T 2005 Acta Phys. Sin. 54 2256] (in Chinese) [张帅, 李养贤, 马巧云, 徐学文, 牛萍娟, 李永章, 牛胜利, 李洪涛 2005 54 2256]
[16] Werner R A, Brand W A 2001 Rapid Commun. Mass Spectrom. 15 501
[17] Rothman L S, Jacquemart D, Barbe A, Benner D C, Birk M, Brown L R, Carleer M R, Carleer M R, Chackerian C, Chance K, Coudert L H, Dana V, Devi V M, Flaud J M, Gamache R R, Goldman A, Hartmann J M, Jucks K W, Maki A G, Mandin J Y, Massie S T, Orphal J, Perrin A, Rinsland C P, Smith M A H, Tennyson J, Tolchenov R N, Toth R A, Auwera J V, Varanasi P, Wagner G 2005 Journal of Quantitative Spectroscopy & Radiative Transfer 96 139
[18] Verdes C L, Engeln A V, Buehler S A, Perrin A 2005 Journal of Quantitative Spectroscopy & Radiative Transfer 90 217
[19] Perrin M Y, Soufiani A 2007 Journal of Quantitative Spectroscopy & Radiative Transfer 103 2697
[20] Mohn J, Werner R A, Buchmann B, Emmenegger L 2007 Molecular Structure 834 95
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[1] Esler M B, Griffith D WT, Wilson S R, Steele L P 2000 Anal. Chem. 72 216
[2] Yakir D, Silveira L da, Sternberg L 2000 Oecologia 123 297
[3] Oppenheimer C, Francis P, Burton M, Maciejewski A J H, Boardman L 1998 Appl. Phys. B 67 505
[4] Castrillo A, Casa G, Burgel V M, Tedesco D, Gianfrani L 2004 Opt. Express 12 6515
[5] Richter D, Erdelyi M, Curl R F, Tittel F K, Oppenheimer C, Duffell H J, Burton M 2002 Opt. Lasers Eng. 37 171
[6] Amorim L C A, Carneiro J P, Cardeal Z L2008 Journal of Chromatography B 865 141
[7] Cao Y C, Sun G Q, Han Y, Sun D L, Wang X 2008 Acta Pedologica Sinica 45 249 (in Chinese) [曹亚澄, 孙国庆, 韩勇, 孙德玲, 王曦 2008 土壤学报 45 249]
[8] Jäger F, Wagner G, Meijer H A J, Kerstel E R T 2005 Isotopes in Environmental and Health Studies 41 373
[9] Castrillo A, Casa G, Palmieri A, Gianfrani L 2006 Isotopes in Environmental and Health Studies 42 47
[10] Saleska S R, Shorter J H, Herndon S, Jimenez R, Mcmanus, J B, Munger J W, Nelson D D, Zahniser M S 2006 Isotopes in Environmental and Health Studies 42 115
[11] Bowling D R, Sargent S D, Tanner B D, Ehleringer J R 2003 Agr. Forest Meteorol. 118 1
[12] Liu Z M, Liu W Q, Gao M G, Tong J J, Zhang T S, Xu L, Wei X L, Jin L, Wang Y P, Chen J 2010 Acta Phys. Sin. 59 5397 (in Chinese) [刘志明, 刘文清, 高闽光, 童晶晶, 张天舒, 徐亮, 魏秀丽, 金岭, 王亚萍, 陈军 2010 59 5397]
[13] Liu Z M, Liu W Q, Gao M G, Tong J J, Zhang T S, Xu L, Wei X L 2008 Chin. Phys. B 17 4184
[14] Wu J G 1994 Techniques and Applications of Modern Fourier Transform Infrared Spectroscopy (Vol. 1) (Beijing: Science and Technology Literature Press) p156 (in Chinese) [吴瑾光 1994 近代傅里叶变换红外光谱技术与应用(上卷) (北京: 科学技术文献出版社) 第156页]
[15] Zhang S, Li Y X, Ma Q Y, Xu X W, Niu P J, Li Y Z, Niu S L, Li H T 2005 Acta Phys. Sin. 54 2256] (in Chinese) [张帅, 李养贤, 马巧云, 徐学文, 牛萍娟, 李永章, 牛胜利, 李洪涛 2005 54 2256]
[16] Werner R A, Brand W A 2001 Rapid Commun. Mass Spectrom. 15 501
[17] Rothman L S, Jacquemart D, Barbe A, Benner D C, Birk M, Brown L R, Carleer M R, Carleer M R, Chackerian C, Chance K, Coudert L H, Dana V, Devi V M, Flaud J M, Gamache R R, Goldman A, Hartmann J M, Jucks K W, Maki A G, Mandin J Y, Massie S T, Orphal J, Perrin A, Rinsland C P, Smith M A H, Tennyson J, Tolchenov R N, Toth R A, Auwera J V, Varanasi P, Wagner G 2005 Journal of Quantitative Spectroscopy & Radiative Transfer 96 139
[18] Verdes C L, Engeln A V, Buehler S A, Perrin A 2005 Journal of Quantitative Spectroscopy & Radiative Transfer 90 217
[19] Perrin M Y, Soufiani A 2007 Journal of Quantitative Spectroscopy & Radiative Transfer 103 2697
[20] Mohn J, Werner R A, Buchmann B, Emmenegger L 2007 Molecular Structure 834 95
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